Hydrogeochemistry of Fe and Mn in small boreal streams: The role of seasonality, landscape type and scale   总被引：1，自引：0，他引：1  

Louise Björkvald  Ishi Buffam  Hjalmar Laudon  Carl-Magnus Mörth 《Geochimica et cosmochimica acta》2008,72(12):2789-2804

Stream water from a stream network of 15 small boreal catchments (0.03-67 km²) in northern Sweden was analyzed for unfiltered (total) and filtered (<0.4 μm) concentrations of iron (Fe_tot and Fe_<0.4) and manganese (Mn_tot and Mn_<0.4). The purpose was to investigate the temporal and spatial dynamics of Fe, Mn and dissolved organic carbon (DOC) as influenced by snow melt driven spring floods and landscape properties, in particular the proportion of wetland area. During spring flood, concentrations of Fe_tot, Fe_<0.4, Mn_tot, Mn_<0.4 and DOC increased in streams with forested catchments (<2% wetland area). In catchments with high coverage of wetlands (>30% wetland area) the opposite behavior was observed. The hydrogeochemistry of Fe was highly dependent on wetlands as shown by the strong positive correlation of the Fe_tot/Al_tot ratio with wetland coverage (r² = 0.89, p < 0.001). Furthermore, PCA analysis showed that at base flow Fe_tot and Fe_<0.4 were positively associated with wetlands and DOC, whereas they were not associated during peak flow at spring flood. The temporal variation of Fe was likely related to varying hydrological pathways. At peak discharge Fe_tot was associated with variables like silt coverage, which highlights the importance of particulates during high discharge events. For Mn there was no significant correlation with wetlands, instead, PCA analysis showed that during spring flood Mn was apparently more dependent on the supply of minerogenic particulates from silt deposits on the stream banks of some of the streams. The influence of minerogenic particulates on the concentration of, in particular, Mn was greatest in the larger, lower gradient streams, characterized by silt deposits in the near-stream zone. In the small forested streams underlain by till, DOC was of greater importance for the observed concentrations, as indicated by the positive correlation of both Fe_tot and Fe_<0.4 with DOC (r² = 0.77 and r² = 0.76, p < 0.001) at the smallest headwater forest site. In conclusion, wetland area and DOC were important for Fe concentrations in this boreal stream network, whereas silt deposits strongly influenced Mn concentrations. This study highlights the importance of studying stream water chemistry from a landscape perspective in order to address future environmental issues concerning mobility of Fe, Mn and associated trace metals.  相似文献   

The International GLONASS Service – Pilot Project     

Robert Weber  James A. Slater 《GPS Solutions》2001,4(4):61-67

The International GLONASS Service – Pilot Project (IGLOS-PP), a project of the International GPS Service, was launched in order to underscore the importance and benefits of integrating data from multiple systmes and techniques within IGS products. At first this article summarizes the contributing organizations and the available infrastructure. Later on the GLONASS related modeling techniques at the involved IGS Analysis Centers are described and we conclude with some remarks concerning the advantages for the expected user commmunity. ? 2001 John Wiley & Sons, Inc.  相似文献   

Primary cumulus platinum minerals in the Monts de Cristal Complex,Gabon: magmatic microenvironments inferred from high-definition X-ray fluorescence microscopy     

Stephen J. Barnes  Louise A. Fisher  Bélinda Godel  Mark A. Pearce  Wolfgang D. Maier  David Paterson  Daryl L. Howard  Christopher G. Ryan  Jamie S. Laird 《Contributions to Mineralogy and Petrology》2016,171(3):23

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Field meeting at Ipswich: Saturday,July 9th, 1932     

G. Slater  A.L. Leach 《Proceedings of the Geologists' Association. Geologists' Association》1932,43(4):290

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Advances in interpretation of subsurface processes with time‐lapse electrical imaging          下载免费PDF全文

K. Singha  F. D. Day‐Lewis  T. Johnson  L. D. Slater 《水文研究》2015,29(6):1549-1576

Electrical geophysical methods, including electrical resistivity, time‐domain induced polarization, and complex resistivity, have become commonly used to image the near subsurface. Here, we outline their utility for time‐lapse imaging of hydrological, geochemical, and biogeochemical processes, focusing on new instrumentation, processing, and analysis techniques specific to monitoring. We review data collection procedures, parameters measured, and petrophysical relationships and then outline the state of the science with respect to inversion methodologies, including coupled inversion. We conclude by highlighting recent research focused on innovative applications of time‐lapse imaging in hydrology, biology, ecology, and geochemistry, among other areas of interest. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Modeling the early evolution of Vesta          下载免费PDF全文

Marie Weisfeiler  Donald L. Turcotte  Louise H. Kellogg 《Meteoritics & planetary science》2017,52(5):859-868

The early evolution of the asteroid Vesta has been extensively studied because of the availability of relevant data, especially important new studies of HED meteorites which originated from Vesta and the Dawn mission to Vesta in 2011–2012. These studies have concluded that an early melting episode led to the differentiation of Vesta into crust, mantle, and core. This melting episode is attributed to the decay of ²⁶Al, which has a half‐life of 7.17 × 10⁵ yr. This heating produced a global magma ocean. Surface cooling of this magma ocean will produce a solid crust. In this paper, we propose a convective heat‐transfer mechanism that effectively cools the asteroid when the degree of melting reaches about 50%. We propose that a cool solid surface crust, which is gravitationally unstable, will founder into the solid–liquid mix beneath and will very effectively transfer heat that prevents further melting of the interior. In this paper, we quantify this process. If Vesta had a very early formation, melting would commence at an age of about 1,30,000 yr, and solidification would occur at an age of about 10 Myr. If Vesta formed with a time delay greater than about 2 Myr, no melting would have occurred. An important result of our model is that the early melting episode is restricted to the first 10 Myr. This result is in good agreement with the radiometric ages of the HED meteorites.  相似文献   

Studies in the drift deposits of the south-western part of Suffolk: Part I. – The structure of the disturbed deposits in the lower part of the gipping valley near Ipswich     

G. Slater 《Proceedings of the Geologists' Association. Geologists' Association》1927,38(2):157-IN1

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Current and future climate variability associated with wintertime precipitation in alpine Australia     

Sonya Louise Fiddes  Alexandre Bernardes Pezza 《Climate Dynamics》2015,44(9-10):2571-2587

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Timing and pace of ice-sheet withdrawal across the marine–terrestrial transition west of Ireland during the last glaciation     

Colm Ó Cofaigh  S. Louise Callard  David H. Roberts  Richard C. Chiverrell  C. K. Ballantyne  David J. A. Evans  Margot Saher  Katrien J. J. Van Landeghem  Rachel Smedley  Sara Benetti  Matthew Burke  Chris D. Clark  Geoff A. T. Duller  Derek Fabel  Stephen J. Livingstone  Stephen Mccarron  Alicia Medialdea  Steven G. Moreton  Fabio Sacchetti 《第四纪科学杂志》2021,36(5):805-832

Understanding the pace and drivers of marine-based ice-sheet retreat relies upon the integration of numerical ice-sheet models with observations from contemporary polar ice sheets and well-constrained palaeo-glaciological reconstructions. This paper provides a reconstruction of the retreat of the last British–Irish Ice Sheet (BIIS) from the Atlantic shelf west of Ireland during and following the Last Glacial Maximum (LGM). It uses marine-geophysical data and sediment cores dated by radiocarbon, combined with terrestrial cosmogenic nuclide and optically stimulated luminescence dating of onshore ice-marginal landforms, to reconstruct the timing and rate of ice-sheet retreat from the continental shelf and across the adjoining coastline of Ireland, thus including the switch from a marine- to a terrestrially-based ice-sheet margin. Seafloor bathymetric data in the form of moraines and grounding-zone wedges on the continental shelf record an extensive ice sheet west of Ireland during the LGM which advanced to the outer shelf. This interpretation is supported by the presence of dated subglacial tills and overridden glacimarine sediments from across the Porcupine Bank, a westwards extension of the Irish continental shelf. The ice sheet was grounded on the outer shelf at ~26.8 ka cal bp with initial retreat underway by 25.9 ka cal bp. Retreat was not a continuous process but was punctuated by marginal oscillations until ~24.3 ka cal bp. The ice sheet thereafter retreated to the mid-shelf where it formed a large grounding-zone complex at ~23.7 ka cal bp. This retreat occurred in a glacimarine environment. The Aran Islands on the inner continental shelf were ice-free by ~19.5 ka bp and the ice sheet had become largely terrestrially based by 17.3 ka bp. This suggests that the Aran Islands acted to stabilize and slow overall ice-sheet retreat once the BIIS margin had reached the inner shelf. Our results constrain the timing of initial retreat of the BIIS from the outer shelf west of Ireland to the period of minimum global eustatic sea level. Initial retreat was driven, at least in part, by glacio-isostatically induced, high relative sea level. Net rates of ice-sheet retreat across the shelf were slow (62–19 m a⁻¹) and reduced (8 m a⁻¹) as the ice sheet vacated the inner shelf and moved onshore. A picture therefore emerges of an extensive BIIS on the Atlantic shelf west of Ireland, in which early, oscillatory retreat was followed by slow episodic retreat which decelerated further as the ice margin became terrestrially based. More broadly, this demonstrates the importance of localized controls, in particular bed topography, on modulating the retreat of marine-based sectors of ice sheets.  相似文献   

Leveraging farmers’ strategies for coping with stress: Seed aid in Ethiopia     

Shawn J. McGuire  Louise Sperling 《Global Environmental Change》2008,18(4):679

Interventions to reduce farmers’ vulnerability to crises rarely build on existing coping strategies. Emergency seed aid offers a unique opportunity to examine links between different types of interventions and local coping mechanisms, as such relief has been abundant and long-term. This study focuses on farmers’ use and assessment of crisis assistance within Ethiopia, where seed aid delivery dates back at least 34 years. Farmers’ abilities to strategize and negotiate inter-/intra-seasonal variability are not being addressed by current supply-driven approaches. Lessons derived from seed aid give insights toward more effective practice for programs aiming to bolster farmers’ resilience in high-stress and uncertain contexts.  相似文献