Die Ladungsbilanz für eine verfeinerte Kristallstruktur von Stranskiit,Zn2 Cu(AsO4)2     

Priv. Doz. Dr. P. Keller  Prof. Dr. H. Hess  P. J. Dunn 《Mineralogy and Petrology》1979,26(3):167-174

Zusammenfassung Die Kristallstruktur des Stranskiits wurde mit neuen Meßdaten, die an einer aus Tsumeb stammenden Probe gewonnen worden waren, bis zuR=0,034 für 1239 unabhängige beobachtete Reflexe verfeinert. Von der verfeinerten Struktur wurde die Ladungsbilanz aufgestellt und besonders im Hinblick auf die Ladungsdeformation des Cu²⁺ diskutiert. Eine Mikrosondenanalyse derselben Probe ergab, daß die tatsächliche Zusammensetzung der angegebenen Formel entspricht.

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Charge balance of a refined crystal structure of stranskiite, Zn₂Cu (AsO₄)₂

Summary The crystal structure of stranskiite was refined with new intensity data obtained from a specimen from Tsumeb toR=0.034 for 1234 observed independent reflections. The charge balance was calculated and discussed particularly with respect of the charge deformation of Cu²⁺. An electron probe microanalysis gave the result that the actual composition of the specimen corresponds to the given formula.

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Indoor radon correlated with soil and subsoil radon potential—a case study     

G. Keller  H. Schneiders  M. Schütz  A. Siehl  R. Stamm 《Environmental Geology》1992,19(2):113-119

High indoor radon concentrations in a uranium-radium low-level area in the Eifel region, Germany, near the village of Döttingen are caused by ascending radon migration following the convection of groundwater and soil gas along pathways (fractures and faults) in the bedrock sediments of Lower Devonian age. Positive radon anomalies in the soil gas are found to coincide with the locations of houses showing the highest concentrations. These houses are older buildings without concrete foundation slabs. Normally radon concentrations in soil gas are highly correlated with the values of emanated radon calculated on the basis of radium content in the surrounding soils and rocks (diffusive radon potential). However, close to zones of tectonic fractures and faults around the maar-type volcano of Döttingen abnormally high radon concentrations, which were transported by circulating groundwater and postvolcanic exhalation of CO₂ (convective radon potential) were detected.  相似文献   

Combined stomach content and δ13C/δ15N analyses of oilfish,escolar, snake mackerel and lancetfish in the western North Atlantic          下载免费PDF全文

Heidi R. Keller  Amy C. Hirons  David W. Kerstetter 《Marine Ecology》2016,37(4):727-736

Large, mesopelagic teleost fishes have a potentially keystone position in the ecology of the pelagic water column, yet remain relatively unstudied when compared with large, commercially important, epipelagic fishes. Here, the ecological roles of four, large, vertically migrating teleosts were examined. Stomach content analyses were performed on 48 oilfish (Ruvettus pretiosis), 35 escolar (Lepidocybium flavobrunneum), 32 snake mackerel (Gempylus serpens) and seven lancetfish (Alepisaurus spp.) collected from pelagic longline gear in the Western North Atlantic Ocean from 2007 to 2010. Of these specimens, stable carbon and nitrogen isotope analyses were also performed on white dorsal muscle tissue from 33 oilfish, 16 escolar, 27 snake mackerel and seven lancetfish. Based on literature length‐at‐maturity values, all escolar, snake mackerel and lancetfish specimens were mature, while 13 of the 33 oilfish were juveniles. Crustaceans, annelids, salps, cephalopods and teleosts were present in the stomachs and were presumed to be prey items. A Kruskal–Wallis test showed the four species to be isotopically segregated in both δ¹³C and δ¹⁵N. Escolar were the most depleted in δ¹³C, followed by adult oilfish, juvenile oilfish and lancetfish, with snake mackerel the most enriched. The depletion in δ¹³C of adult oilfish and escolar may have been attributable to high C/N values, which were strongly correlated with length in oilfish, weakly correlated with length in escolar and moderately correlated with length in snake mackerel and lancetfish. The high C/N was likely due to the high lipid concentration of these fishes. Other factors that may have contributed to the depletion in δ¹³C may include spawning or a change in carbon source within the ecosystem. Large escolar occupied the highest trophic level (δ¹⁵N = 10.20), followed by snake mackerel (δ¹⁵N = 9.66), adult oilfish (δ¹⁵N = 9.32), lancetfish (δ¹⁵N = 9.05) and juvenile oilfish (δ¹⁵N = 7.83). A marked change in oilfish δ¹³C and C/N at 30–35 cm fork length coincided with a presumed length‐at‐maturity.  相似文献   

Effective sub-Zechstein salt imaging using low-frequency seismics — Results of the GRUNDY 2003 experiment across the Variscan front in the Polish Basin     

M. Malinowski  M. Grad  A. Guterch  E. Takcs  Z. liwi&#x;ski  L. Antonowicz  E. Iwanowska  G.R. Keller  E. Heged&#x;s 《Tectonophysics》2007,439(1-4):89-106

The extent of the Variscan deformation front is one of the key problems of the regional geology of the Central European Permian Basin system, particularly in its Polish part. Conventional reflection seismics usually fails to produce a satisfactory image of the pre-Permian strata due to the shielding effect of Zechstein (Upper Permian) evaporites. Thus we used a novel seismic acquisition technique to study the base of the Permian complex and its Variscan basement. In the GRUNDY 2003 experiment we combined wide-angle reflection–refraction measurements with the near-vertical reflection seismics by the use of the constant geophone array with dense (100 m) receiver spacing occupying 50-km long profile. 3D design of the experiment, covering 50 × 10 km area, helped in eliminating the effect of out-of-plane propagations and local inhomogeneities. An effective integration of traveltime tomography, CDP reflection processing and prestack depth migration of wide-angle reflections applied to our data, allowed us to present the model in which we deduced the contact zone of the Variscan overthrust structure (Variscan front) with its molasse-filled foredeep. The latter might be a gas-generation zone, which is of a great importance for hydrocarbons prospecting in this area.  相似文献   

Peralkaline silicate lavas at Oldoinyo Lengai, Tanzania   总被引：1，自引：0，他引：1  

Jurgis Klaudius  Jrg Keller 《Lithos》2006,91(1-4):173-190

A detailed study of Oldoinyo Lengai has led to the recognition of two major cone-building stages. An early, predominantly phonolitic stage, Lengai I, forms the southern cone. The recent nephelinitic Lengai II developed following a major sector collapse event over Lengai I. Petrography of Lengai II lavas show that nephelinite is combeite- and wollastonite-bearing. All Oldoinyo Lengai lavas are peralkaline and highly evolved in terms of low Mg#, Ni and Cr values. Within the unique Lengai II combeite–wollastonite–nephelinite (CWN) peralkalinity increases with time to extreme values (Na + K)/Al = 2.36. Mineralogical expression of peralkalinity is the presence of combeite and Na-rich clinopyroxene. In addition, exceptionally high Fe₂O₃ (up to 10.28 wt.%) in nepheline is an indicator for alumina deficiency. Combeite also shows high Fe³⁺. Phonolite and CWN of Lengai I and Lengai II show similarly enriched LILE and LREE values and generally parallel patterns in PM normalized and REE plots.  相似文献   

The mineral isotope composition of two Precambrian carbonatite complexes from the Kola Alkaline Province – Alteration versus primary magmatic signatures     

M. Tichomirowa  G. Grosche  J. Gtze  B.V. Belyatsky  E.V. Savva  J. Keller  W. Todt 《Lithos》2006,91(1-4):229-249

We investigated the isotope composition (O, C, Sr, Nd, Pb) in mineral separates of the two Precambrian carbonatite complexes Tiksheozero (1.98 Ga) and Siilinjärvi (2.61 Ga) from the Karelian–Kola region in order to obtain information on Precambrian mantle heterogeneity. All isotope systems yield a large range of variations. The combination of cathodoluminescence imaging with stable and radiogenic isotopes on the same samples and mineral separates indicates various processes that caused shifts in isotope systems. Primary isotope signatures are preserved in most calcites (O, C, Sr, Pb), apatites (O, Sr, Nd), amphiboles (O), magnetites (O), and whole rocks (Sr, Nd).

The primary igneous C and O isotope composition is different for both complexes (Tiksheozero: δ¹³C = − 5.0‰, δ¹⁸O = 6.9‰; Siilinjärvi: δ¹³C = − 3.7‰, δ¹⁸O = 7.4‰) but very uniform and requires homogenization of both carbon and oxygen in the carbonatite melt. The lowest Sr isotope ratios of our carbonates and apatites from the Archaean Siilinjärvi (0.70137) and the Palaeoproterozoic Tiksheozero (0.70228) complexes are in the range of bulk silicate earth (BSE). Positive ε_Nd values of the two carbonatites point to very early Archaean enrichment of Sm/Nd in the Fennoscandian mantle. No HIMU components could be detected in the two complexes, whereas Tiksheozero carbonatites give the first indication of Palaeoproterozoic U depletion for Fennoscandia.

Sub-solidus exchange processes with water during emplacement and cooling of carbonatites caused an increase in the oxygen isotope composition of some carbonates and probably also an increase of their ⁸⁷Sr/⁸⁶Sr ratio. A larger increase of initial Sr isotope ratios was found in carbonatized silicic rocks compared to carbonatite bodies. The Svecofennian metamorphic overprint (1.9–1.7 Ga) caused reset of Rb/Sr (mainly mica) and Pb/Pb (mainly apatite) isochron systems.  相似文献   

Optimisation of the Operation of an Electrochemical Process To Treat TBT‐contaminated Sediments on a Pilot Scale     

Eduardo Arevalo  Arne Keller  Heinz Stichnothe  Wolfgang Calmano 《洁净——土壤、空气、水》2004,32(6):401-410

Since at least three decades tributyltin had been commonly used in paint formulations to protect ship hulls and submersed surfaces from fouling. This has resulted in negative and Technology, effects to the marine environment due to its high toxicity towards non‐target organisms and to its accumulation in sediments, especially near point sources of pollution. Even if a ban of TBT for its application in anti‐fouling paints is enforced the problem of TBT‐contaminated sediments will remain for the coming years due to the low degradation rates of organotin in sediments. In this work an electrochemical process at a pilot scale to destroy TBT in sediments was investigated. Previous experiences at a laboratory and technical scale have demonstrated the potential of this process to electrolytically degrade organotin species in sediments. This article deals with the optimisation of the pilot plant performance in terms of organotin degradation and operation costs monitoring additionally the effect of the electrochemical treatment on other pollutants such as heavy metals, PCBs, and PAHs. The aim was to investigate by means of a parametric study the range of operating conditions required to destroy TBT down to concentrations lower than 100 μg/kg; to determine the influence of those parameters on the performance of the process; and to evaluate the operation costs associated to the process. It was determined that it was possible to destroy TBT down to 100 μg/kg at current densities in the range of 4.4 to 6.6 mA/cm² and chloride concentrations of least of 0.2 mol/L with operation costs of 13 to 18 EUR/m³.  相似文献   

Stratigraphy of the Kos Plateau Tuff: product of a major Quaternary explosive rhyolitic eruption in the eastern Aegean, Greece     

S. R. Allen  E. Stadlbauer  J. Keller 《International Journal of Earth Sciences》1999,88(1):132-156

 The Kos Plateau Tuff (KPT) erupted during a moderate-volume explosive rhyolitic event approximately 161 ka from a source south of Kos in the eastern Aegean sea. Six major stratigraphic units have been identified, from A at the base, to F, uppermost. Unit A is a widespread vitric ash fall layer that is thickest (1.5 m), and most extensive, southeast of the source. Unit B is a 1- to 2-m-thick, low-angle cross-stratified armoured pumice lapilli and ash layer found on Kos. Unit C resembles unit B but includes a greater abundance of lithic lapilli, less fine ash, is only diffusely stratified and is on Kos and west of the source. Unit D includes a sequence of three non-welded, 1- to 20-m-thick ignimbrites that extend radially >38 km from the source in areas of low topography. Unit E is a sequence of two non-welded, 3- to 8-m-thick ignimbrites which occur radially from the vent regardless of topography, >64 km from source. Unit F has a 6-m-thick, basal, low-angle cross-stratified armoured pumice lapilli and ash part probably deposited radially from source. The upper part of unit F is a widespread >1-m-thick vitric ash fall layer, found to at least 50 km from the source. These six units represent a change in eruptive conditions from initial and final phreatomagmatic activity depositing fallout and internally stratified pyroclastic density current deposits to "dry" explosive during the more intense phases of the eruption which generated ignimbrites. Received: 8 June 1998 / Accepted: 14 January 1999  相似文献   

Paläotopographie und Kleinfazies     

Gerhard Keller 《International Journal of Earth Sciences》1956,45(1):128-134

Zusammenfassung Das mit Hilfe der paläotopographischen Betrachtungsweise bis in kleinste zeitliche und räumliche Einheiten zu erkennende Relief sinkender Erdkrustenteile bewirkt eine Aufgliederung der Faziestypen in örtliche Kleinfazies. Die Einschaltung von autochthonen Streifenkohlenflözen verleiht die Möglichkeit, die Kleinfazies mit dem Wasserspiegel paralischer Bildungsräume zu verknüpfen, so daß die Großbewegungen epirogener Undationen nicht nur in ihre kleinsten räumlichen und zeitlichen Vorgänge aufgelöst, sondern auch mit absoluten Senkungsmaßen belegt werden können. Epirogenese ist die Summe dieser Kleinstbewegungen, wobei das Maß. frühdiagenetischer Setzungen und die Reliefbelebung durch außerhalb des Sedimentationsraums ausgelöste erosive Vorgänge von jenen zu trennen ist.  相似文献   

Interaction of a normal shock wave with a compressible turbulent flow     

J. Keller  W. Merzkirch 《Mineralium Deposita》1994,29(1):241-248

A speckle photographic method, which is sensitive to changes of gradients in fluid density, is applied for analyzing a compressible turbulent air flow with density fluctuations. Spatial correlation coefficients, turbulent length scales, and energy spectra are determined under the assumption of homogeneous isotropic turbulence. The experiments are performed in a shock tube where the flow is passed through a turbulence grid. Measurements are taken before and after the turbulent regime interacts with the normal shock wave reflected from the tube's end wall. Amplification of the turbulence intensity by the shock interaction process is verified quantitatively and is shown to be restricted to the lower wave numbers in the spectrum.A version of this paper was presented at the 11th Symposium on Turbulence, University of Missouri-Rolla, Oct. 17–19, 1988.To Professor Dr.-Ing. Klaus Gersten on the occasion of his 60th birthday  相似文献