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131.
A method is described for the detection and identification of dissolved organic compounds (DOCs) in various water samples. Acid treated active silica gel sorbent (pH 3) was packed into a micro‐column and used as a solid‐phase extraction medium for adsorption of DOCs. Silica particles‐adsorbed‐organic species were then divided into equal portions followed by suspension into various organic solvents of different polarities such as methanol, acetone, ethyl acetate, and toluene. Suspended silica‐adsorbed‐organic species were shaken for 1 h at room temperature and the organic extracts were subjected to GC–MS analysis under temperature programming conditions for qualitative detection and identification of these species. Blank solvents and silica samples were also subjected to the same extraction procedures and GC–MS analysis for comparison. The mass spectrum of each eluted chromatographic peak was library searched or manually interpreted to identify the compound.  相似文献   
132.
ABSTRACT

The problem of estimation of suspended load carried by a river is an important topic for many water resources projects. Conventional estimation methods are based on the assumption of exact observations. In practice, however, a major source of natural uncertainty is due to imprecise measurements and/or imprecise relationships between variables. In this paper, using the Multivariate Adaptive Regression Splines (MARS) technique, a novel fuzzy regression model for imprecise response and crisp explanatory variables is presented. The investigated fuzzy regression model is applied to forecast suspended load by discharge based on two real-world datasets. The accuracy of the proposed method is compared with two well-known parametric fuzzy regression models, namely, the fuzzy least-absolutes model and the fuzzy least-squares model. The comparison results reveal that the MARS-fuzzy regression model performs better than the other models in suspended load estimation for the particular datasets. This comparison is done based on four goodness-of-fit criteria: the criterion based on similarity measure, the criterion based on absolute errors and the two objective functions of the fuzzy least-absolutes model and the fuzzy least-squares model. The proposed model is general and can be used for modelling natural phenomena whose available observations are reported as imprecise rather than crisp.
Editor D. Koutsoyiannis; Associate editor H. Aksoy  相似文献   
133.
ABSTRACT

The application of artificial neural networks (ANNs) has been widely used recently in streamflow forecasting because of their ?exible mathematical structure. However, several researchers have indicated that using ANNs in streamflow forecasting often produces a timing lag between observed and simulated time series. In addition, ANNs under- or overestimate a number of peak flows. In this paper, we proposed three data-processing techniques to improve ANN prediction and deal with its weaknesses. The Wilson-Hilferty transformation (WH) and two methods of baseflow separation (one parameter digital filter, OPDF, and recursive digital filter, RDF) were coupled with ANNs to build three hybrid models: ANN-WH, ANN-OPDF and ANN-RDF. The network behaviour was quantitatively evaluated by examining the differences between model output and observed variables. The results show that even following the guidelines of the Wilson-Hilferty transformation, which significantly reduces the effect of local variations, it was found that the ANN-WH model has shown no significant improvement of peak flow estimation or of timing error. However, combining baseflow with streamflow and rainfall provides important information to ANN models concerning the flow process operating in the aquifer and the watershed systems. The model produced excellent performance in terms of various statistical indices where timing error was totally eradicated and peak flow estimation significantly improved.
Editor D. Koutsoyiannis; Associate editor Y. Gyasi-Agyei  相似文献   
134.
In this study,a new analytical approach is developed to analyze the free nonlinear vibration of conservative two-degree-of-freedom(TDOF) systems.The mathematical models of these systems are governed by second–order nonlinear partial differential equations.Nonlinear differential equations were transferred into a single equation by using some intermediate variables.The single nonlinear differential equations are solved by using the first order of the Hamiltonian approach(HA).Different parameters,which have a significant impact on the response of the systems,are considered and discussed.Some comparisons are presented to verify the results between the Hamiltonian approach and the exact solution.The maximum relative error is less than 2.2124 % for large amplitudes of vibration.It has been established that the first iteration of the Hamiltonian approach achieves very accurate results,does not require any small perturbations,and can be used for a wide range of nonlinear problems.  相似文献   
135.
ABSTRACT

Road intersection data have been used across a range of geospatial analyses. However, many datasets dating from before the advent of GIS are only available as historical printed maps. To be analyzed by GIS software, they need to be scanned and transformed into a usable (vector-based) format. Because the number of scanned historical maps is voluminous, automated methods of digitization and transformation are needed. Frequently, these processes are based on computer vision algorithms. However, the key challenges to this are (1) the low conversion accuracy for low quality and visually complex maps, and (2) the selection of optimal parameters. In this paper, we used a region-based deep convolutional neural network-based framework (RCNN) for object detection, in order to automatically identify road intersections in historical maps of several cities in the United States of America. We found that the RCNN approach is more accurate than traditional computer vision algorithms for double-line cartographic representation of the roads, though its accuracy does not surpass all traditional methods used for single-line symbols. The results suggest that the number of errors in the outputs is sensitive to complexity and blurriness of the maps, and to the number of distinct red-green-blue (RGB) combinations within them.  相似文献   
136.
Hydroelastic vibration and buckling analysis of horizontal rectangular plates resting on Pasternak foundation and subjected to linearly varying in-plane loads is investigated for different boundary conditions. Fluid is assumed to be inviscid and incompressible. To analyze the interaction of the Mindlin plate with the elastic foundation and fluid system, three displacement components of the plate are expressed in the Ritz method by adopting a set of static Timoshenko beam functions satisfying geometric boundary conditions. Convergence study is first carried out to confirm the stability of the present method. Then, a few comparisons are made for limited cases between present results and the available data in the literature. Finally, parametric study is conducted to highlight the effects of loading factors, fluid levels, foundation stiffness parameters, aspect ratios, thickness to width ratios and different boundary conditions on the critical buckling loads and wet natural frequencies of rectangular plates.  相似文献   
137.
Geodynamic activity in the area of West Bohemia is typified by the occurrence of earthquake swarms, Quaternary volcanism and high flux of mantle-derived CO2. The highest swarm activity occurs beneath the eastern edge of the Cheb basin, which is delineated by the NW-SE trending morphologically pronounced Mariánské Lázn?? Fault (MLF) controlling the formation of the basin. The previous trenching survey across the MLF zone has identified several fault strands with possible Quaternary activity. In this paper we present the results of the geophysical survey focused to trace the faults signatures in geophysical sections and to build an image of near surface tectonics. The method of electric resistivity tomography (ERT) along two profiles parallel to the trench identified a strong resistivity contrast between the bodies of sandy gravels in the middle and conductive clayey sands to the west and weathered crystalline basement to the east. The 2-D ground penetration radar (GPR) sections show direct correlation of reflections with lithological boundaries identified in the trench. As expected, the GPR signal amplitudes increase with the resistivities found in the ERT sections. Two of the four faults identified in the trench are indicated in the resistivity and GPR sections. A 3-D GPR measurement has identified a spot of high amplitudes elongated parallel to the MLF trend, which coincides with the high resistivity body. To improve the signal-to-noise ratio of the time slices we stacked the GPR time slices within vertically homogeneous blocks. This provided a contrast image of the sand-gravel body including its boundaries in three dimensions. The detailed analysis of the 3-D GPR cube revealed additional fault that limits the highly reflective sands and appears to be offset by another younger fault. Our results suggest a complex fault pattern in the studied area, which deserves a further study.  相似文献   
138.
Excessive amounts of mineral fertilizers are unnecessarily applied to agricultural soils in Egypt to increase crop yield. The current study aims at assessing the impacts of fertilization with different mineral fertilizers for different cultivation periods on the accumulation of heavy metals in soils and plants grown thereon. In addition, human risks resulted due to the exposure to these metal ions through ingestion, and dermal routes were evaluated. Soil and plant samples were collected from several locations in El‐Behira Governorate, Egypt and their heavy metal contents were measured. The result indicated that there is a continuous accumulation of heavy metals in the soils and the plants grown thereon. Calculation of the hazard index (HI) revealed that humans, especially children, have a potential health risk for both Pb and Cd, which have levels greater than the safe level (1). Finally, the obtained results showed that the continuous application of mineral fertilizers containing high levels of heavy metals pose a potential health threat.  相似文献   
139.
The reports after major earthquakes indicate that the earthquake-induced pounding between insufficiently separated buildings may lead to significant damage or even total collapse of structures. An intensive study has recently been carried out on mitigation of pounding hazards so as to minimize the structural damages or prevent collisions at all. The aim of this paper is to investigate the effectiveness of the method when two adjacent three-storey buildings with different (substantially different) dynamic properties are connected at each storey level by link elements (springs, dashpots or viscoelastic elements). The results of the study indicate that connecting the structures by additional link elements can be very beneficial for the lighter and more flexible building. The largest decrease in the response of the structure has been obtained for links with large stiffness or damping values, which stands for the case when two buildings are fully connected and vibrate in-phase. Moreover, by comparing the effectiveness of different types of link elements, it has been confirmed that the use of viscoelastic elements reduces the peak displacement of the structure at lower stiffness and damping values comparing to the case when spring and dashpot elements are applied alone. On the other hand, the results of the study demonstrate that applying the additional link elements does not really change the response of the heavier and stiffer building. The final conclusion of the study indicates that linking two buildings allows us to reduce the in-between gap size substantially while structural pounding can be still prevented.  相似文献   
140.
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