Self-diffusion of water and its dependence on temperature and ionic strength in highly compacted montmorillonite, illite and kaolinite     

Ftima Gonzlez Snchez  Luc R. Van Loon  Thomas Gimmi  Andreas Jakob  Martin A. Glaus  Larryn W. Diamond 《Applied Geochemistry》2008,23(12):3840-3851

The effect of temperature and ionic strength on the diffusion of HTO parallel to the direction of compaction through 5 highly compacted clay minerals (bulk dry density, ρ_b,d = 1.90 ± 0.05 Mg/m³), namely montmorillonite (Na- and Ca-form), illite (Na- and Ca-form), and kaolinite, was studied. The diffusion experiments were carried out at temperatures between 0 °C and 60 °C and at ionic strengths of 0.01 M and 1 M NaCl for the Na-form clays and kaolinite, and of 0.005 M and 0.5 M CaCl₂ for the Ca-form. The ionic strength had an insignificant influence on the values of the effective diffusion coefficient (variation by less than 10%) for the clays under study at this degree of compaction. The effective diffusion coefficients followed the order Na-montmorillonite < Ca-montmorillonite < Ca-illite < Na-illite  kaolinite. It is thought that the differences between Na- and Ca-montmorillonite originate from the larger size particles, and thus the lower tortuosity of the latter; whereas the differences between Na- and Ca-illite are related to the different degree of solvation of the Na and Ca cations. The activation energies were successfully calculated using the Arrhenius law. Swelling clays (Na- and Ca-montmorillonite) had slightly larger activation energy values (20 kJ/mol) compared to bulk water (17 kJ/mol); Ca-illite (16 kJ/mol), Na-illite (13 kJ/mol) and kaolinite (14.4 kJ/mol) lower values than that of bulk water. The low activation energies of the last three clays may be related to weaker H-bonds between water and the clay surfaces compared to those in bulk water.  相似文献   

Structural,mineralogical, and paleoflow velocity constraints on Hercynian tin mineralization: the Achmmach prospect of the Moroccan Central Massif     

El Mahjoub Mahjoubi  Alain Chauvet  Lakhlifi Badra  Stanislas Sizaret  Luc Barbanson  Abdelkader El Maz  Yan Chen  Méderic Amann 《Mineralium Deposita》2016,51(3):431-451

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Experimental and Numerical Study of Wind and Turbulence in a Near-Field Dispersion Campaign at an Inhomogeneous Site     

Xiao Wei  Eric Dupont  Eric Gilbert  Luc Musson-Genon  Bertrand Carissimo 《Boundary-Layer Meteorology》2016,160(3):475-499

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Multidimensional Similarity Measuring for Semantic Trajectories   总被引：1，自引：0，他引：1       下载免费PDF全文

Andre Salvaro Furtado  Despina Kopanaki  Luis Otavio Alvares  Vania Bogorny 《Transactions in GIS》2016,20(2):280-298

Most existing approaches aiming at measuring trajectory similarity are focused on two‐dimensional sequences of points, called raw trajectories. However, recent proposals have used background geographic information and social media data to enrich these trajectories with a semantic dimension, giving rise to the concept of semantic trajectories. Only a few works have proposed similarity measures for semantic trajectories or multidimensional sequences, having limitations such as predefined weight of the dimensions, sensitivity to noise, tolerance for gaps with different sizes, and the prevalence of the worst dimension similarity. In this article we propose MSM, a novel similarity measure for multidimensional sequences that overcomes the aforementioned limitations by considering and weighting the similarity in all dimensions. MSM is evaluated through an extensive experimental study that, based on a seed trajectory, creates sets of semantic trajectories with controlled transformations to introduce different kinds and levels of dissimilarity. For each set, we compute the similarity between the seed and the transformed trajectories, using different measures. The results showed that MSM was more robust and efficient than related approaches in the domain of semantic trajectories.  相似文献   

Appareil pour la prise d'échantillons de limons lacustres     

Emile Andre 《Aquatic Sciences - Research Across Boundaries》1922,2(1-2):188-192

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A static drilling riser model using free boundary conditions     

Luc Huyse  Mansa C. Singh  Marc A. Maes 《Ocean Engineering》1997,24(5):431-444

A static three-dimensional analytical method for drilling risers experiencing large displacements and slip at the top joint is presented. The riser is described in cylindrical coordinates as a three-dimensional tensioned string, without bending or torsional stiffness. The vertical vessel displacement is not taken into account. The equilibrium configuration is obtained from the stationary condition of the total potential energy functional. Kinematic boundary conditions are introduced for the radial displacement only. The riser orientation at the top directly follows from the natural boundary conditions based on the variational treatment of the energy functional.  相似文献   

A pilot tagging experiment on European hake (Merluccius merluccius): methodology and preliminary results     

de Pontual  Helene; Bertignac  Michel; Battaglia  Andre; Bavouzet  Gerard; Moguedet  Philippe; Groison  Anne-Laure 《ICES Journal of Marine Science》2003,60(6):1318-1327

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Assessment of population size and migration routes of silver eel in the River Rhine based on a 2-year combined mark-recapture and telemetry study     

Breteler  Jan Klein; Vriese  Tim; Borcherding  Jost; Breukelaar  Andre; Jorgensen  Lothar; Staas  Stefan; de Laak  Gerard; Ingendahl  Detlev 《ICES Journal of Marine Science》2007,64(7):1450-1456

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Sedimentary record of redox-sensitive elements (U, Mn, Mo) in a transitory anoxic basin (the Thau lagoon, France)   总被引：4，自引：0，他引：4  

Franoise Elbaz-Poulichet  Jean Luc Seidel  Didier Jzquel  Edouard Metzger  Franois Prvot  Caroline Simonucci  Grard Sarazin  Eric Viollier  Henri Etcheber  Jean-Marie Jouanneau  Olivier Weber  Olivier Radakovitch 《Marine Chemistry》2005,95(3-4):271-281

In order to further document the relation between redox conditions and the sedimentary record of Mn, U and Mo in a transitory anoxic water basin, their distribution has been studied along two profiles in the Thau lagoon (France). Sediments and pore-water have been sampled at two contrasting sites located, respectively, in the shellfish-farming area and in the centre of the lagoon. In the shellfish-farming area, the particulate organic carbon (POC) data indicate a more rapid organic matter mineralisation compared to the centre of the lagoon. This results in a sharper redox gradient characterized by the appearance of H₂S in pore-water a few millimetres below the sediment–water interface. In the centre of the lagoon, H₂S appears at a depth of 35 cm.In both cores, sedimentary Mn is relatively depleted through out the whole sedimentary column and varies with the proportion of clay minerals. After an initial release into solution at the sediment–water interface in relation to Mn-oxide reductive dissolution, authigenic U is immobilized when sulphides appear. Despite the occurrence of anoxic conditions at the sediment–water interface at the site influenced by shellfish farming, the burial of U is reduced by bioturbation, which raises reducing sediments to the surface. In the centre of the lagoon, Mo profiles reflect continuous diffusion into pore water and immobilization at 15 cm probably in anoxic microenvironments. At shellfish farms, dissolved Mo undergoes removal with sulphides but contrary to U, sedimentary Mo does not appear to be strongly affected by bioturbation. The profile indicates an increase in the frequency of anoxia crises during the second half of the 20th century.  相似文献   

Permineralization process promotes preservation of Holocene macrofossil charcoal in soils     

Guillaume De Lafontaine  Pierre‐Luc Couillard  Serge Payette 《第四纪科学杂志》2011,26(6):571-575

The use of macrofossil soil charcoal as a palaeoecological tool to reconstruct past vegetation, climate or fire history has gained much interest in recent years. Yet little is known about taphonomy of charcoal in soils. Here we assessed the putative loss of palaeoecological information due to charcoal fragmentation after burial. We found no significant loss of charcoal mass with time. Instead, we found a significant positive relationship between the mass of charcoal particles and their age. Permineralization of charcoal particles older than ca. 5200 a explained the increased charcoal mass with time in mineral soils. The permineralization process increased the density of charcoal particles (resulting in a twofold particles mass increase) and thus offers a protection against subsequent degradation. Our results suggest high stability of palaeoecological information from charcoal macrofossils buried in mineral soils at least over the Holocene timescale. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献