Temporal Changes in Seawater Carbonate Chemistry and Carbon Export from a Southern California Estuary     

May-Linn Paulsen  Andreas J. Andersson  Lihini Aluwihare  Tyler Cyronak  Sydney D’Angelo  Charlie Davidson  Hany Elwany  Sarah N. Giddings  Heather N. Page  Magali Porrachia  Stephen Schroeter 《Estuaries and Coasts》2018,41(4):1050-1068

Estuaries are important subcomponents of the coastal ocean, but knowledge about the temporal and spatial variability of their carbonate chemistry, as well as their contribution to coastal and global carbon fluxes, are limited. In the present study, we measured the temporal and spatial variability of biogeochemical parameters in a saltmarsh estuary in Southern California, the San Dieguito Lagoon (SDL). We also estimated the flux of dissolved inorganic carbon (DIC) and total organic carbon (TOC) to the adjacent coastal ocean over diel and seasonal timescales. The combined net flux of DIC and TOC (F_DIC?+?TOC) to the ocean during outgoing tides ranged from ??1.8±0.5?×?10³ to 9.5±0.7?×?10³?mol C h^?1 during baseline conditions. Based on these fluxes, a rough estimate of the net annual export of DIC and TOC totaled 10±4?×?10⁶?mol C year^?1. Following a major rain event (36 mm rain in 3 days), F_DIC?+?TOC increased and reached values as high as 29.0 ±?0.7?×?10³?mol C h^?1. Assuming a hypothetical scenario of three similar storm events in a year, our annual net flux estimate more than doubled to 25 ±?4?×?10⁶?mol C year^?1. These findings highlight the importance of assessing coastal carbon fluxes on different timescales and incorporating event scale variations in these assessments. Furthermore, for most of the observations elevated levels of total alkalinity (TA) and pH were observed at the estuary mouth relative to the coastal ocean. This suggests that SDL partly buffers against acidification of adjacent coastal surface waters, although the spatial extent of this buffering is likely small.  相似文献   

Geospatial web services pave new ways for server-based on-demand access and processing of Big Earth Data     

Julia Wagemann  Oliver Clements  Ramiro Marco Figuera  Angelo Pio Rossi  Simone Mantovani 《International Journal of Digital Earth》2018,11(1):7-25

ABSTRACT

Big Earth Data has experienced a considerable increase in volume in recent years due to improved sensing technologies and improvement of numerical-weather prediction models. The traditional geospatial data analysis workflow hinders the use of large volumes of geospatial data due to limited disc space and computing capacity. Geospatial web service technologies bring new opportunities to access large volumes of Big Earth Data via the Internet and to process them at server-side. Four practical examples are presented from the marine, climate, planetary and earth observation science communities to show how the standard interface Web Coverage Service and its processing extension can be integrated into the traditional geospatial data workflow. Web service technologies offer a time- and cost-effective way to access multi-dimensional data in a user-tailored format and allow for rapid application development or time-series extraction. Data transport is minimised and enhanced processing capabilities are offered. More research is required to investigate web service implementations in an operational mode and large data centres have to become more progressive towards the adoption of geo-data standard interfaces. At the same time, data users have to become aware of the advantages of web services and be trained how to benefit from them most.  相似文献   

Environmental tracers and indicators bringing together groundwater,surface water and groundwater-dependent ecosystems: importance of scale in choosing relevant tools     

G. Bertrand  D. Siergieiev  P. Ala-Aho  P. M. Rossi 《Environmental Earth Sciences》2014,72(3):813-827

Groundwater–surface water (GW–SW) interactions cover a broad range of hydrogeological and biological processes and are controlled by natural and anthropogenic factors at various spatio-temporal scales, from watershed to hyporheic/hypolentic zone. Understanding these processes is vital in the protection of groundwater-dependent ecosystems increasingly required in water resources legislation across the world. The use of environmental tracers and indicators that are relevant simultaneously for groundwater, surface water and biocenoses–biotope interactions constitutes a powerful tool to succeed in the management task. However, tracer type must be chosen according to the scale of interest and tracer use thus requires a good conceptual understanding of the processes to be evaluated. This paper reviews various GW–SW interaction processes and their drivers and, based on available knowledge, systemises application of conservative tracers and semi-conservative and reactive environmental indicators at different spatial scales. Biocenoses–biotopes relationships are viewed as a possible transition tool between scales. Relation between principal application of the environmental tracers and indicators, examples and guidelines are further proposed for examining GW–SW interactions from a hydrogeological and biological point of view by demonstrating the usability of the tracers/indicators and providing recommendations for the scientific community and decision makers.  相似文献   

Multi-methodological investigation of kunzite, hiddenite, alexandrite, elbaite and topaz, based on laser-induced breakdown spectroscopy and conventional analytical techniques for supporting mineralogical characterization     

Manuela Rossi  Marcella Dell’Aglio  Alessandro De Giacomo  Rosalba Gaudiuso  Giorgio Saverio Senesi  Olga De Pascale  Francesco Capitelli  Fabrizio Nestola  Maria Rosaria Ghiara 《Physics and Chemistry of Minerals》2014,41(2):127-140

Gem-quality alexandrite, hiddenite and kunzite, elbaite and topaz minerals were characterized through a multi-methodological investigation based on EMPA-WDS, LA-ICP-MS, and laser-induced breakdown spectroscopy (LIBS). With respect to the others, the latter technique enables a simultaneous multi-elemental composition without any sample preparation and the detection of light elements, such as Li, Be and B. The criteria for the choice of minerals were: (a) the presence of chromophore elements in minor contents and/or as traces; (b) the presence of light lithophile elements (Li, Be and B); (c) different crystal chemistry complexity. The results show that LIBS can be employed in mineralogical studies for the identification and characterization of minerals, and as a fast screening method to determine the chemical composition, including the chromophore and light lithophile elements.  相似文献   

A prototype system for space–time assessment of rainfall-induced shallow landslides in Italy     

Lorella Montrasio  Roberto Valentino  Angela Corina  Lauro Rossi  Roberto Rudari 《Natural Hazards》2014,74(2):1263-1290

In the last decades, physically based distributed models turned out rather promising to achieve the space–time assessment of shallow landslides at large spatial scale. This technical note deals with the application of a physically based stability model named Shallow Landslides Instability Prediction (SLIP), which has been adopted by the Department of National Civil Protection of Italy as a prototype early warning system for rainfall-induced shallow landslides on national scale. The model is used as a main methodology to create space–time shallow landslide susceptibility maps based on a simple deterministic slope-stability approach, combined with high-resolution rainfall information and geographic information system-based geospatial datasets. The safety factor as an index to measure slope instability is modeled as function of topographic, geologic, geotechnical and hydrologic variables. Although the main aim of this work was to prove the operational viability of such model on a nationwide domain and some simplification are adopted at this stage, hind cast tests on some relevant case histories of shallow landslides occurred between October 2009 and October 2011 showed that the model has skill in representing both timing and location of those shallow landslides.  相似文献   

Geometallurgical Modeling at Olympic Dam Mine, South Australia     

Jeff B. Boisvert  Mario E. Rossi  Kathy Ehrig  Clayton V. Deutsch 《Mathematical Geosciences》2013,45(8):901-925

Modeling of geometallurgical variables is becoming increasingly important for improved management of mineral resources. Mineral processing circuits are complex and depend on the interaction of a large number of properties of the ore feed. At the Olympic Dam mine in South Australia, plant performance variables of interest include the recovery of Cu and U₃O₈, acid consumption, net recovery, drop weight index, and bond mill work index. There are an insufficient number of pilot plant trials (841) to consider direct three-dimensional spatial modeling for the entire deposit. The more extensively sampled head grades, mineral associations, grain sizes, and mineralogy variables are modeled and used to predict plant performance. A two-stage linear regression model of the available data is developed and provides a predictive model with correlations to the plant performance variables ranging from 0.65–0.90. There are a total of 204 variables that have sufficient sampling to be considered in this regression model. After developing the relationships between the 204 input variables and the six performance variables, the input variables are simulated with sequential Gaussian simulation and used to generate models of recovery of Cu and U₃O₈, acid consumption, net recovery, drop weight index, and bond mill work index. These final models are suitable for mine and plant optimization.  相似文献   

An analytical method for the evaluation of the in-plan irregularity of non-regularly asymmetric buildings     

Melina Bosco  Edoardo M. Marino  Pier Paolo Rossi 《Bulletin of Earthquake Engineering》2013,11(5):1423-1445

This paper describes a new method for the evaluation of the static eccentricity $e_{s}$ and the ratio $\Omega _{\uptheta } $ of uncoupled torsional to lateral frequencies in real multi-storey buildings. The above-mentioned parameters greatly affect the lateral-to-torsional coupling of the response of asymmetric systems and thus are of paramount importance in the assessment of the in-plan irregularity of buildings. The proposed method, which is a generalization of that suggested by Calderoni et al. (Earthq Spectra 18(2):219–231, 2002), allows the calculation of the static eccentricity $e_{s}$ and the ratio $\Omega _{\uptheta } $ from the structural response to arbitrary distributions of forces and torsional couples. The effectiveness of the method is validated on some regularly and non-regularly asymmetric buildings characterised by different in-plan irregularity. The analyses demonstrate that the results of the method are rigorous in the case of regularly asymmetric systems and only slightly depend upon the heightwise distribution of the forces in the case of non-regularly asymmetric systems. Finally, the values of the static eccentricity $e_{s}$ and the ratio $\Omega _{\uptheta } $ resulting from the proposed method are compared to those obtained by means of the procedure suggested by Makarios and Anastassiadis in (Struct Des Tall Spec Build 7(1):33–55, 1998a; Struct Des Tall Spec Build 7(1):57–71, 1998b) .  相似文献   

Comparison of nonlinear static methods for the assessment of asymmetric buildings     

Melina Bosco  Aurelio Ghersi  Edoardo M. Marino  Pier Paolo Rossi 《Bulletin of Earthquake Engineering》2013,11(6):2287-2308

Traditional nonlinear static methods, e.g. the original version of the N2 method implemented in Eurocode 8, are not always effective in the assessment of asymmetric structures because of the errors committed in the evaluation of the torsional response. To overcome this shortcoming, two methods have recently been suggested by Kreslin and Fajfar (Bull Earthquake Eng 10(2):695–715, 2012) and Bosco et al. (Earthq Eng Struct Dyn 41:1751–1773, 2012). In particular, the method proposed by Kreslin and Fajfar adjusts the results of the nonlinear static analysis by means of those of a standard modal response spectrum analysis. In the method proposed by Bosco et al., the researchers suggested the use of two nonlinear static analyses characterized by lateral forces applied to different points of the deck. In this paper, the two improved nonlinear static methods and the original N2 method are applied to predict the maximum dynamic response of single- and multi-storey systems subjected to artificial and recorded accelerograms. The results highlight that the improved nonlinear static methods provide estimates which are more accurate than those of the original N2 method. Further, the comparison of the results identifies the range of the structural properties within which the original N2 method is still reliable and the range within which one of the two improved methods should be preferred.  相似文献   

Improving basin scale shallow landslide modelling using reliable soil thickness maps   总被引：3，自引：0，他引：3  

Samuele Segoni  Guglielmo Rossi  Filippo Catani 《Natural Hazards》2012,61(1):85-101

Soil thickness is a well-known factor controlling shallow landsliding. Notwithstanding, its spatial organisation over large areas is poorly understood, and in basin scale slope analyses it is often established using simple methods. In this paper, we apply five different soil thickness models in two test sites, and we use the obtained soil thickness maps to feed a slope stability model. Validation quantifies how errors in soil thickness influence the resulting factor of safety and points out which method grants the best results. In particular, in our cases, slope-derived soil thickness patterns produced the worst slope stability assessment, while the use of reliable soil thickness maps obtained by means of a more complex geomorphologically indexed model improved shallow landslides modelling.  相似文献   

Assessment of perfluorinated compounds (PFCs) in plasma of bottlenose dolphins from two southeast US estuarine areas: relationship with age, sex and geographic locations     

Fair PA  Houde M  Hulsey TC  Bossart GD  Adams J  Balthis L  Muir DC 《Marine pollution bulletin》2012,64(1):66-74

Plasma PFCs were measured in 157 bottlenose dolphins (Tursiops truncatus) sampled from two US southeast Atlantic sites (Charleston (CHS), SC and Indian River Lagoon (IRL), FL) during 2003-2005. ∑PFCs, perfluoroalkyl carboxylates (∑PFCAs), perfluoroalkyl sulfonates (∑PFSAs) and individual compounds were significantly higher in CHS dolphins for all age/sex categories compared to IRL dolphins. Highest ∑PFCs concentrations occurred in CHS juvenile dolphins (2340 ng/g w.w.); significantly higher than found in adults (1570 ng/g w.w. males; 1330 ng/g w.w. females). ∑PFCAs were much greater in CHS dolphins (≈ 21%) compared to IRL dolphins (≈ 7%); ∑PFSAs were 79% in CHS dolphins versus 93% in IRL dolphins. PFOS, the dominant compound, averaged 72% and 84%, respectively, in CHS and IRL dolphins. Decreasing PFC levels occurred with age on the bioaccumulation of PFCs in both sites. These observations suggest PFC accumulation in these two dolphin populations are influenced by site-specific exposures with significantly higher levels in CHS dolphins.  相似文献