Fluorescence as a Tool for Tracing the Organic Contamination from Pulp Mill Effluents in Surface Waters     

Eduarda B. H. Santos  Olga M. S. Filipe  Regina M. B. O. Duarte  Helena Pinto  Armando C. Duarte 《洁净——土壤、空气、水》2001,28(7):364-371

Three‐dimensional fluorescence spectra of water samples from an eucalyptus bleached kraft pulp mill and from a river, upstream and downstream of the discharge of the effluent, revealed the existence of a peak at δ_exc = 280 nm and δ_em = 340 nm Δδ = 60 nm), characteristic of effluentπs organic matter. Humic substances were isolated from the effluent by sequential adsorption onto resins XAD‐8 and XAD‐4 in series. Their synchronous fluorescence spectra with Δδ = 60 nm do also exhibit an intense signal at δ_exc = 280 nm (≈ 300 nm in the humic acid fraction). The peak is absent in the spectra of humic substances isolated from a non‐polluted site of the river, but it is clearly seen in the spectra of the humic substances from a site downstream of the discharge of the effluent. Synchronous fluorescence spectra (Δδ = 60 nm) of water samples from the river and its lagoon were recorded and revealed to be an easy and fast way of tracing the organic contamination from the effluent.  相似文献   

Carbon isotopic fractionation in macroalgae from Cádiz Bay (Southern Spain): Comparison with other bio-geographic regions     

Jesús M. Mercado  Carmen B. de los Santos  J. Lucas Pérez-Lloréns  Juan J. Vergara 《Estuarine, Coastal and Shelf Science》2009

The ¹³C signature of forty-five macroalgal species from intertidal zones at Cádiz Bay was analysed in order to research the extension of diffusive vs. non-diffusive utilisation of dissolved inorganic carbon (DIC) and to perform a comparison with data published for other bio-geographic regions. The ∂¹³C values ranged from −6.8‰ to −33‰, although the span of variation was different depending on the taxa. Thus, ∂¹³C for Chlorophyta varied from −7‰ (Codium adhaerens) to −29.6‰ (Flabellia petiolata), while all the Phaeophyceae (excepting Padina pavonica with ∂¹³C higher than −10‰) had values between −10‰, and −20‰. The widest variation range was recorded in Rhodophyta, from values above −10‰ (Liagora viscida) to values lower than −30‰ obtained in three species belonging to the subclass Rhodymeniophycidae. Accordingly, the mean ∂¹³C value calculated for red algae (−20.2‰) was significantly lower than that for brown (−15.9‰) and green algae (−15.6‰). Most of the analysed red algae were species inhabiting crevices and the low intertidal fringe which explains that, on average, the shaded-habitat species had a ∂¹³C value lower than those growing fully exposed to sun (i.e. in rockpools or at the upper intertidal zone). The comparison between the capacity for non-diffusive use of DIC (i.e. active or facilitated transport of HCO₃⁻ and/or CO₂) and the ∂¹³C values reveals that values more negative than −30‰ indicate that photosynthesis is dependent on CO₂ diffusive entry, whereas values above this threshold would not indicate necessary the operation of a non-diffusive DIC transport mechanism. Furthermore, external carbonic anhydrase activity (_extCA) and ∂¹³C values were negatively correlated indicating that the higher the dependence of the photosynthesis on the CO₂ supplied from HCO₃⁻ via _extCA, the lower the ∂¹³C in the algal material. The comparison between the ∂¹³C values obtained for the analysed species and those published for species inhabiting other bio-geographic areas (warm-temperate, cold and polar) suggests that globally (at least for the red and brown algae) the non-diffusive entry of DIC is more widely spread among the species from Cádiz Bay than among those of polar regions. If it is assumed that non-diffusive use of DIC implies saturation of photosynthesis at the present-day CO₂ concentration in seawater, our data indicate that the potential impact of the acidification on photosynthesis in the seaweed communities will be different depending on the latitude.  相似文献   

Tidal and river discharge forcing upon water and sediment circulation at a rock-bound estuary (Guadiana estuary,Portugal)     

E. Garel  L. Pinto  A. Santos  Ó. Ferreira 《Estuarine, Coastal and Shelf Science》2009

The relative impacts of tidal (neap, spring) and river discharge (including a flood event) forcing upon water and sediment circulation have been examined at the rock-bound Guadiana estuary. Near-bed and vertical profiles of current, salinity, turbidity, plus surface suspended sediment concentrations (SSC, at some stations only), were collected at the lower and central/upper estuary during tidal and fortnightly cycles. In addition, vertical salinity and turbidity profiles were collected around high and low water along the estuary. Tidal asymmetry produced faster currents on the ebb than on the flood, especially at the mouth. This pattern of seaward current dominance was enhanced with increasing river flow, due to horizontal advection that was confined within the narrow estuarine channel. The freshwater inputs and, at a degree less, the tidal range controlled the vertical mixing and stratification importance. Well-mixed (spring) and partially stratified (neap) conditions alternated during periods of low river flows, with significant intratidal variations induced by tidal straining (especially at the partially stratified estuary). Highly stratified conditions developed with increasing river discharge. Intratidal variability in the pycnocline depth and thickness resulted from current shear during the ebb. A salt wedge with tidal motion was observed at the lower estuary during the flood event. Depending on the intensity of turbulent mixing, the residual water circulation was dominantly controlled either by tidal asymmetry or gravitational circulation. The SSC was governed by cyclical local processes (resuspension, deposition, mixing, advection) driven by the neap-spring fluctuations in tidal current velocities. More, intratidal variability in stratification indicated the significance of tidal pumping at the partially and highly stratified estuary. The estuary turbidity maximum (ETM) was enhanced with increasing current velocities, and displaced downstream during periods of high river discharge. During the flood event, the ETM was expelled out of the estuary, and the SSC along the estuary was controlled by the sediment load from the drainage basin. Under these highly variable river flow conditions, our observations suggest that sand is exported to the nearshore over the long-term (>years).  相似文献   

Possibilities of discriminating tropical secondary succession in Amazônia using hyperspectral and multiangular CHRIS/PROBA data     

Lênio Soares Galvão  Flávio Jorge PonzoniVeraldo Liesenberg  João Roberto dos Santos 《International Journal of Applied Earth Observation and Geoinformation》2009

CHRIS/PROBA data collected in the Brazilian Amazônia in 4 view angles (−36°, nadir, +36°, +55°) and 62 bands (410–1000 nm range) were evaluated for the discrimination between primary forest and 3 stages of secondary succession after deforestation: initial (SS1; <5 years), intermediate (SS2; 5–15 years) and advanced (SS3; >15 years). Single view angle and multiangular approaches (nadir plus anisotropic information derived from reflectance ratios between view angles) were tested for discrimination. Both approaches used principal components analysis (PCA) applied to pixel spectra representative of each class in order to reduce data dimensionality at each dataset, to enhance separability between the classes, and to provide input variables for multiple discriminant analysis (MDA). The results showed that the off-nadir viewing improved discrimination between the successional stages. Discrimination between SS2 and SS3 was enhanced with PCA at +36° view angle. Primary forest and SS3 presented a more anisotropic behavior than SS2 and SS1, especially in the backward scattering direction (positive view angles) in which great amounts of sunlit canopy components were viewed by the sensor. MDA classification results showed that the multiangular approach produced an overall improvement in the discrimination. From the single (nadir) to the multiangular approach, classification accuracy using a separate set of pixels increased from 83.3% to 98.3% for SS1, 53.3% to 70.0% for SS2, and 58.3% to 76.7% for SS3. The nadir and multiangular classifications were statistically different at a 0.05% level of significance. Kappa statistics increased from 0.63 to 0.82. The results showed that multiangular data can improve the differentiation between primary forest and old stages of natural vegetation regrowth, which have been reported in the literature as the most difficult classes to be mapped in the Amazonian environment.  相似文献   

Provenance record of late Maastrichtian–late Palaeocene Andean Mountain building in the Amazonian retroarc foreland basin (Madre de Dios basin,Peru)          下载免费PDF全文

Mélanie Louterbach  Martin Roddaz  Pierre‐Olivier Antoine  Laurent Marivaux  Sylvain Adnet  Julien Bailleul  Elton Dantas  Roberto Ventura Santos  Farid Chemale Jr  Patrice Baby  Caroline Sanchez  Ysabel Calderon 《地学学报》2018,30(1):17-23

Biostratigraphic, sedimentological and provenance analyses suggest that a proto‐Andean Cordillera already existed in southern Peru by late Maastrichtian–late Palaeocene times. A 270‐m‐thick stratigraphic section shows changes in depositional environments from shallow marine (early Maastrichtian) to non‐marine (late Maastrichtian) then back to estuarine (late Palaeocene) conditions. An erosional surface separates lower Maastrichtian from upper Maastrichtian deposits. Above this surface, the late Maastrichtian unit exhibits moderately developed palaeosols and syn‐sedimentary normal faults. The sedimentary evolution is accompanied by a decrease in sedimentation rate and by changes in provenance. Shallow marine lower Maastrichtian deposits have a cratonic provenance as shown by their low εNd(0) values (?15 to ?16) and the presence of Precambrian inherited zircon grains. The upper Maastrichtian deposits have a mixed Andean and cratonic origin with εNd(0) values of ~12.6 and yield the first Cretaceous and Permo‐Triassic zircon grains. Estuarine to shallow marine upper Palaeocene deposits have an Andean dominant source as attested by higher εNd(0) values (?6 to ?10) and by the presence of Palaeozoic and Late Cretaceous zircon grains. The changes in depositional environments and sedimentation rates, as well as the shift in detrital provenance, are consistent with a late Maastrichtian–late Palaeocene period of Andean mountain building. In agreement with recently published studies, our data suggest that an Andean retroarc foreland basin was active by late Maastrichtian–late Palaeocene times.  相似文献   

The Dramas of the Marine Extractive Reserve Managers in Brazil: Navigating through Multiple Institutions     

Deborah Santos Prado  Fábio de Castro  Cristiana Simão Seixas 《社会与自然资源》2020,33(5):651-668

Abstract

In this paper, we describe and analyze the co-management institutional framework at 21 Brazilian Marine Extractive Reserves (MERs) and present the dramas of its implementation from the local manager’s perspective. We categorized the governance instruments of MERs into (i) instruments for land/sea tenure and beneficiaries’ recognition, (ii) territorial use planning, (iii) institutional arenas for discussion and deliberation, as well as (iv) public policies. Although the legal arrangements of these protected areas address fundamental dimensions of governance, we present the challenges of its implementation based on the voice of local managers. The managers are the bridge between the central government and communities, dealing with the implementation of the institutional framework in a reality of multi-level and multi-scale drama: from local to national dilemmas, from organizational to structural ones. We explore these dramas and highlight the institutional dilemmas based on the paradoxes between legalism and social emancipation.  相似文献   

Correction to: Spatiotemporal variability of vegetation due to drought dynamics (2012–2017): a case study of the Upper Paraíba River basin,Brazil     

da Silva  Glauciene Justino Ferreira  de Oliveira  Nádja Melo  Santos  Celso Augusto Guimarães  da Silva  Richarde Marques 《Natural Hazards》2020,102(3):965-965

Natural Hazards - This correction stands to support the updating of the original article for changing the name Glauciene Justino Ferreira to Glauciene Justino Ferreira da Silva. The author group...  相似文献   

Reply to ‘Comment on: Rainfall,fog and throughfall dynamics in a subtropical ridge top cloud forest,National Park of Garajonay (La Gomera,Canary Islands,Spain)’ by A. Ritter and C.M. Regalado     

G. García‐Santos  L. A. Bruijnzeel 《水文研究》2013,27(7):1129-1132

This Reply aims to clarify and address many of the errors introduced to the discussion of our original paper (García‐Santos and Bruijnzeel, 2011; referred to henceforth as GSB2011) in the comment by Ritter and Regalado (2012) (henceforth referred to as RRR2012) as explained more fully under replies nos. 1–6, 8–12 and 14–18 below. Two (largely inconsequential) shortcomings in our original paper as detected by RRR2012 are acknowledged (see replies nos. 7 and 13 below). It is concluded that the majority of the comments offered by RRR2012 are unfounded as well as unnecessary. In summary, the two errors in GSB2011 spotted by RRR2012 (see points 7 and 13 below) could easily have been addressed in an erratum. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Dimensionality reduction in drought modelling     

João Filipe Santos  Maria Manuela Portela  Inmaculada Pulido‐Calvo 《水文研究》2013,27(10):1399-1410

For monitoring hydrological events characterized by high spatial and temporal variability, the number and location of recording stations must be carefully selected to ensure that the necessary information is collected. Depending on the characteristics of each natural process, certain stations may be spurious or redundant, whereas others may provide most of the relevant data. With the objective of reducing the costs of the monitoring system and, at the same time, improving its operational effectiveness, three procedures were applied to identify the minimum network of rain gauge stations able to capture the characteristics of droughts in mainland Portugal. Drought severity is characterized by the standardized precipitation index applied to the timescales of 1, 3, 6 and 12 consecutive months. The three techniques used to reduce the dimensionality of the network of rain gauges were as follows: (i) artificial neural networks with sensitivity analysis, (ii) application of the mutual information criterion and (iii) K‐means cluster analysis using Euclidean distances. The results demonstrated that the best dimensionality reduction method was case dependent in the three regions of Portugal (northern, central and southern) previously identified by cluster analysis. All the reduction techniques lead to the selection of a subset of rain gauges capable of reproducing the original temporal patterns of drought. For specific severe drought events in Portugal in the past, the comparison between drought spatial patterns obtained with the original stations and the selected subset indicated that the subset produced statistically satisfactory results (correlation coefficients higher than 0.6 and efficiency coefficients higher than 0.5). Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Modern sedimentation processes in a wave-dominated coastal embayment: Espírito Santo Bay,southeast Brazil     

Alex Cardoso Bastos  Daphnne Moraes Costa Moscon  Dannilo Carmo  José Antonio Baptista Neto  Valéria da Silva Quaresma 《Geo-Marine Letters》2015,35(1):23-36

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