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Concentrations and calculated fluxes of trace metals into Bermuda nearshore marine and lake sediments are presented. In areas affected by anthropogenic activity, metal profiles show surface sediment enrichments similar to those observed in North American and European lacustrine and estuarine sediments. Atmospheric fluxes of Cu, Zn and Pb into the lake sediments are higher than those of rural areas in North America. These high fluxes are assumed to be due to jet-fuel combustion. Sediment profiles in the Hamilton City area indicate increased anthropogenic input of Cu and Pb compared to other marine locations.  相似文献   
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The reduction of sulfate by sulfate reducing bacteria in the anoxic zone is an extremely important process during early diagenesis of marine sediments. Our data from Great Bay, NH reinforce the proposal that the rate of sulfate reduction is directly proportional to the reactivity of the organic matter or the amount of readily metabolizable organic matter present in the sediment and, hence, the source of the organic material in the anoxic zone. It appears that organic matter rich in marine organic remains is more easily degraded in the anoxic zone and that sulfate reduction rates can vary considerably in an estuarine system where many types of organic material may be deposited.  相似文献   
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Radial velocity anomalies in the lower mantle that give rise to triplications in the travel-time curve for short-periodP waves will produce arrivals havingdT/d values that differe by roughly 0.2–0.5 s/deg. The first two arrivals associated with such triplications will be separated by less than one second over a distance range of 4°–10° they may not, therefore, be separable visually on single seismograms, so that their presence can only be inferred from some measurable property that depends on their mutual interference. If there are lateral variations in the regions of anomalous velocity gradients, the interfering signals will also have different azimuths of arrival. Using two synthetic wavelets we have investigated the effect of interference on bothdT/d and azimuth measurements at the Yellowknife Array. We found that if the interfering pulses have a dominant frequencyv, there is a range of time separations (0.30/v0.55/v) over which the measureddT/d and azimuth values may fluctuate by much more than the differences indT/d and azimuth between the interfering signals. We have evaluated the following empirically defined functions for three different primary signals, and for three different relative amplitudes of the interfering signals:f (t), the drift function, which expresses how the measured slownesses,p, and azimuths, , differ from the slownesses and azimuths of the primary wavelets; f(), the range function, which describes the behaviour of the upper and lower bounds ofp and as a function of the difference in arrival times of the signals, andf , studied the properties of these functions, and have outlined how these properties provide criteria based on the numerical and statistical characteristics of the arrival vectors, and on the waveform of the signal that will enable small radial velocity anomalies to be more clearly delineated.Contribution No. 863 from the Earth Physics Branch.  相似文献   
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Coal of the Narragansett basin generally has been considered to be anthracite and/or meta-anthracite. However, no single reliable method has been used to distinguish these two ranks in this basin. Three methods — chemical, X-ray, and petrographic — have been used with some degree of success on coal of the Narragansett basin, but too often the results are in conflict. Chemical methods have been limited by inadequate sampling on a coal-bed-by-coal-bed basis and by a lack of analyses made according to (American Society for Testing and Materials, 1974) standard specifications.In addition, when corrections are made by using the Parr formulas, as required by the ASTM (1974) procedures, the generally high to very high ash content of coal from the Narragansett basin causes the fixed-carbon content to appear higher than it actually is. X-ray methods using the degree of graphitization as a measure of rank are not reliable because some of the graphite is related to shearing and brecciation associated with folding and faulting. Petrographic methods using reflectance on vitrinite give results that are generally consistent with results from chemical determinations. However, it is not clear whether the mean maximum reflectance or mean bireflectance is a better indicator of similar rank of such high-rank coals that have been structurally deformed.Coal from the Cranston Mine, RI, is probably meta-anthracite and coal from the Portsmouth Mine is probably anthracite. These ranks are based on chemical,X-ray, and petrographic data and are supported by associated metamorphic mineral assemblages that indicate that the Cranston Mine is in a higher metamorphic zone than the zone containing the Porthmouth Mine. Interpretation of the rank of Mansfield, MA, coal on the basis of extant chemical data is difficult because it is an impure coal with an ash content of 33 to 50%. Reflectance data indicate that the Mansfield, Foxborough, and Plainville coals in the northern part of the Narragansett basin are meta-anthracite but this is in disagreement with the rank suggested by the low degree of metamorphism of the associated rocks.  相似文献   
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Previous geochemical and microbiological studies in the Cariaco Basin indicate intense elemental cycling and a dynamic microbial loop near the oxic-anoxic interface. We obtained detailed distributions of sulfur isotopes of total dissolved sulfide and sulfate as part of the on-going CARIACO time series project to explore the critical pathways at the level of individual sulfur species. Isotopic patterns of sulfate (δ34SSO4) and sulfide (δ34SH2S) were similar to trends observed in the Black Sea water column: δ34SH2S and δ34SSO4 were constant in the deep anoxic water (varying within 0.6‰ for sulfide and 0.3‰ for sulfate), with sulfide roughly 54‰ depleted in 34S relative to sulfate. Near the oxic-anoxic interface, however, the δ34SH2S value was ∼3‰ heavier than that in the deep water, which may reflect sulfide oxidation and/or a change in fractionation during in situ sulfide production through sulfate reduction (SR). δ34SH2S and Δ33SH2S data near the oxic-anoxic interface did not provide unequivocal evidence to support the important role of sulfur-intermediate disproportionation suggested by previous studies. Repeated observation of minimum δ34SSO4 values near the interface suggests ‘readdition’ of 34S-depleted sulfate during sulfide oxidation. A slight increase in δ34SSO4 values with depth extended over the water column may indicate a reservoir effect associated with removal of 34S-depleted sulfur during sulfide production through SR. Our δ34SH2S and Δ33SH2S data also do not show a clear role for sulfur-intermediate disproportionation in the deep anoxic water column. We interpret the large difference in δ34S between sulfate and sulfide as reflecting fractionations during SR in the Cariaco deep waters that are larger than those generally observed in culturing studies.  相似文献   
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Debris flows are a prevalent and destructive mass-wasting type in many mountainous regions throughout the world, yet the recent identification of a debris flow topographic signature has not been incorporated into landslide inventories. We have detected this signature in a digital elevation model of the mountainous Oconaluftee River basin of the southern Appalachians, USA, where we have conducted mass-wasting inventories. We evaluate the applicability of this topographic signature in debris flow mapping efforts using inventories created by semiautomated classification of topographic derivative and vegetation index maps. Debris flow detection was increased by 12 % when the inventory was limited to the portion of the landscape that exhibits the debris flow topographic signature. The extent of drainages with this topographic signature, which have areas of 6 to 35 km2, is corroborated by analyses of channel form, knickpoint and bedrock distributions, and hypsometry. This mass-wasting inventory technique provides a more focused approach to statistically characterize the land surface, which resulted in increased inventory proficiency across a landscape with an extensive and relatively well-documented debris flow history.  相似文献   
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