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Nina Caf Pierre Sabatier Andrej Šmuc Nives Ogrinc Matej Dolenec William Rapuc Doris Potočnik Ulrich von Grafenstein Maja Andrič 《第四纪科学杂志》2023,38(1):107-122
Small mountain lakes are natural archives for understanding long-term natural and anthropogenic impact on the environment. This study focused on long-term (last ca. 13 000 years) vegetation changes and sedimentary processes in the catchment area of Lake Planina pri jezeru (1430 m a.s.l.) by using mineralogical, geochemical and palynological methods. Palynological results suggest that regional vegetation between 12 900 and 11 700 cal a bp was a herbaceous–forest tundra (Pinus, Artemisia, Poaceae ). Climate warming at the beginning of the Holocene (ca. 11 700 cal a bp ) caused the transition from a wetland (Cyperaceae) to an eutrophic lake with alternating anoxic (pyrite) and oxic conditions (gypsum). In addition, the surrounding area became forested (Picea, Larix, Ulmus). Fagus expanded at 10 200 cal a bp and Abies at 8200 cal a bp. Between 7500 and 4300 cal a bp , human impact on the environment was barely noticeable and mostly limited to grazing. During 4300–430 cal a bp human impact became more evident and gradually increased. The greatest influence was observed from 430 cal a bp onwards, when excessive exploitation of the surrounding area (logging and grazing) severely eutrophicated the lake. 相似文献
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The ability of a nested model to accurately simulate the subarctic climate is studied here. Two issues have been investigated: Model??s internal variability (IV) and the impact of domain size (DS). For this purpose we combine the ??perfect model?? approach, Big-Brother Experiment (BBE) (Denis et al. in Clim Dyn 18:627?C646, 2002) with the ensemble of simulations. The advantage of this framework is the possibility to study small-scale climate features that constitute the main added value of RCM. The effects of the DS on result were studied by employing two Little-Brother (LB) domain sizes. IV has been evaluated by introducing small differences in initial conditions in an ensemble of 20 simulations over each LB. Results confirm previous findings that the IV is more important over the larger domain of integration. The temporal evolution over two domain sizes is rather different and depends strongly on the synoptic situation. Small-scales solution over the larger domain diverges freely from the boundary forcing in some periods. Over the smaller domain, the amplitude of small-scale transient eddies is systematically underestimated, especially at higher altitude characterized by the strongest winds along the storm tracks. Over the larger domain, the amplitude of small-scale transient eddies is better represented. However, the weaker control by the lateral boundaries over the larger domain results in solutions with large internal variability. As a result, the ensemble average strongly underestimates the transient-eddy variance due to partial destructive interference of individual ensemble member solutions. 相似文献
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Hilde De Clercq Maja Jovanović Kirsten Linnow Michael Steiger 《Environmental Earth Sciences》2013,69(5):1751-1761
The behaviour of two types of limestones having a different porosity, Maastricht and Euville limestone, laden with aqueous solutions of equimolar mixtures of sodium sulphate/sodium nitrate or sodium sulphate/potassium sulphate was investigated. At 50 % RH, the efflorescences on Maastricht samples during the first 30 h of drying consisted of similar amounts of thenardite and darapskite in case of an equimolar mixture of sodium sulphate/sodium nitrate while those on Euville samples under the same conditions contained mainly darapskite. After drying at 20 °C and 85 % RH, thenardite, formed through the precipitation and dehydration of mirabilite, was mostly detected in the efflorescences on both Maastricht and Euville samples. Re-wetting by increasing the RH from 50 to 85 % resulted in substantial damage on Maastricht stone laden with an equimolar mixture of sodium sulphate/sodium nitrate as a consequence of high supersaturation of mirabilite. In case of a contamination with equimolar amounts of sodium sulphate and potassium sulphate, the efflorescence on both limestones during drying at 50 % RH contained predominantly aphthitalite. The observed crystallisation behaviour is compared to the theoretical behaviour. The results indicate a strong influence of stone properties on the crystallisation behaviour of salt mixtures. 相似文献
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Darka Marković Bojan Jokić Zoran Šaponjić Branislav Potkonjak Petar Jovančić Maja Radetić 《洁净——土壤、空气、水》2013,41(10):1002-1009
This paper discusses the possibility of immobilization of TiO2 nanoparticles onto recycled wool‐based nonwoven material, which can be utilized for removal of dyes from wastewater. The photocatalytic activity of TiO2 nanoparticles deposited on the nonwoven material was evaluated in the aqueous solution of direct dye C.I. Direct Blue 78 under the UV illumination. Nonwoven material modified with TiO2 nanoparticles provides complete removal of dye from the solution already after 4–6 h of UV illumination. However, photodegradation of the dye adsorbed on the nonwoven material was obtained within 24 h of UV illumination. The rate of dye adsorption and photodegradation depends on the amount of deposited TiO2 nanoparticles. The increase of initial dye concentration induced decrease in photocatalytic efficiency of immobilized TiO2 nanoparticles. The highest photodegradation rate was achieved in acidic conditions. Elevated temperatures positively affected the removal of dye from solution. Photocatalytic activity of TiO2 nanoparticles deposited on nonwoven material was preserved after three photodegradation cycles. 相似文献
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Maja I. Wegmann Ulrich Riller Fernando D. Hongn Johannes Glodny Onno Oncken 《Journal of South American Earth Sciences》2008,26(1):78-90
The Cerro Durazno Pluton belongs to a suite of Paleozoic granitoid intrusions in NW-Argentina, that are central for understanding the tectonic setting of the western margin of Gondwana in Ordovician and Silurian times. The pluton and its host rocks were tectonically overprinted by metamorphic mineral shape fabrics formed under middle greenschist-facies metamorphic conditions and associated with the nearby Agua Rosada Shear Zone. Kinematic analysis of the shear zone based on the geometric relationship between individual segments of the shear plane and principal axes of mineral fabric ellipsoids indicates reverse-sense of shear with a minor component of left-lateral displacement. This is compatible with the kinematics of other ductile deformation zones in this area, collectively forming a network, which accomplished orogen-parallel extension in addition to vertical thickening. Using the Rb–Sr isotopic system, an undeformed pegmatite dike of the Cerro Durazno Pluton was dated at 455.8 ± 3.6 Ma and mineral fabrics of the Agua Rosada Shear Zone formed at middle greenschist-facies metamorphism gave deformation ages of 437.0 ± 3.8 Ma and 428.4 ± 4.5 Ma. Thus, tectonic overprint at low metamorphic grade occurred about 20–30 Ma after terminal magmatism in the Cerro Durazno area. Our data from the Cerro Durazno area and regional considerations suggest that the western margin of Gondwana was characterized by orogen-parallel extension in addition to crustal thickening as well as episodes of magmatism and ductile deformation that varied greatly in time and space. 相似文献
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A spectrophotometric procedure for the determination of aldehydes was optimized for use in seawater, it involves the sequential reaction of aldehydes with 3-methyl-2-benzothiazolinone hydrazone hydrochloride (MBTH) and FeCl3 to produce a colored compound which is soluble in 50% acetone. The standard curve obeyed Beer's law to 90 μM formaldehyde in 0.7 m NaCl. The molar absorptivity of 21 800 absorbance units μM?1 cm?1 at 635 nm was not affected by changes in salinity. The limit of detection was 180 nM HCHO l?1 when a pathlength of 1 cm was used, and 72 nM HCHO l?1 when a pathlength of 5 cm was used.The MBTH procedure was used to compare formaldehyde production in cultures of the marine methanotroph, Methylomonas pelagica, growing on methane or methanol. The average rate of formaldehyde production, normalized to cell number, was almost 20 times greater in cultures grown on methanol than in cultures grown on methane.A depth profile of aldehyde concentrations from a station in the Peru upwelling region (10°S, 79°W) showed one peak in the oxygen gradient in the photic zone (80 m), two in the oxygen minimum (200 and 300 m), and one in the oxygen gradient below the minimum (800m). Aldehyde concentrations ranged from 0.6 to 8.8 μM formaldehyde equivalents l?1. Except for the maxima where the aldehydes account for 13–15% of expected DOC concentrations, the background level of aldehydes was approximately 1% of DOC. 相似文献
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Snežana S. Nenadović Ljiljana M. Kljajević Maja A. Nešić Marijana Ž. Petković Katarina V. Trivunac Vladimir B. Pavlović 《Environmental Earth Sciences》2017,76(2):79
The paper presents chemical and structural analysis of geopolymer materials which are obtained by alkali-activated calcined clay (metakaolin) originated from Serbia under strictly defined conditions. Characterization of the metakaolin and geopolymers molecular structure has been done using X-ray diffraction, scanning electron microscope, Fourier transform infrared spectroscopy and matrix-assisted laser desorption ionization time-of-flight mass spectrometry. The paper presents the possibility of obtaining geopolymer structure and differences in chemical and structural characterization of these materials taking into account the concentration of NaOH as a variable parameter. The results of MALDI analysis of metakaolin and synthesized geopolymer structures using various matrix system: 2,4,6 trihydroxyacetophenone (THAP), α-cyano-4-hydroxycinnamic, 2,6 dihydroxyacetophenone and laser desorption/ionization, have shown that THAP matrix is the most appropriate for analysing these aluminosilicate materials. 相似文献
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P. G. Brown P. J. A. McCausland A. R. Hildebrand L. T. J. Hanton L. M. Eckart H. Busemann D. Krietsch C. Maden K. Welten M. W. Caffee M. Laubenstein D. Vida F. Ciceri E. Silber C. D. K. Herd P. Hill H. Devillepoix Eleanor K. Sansom Martin Cupák Seamus Anderson R. L. Flemming A. J. Nelson M. Mazur D. E. Moser W. J. Cooke D. Hladiuk Barbara Malečić Maja Telišman Prtenjak R. Nowell The Golden Meteorite Consortium 《Meteoritics & planetary science》2023,58(12):1773-1807