Extraction kinetics of strontium with SDS and Twain in celestine     

LIU Chenglun  SU Zhimin  XU Longjun  ZHANG Li  XIE Taiping  WANG Yuan 《中国地球化学学报》2013,32(3):269-272

Strontium in celestine was activated in Twain-40 with the wetting and emulsifying methods. And strontium extract ratio increased providing that the negative effects of oxygen containing functional groups were eliminated on celestine surface. In the paper, the factors affecting the extraction of strontium in celestine were investigated with orthogonal experiments. The optimal conditions were described as follows: mass ratio of celestine to extracting aid=2.6:1, the solid-liquid ratio of extracting aid solvent composed was m(SDS): m(Twain 40): m(HCl)=6:1:2, when celestine was ground as small as less than 0.075mm in size, and extracted for 6 hours at 333K. The strontium extract ratio increased by 61.33% and reached 97.21%, while the ratio from the comparative experiment (without extracting aid agent) was only 35.88%. Extraction kinetics of strontium in celestine showed that the diffusion process was a controlling step, and the apparent active energy was about 14.1 kJ/mol. The research results were helpful to fully utilize strontium of celestine.  相似文献   

Stochastic procedure for the simulation of synthetic main shock‐aftershock ground motion sequences          下载免费PDF全文

Sheng Hu  Paolo Gardoni  Longjun Xu 《地震工程与结构动力学》2018,47(11):2275-2296

According to the current seismic codes, structures are designed to resist the first damaging earthquake during their service life. However, after a strong main shock, a structure may still face damaging aftershocks. The main shock‐aftershock sequence may result in major damage and eventually the collapse of a structure. Current studies on seismic hazard mainly focus on the modeling and simulation of main shocks. This paper proposes a 3‐step procedure to generate main shock‐aftershock sequences of pairs of horizontal components of a ground motion at a site of interest. The first step generates ground motions for the main shock using either a source‐based or site‐based model. The second step generates sequences of aftershocks' magnitudes, locations, and times of occurrence using either a fault‐based or seismicity‐based model. The third step simulates pairs of ground motion components using a new empirical model proposed in this paper. We develop prediction equations for the controlling parameters of a ground motion model, where the predictors are the site condition and the aftershock characteristics from the second step. The coefficients in the prediction equations and the correlation between the model parameters (of the 2 horizontal components of 1 record and of several records in 1 sequence) are estimated using a database of aftershock accelerograms. A backward stepwise deletion method is used to simplify the initial candidate prediction equations and avoid overfitting the data. The procedure, based on easily identifiable engineering parameters, is a useful tool to incorporate effects of aftershocks into seismic analysis and design.  相似文献   

The effects of estuarine processes on the fluxes of inorganic and organic carbon in the Yellow River estuary   总被引：1，自引：0，他引：1  

Dianjun Gu  Longjun Zhang  Liqing Jiang 《中国海洋大学学报(英文版)》2009,8(4):352-358

Riverine carbon flux is an important component of the global carbon cycle. The spatial and temporal variations of organic and inorganic carbon were examined during both dry and wet seasons in the Yellow River estuary. Concentrations of dissolved organic carbon (DOC) and dissolved inorganic carbon (DIC) in the Yellow River during dry seasons were higher than those during wet seasons. The effective concentrations of DOC (C_DOC*) were higher than the observed DOC at zero salinity. This input of DOC in the Yellow River estuary was due to sediment desorption processes in low salinity regions. In contrast to DOC, the effective concentrations of DIC were 10% lower than the DIC measured at freshwater end, and the loss of DIC was caused by CaCO₃ precipitation in low salinity region. Particulate organic carbon (POC) and particulate inorganic carbon (PIC) contents of the particles stabilized to constant values (0.5%±0.05% and 1.8%±0.2%, respectively) within the turbidity maximum zone (TMZ) and showed no noticeable seasonal variations. A rapid drop of PIC and rise of POC occurred simultaneously outside the TMZ due to an intense dilution of riverine inorganic-rich particles being transported into a pool of aquatic organic-poor particles outside the TMZ. Annually, the Yellow River transported 6.95×10⁵ t of DIC, 0.64×10⁵ t of DOC, 78.58×10⁵ t of PIC and 2.29×10⁵ t of POC to the sea.  相似文献