Hydrocarbon contamination in mussels from Guanabara Bay     

Azevedo LA  de Andrade Brüning IM  Moreira I 《Marine pollution bulletin》2004,49(11-12):1120-1122

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Plate kinematics, origin and tectonic emplacement of supra-subduction ophiolites in SE Asia   总被引：2，自引：0，他引：2  

Manuel Pubellier  Christophe Monnier  Ren Maury  R. Tamayo 《Tectonophysics》2004,392(1-4):9

A unique feature of the Circum Pacific orogenic belts is the occurrence of ophiolitic bodies of various sizes, most of which display petrological and geochemical characteristics typical of supra-subduction zone oceanic crust. In SE Asia, a majority of the ophiolites appear to have originated at convergent margins, and specifically in backarc or island arc settings, which evolved either along the edge of the Sunda (Eurasia) and Australian cratons, or within the Philippine Sea Plate. These ophiolites were later accreted to continental margins during the Tertiary. Because of fast relative plate velocities, tectonic regimes at the active margins of these three plates also changed rapidly. Strain partitioning associated with oblique convergence caused arc-trench systems to move further away from the locus of their accretion. We distinguish “relatively autochthonous ophiolites” resulting from the shortening of marginal basins such as the present-day South China Sea or the Coral Sea, and “highly displaced ophiolites” developed in oblique convergent margins, where they were dismantled, transported and locally severely sheared during final docking. In peri-cratonic mobile belts (i.e. the Philippine Mobile Belt) we find a series of oceanic basins which have been slightly deformed and uplifted. Varying lithologies and geochemical compositions of tectonic units in these basins, as well as their age discrepancies, suggest important displacements along major wrench faults.We have used plate tectonic reconstructions to restore the former backarc basins and island arcs characterized by known petro-geochemical data to their original location and their former tectonic settings. Some of the ophiolites occurring in front of the Sunda plate represent supra-subduction zone basins formed along the Australian Craton margin during the Mesozoic. The Philippine Sea Basin, the Huatung basin south of Taiwan, and composite ophiolitic basements of the Philippines and Halmahera may represent remnants of such marginal basins. The portion of the Philippine Sea Plate carrying the Taiwan–Philippine arc and its composite ophiolitic/continental crustal basement might have actually originated in a different setting, closer to that of the Papua New Guinea Ophiolite, and then have been displaced rapidly as a result of shearing associated with fast oblique convergence.  相似文献   

Generalized thermostatistics and wavelet analysis of solar wind and proton density variability     

Maurício Jos Alves Bolzan  Reinaldo Roberto Rosa  Fernando Manuel Ramos  Paulo Roberto Fagundes  Yogeshwar Sahai 《Journal of Atmospheric and Solar》2005,67(17-18):1843

In this paper, we analyze the probability density function (PDF) of solar wind velocity and proton density, based on generalized thermostatistics (GT) approach, comparing theoretical results with observational data. The time-series analyzed were obtained from the SOHO satellite mission where measurements were sampled every hour. We present in the investigations data for two years of different solar activity: (a) moderate activity (MA) period (1997) and (b) high activity (HA) period (2000). For the MA period, the results show good agreement between experimental data and GT model. For the HA period, the agreement between experimental and theoretical PDFs was fairly good, but some distortions were observed, probably due to intermittent characteristics of turbulent processes. As a complementary analysis, the global wavelet spectrum (GWS) was obtained, allowing the characterization of the predominant temporal variability scales for both periods and the stochastic aspects of the nonlinear solar wind variability are discussed.  相似文献   

Petrogenesis of the Eocene and Mio–Pliocene alkaline basaltic magmatism in Meseta Chile Chico, southern Patagonia, Chile: Evidence for the participation of two slab windows     

Felipe Espinoza  Diego Morata  Ewan Pelleter  Ren  C. Maury  Manuel Su  rez  Yves Lagabrielle  Mireille Polv    Herv  Bellon  Joseph Cotten  Rita De la Cruz  Christelle Guivel 《Lithos》2005,82(3-4):315-343

The Meseta Chile Chico (MCC, 46.4°S) is the westernmost exposure of Eocene (lower basaltic sequence, LBS; 55–40 Ma, K–Ar ages) and Mio–Pliocene (upper basaltic sequence, UBS; 16–4 Ma, K–Ar ages) flood basalt volcanism in Patagonia. The MCC is located south of the Lago General Carrera-Buenos Aires (LGCBA), southeast from the present day Chile Triple Junction (CTJ), east of the actual volcanic gap between Southern South Volcanic Zone and Austral Volcanic Zone (SSVZ and AVZ, respectively) and just above the inferred location of the South Chile Ridge segment subducted at 6 Ma (SCR-1). Erupted products consist of mainly ne-normative olivine basalt with minor hy-normative tholeiites basalt, trachybasalt and basanite. MCC lavas are alkaline (42.7–53.1 wt.% SiO₂, 3–8 wt.% Na₂O+K₂O) and relatively primitive (Ni: 133–360 ppm, Cr: 161–193 ppm, Co: 35–72 ppm, 4–16.5 MgO wt.%). They have a marked OIB-like signature, as shown by their isotopic compositions (⁸⁷Sr/⁸⁶Sr_o=0.70311–0.70414 and εNd=+4.7–+5.1) and their incompatible trace elements ratios (Ba/La=10–20, La/Nb=0.46–1.09, Ce/Pb=15.52–27.5, Sr/La<25), reflecting deep mantle origin. UBS-primitive lavas have characteristics similar to those of the Eocene LBS basalts, while UBS-intermediate lavas show geochemical imprints (La/Nb>1, Sr/La>25, low Ce/Pb, Nb/U) compatible with contamination by arc/slab-derived and/or crustal components. We propose that the genesis and extrusion of magmas is related to the opening of two slab windows due to the subduction of two active ridge segments beneath Patagonia during Eocene and Mio–Pliocene.  相似文献   

A diffusion model for the development of a boundary layer in lakes   总被引：1，自引：0，他引：1  

Frank Peeters  Gabriel Piepke  Manuel Gloor 《Aquatic Sciences - Research Across Boundaries》1997,59(2):95-114

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Stratospheric ozone variability near the IMF sector boundary     

Jan Laštovička  Manuel Gil  Reviewer L. Křivský 《Studia Geophysica et Geodaetica》1988,32(3):313-317

Summary We search for the effects of the interplanetary magnetic field (IMF) sector boundary crossing (SBC) in upper stratospheric ozone. The SBUV data (Nimbus-7) at the 10, 3 and 1 hPa levels are analysed for latitudes 45° N and 55° N for winters of the period December 1979 to December 1982. An effect of the IMF SBC wos only found at the 10 hPa level. These first results concerning the IMF SBC effect in upper stratospheric ozone are rather preliminary.

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Preliminary investigations on the occurrence of diagenetic dolomite in surface sediments of Lagoa Vermelha,Brazil     

I. Moreira  R. Patchineelam Dr.  A. de Luca Rebello 《GeoJournal》1987,14(3):357-360

Studies on the precipitation of carbonates in a hypersaline lagoon revealed the presence of diagenetic dolomite at very shallow sediment depths. The relation of magnesium to calcium concentration both in interstitial and surface waters are within the range predicted in the literature for this occurence. Lower values encountered in some samples were linked to interactions with fresh groundwater.  相似文献   

Uptake of dissolved Cd by biogenic and abiogenic aragonite: a comparison with sorption onto calcite   总被引：3，自引：0，他引：3  

Manuel Prieto  Pablo Cubillas 《Geochimica et cosmochimica acta》2003,67(20):3859-3869

The uptake of Cd²⁺ by aragonite and calcite is investigated by combining macroscopic measurements with some qualitative sorption experiments performed in a hydrogel medium. Both biogenic and abiogenic aragonites were studied in order to evaluate the process on materials with different textures. Assuming that sorption occurs by surface precipitation of metal-bearing solids, the gel produces a drastic decrease in the nucleation density, which allows for the precipitation of crystallites that are large enough to be analysed by scanning electron microscopy and characterized by glancing-incidence X-ray techniques. The macroscopic study reveals that aragonite is a powerful sorbent for cadmium in aqueous environments. Microscopic observations indicate that cadmium is sorbed onto aragonite by surface precipitation of (Cd, Ca)CO₃ solid solutions with a calcite-type structure. The precipitating individuals grow randomly oriented on the surface to reach sizes in the micrometre range. As a consequence, the concentration of cadmium in the aqueous solution decreases dramatically to values controlled by the low solubility of the cadmium-rich end member. This mechanism involves simultaneous dissolution-crystallization and is the same for both abiogenic and biogenic aragonites, the only difference being a result of the higher specific surface area of the biogenic starting material. Long-term uptake of cadmium by calcite occurs through a similar dissolution-crystallization mechanism, the final outcome being virtually the same, that is, surface precipitation of (Cd,Ca)CO₃ solid solutions. In this case, however, substrate and precipitate are isostructural and the process occurs by oriented overgrowth of thin lamellar crystallites, which spread to quickly cover the surface by a layer a few nanometers thick. This epitaxial layer armors the substrate from further dissolution, so that the process stops when only a small amount of cadmium has been removed from the fluid. As a result, the “sorption capacity” of calcite is considerably lower than that of aragonite. The study illustrates reaction pathways and “partial” equilibrium endpoints in surface-precipitation processes involving solid solutions.  相似文献   

Vesiculation and vesicle loss in mid-ocean ridge basalt glasses: He, Ne, Ar elemental fractionation and pressure influence     

Philippe Sarda  Manuel Moreira 《Geochimica et cosmochimica acta》2002,66(8):1449-1458

Sarda and Graham (1990) proposed that in mid-ocean ridge basalts (MORBs), degassing occurs through equilibrium vesiculation followed by various extents of vesicle loss. This model predicts that in a bulk sample of MORB glass with vesicles, the rare gases represent a binary mixture between a vesicle component and a component dissolved in the melt. As vesiculation is expected to produce very different rare gas concentrations and elemental ratios in gas and melt, binary mixing systematics should be recorded in the MORB rare gas abundance data. Indeed, a large range of ⁴He/⁴⁰Ar∗ ratios was known to exist, but these binary mixing systematics remained elusive because helium was used as a proxy for rare gas abundance because helium is not affected by air addition. Here we show that using Ar instead of He, the ⁴He/⁴⁰Ar∗ ratio is higher where the Ar concentration is lower, as expected from simple binary mixing systematics.Taking advantage of the growing Ne database, we further show that the predicted binary mixing is recorded by the He-Ar and He-Ne couples, provided He concentration is not used to trace vesicle abundance. This is because a significant part of helium remains in the melt due to its higher solubility. In contrast, Ar or Ne concentrations, which can both be corrected for air addition, clearly trace vesicles and yield binary mixing patterns that hold for ridges worldwide. The model of vesiculation and vesicle loss thereby finds geochemical support in the rare gas abundance data.The He-Ne-Ar concentration data is best explained by assuming the ratio of helium to neon or argon solubility is about 5 to 15 times higher than values measured in 1 bar laboratory experiments, due to higher He and lower Ne and Ar solubilities. We propose that this is a pressure effect, and vesiculation mainly occurs during magma ascent in the mantle after melting.  相似文献   

Water organisation at the solid–aqueous solution interfaceOrganisation de l'eau à l'interface solide–solution aqueuse     

Laurent J. Michot  Frédéric Villiéras  Michèle François  Isabelle Bihannic  Manuel Pelletier  Jean-Maurice Cases 《Comptes Rendus Geoscience》2002,334(9):611-631

The aim of this review is to examine the present knowledge about water structure close to an interface or confined in porous spaces. First, the structure of liquid water is briefly described. Though its understanding remains incomplete, it appears that it is largely dominated by the hydrogen bond network and its dynamical evolution. The presence of any ‘foreign’ substance in water perturbs such a structure by changing at least locally the hydrogen bond network. For this reason, the presence of a solid interface significantly modifies the structure of the first adsorbed layers. Whatever the support, it is now clearly evidenced that structural perturbations are limited to distances lower than 10–15 Å from the interface. The nature, energetic heterogeneity and hydrophilicility/hydrophobicity of the solid surface influence the arrangement of water molecules. This surface organisation must definitely be considered when studying adsorption phenomena at the solid–aqueous solution interface. The relevance of such problems to geosciences is illustrated by a few situations in which water structure plays a prominent role. To cite this article: L.J. Michot et al., C. R. Geoscience 334 (2002) 611–631.  相似文献