Simultaneous use of geochemical and geophysical methods to characterise abandoned landfills     

José F. Noguera  Lluís Rivero  Xavier Font  Andrés Navarro  Francisco Martínez 《Environmental Geology》2002,41(8):898-905

. Groundwater sampling and geophysical methods determined a serious contamination problem associated with refilled exploitation sites at the Cal Dimoni area, Llobregat delta, Barcelona, Spain. To characterise this process, hydrogeochemical analyses were performed and showed the following modifications to groundwater chemical composition: increasing pH values, changing redox conditions, significant increases in total organic carbon (TOC) and certain trace elements, and high groundwater conductivity values. Major ion content accumulations were found under the refilled area. In contrast, elements involved in the oxidation–reduction processes, such as iron, manganese and nitrates, clearly diminished. Electromagnetic prospecting methods were also performed and delineated the contamination plume extent. These methods also showed separate sources of contamination, one clearly related to the groundwater–refilled zone leachate interaction, another as a consequence of the manure–accumulation surface site. Geochemical and geophysical methods have shown similar results for locating groundwater contamination sources, and for determining leachate generation mechanisms and flow paths.  相似文献   

Iron(II) oxide determination in rocks and minerals     

Sandra Andrade  Raphael HypolitoHorstpeter H.G.J. Ulbrich  Marinês L. Silva 《Chemical Geology》2002,182(1):85-89

The determination of FeO of geologic materials by modern instrumental methods (such as atomic absorption spectroscopy (AAS), inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray fluorescence (XRF), etc.) cannot distinguish between different oxidation states of elements. In many cases, the oxidation state of Fe has to be known in order to perform several chemical calculations (norms, etc.) and discuss the reactions that occur during weathering, hydrothermal alteration and other processes. A modified Wilson method is proposed, giving reproducible results in a much shorter time than the classical method. Back-titration with potassium dichromate and an Fe(II) and ammonia sulphate solution is used, after dissolution of the sample powder in a heated HF/H₃PO₄ mixture and an ammonium vanadate solution. This modified method, tested with several international reference materials, gives reliable results, equivalent to the ones cited in the literature for the reference materials.  相似文献   

Propriétés fractales de la fragmentation et processus stochastiques de fracturation : approche géométrique 3D à l'aide du modèle ObsifracFractal properties of fragmentation and stochastic fracturing processes: geometrical 3D approach by OBSIFRAC model     

Luc Empereur-Mot  Thierry Villemin 《Comptes Rendus Geoscience》2002,334(2):127-133

A numerical rock fragmentation model was elaborated, producing a 3D puzzle of convex polyhedra, geometrically described in a database. In the first scenario, a constant proportion of blocks are fragmented at each step of the process and leads to fractal distribution. In the second scenario, division affects one random block at each stage of the process, and produces a Weibull volume distribution law. Imposing a minimal distance between the fractures, the third scenario reveals a power law. The inhibition of new fractures in the neighbourhood of existing discontinuities could be responsible for fractal properties in rock mass fragmentation. To cite this article: L. Empereur-Mot, T. Villemin, C. R. Geoscience 334 (2002) 127–133.  相似文献   

The importance of a small wall deformation in the three-dimensional acoustic logging results   总被引：1，自引：0，他引：1  

Luís Godinho  António Tadeu 《Geophysical Journal International》2002,151(2):403-415

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Phénomènes karstiques fossiles et actuels au sein des formations métamorphiques silico-alumineuses de la nappe pan-africaine de Yaoundé (Sud-Cameroun)Fossil and present-time karstic phenomena in silico-aluminous metamorphic formations of the Pan-African nappe of Yaoundé (South-Cameroon)     

Jean-Paul Vicat  Hubert Mvondo  Luc Willems  André Pouclet 《Comptes Rendus Geoscience》2002,334(8):545-550

Numerous karstic features have been recognised in the non-carbonaceous micaschists and gneisses of the Yaoundé Pan-African nappe, south of Cameroon. It is shown that their formation was controlled by the structural features of the rocks. The wells and the pipes in the bedrock outcrops point out a current karstification process, resulting from the plagioclase dissolution by the acid rain waters. Hill wall alveoli and caves, of pre-Miocene age, are exhumed features that were done by dissolution in the aquiferous underground. To cite this article: J.-P. Vicat et al., C. R. Geoscience 334 (2002) 545–550.  相似文献   

Sea cliffs resulting from late Miocene extensional tectonics: the Serra Gelada case study (Betic Cordillera, Spain)     

Alfonso Ybenes  Pedro Alfaro  Jos Delgado  Antonio Estvez  Jesús M. Soria 《Geomorphology》2002,42(3-4)

The Serra Gelada sea cliffs are carved in Mesozoic carbonate rocks belonging to the External Zones of the eastern Betic Cordillera (Alicante, SE Spain). Several normal faults with vertical slips of more than a hundred metres have played an important role in the origin of this coastline. Some previous studies propose that the present cliff morphology was mainly originated by Quaternary fault activity. However, the integration of geomorphological features, stratigraphical and sedimentological data, together with the results of the tectonic analysis of fractures occurring in Serra Gelada, and a detailed study of seismic reflection profiles carried out in the adjacent continental shelf, indicate that these normal faults were active mainly during the late Miocene. Therefore, the Serra Gelada sea cliffs represent a tectonically controlled long-term landscape. Thus, normal faults have not significantly modified the Serra Gelada relief since then. Furthermore, the northern part of the Serra Gelada cliff may be considered as an inherited pre-Quaternary relict palaeocliff since it has only undergone very little erosive recession.  相似文献   

Use of Noise to Augment Training Data: A Neural Network Method of Mineral–Potential Mapping in Regions of Limited Known Deposit Examples     

Warick M. Brown  Tamás D. Gedeon  David I. Groves 《Natural Resources Research》2003,12(2):141-152

One of the main factors that affects the performance of MLP neural networks trained using the backpropagation algorithm in mineral-potential mapping isthe paucity of deposit relative to barren training patterns. To overcome this problem, random noise is added to the original training patterns in order to create additional synthetic deposit training data. Experiments on the effect of the number of deposits available for training in the Kalgoorlie Terrane orogenic gold province show that both the classification performance of a trained network and the quality of the resultant prospectivity map increasesignificantly with increased numbers of deposit patterns. Experiments are conducted to determine the optimum amount of noise using both uniform and normally distributed random noise. Through the addition of noise to the original deposit training data, the number of deposit training patterns is increased from approximately 50 to 1000. The percentage of correct classifications significantly improves for the independent test set as well as for deposit patterns in the test set. For example, using ±40% uniform random noise, the test-set classification performance increases from 67.9% and 68.0% to 72.8% and 77.1% (for test-set overall and test-set deposit patterns, respectively). Indices for the quality of the resultant prospectivity map, (i.e. D/A, D × (D/A), where D is the percentage of deposits and A is the percentage of the total area for the highest prospectivity map-class, and area under an ROC curve) also increase from 8.2, 105, 0.79 to 17.9, 226, 0.87, respectively. Increasing the size of the training-stop data set results in a further increase in classification performance to 73.5%, 77.4%, 14.7, 296, 0.87 for test-set overall and test-set deposit patterns, D/A, D × (D/A), and area under the ROC curve, respectively.  相似文献   

Use of Fuzzy Membership Input Layers to Combine Subjective Geological Knowledge and Empirical Data in a Neural Network Method for Mineral-Potential Mapping   总被引：3，自引：0，他引：3  

Brown  Warick  Groves  David  Gedeon  Tamás 《Natural Resources Research》2003,12(3):183-200

Use of GIS layers, in which the cell values represent fuzzy membership variables, is an effective method of combining subjective geological knowledge with empirical data in a neural network approach to mineral-prospectivity mapping. In this study, multilayer perceptron (MLP), neural networks are used to combine up to 17 regional exploration variables to predict the potential for orogenic gold deposits in the form of prospectivity maps in the Archean Kalgoorlie Terrane of Western Australia. Two types of fuzzy membership layers are used. In the first type of layer, the statistical relationships between known gold deposits and variables in the GIS thematic layer are used to determine fuzzy membership values. For example, GIS layers depicting solid geology and rock-type combinations of categorical data at the nearest lithological boundary for each cell are converted to fuzzy membership layers representing favorable lithologies and favorable lithological boundaries, respectively. This type of fuzzy-membership input is a useful alternative to the 1-of-N coding used for categorical inputs, particularly if there are a large number of classes. Rheological contrast at lithological boundaries is modeled using a second type of fuzzy membership layer, in which the assignment of fuzzy membership value, although based on geological field data, is subjective. The methods used here could be applied to a large range of subjective data (e.g., favorability of tectonic environment, host stratigraphy, or reactivation along major faults) currently used in regional exploration programs, but which normally would not be included as inputs in an empirical neural network approach.  相似文献   

Distribution and effectiveness of nivation in Mediterranean mountains: Peñalara (Spain)     

David Palacios  Nuria de Andrs  Enrique Luengo 《Geomorphology》2003,54(3-4):157-178

Snow accumulation is responsible for geomorphic and biogeographic processes taking place in the southern sector of the Peñalara massif in central Spain (40°51′N, 3°57′W; max. altitude 2428 m at Pico de Peñalara). This work compares the intensity of nivation on the eastern slope, leeward of the prevailing westerly winds and heavily eroded by glacial activity during the Pleistocene, to that of the western slope on the windward side, unaffected by glacial erosion and completely covered by a thick weathering mantle. On the eastern slope, nivation is effective only where the weathering mantle is exposed or on morainic formations. It does not occur on the landforms derived from glacial erosion. In contrast, the western side shows almost no evidence of snow action except where catastrophic mass movements have altered the regularity of the slope. During the post-glacial epoch, nivation cirques formed in the scars left by mass wasting. In the last 30 years, spring temperatures have increased and this activity has diminished. The pattern of evolution observed at Peñalara can be extrapolated to other Mediterranean mountains with similar characteristics such as marginal glacial activity during the Pleistocene, unconsolidated formations on the summits caused by chemical weathering, and dry, hot summers that can increase the effectiveness of nivation.  相似文献   

Extracting flow structures from tracer data     

Judit Schneider  Tamás Tél 《Ocean Dynamics》2003,53(2):64-72

A method of visualizing structures in closed chaotic flows out of homogenous particle distributions is presented in the example of models of a meandering jet. To this end, the system will be leaked or opened up by defining a region of the flow, so that a particle is considered to be escaped if it leaves this region. By applying this method to an ensemble of nonescaped tracers, we are able to characterize mixing processes by visualizing the converging and stretching filamentations (stable and unstable manifolds) in the flow without using additional mathematical tools. The possibility of applying the algorithm to analyze buoy data, and a comparison with the finite time manifolds are discussed.  相似文献