Chemometric analysis of <Superscript>137</Superscript>Cs activity and heavy metals distribution in the Tatras’ soil     

M. Stobiński  B. Kubica 《International Journal of Environmental Science and Technology》2017,14(6):1217-1224

The goal of the paper was to determine the activity of ¹³⁷Cs and ⁴⁰K radionuclides as well as heavy metals Zn, Cr, Pb in soil samples taken from the Tatra National Park in the south of Poland. The samples were obtained as cores (10 cm in diameter) from the top 10-cm layer of the soil. Each sample was divided into three subsamples (a, b and c), where a was the subsample closest to the surface and c was the deepest one. Activity of the radionuclides was determined by means of gamma spectrometry, while analysis of heavy metals was performed (after microwave digestion) using atomic absorption spectrometry technique. The highest activity of cesium-137 was detected (5112 ± 120 Bq kg^?1) in the “a” layer of the core with the peak concentration of cesium-137 (14,452 ± 278 Bq m^?2) in the whole soil core. The highest detected concentration of heavy metals was: Zn—52.8 ± 4.4 mg kg^?1, Pb—260.1 ± 9.4 mg kg^?1, Cr—52.8 ± 4.4 mg kg^?1, respectively. Cluster analysis and principal component analysis were used to examine the obtained data. Application of statistical analysis tools allowed specifying the interdependencies between the examined variables.  相似文献   

The use of selected research methods to describe the pore space of dolomite from copper ore mine,Poland     

Anna Pajdak  Katarzyna Godyń  Mateusz Kudasik  Tomasz Murzyn 《Environmental Earth Sciences》2017,76(11):389

Basic knowledge of the characteristics of copper-bearing rock such as dolomite is essential to locate those areas of the deposit which have different structural and textural properties. Those regions can be important in terms of the assessment of the possibilities of gas accumulating in them as well as in terms of gasogeodynamic hazard. To better understand those threats, it is necessary to locate, monitor and analyse those areas in detail. This article characterises the structural and textural parameters of dolomite from the Polkowice–Sieroszowice copper mine in Poland. The study involved five samples from various areas of the mine. A number of research methods were selected. Reflected and transmitted light microscopy (MS), computer microtomography (Micro-CT), gas adsorption porosimetry (LPNA), mercury porosimetry (MIP), helium and quasi-fluid pycnometry (Pycno. He, DryFlo). Each of the methods examined a different scope of the pore size, which enabled to achieve a full view of the porous nature of those rocks. We determined their porosity (open, closed, total), surface area as well as mean size and volume of the pores. Also, we studied the character and the pore size distribution from a few nm to a few mm. Comprehensive dolomite properties analyses showed that these rocks are characterised by high structural variability. They have mesopores and macropores but few micropores. The analyses presented in this paper are determined by a large petrographic diversity of the deposits containing dolomite. This article is an example of a comprehensive approach to the rock analysis in copper ore mines.  相似文献   

Gravimetric monitoring of the first field‐wide steam injection in a fractured carbonate field in Oman – a feasibility study          下载免费PDF全文

Marcin Glegola  Pavel Ditmar  Femke Vossepoel  Rob Arts  Fahad Al‐Kindy  Roland Klees 《Geophysical Prospecting》2015,63(5):1256-1271

Gas‐Oil Gravity Drainage is to be enhanced by steam injection in a highly fractured, low permeability carbonate field in Oman. Following a successful pilot, field‐wide steam injection is being implemented, first of this type in the world. A dedicated monitoring program has been designed to track changes in the reservoir. Various observations are to be acquired, including, surface deformation, temperature measurements, microseismic, well logs, pressure and saturation measurements to monitor the reservoir. Because significant changes in the reservoir density are expected, time‐lapse gravimetry is also being considered. In this paper we investigate the feasibility of gravimetric monitoring of the thermally enhanced gravity drainage process at the carbonate field in Oman. For this purpose, forward gravity modelling is performed. Based on field groundwater measurements, the estimates of the hydrological signal are considered and it is investigated under what conditions the groundwater influences can be minimized. Using regularized inversion of synthetic gravity data, we analyse the achievable accuracy of heat‐front position estimates. In case of large groundwater variations at the field, the gravity observations can be significantly affected and, consequently, the accuracy of heat‐front monitoring can be deteriorated. We show that, by applying gravity corrections based on local observations of groundwater, the hydrological influences can to a large extent be reduced and the accuracy of estimates can be improved. We conclude that gravimetric monitoring of the heat‐front evolution has a great potential.  相似文献   

Semiannual and annual oscillations of sea level and their impact on asymmetry between El Niño and La Niña episodes     

Małgorzata Świerczyńska  Tomasz Niedzielski  Wiesław Kosek 《Studia Geophysica et Geodaetica》2014,58(2):302-325

The purpose of this paper is twofold. First, we demonstrate that the asymmetry between El Niño and La Niña events recorded in sea level variation occurs only during extreme episodes of El Niño/Southern Oscillation. Second, we explain that the asymmetry is controlled by certain regular cycles which have time-variable amplitudes. Gridded maps of sea level anomaly that form a spatial-temporal time series (spatial resolution: 1° × 1°, sampling interval: 1 week) spanning the time interval from 14/10/1993 to 18/04/2012 were used. We examined those time series and found that certain regular harmonic signals (periods: 365, 182, 120, 90 and 62 days) are dominant terms of their temporal variability. By subtracting those oscillations from sea level anomaly data, residuals were determined. Using skewness and kurtosis as measures of asymmetry and nonlinearity — after adopting 10-year moving window — we found that the extreme El Niño 1997/1998 has been a dominant driving force of the asymmetry and nonlinearity of El Niño/Southern Oscillation since the end of 1993. In order to detect residual signals that are responsible for the asymmetry, we applied the Fourier Transform Band Pass Filter and found that there are two important oscillations remaining in the residual sea level anomaly data, i.e. the annual and semiannual ones with time-varying amplitudes. We hypothesize that temporarily uneven amplitudes have meaningful impact on the aforementioned asymmetry.  相似文献   

Adsorption Kinetics of Acid Dye Acid Red 88 onto Magnetic Multi‐Walled Carbon Nanotubes‐Fe3C Nanocomposite          下载免费PDF全文

Wojciech Konicki  Iwona Pełech  Ewa Mijowska  Izabella Jasińska 《洁净——土壤、空气、水》2014,42(3):284-294

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Lidar observations of volcanic dust over Polish Polar Station at Hornsund after eruptions of Eyjafjallajökull and Grímsvötn     

Grzegorz Karasiński  Michał Posyniak  Magdalena Bloch  Piotr Sobolewski  Łukasz Małarzewski  Jakub Soroka 《Acta Geophysica》2014,62(2):316-339

Two significant volcanic eruptions, i.e., Eyjafjallajökull (April–May 2010) and Grímsvötn (May 2011) took place recently in Iceland. Within a few days after eruptions, layers of high aerosol concentration have been observed by multiwavelength lidar of the Polish Polar Station at Hornsund, Svalbard. Measurements of the aerosol’s optical properties indicated a possible presence of volcanic ash transported over the Station. The latter presumption was confirmed by the computed backward trajectories of air masses, showing their paths passing over the location of volcanoes.  相似文献   

Assimilation and diffusion during xenolith-magma interaction: a case study of the Variscan Karkonosze Granite, Bohemian Massif     

Marta Adamuszek  Timm John  Marcin Dabrowski  Yuri Y. Podladchikov  Ralf Gertisser 《Mineralogy and Petrology》2009,97(3-4):203-222

Magmatic enclaves from the Rudolfov quarry near Liberec (Czech Republic) are interpreted to represent remnants of lamprophyric melt that intruded the Karkonosze granite at a stage at which the granite was not fully solidified. Based on the observation that larger enclaves are generally more circular than the smaller ones, we conclude that bigger blobs of mafic magma became more spherical during flow in the gravity field (sink or float). This flow is also interpreted to be responsible for the incorporation of mineral grains into the enclaves and may have facilitated the assimilation of granitic melt. Linear mixing trends on Harker diagrams for most network-forming and mainly slow-diffusing or fluid-immobile elements indicate such an assimilation process between granite and lamprophyre. In contrast, all fast-diffusing or fluid-mobile elements display scattered element distributions, implying that chemical diffusion also played a role. Pressure and temperature for this late magmatic stage are estimated at around 1 kbar and 500°C. These results suggest that two processes modified the composition of the enclaves in the Karkonosze granite: (1) assimilation (mechanical mixing) of granitic melt during the injection of the lamprophyric melt and the subsequent flow of the forming enclaves in the gravity field (responsible for the linear mixing trends) and (2) diffusion-controlled redistribution of elements between both solidifying rock types at the magmatic stage and/or due to late-stage magmatic fluids (responsible for the scattering and deviation from the linear mixing trends).  相似文献   

ECHOBASE—A portable geographic fishery research database system     

Andrzej Stepnowski  Janusz Burczyński  Marek Ostrowski  Marek Moszynski  Jacek Lenkiewicz  Andrzej Partyka 《Marine Geodesy》2013,36(3):269-280

A geographic fishery research database system (GFRDBS), called ECHOBASE, for storing and management of data on pelagic fish resources from acoustic surveys and catch samples, combined with environmental data in a geographic context, has been developed. The system constitutes a portable and inexpensive yet powerful tool for fishery research and environmental monitoring and provides on‐board data processing and mapping capabilities.

Data are acquired from an echosounder, echo signal processor, environmental profiler (CTD probe), and Global Positioning System (GPS) receiver. The electronic digitized maps (based on C‐MAP public format files) provide active on‐screen nautical charts.

The basic GFRDBS platform is a portable PC 486 machine, which is used as an on‐board data acquisition and processing tool running under MS Windows 3.1 operating environment. The system is designed around the Borland's PARADOX package, which provides a relational database for managing acoustic, catch, and environmental data. The ECHOBASE programs were written in Borland C ++ language as a Windows application.  相似文献   

TraceeElements in Leccinum scabrum mushrooms and topsoils from Kłodzka Dale in Sudety Mountains, Poland     

ZHANG Dan  ZHANG Yu  MORAWSKA Ewa  BIELAWSKI Leszek  KRASINSKA Grazyna  DREWNOWSKA Ma gorzata  PANKAVEC Sviatlana  SZYMANSKA Karolina  FALANDYSZ Jerzy 《山地科学学报》2013,10(4):621-627

In the current study, we determined concentrations and transfer rates of Ag, Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, P, Rb, Sr and Zn to Brown Birch Scaber Stalks (Leccinum scabrum) mushrooms emerged in the area of Sudety Mountains (Sudetes) in Poland. Fruiting bodies and topsoil samples beneath L. scabrum were collected form the K odzka Dale. The trace elements were determined using validated method and inductively coupled plasma - atomic emission spectroscopy (ICP-AES) for final measurement. Mushrooms contained Ag, Cr, Hg, Co, Ni and Sr at < 1.0 μg/g dry weight; Ba and Pb at ~1.0 μg/g dw; Cd at < 5 μg/g dw; Cu and Mn at > 10 μg/g dw; Al and Ca at ~100 μg/g dw; Fe, Na, Rb and Zn at 100 to 500 μg/g dw, Mg at ~1,000 μg/g dw; P at ~5,000 μg/g dw and K at ~30,000 μg/g dw. Ca, Mn and Ni were nearly equally distributed between stipes and caps; stipes compared to caps were enriched in Ba, Na and Sr, while caps were enriched in Ag, Al, Cd, Co, Cr, Cu, Fe, K, P, Pb, Rb and Zn. The values of bioconcentration factor (BCF) varied highly depending on chemical element and were >1 for Ag, Cd, Cu, K, Mg, Na, P, Rb and Zn, while <1 for Al, Ba, Ca, Co, Cr, Fe, Mn, Ni, Pb and Sr. Topsoil showed elevated content of lead and mean concentration was 99 ± 32 μg/g dw, while cadmium was at 0.41 ± 0.15 and those two highly toxic to human elements occurred in edible caps of L. scabrum at 4.5 ± 2.2 and 2.9 ± 2.0 μg/g dw, respectively.  相似文献   

Differences in the abiotic parameters of water in coastal lakes in the light of the EU water framework directive: An example of the Polish southern Baltic coast     

Roman Cieśliński  Maciej Major 《Acta Geophysica》2012,60(4):1159-1179

Coastal lakes have a specific hydrological regime determined by the influence of sea and inland water and the local hydrographic conditions. There are several problems concerning the protection and assessment of water quality of these bodies. The most important features differentiating coastal lakes from other lakes are: high salinity, a wide range of seasonal and short-term water quality changes, and specific aquatic ecosystems adapted to these conditions. These matters have not been sufficiently taken into account in the existing classifications and typologies of lakes in Poland. The problem has not been solved by the establishment of the adequate reference conditions and new guidelines for the classification of water status (which are being prepared according to the Common Strategy for the Implementation of the Water Framework Directive) regarding inland surface waters (rivers and lakes) and marine waters (coastal and transitional). An important issue is to define criteria which would help to distinguish all those hydrographic objects and to establish water quality standards for them.  相似文献