Effects of estuarine organic matter biogeochemistry on the bioaccumulation of PAHs by two epibenthic species     

S. Mitra  P. L. Klerks  T. S. Bianchi  J. Means  K. R. Carman 《Estuaries and Coasts》2000,23(6):864-876

Polycyclic aromatic hydrocarbon (PAH) biota-sediment accumulation factors (BSAF) were quantified in sediments from two sites in southeastern Louisiana in a 14 d microcosm study usingPalaemonetes pugio, andRangia cuneata and two radiolabeled PAHs, phenanthrene and benzo[a]pyrene (b[a]p). For both PAHs studied, mean BSAFs were significantly higher (p<0.0001) in both organisms in sediments from Bayou Trepagnier, (BSAF=0.628 g OC g TLE⁻¹), a brackish swamp, compared to Pass Fourchon (0.065 g OC g TLE⁻¹), a coastal salt marsh. In order to explain observed patterns in BSAFs, organic carbon-normalized PAH distribution coefficients between the sediment and freely dissolved phases (K_OC)_OBS were determined as well as the various geochemical variables of particulate and dissolved organic matter (POM and DOM, respectively). These included analyses of particle surface area, total organic carbon (TOC), carbon to nitrogen ratios (C∶N), and dissolved organic carbon (DOC). Bayou Trepagnier was higher in surface area, TOC, C∶N, as well as DOC suggesting that the difference in BSAFs may be attributed to compositional differences in POM and DOM between sites. We can not exclude the possibility that other factors (such as differences in organism behavior resulting from contrasting sediment characteristics) were responsible for BSAFs varying between the two sites. Phenanthrene BSAFs were typically higher than b[a]p BSAFs, suggesting contaminants were limited in their desorption from sediment particles as a function of PAH molecular weight. Mean BSAFs for both PAHs were higher on Day 7 than on Day 14. The reason for this decrease is unclear, but did not appear to be due to organisms becoming increasingly stressed in the microcosms. Visual observations indicated that animals remained feeding while no decreases in organism total lipid levels were detected. The trends in BSAFs between sites and over the time course of this experiment suggest that contaminant bioaccumulation in estuarine systems should not be considered to be an equilibrium process.  相似文献   

Volatile-induced magma differentiation in the plumbing system of Mt. Etna volcano (Italy): evidence from glass in tephra of the 2001 eruption     

Carmelo Ferlito  Marco Viccaro  Renato Cristofolini 《Bulletin of Volcanology》2008,70(4):455-473

Mount Etna volcano was shaken during the summer 2001 by one of the most singular eruptive episodes of the last centuries. For about 3 weeks, several eruptive fractures developed, emitting lava flows and tephra that significantly modified the landscape of the southern flank of the volcano. This event stimulated the attention of the scientific community especially for the simultaneous emission of petrologically distinct magmas, recognized as coming from different segments of the plumbing system. A stratigraphically controlled sampling of tephra layers was performed at the most active vents of the eruption, in particular at the 2,100 m (CAL) and at the 2,550 m (LAG) scoria cones. Detailed scanning electron microscope and energy dispersive x-ray spectrometer (SEM-EDS) analyses performed on glasses found in tephra and comparison with lava whole rock compositions indicate an anomalous increase in Ti, Fe, P, and particularly of K and Cl in the upper layers of the LAG sequence. Mass balance and thermodynamic calculations have shown that this enrichment cannot be accounted for by “classical” differentiation processes, such as crystal fractionation and magma mixing. The analysis of petrological features of the magmas involved in the event, integrated with the volcanological evolution, has evidenced the role played by volatiles in controlling the magmatic evolution within the crustal portion of the plumbing system. Volatiles, constituted of H₂O, CO₂, and Cl-complexes, originated from a deeply seated magma body (DBM). Their upward migration occurred through a fracture network possibly developed by the seismic swarms during the period preceding the event. In the upper portion of the plumbing system, a shallower residing magma body (ABT) had chemical and physical conditions to receive migrating volatiles, which hence dissolved the mobilized elements producing the observed selective enrichment. This volatile-induced differentiation involved exclusively the lowest erupted portion of the ABT magma due to the low velocity of volatiles diffusion within a crystallizing magma body and/or to the short time between volatiles migration and the onset of the eruption. Furthermore, the increased amount of volatiles in this level of the chamber strongly affected the eruptive behavior. In fact, the emission of these products at the LAG vent, towards the end of the eruption, modified the eruptive style from classical strombolian to strongly explosive.  相似文献   

Sources of organic matter in surface sediments of the Louisiana Continental margin: Effects of major depositional/transport pathways and Hurricane Ivan     

Troy P. Sampere  Thomas S. Bianchi  Stuart G. Wakeham  Mead A. Allison   《Continental Shelf Research》2008,28(17):2472-2487

Lignin and pigment biomarkers were analyzed in surface sediments of the Louisiana Continental margin (LCM) to distinguish differences in the degradative state of sedimentary organic matter along and between two major depositional pathways (along shore and offshore to the Mississippi Canyon) from Southwest (SW) Pass in July 2003. Barataria Bay, an inter-distributary estuary, was also assessed as a potential source of terrestrial organic matter to the LCM. Sediment signatures taken along the same pathways after Hurricane Ivan (October 2004) were compared with the pre-Ivan signature to elucidate carbon dynamics after major hurricane events. Density fractions were investigated at key stages across the LCM. Mississippi Canyon sediments are a depocenter for labile and refractory organic matter derived from river and previously deposited shelf sediments. Barataria Bay material may be a contributing source of sedimentary organic matter in shallow shelf areas bordering the bay and is thus potentially important in carbon cycling in sediments of these shallow areas; however, our results show that organic matter inputs from the bay were likely rapidly decomposed and/or diluted. Hurricane Ivan mobilized sedimentary organic carbon (SOC) offshore and homogenized terrestrial sediment parameters and gradients. As observed through pigment concentrations sediments tended to equilibrate to a more steady-state condition within months of the disturbance. Insights from density fractions show that selective degradation and aggregation/flocculation processes were also very important processes during cross-shelf transport. Zooplankton grazing, largely on diatoms and other algae, was a shelf wide phenomenon, however, grazing products dominated the marine-derived SOC in margin sediments west of the birdsfoot delta indicated by the abundance of steryl chlorin esters (SCEs).  相似文献   

Shallow reflection seismic evidence of tectonic activity in the Cheb Basin,NW Bohemia     

Felix Halpaap  Marco Paschke  Florian Bleibinhaus 《Studia Geophysica et Geodaetica》2018,62(1):80-101

With a high-resolution seismic survey, we targeted the shallow structural features of the Cheb Basin, Northwest Bohemia. The aim of this study was to evaluate these features’ relation to seismic activity below the Cheb Basin with the first reflection seismic image of parts of the basin. We recorded a densely sampled, 3200 m long seismic survey stretching from Kopanina towards SE, into the basin. From the recordings of 170 shots at 192 geophones with 384-m total spread, we obtained a reflection seismic image down to the basement at 300-m depth, supplemented by a shallow tomographic velocity model for the uppermost 40 m. Strong lateral velocity contrasts indicate Quaternary river terraces, into which the Plesná river incises. We observe reverse faults in the lower basin sediments, which we interpret as signs of a push-up structure related to the N-S oriented Po?átky-Plesná Zone (PPZ). However, we do not observe any vertical fault offsets in the younger sedimentary layers, which suggests that any normal or reverse faulting must be older than 20 Ma. The image agrees well with previous lithostratigraphic borehole data and previous sedimentological and tectonic models. Our explanation for the formation of the escarpment at the eastern bank of the Plesná valley, previously interpreted as outcrop of the PPZ, relies solely on incision of the Plesná river into weak sediments.  相似文献   

Characterisation of ground motion recording stations in the Groningen gas field     

Rik Noorlandt  Pauline P. Kruiver  Marco P. E. de Kleine  Marios Karaoulis  Ger de Lange  Antonio Di Matteo  Julius von Ketelhodt  Elmer Ruigrok  Benjamin Edwards  Adrian Rodriguez-Marek  Julian J. Bommer  Jan van Elk  Dirk Doornhof 《Journal of Seismology》2018,22(3):605-623

The seismic hazard and risk analysis for the onshore Groningen gas field requires information about local soil properties, in particular shear-wave velocity (V_S). A fieldwork campaign was conducted at 18 surface accelerograph stations of the monitoring network. The subsurface in the region consists of unconsolidated sediments and is heterogeneous in composition and properties. A range of different methods was applied to acquire in situ V_S values to a target depth of at least 30 m. The techniques include seismic cone penetration tests (SCPT) with varying source offsets, multichannel analysis of surface waves (MASW) on Rayleigh waves with different processing approaches, microtremor array, cross-hole tomography and suspension P-S logging. The offset SCPT, cross-hole tomography and common midpoint cross-correlation (CMPcc) processing of MASW data all revealed lateral variations on length scales of several to tens of metres in this geological setting. SCPTs resulted in very detailed V_S profiles with depth, but represent point measurements in a heterogeneous environment. The MASW results represent V_S information on a larger spatial scale and smooth some of the heterogeneity encountered at the sites. The combination of MASW and SCPT proved to be a powerful and cost-effective approach in determining representative V_S profiles at the accelerograph station sites. The measured V_S profiles correspond well with the modelled profiles and they significantly enhance the ground motion model derivation. The similarity between the theoretical transfer function from the V_S profile and the observed amplification from vertical array stations is also excellent.  相似文献   

Watershed and ocean controls of salt marsh extent and resilience     

Fateme Yousefi Lalimi  Marco Marani  James Brendan Heffernan  Andrea D'Alpaos  A. Brad Murray 《地球表面变化过程与地形》2020,45(6):1456-1468

The formation and evolution of tidal platforms are controlled by the feedbacks between hydrodynamics, geomorphology, vegetation, and sediment transport. Previous work mainly addresses dynamics at the scale of individual marsh platforms. Here, we develop a process-based model to investigate salt marsh depositional/erosional dynamics and resilience to environmental change at the scale of tidal basins. We evaluate how inputs of water and sediment from river and ocean sources interact, how losses of sediment to the ocean depend on this interaction, and how erosional/depositional dynamics are coupled to these exchanges. Model experiments consider a wide range of watershed, basin, and oceanic characteristics, represented by river discharge and suspended sediment concentration, basin dimensions, tidal range, and ocean sediment concentration. In some scenarios, the vertical accretion of a tidal flat can be greater than the rate of sea level rise. Under these conditions, vertical depositional dynamics can lead to transitions between tidal flat and salt marsh equilibrium states. This type of transition occurs much more rapidly than transitions occurring through horizontal marsh expansion or retreat. In addition, our analyses reveal that river inputs can affect the existence and extent of marsh/tidal flat equilibria by both directly providing suspended sediment (favoring marshes) and by modulating water exchanges with the ocean, thereby indirectly affecting the ocean sediment input to the system (favoring either marshes or tidal flats depending on the ratio of the river and ocean water inputs and their sediment concentrations). The model proposed has the goal of clarifying the roles of the main dynamic processes at play, rather than of predicting the evolution of a particular tidal system. Our model results most directly reflect micro- and meso-tidal environments but also have implications for macro-tidal settings. The model-based analyses presented extend our theoretical understanding of marsh dynamics to a greater range of intertidal environments. © 2020 John Wiley & Sons, Ltd.  相似文献   

River,Coastal and Estuarine Morphodynamics Selected papers from the 10th anniversary of the RCEM Symposium     

Guido Zolezzi  Luca Carniello  Andrea D'Alpaos  Stefano Lanzoni  Marco Tubino 《地球表面变化过程与地形》2020,45(5):1311-1314

This Special Issue collects 17 selected contributions from participants to the 10th edition of the RCEM (River, Coastal and Estuarine Morphodynamics) Symposium, organized in Padova-Trento (Italy) in September 2017. The series of biennial RCEM symposia has the key goal of enhancing interaction and promoting integration among the scientific communities focused on the morphological dynamics of river, coastal and estuarine environments, through various combinations of theoretical, observational, experimental and modelling approaches. The 17 contributions to this Special Issue contain four state-of-science reviews and overall offer a broad view of the cross-cutting perspective adopted when addressing morphodynamics. Such a perspective accounts for the mutual interplay between morphology, fluid dynamics and other environmental factors, and has presently become a widespread paradigm to address landscape evolution. © 2020 John Wiley & Sons, Ltd.  相似文献   

Sustained post-seismic effects on groundwater flow in fractured carbonate aquifers in Central Italy     

Lucia Mastrorillo  Michele Saroli  Stefano Viaroli  Francesca Banzato  Daniela Valigi  Marco Petitta 《水文研究》2020,34(5):1167-1181

A sustained increase in spring discharges was monitored after the 2016 Central Italy seismic sequence in the fractured carbonate aquifer of Valnerina–Sibillini Mts. The groundwater surplus recorded between August 2016 and November 2017 was determined to be between 400 and 500 × 10⁶ m³. In fractured aquifers, the post-seismic rise in spring discharges is generally attributed to an increase in bulk permeability caused by the fracture cleaning effect, which is induced by pore pressure propagation. In the studied aquifers, the large amount of additional discharge cannot only be attributed to the enhanced permeability, which was evaluated to be less than 20% after each main seismic event. A detailed analysis of the spring discharge hydrographs and of the water level at five gauging stations was carried out to determine the possible causes of this sudden increase in groundwater outflow. Taking into account the geological and structural framework, a conceptual model of a basin-in-series has been adopted to describe the complex hydrogeological setting, where the thrusts and extensional faults have clearly influenced the groundwater flow directions before and after the seismic sequence. The prevalent portion of the total post-seismic discharge surplus not explained by the increase in permeability has been attributed to changes in the hydraulic gradient that caused seismogenic fault rupture and the disruption in the upgradient sector of the aquifer. The additional flow calculated through the breach of the pre-existing hydrostructural barrier corresponds to approximately 470 × 10⁶ m³. This value is consistent with the total discharge increase measured in the whole study area, validating the proposed conceptual model. Consequently, a shift in the piezometric divide of the hydrogeological system has been induced, causing a potentially permanent change that lowers the discharge amount of the eastern springs.  相似文献   

An errors-in-variables model based on the Birnbaum–Saunders distribution and its diagnostics with an application to earthquake data     

Carrasco  Jalmar M. F.  Figueroa-Zu&#;iga  Jorge I.  Leiva  Victor  Riquelme  Marco  Aykroyd  Robert G. 《Stochastic Environmental Research and Risk Assessment (SERRA)》2020,34(2):369-380

Stochastic Environmental Research and Risk Assessment - Regression modelling where explanatory variables are measured with error is a common problem in applied sciences. However, if inappropriate...  相似文献   

Reliability-based optimal design of nonlinear viscous dampers for the seismic protection of structural systems     

Domenico Altieri  Enrico Tubaldi  Marco De Angelis  Edoardo Patelli  Andrea Dall’Asta 《Bulletin of Earthquake Engineering》2018,16(2):963-982

Viscous dampers are widely employed for enhancing the seismic performance of structural systems, and their design is often carried out using simplified approaches to account for the uncertainty in the seismic input. This paper introduces a novel and rigorous approach that allows to explicitly consider the variability of the intensity and characteristics of the seismic input in designing the optimal viscous constant and velocity exponent of the dampers based on performance-based criteria. The optimal solution permits controlling the probability of structural failure, while minimizing the damper cost, related to the sum of the damper forces. The solution to the optimization problem is efficiently sought via the constrained optimization by linear approximation (COBYLA) method, while Subset simulation together with auxiliary response method are employed for the performance assessment at each iteration of the optimization process. A 3-storey steel moment-resisting building frame is considered to illustrate the application of the proposed design methodology and to evaluate and compare the performances that can be achieved with different damper nonlinearity levels. Comparisons are also made with the results obtained by applying simplifying approaches, often employed in design practice, as those aiming to minimize the sum of the viscous damping constant and/or considering a single hazard level for the performance assessment.  相似文献