Gaschromatographische Bestimmung von polychlorierten Biphenylen in Wasser nach Headspace-Festphasenmikroextraktion     

J. Koch  P. Vlker 《洁净——土壤、空气、水》1997,25(4):179-190

Gas-chromatographic Determination of Polychlorinated Biphenyls in Water after Headspace Solid-phase Microextraction Headspace-analytical techniques are usually applied to the determination of easily volatile substances in water, whereas semivolatiles are generally isolated by liquid-liquid or solid-phase extraction. In the present paper, a method is presented for isolating high boiling polychlorinated biphenyls (PCB) using headspace solid-phase microextraction at elevated temperature. In spite of their low vapor pressure, the analytes are adsorbed very efficiently on a poly-dimethylsiloxane-coated fiber. Thus, in combination with GC/ECD, a very simple and sensitive solventless determination of PCB is accomplished. Using the simplest possible standard conditions, limits of determination in the lowest nanogram-per-liter range are achieved. Further increased sensitivity down to the ppq (parts per quadrillion) range is possible by stirring and increasing the sample volume and adsorption time. Moderate matrix effects have been observed in some surface and groundwaters.  相似文献   

探测冰盖和多年冻土层的融冰探头研发     

Norbert I. K 《冰川冻土》2004,26(Z1):310-318

The exploration of ice sheets by melting vertical holes into the ground has some tradition in terrestrial glaciology. Such probes have been used since the 1960's to investigate the vertical structure of the ice in Greenland and Antarctica and in alpine glaciers. In this paper we look into the possibility to develop similar devices for use on extraterrestrial icy bodies, like e.g. the polar areas on Mars or the icy satellites of the outer solar system. We report on some basic experiments performed in the cryo-vacuum laboratory of the Space Research Institute of the Austrian Academy of Sciences, Graz. In these experiments the penetration of a simple melting probe into compact and porous water ice (with a snow-like texture) was monitored, both under vacuum conditions and under air pressure. The observed penetration speeds for a given power supply are compared with a simple mathematical model. We conclude that a miniature melting probe with small overall dimensions and a reasonable power demand could well be part of the payload of a future planetary mission, for example to the poles of Mars. Such missions are currently under discussion in several space agencies. Moreover such probes could also e? ectively be used in terrestrial environments. A possible design is presented at the end of the paper.  相似文献   

内蒙古温带半干旱羊草草原N₂O通量及其影响因素   总被引：5，自引：2，他引：5  

董云社  齐玉春  Manfred Domroes  耿元波  杨小红  刘立新  刘杏认 《地理研究》2004,23(6):776-784

利用静态箱 -气相色谱法于 2 0 0 1～ 2 0 0 3年对内蒙古锡林河流域羊草草原进行了连续 2年的野外定位试验 ,获得羊草草原原状群落与土壤N2 O年排放通量分别在 3 91～ 4 71μgm- 2h- 1以及 5 5 0～ 10 0 3μgm- 2 h- 1范围内变动 ,证明内蒙古温带半干旱羊草草原生态系统是大气中N2 O的源 ;系统分析了羊草草原N2 O通量的季节变化、源汇特征以及关键的环境因子对草地N2 O通量的影响等 ,建立了N2 O通量与环境因子间的回归方程 ;并利用两年连续完整的观测数据对羊草草原N2 O年排放量进行了估算  相似文献   

Determining the maximum degree of harmonic coefficients in geopotential models by Monte Carlo methods   总被引：1，自引：0，他引：1  

K. R. Koch r 《Studia Geophysica et Geodaetica》2005,49(3):259-275

Random errors for the harmonic coefficients of a geopotential model are generated from the matrix of normal equations by a parallel computer applying the Gibbs sampler. This leads to random values for the harmonic coefficients. They are transformed by nonlinear, quadratic transformations to random values for the square roots of degree variances, of mean squares of geoid undulations and gravity anomalies. The expected values of these quantities are not equal to the values of these quantities computed by the estimated harmonic coefficients, due to correlations and errors in the estimation. By hypothesis tests estimated harmonic coefficients distorted by correlations and errors are detected. Applying the tests to the geopotential model ITG-CHAMP01 of the Institute of Theoretical Geodesy in Bonn it is concluded that above the degree 62 the harmonic coefficients cannot add any information to the geopotential model.  相似文献   

Molecular formulae of marine and terrigenous dissolved organic matter detected by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry     

Boris P. Koch  Matthias Witt  Thorsten Dittmar 《Geochimica et cosmochimica acta》2005,69(13):3299-3308

The chemical structure of refractory marine dissolved organic matter (DOM) is still largely unknown. Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR-MS) was used to resolve the complex mixtures of DOM and provide valuable information on elemental compositions on a molecular scale. We characterized and compared DOM from two sharply contrasting aquatic environments, algal-derived DOM from the Weddell Sea (Antarctica) and terrigenous DOM from pore water of a tropical mangrove area in northern Brazil. Several thousand molecular formulas in the mass range of 300-600 Da were identified and reproduced in element ratio plots. On the basis of molecular elemental composition and double-bond equivalents (DBE) we calculated an average composition for marine DOM. O/C ratios in the marine samples were lower (0.36 ± 0.01) than in the mangrove pore-water sample (0.42). A small proportion of chemical formulas with higher molecular mass in the marine samples were characterized by very low O/C and H/C ratios probably reflecting amphiphilic properties. The average number of unsaturations in the marine samples was surprisingly high (DBE = 9.9; mangrove pore water: DBE = 9.4) most likely due to a significant contribution of carbonyl carbon. There was no significant difference in elemental composition between surface and deep-water DOM in the Weddell Sea. Although there were some molecules with unique marine elemental composition, there was a conspicuous degree of similarity between the terrigenous and algal-derived end members. Approximately one third of the molecular formulas were present in all marine as well as in the mangrove samples. We infer that different forms of microbial degradation ultimately lead to similar structural features that are intrinsically refractory, independent of the source of the organic matter and the environmental conditions where degradation took place.  相似文献   

Anthropogenic particle dispersions in topsoils of the Middle Nile Delta: a preliminary study on the contamination around industrial and commercial areas in Egypt     

Atef M. Abu Khatita  Helga de Wall  Roman Koch 《Environmental Earth Sciences》2016,75(3):264

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Luminescence dating of ice‐marginal deposits in northern Germany: evidence for repeated glaciations during the Middle Pleistocene (MIS 12 to MIS 6)          下载免费PDF全文

Julia Roskosch  Jutta Winsemann  Ulrich Polom  Christian Brandes  Sumiko Tsukamoto  Axel Weitkamp  Werner A. Bartholomäus  Dierk Henningsen  Manfred Frechen 《Boreas: An International Journal of Quaternary Research》2015,44(1):103-126

The exact number, extent and chronology of the Middle Pleistocene Elsterian and Saalian glaciations in northern Central Europe are still controversial. This study presents new luminescence data from Middle Pleistocene ice‐marginal deposits in northern Germany, giving evidence for repeated glaciations during the Middle Pleistocene (MIS 12 to MIS 6). The study area is located in the Leine valley south of the North German Lowlands. The data set includes digital elevation models, high‐resolution shear wave seismic profiles, outcrop and borehole data integrated into a 3D subsurface model to reconstruct the bedrock relief surface. For numerical age determination, we performed luminescence dating on 12 ice‐marginal and two fluvial samples. Luminescence ages of ice‐marginal deposits point to at least two ice advances during MIS 12 and MIS 10 with ages ranging from 461±34 to 421±25 ka and from 376±27 to 337±21 ka. The bedrock relief model and different generations of striations indicate that the older ice advance came from the north and the younger one from the northeast. During rapid ice‐margin retreat, subglacial overdeepenings were filled with glaciolacustrine deposits, partly rich in re‐worked Tertiary lignite and amber. During MIS 8 and MIS 6, the study area may have been affected by two ice advances. Luminescence ages of glaciolacustrine delta deposits point to a deposition during MIS 8 or early MIS 6, and late MIS 6 (250±20 to 161±10 ka). The maximum extent of both the Elsterian (MIS 12 and MIS 10) and Saalian glaciations (MIS 8? and MIS 6) approximately reached the same position in the Leine valley and was probably controlled by the formation of deep proglacial lakes in front of the ice sheets, preventing a further southward advance.  相似文献   

Segmentation and kinematics of the North America‐Caribbean plate boundary offshore Hispaniola          下载免费PDF全文

Sylvie Leroy  Nadine Ellouz‐Zimmermann  Jordane Corbeau  Frédérique Rolandone  Bernard Mercier de Lépinay  Bertrand Meyer  Roberte Momplaisir  José‐Luis Granja Bruña  Anne Battani  Céline Baurion  Evgueni Burov  Valérie Clouard  Rémy Deschamps  Christian Gorini  Youri Hamon  Manfred Lafosse  Jottin Leonel  Laetitia Le Pourhiet  Pilar Llanes Estrada  Nicolas Loget  Francis Lucazeau  Daniel Pillot  Jeffrey Poort  Kevin R. Tankoo  José‐Luis Cuevas  José‐Fernando Alcaide  Claude Jean Poix  Alfonso Muñoz‐Martin  Serge Mitton  Yamil Rodriguez  Julien Schmitz  Leonardo Seeber  Andres Carbo‐Gorosabel  Santiago Muñoz 《地学学报》2015,27(6):467-478

We explored the submarine portions of the Enriquillo–Plantain Garden Fault zone (EPGFZ) and the Septentrional–Oriente Fault zone (SOFZ) along the Northern Caribbean plate boundary using high‐resolution multibeam echo‐sounding and shallow seismic reflection. The bathymetric data shed light on poorly documented or previously unknown submarine fault zones running over 200 km between Haiti and Jamaica (EPGFZ) and 300 km between the Dominican Republic and Cuba (SOFZ). The primary plate‐boundary structures are a series of strike‐slip fault segments associated with pressure ridges, restraining bends, step overs and dogleg offsets indicating very active tectonics. Several distinct segments 50–100 km long cut across pre‐existing structures inherited from former tectonic regimes or bypass recent morphologies formed under the current strike‐slip regime. Along the most recent trace of the SOFZ, we measured a strike‐slip offset of 16.5 km, which indicates steady activity for the past ~1.8 Ma if its current GPS‐derived motion of 9.8 ± 2 mm a^?1 has remained stable during the entire Quaternary.  相似文献   

Mauer – the type site of Homo heidelbergensis: palaeoenvironment and age     

Günther A. Wagner  Lutz Christian Maul  Manfred Löscher  H. Dieter Schreiber 《Quaternary Science Reviews》2011,30(11-12):1464-1473

The mandible of Homo heidelbergensis was found 1907 in the sand pit Grafenrain at Mauer in coarse fluvial sands 24 m below the surface, deposited in a former course of the Neckar River. These ‘Mauer sands’ are overlain by a series of glacial-climate loess deposits with intercalated interglacial palaeosols, which can be correlated with Quaternary climate history, thus indicating an early Middle Pleistocene age for H. heidelbergensis. The ‘Mauer sands’ are famous for their rather rich mammal fauna, which clearly indicates interglacial climate conditions. The faunal evidence – in particular the micromammals – place the ‘Mauer sands’ into MIS 15 or MIS 13 although most stratigraphic arguments favour correlation to MIS 15 and therefore to an age of ca 600 ka.  相似文献   

Loose Space: Possibility and Diversity in Urban Life – Edited by Karen A. Franck and Quentin Stevens     

Regan Koch 《New Zealand geographer》2010,66(2):174-176

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