Metal-enriched nanoparticles and black carbon: A perspective from the Brazil railway system air pollution     

Bianca D. Lima  Elba C. Teixeira  James C. Hower  Matheus S. Civeira  Omar Ramírez  Cheng-Xue Yang  Marcos L.S. Oliveira  Luis F.O. Silva 《地学前缘(英文版)》2021,12(3):101129

Having a better understanding of air pollutants in railway systems is crucial to ensure a clean public transport. This study measured, for the first time in Brazil, nanoparticles (NPs) and black carbon (BC) on two ground-level platforms and inside trains of the Metropolitan Area of Porto Alegre (MAPA). An intense sampling campaign during thirteen consecutive months was carried out and the chemical composition of NPs was examined by advanced microscopy techniques. The results showed that highest concentrations of the pollutants occur in colder seasons and influenced by variables such as frequency of the trains and passenger densities. Also, internal and external sources of pollution at the stations were identified. The predominance of NPs enriched with metals that increase oxidative stress like Cd, Fe, Pb, Cr, Zn, Ni, V, Hg, Sn, and Ba both on the platforms and inside trains, including Fe-minerals as hematite and magnetite, represents a critical risk to the health of passengers and employees of the system. This interdisciplinary and multi-analytical study aims to provide an improved understanding of reported adverse health effects induced by railway system aerosols.  相似文献   

The response of vegetation at the end of the last glacial period (MIS 3 and MIS 2) in littoral areas of NW Iberia     

Luis Gómez‐Orellana  Pablo Ramil‐Rego  Castor Muñoz Sobrino 《Boreas: An International Journal of Quaternary Research》2013,42(3):729-744

This paper describes and discusses the palaeobotanical data obtained from organic levels of two exposed deposits on the Atlantic shore of the northwestern Iberian Peninsula. Radiocarbon dating assigns these levels to a period of marine regression at the end of MIS 3 and the beginning of the Last Glacial Maximum. The pollen record shows an initial predominance of tree taxa (mainly deciduous, including the presence of Fagus far from its current limit), followed by an episode of partial forest retraction related to the end of MIS 3 and the beginning of the Last Glacial Maximum. However, the presence of numerous tree taxa in the record, even during the cold intervals associated with Heinrich events, points to the existence of sheltered refugia for these species during this period, in keeping with the conclusions of recent reviews of the vegetation dynamics of this region for the Lateglacial and the Holocene.  相似文献   

Re‐establishment of soil water repellency after destruction by intense burning in a Mediterranean heathland (SW Spain)     

Antonio Jordán  Félix A. González  Lorena M. Zavala 《水文研究》2010,24(6):736-748

Soil water repellency has been conventionally considered as a fire‐induced effect, but an increasing number of studies have suggested that natural background repellency occurs in many soil types, and many of them have suggested that water repellency can be re‐established over time after being destroyed. An experimental fire was conducted to study changes of the soil surface during the first 18 months following intense burning. The main objectives of this paper are as follows: (1) to investigate in situ water repellency changes at three soil depths (0, 2 and 4 cm) immediately after burning; (2) to evaluate the medium‐term evolution of water repellency under field conditions; and (3) to outline the main hydrological consequences of these changes. Also, different water repellency tests (water drop penetration time, ethanol percentage test (EPT) and contact angle (CA) between water drops and the soil surface) were carried out for comparison purposes. Field experiments showed that soil water repellency was partly destroyed after intense burning. Changes were relatively strong at the soil surface, but diminished progressively with depth. Levels of water repellency were practically re‐established 18 months after burning. This suggests that water repellency in the studied area is not necessarily a consequence of fire, but can instead be a natural attribute. Finally, although limited in time, destruction of soil water repellency has important consequences for runoff flow generation and soil loss rates, and, indirectly, for water quality. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Groundwater contamination with arsenic and other trace elements in an area of the pampa,province of Córdoba,Argentina   总被引：1，自引：0，他引：1  

Hugo B. Nicolli  Jose M. Suriano  Miguel A. Gomez Peral  Luis H. Ferpozzi  Omar A. Baleani 《Environmental Geology》1989,14(1):3-16

A geochemical study of groundwater of the pampa in the province of Córdoba, Argentina, was performed; the area covered approximately 10,000 km².Physical-chemical parameters, dissolved solids, and seven trace elements were determined in 60 selected water samples. Systematic and accurate measurements of arsenic, flourine, and vanadium were performed for the first time. Three trace element contaminants not reported earlier were found: an important one, selenium, and two others of less known effects, uranium and molybdenum.Eighty-four percent of the water analyzed showed arsenic contents over 0.05 mg/L, maximum contaminant level established by the U.S. Environmental Protection Agency (1982). The frequency distribution of trace elements was analyzed, and its fit to the lognormal distribution was proved by means of the Pearson and Kolmogorov-Smirnov test; the geographic distribution of the seven trace elements was mapped and its correlation with the anion-cation composition of the water was studied.The maximum arsenic, fluorine, vanadium, and uranium contents were found in the western part of the area under study, in waters containing dominant alkali metals in the cation composition. Maximum selenium and antimony contents were found in the eastern part of the area, while molybdenum distribution does not show any relationship with the other two groups. In addition, the geographic distribution of the trace elements seems to be related to the subsurface structure, which has been inferred using interactive digital analysis of Landsat imagery. The movements of the subsoil have disturbed surface and subsurface drainage influencing the water salinity and trace element contents.In order to investigate the origin of the contamination, 54 loess samples were collected in wells at depths ranging from the surface down to the water table. This loess, which has a high proportion of volcanic components, mainly rhyolitic glass, exhibits a chemical composition corresponding to that of a dacite.The loess and the volcanic glass show anomalous contents of all contaminant trace elements, mainly arsenic and selenium. For this reason loess is considered the most important contamination source in the groundwater under study.  相似文献   

Post glacial lacustrine event sedimentation in an ancient mountain setting: Carboniferous Lake Malanzán (Western Argentina)     

Luis Alberto Buatois  Maria Gabriela Mángano 《Journal of Paleolimnology》1995,14(1):1-22

Lacustrine deposits of the Malanzán Formation record sedimentation in a small and narrow mountain paleovalley. Lake Malanzán was one of several water bodies formed in the Paganzo Basin during the Late Carboniferous deglaciation. Five sedimentary facies have been recognized. Facies A (Dropstones-bearing laminated mudstones) records deposition from suspension fall-out and probably underflow currents coupled with ice-rafting processes in a basin lake setting. Facies B (Ripple cross-laminated sandstones and siltstones) was deposited from low density turbidity currents in a lobe fringe environment. Facies C (Massive or graded sandstones) is thought to represent sedimentation from high and low density turbidity currents in sand lobes. Facies D (Folded sandstones and siltstones) was formed from slumping in proximal lobe environments. Facies E (Wave-rippled sandstones) records wave reworking of sands supplied by turbidity currents above wave base level.The Lake Malanzán succession is formed by stacked turbidite sand lobe deposits. These lobes were probably formed in proximal lacustrine settings, most likely relatively high gradient slopes. Paleocurrents indicate a dominant direction from cratonic areas to the WSW. Although the overall sequence shows a regressive trend from basin fine-grained deposits to deltaic and braided fluvial facies, individual lobe packages lack of definite vertical trends in bed thickness and grain size. This fact suggests aggradation from multiple-point sources, rather than progradation from single-point sources. Sedimentologic and paleoecologic evidence indicate high depositional rate and sediment supply. Deposition within the lake was largely dominated by event sedimentation. Low diversity trace fossil assemblages of opportunistic invertebrates indicate recolonization of event beds under stressed conditions.Three stages of lake evolutionary history have been distinguished. The vertical replacement of braided fluvial deposits by basinal facies indicates high subsidence and a lacustrine transgressive episode. This flooding event was probably linked to a notable base level rise during postglacial times. The second evolutionary stage was typified by the formation of sand turbidite lobes from downslope mass-movements. Lake history culminates with the progradation of deltaic and braided fluvial systems  相似文献   

On the use of the checker-board test to assess the resolution of tomographic inversions   总被引：4，自引：1，他引：4  

Jean-Jacques Lév&#;que  Luis Rivera  Gérard Wittlinger 《Geophysical Journal International》1993,115(1):313-318

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Taphonomy of guanaco bones in Tierra del Fuego     

Luis Alberto Borrero 《Quaternary Research》1990,34(3)

Guanaco carcasses are deposited in great quantities in Cabo San Pablo, Tierra del Fuego (Argentina), as a result of winter stress. Taphonomic studies indicate that the gnawing action of foxes on guanaco (Lama guanicoe) carcasses produces only very tenuous marks on the bones. Lack of sustained interest in the carcasses by carnivores results in slow disarticulation. The articulated and disarticulated bones are exposed to heavy trampling by guanacos, a process that produces vertical migration of small/dense bones and fracturing of the most weathered bones. An understanding of this ongoing process is important for local archaeology, since modern bones are migrating into archaeological contexts. A regional approach to taphonomy is the most appropriate instrument to solve this and other related problems.  相似文献   

Cu, Cd and Zn in Blanca Bay surface sediments, Argentina     

JosLuis Sericano  Adan E. Pucci 《Marine pollution bulletin》1982,13(12):429-431

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Metamorphic gradients in burial metamorphosed vesicular lavas: Comparison of basalt and spilite in Cretaceous basic flows from central Chile     

Beatriz Levi  Luis Aguirre  Jan Olov Nyström 《Contributions to Mineralogy and Petrology》1982,80(1):49-58

Partial spilitization of a 9 km thick pile of flood basalts with highly vesicular flow tops gave rise to patterns of secondary mineralogy at different scales: (a) a local pattern of mineralogical variation from the almost unaltered bottom towards the altered top of each flow, and (b) an overall pattern, comparing flow tops throughout the pile, with changes in mineralogical composition within a sequence of metamorphic zones and facies. The local patterns mimic the trend of the overall pattern, but are of opposite direction and telescoped. Thus, a gradual ordering and Andepletion of the secondary albite and increases in the Fe^*/Al ratio of epidote and pumpellyite upwards within individual flows are comparable in range to corresponding overall changes downwards throughout several kilometres. The mineralogical changes within the flows diminish in range towards the more altered deeper part of the pile.The local and overall patterns cannot be interpreted in terms of grade. They represent trends from metastable towards stable equilibrium, this latter only approached in the flow tops of the lower part of the pile. The patterns of secondary mineralogy were formed by an interplay of metamorphic gradients at different scales at any given time, and as burial proceeded. The overall pattern was caused by depth-controlled gradients: increasing P _fluid, temperature and temperature-induced increase of reaction rates, and decreasing fO₂ (downwards in the pile). The local patterns resulted from permeability-controlled gradients: increasing reaction rates, fO₂ and contrast in chemical activity between different domains, and decreasing P _fluid (upwards in each flow). The mineralogical observations reported in this paper fall into line if the overall temperature-induced increase of reaction rates and the local permeability-controlled rate factors played the leading role during burial metamorphism of the pile.  相似文献   

Dynamics of lava flow fronts, Arenal Volcano, Costa Rica     

Andrea Borgia  Scott Linneman  Daniel Spencer  Luis Diego Morales  Jose Brenes Andre 《Journal of Volcanology and Geothermal Research》1983,19(3-4)

Arenal Volcano has effused basaltic andesite lava flows nearly continuously since September, 1968. The two different kinds of material in flows, lava and lava debris, have different rheologic properties and dynamic behavior. Flow morphology depends on the relationship between the amount and distribution of the lava and the debris, and to a lesser extent the ground morphology.Two main units characterize the flows: the channel zone and the frontal zone. The channel zone consists of two different units, the levées and the channel proper. A velocity profile in the channel shows a maximum value at the plug where the rate of shear is zero, and a velocity gradient increasing outward until, at the levées, the velocity becomes zero. Cooling produces a marked temperature gradient in the flow, leading to the formation of debris by brittle fracture when a critical value of shear rate to viscosity is reached. When the lava supply ceases, much of this debris and part of the lava is left behind after the flow nucleus drains out, forming a collapsed channel.Processes at the frontal zone include levée formation, debris formation, the change in shape of the front, and the choice of the flow path. These processes are controlled primarily by the rheological properties of the lava.Frontal zone dynamics can be understood by fixing the flow front as the point of reference. The lava flows through the channel into the front where it flows out into the levées, thereby increasing the length of the channel and permitting the front to advance. The front shows a relationship of critical height to the yield strength (τ₀) surface tension, and slope; its continued movement is activated by the pressure of the advancing lava in the channel behind. For an ideal flow (isothermal, homogeneous, and isotropic) the ratio of the section of channel proper to the section of levées is calculated and the distance the front will have moved at any time t_x can be determined once the amount of lava available to the front is known. Assuming that the velocity function of the front {G(t)} during the collapsing stage is proportional to the entrance pressure of the lava at the channel-front boundary, an exponential decrease of velocity through time is predicted, which shows good agreement with actual frontal velocity measurements taken on two flows. Local variations in slope have a secondary effect on frontal velocities.Under conditions of constant volume the frontal zone can be considered as a machine that consumes energy brought in by the lava to perform work (front advancement). While the front will use its potential energy to run the process, the velocity at which it occurs is controlled by the activation energy that enters the system as the kinetic energy of the lava flowing into the front. A relation for the energy contribution due to frontal acceleration is also derived. Finally the entrance pressure, that permits the front to deform, is calculated. Its small value confirms that the lava behaves very much like a Bingham plastic.  相似文献