Prediction of the abiotic degradability of organic compounds in the troposphere     

Hans Güsten  Leo Klasinc  Dubravko Marić 《Journal of Atmospheric Chemistry》1984,2(1):83-93

A statistically relevant correlation between the reaction rate coefficient, k _OH, for the OH radical reaction with 161 organic compounds in the gas phase at 300 K, and the corresponding vertical ionisation energies E _i,v, reveals two classes of compounds: aromatics where –log(k _OH/cm³s^-1)3/2E _i,v(eV)–2 and aliphatics where –log(k _OH/cm³s^-1)4/5E _i,v(eV)+3. The prediction of the rate coefficient, k _OH, for the reaction of OH with organic molecules from the above equations has a probability of about 90%. Assuming a global diurnal mean of the OH radical concentration of 5×10⁵ cm³, the upper limit of the tropospheric half-life of organic compounds and their persistence can be estimated.  相似文献   

Kriging of water levels in the Souss aquifer,Morocco   总被引：2，自引：0，他引：2  

Mohamed Aboufirassi  Miguel A. Mariño 《Mathematical Geosciences》1983,15(4):537-551

Universal kriging is applied to water table data from the Souss aquifer in central Morocco. The procedure accounts for the spatial variability of the phenomenon to be mapped. With the use of measured elevations of the water table, an experimental variogram is constructed that characterizes the spatial variability of the measured water levels. Spherical and Gaussian variogram models are alternatively used to fit the experimental variogram. The models are used to develop contour maps of water table elevations and corresponding estimation variances. The estimation variances express the reliability of the kriged water table elevation maps. Universal kriging also provides a contour map of the expected elevation of the water table (drift). The differences between the expected and measured water table elevations are called residuals from the drift. Residuals from the drift are compared with residuals obtained by more traditional least-squares analysis.  相似文献   

Crustal structure in and around the region of the 1995 Kobe Earthquake deduced from a wide-angle and refraction seismic exploration     

Takeshi Ohmura  Takeo Moriya  Chengshi Piao  Takaya Iwasaki  Toshikastu Yoshi  Shin'ichi Sakai  Tetsuya Takeda  Kaoru Miyashita  Humihito Yamazaki  Kiyoshi Ito  Akira Yamazaki  Yoji Shimada  Katsuya Tashiro  Hiroki Miyamachi 《Island Arc》2001,10(3-4):215-227

Abstract The 1995 Kobe (Hyogo-ken Nanbu) earthquake (M_JMA 7.2, M_w 6.9) occurred on Jan. 17, 1995, at a depth of 17 km, beneath the areas of southern part of Hyogo prefecture and Awaji Island. To investigate P-wave velocity distribution and seismological characteristics in the aftershock area of this great earthquake, a wide-angle and refraction seismic exploration was carried out by the Research Group for Explosion Seismology (RGES) . The profile including 6 shot points and 205 observations was 135 km in length, extending from Keihoku, Northern Kyoto prefecture, through Kobe, to Seidan on Awaji Island. The charge of each shot was 350–700 kg. The P-wave velocity structure model showed a complicated sedimentary layer which is shallower than 2.5 km, a 2.5 km-thick basement layer whose velocity is 5.5 km/s, overlying the crystalline upper crust, and the boundary between the upper and lower crust.
Almost all aftershock hypocenters were located in the upper crust. However, the structure model suggests that the hypocenters of the main shock and some aftershock clusters were situated deeper than the boundary between the upper and lower crust. We found that the P-velocity in the upper crust beneath the northern part of Awaji Island is 5.64 km/s which is 3% lower than that of the surrounding area. The low-velocity zone coincides with the region where the high stress moment release was observed.  相似文献   

Groundwater quality on the territory of Kikinda municipality (Vojvodina,Serbia)     

Nenad Marić  Sanja Mrazovac Kurilić  Ivan Matić  Stanko Sorajić  Jelena Zarić 《Environmental Earth Sciences》2014,72(2):525-534

This paper provides insight into the quality of groundwater used for public water supply on the territory of Kikinda municipality (Vojvodina, Serbia) and main processes which control it. The following parameters were measured: color, turbidity, pH, KMnO₄ consumption, TDS, EC, NH₄ ⁺, Cl^?, NO₂ ^?, NO₃ ^?, Fe, Mn, total hardness, Ca²⁺, Mg²⁺, SO₄ ²⁺, HCO₃ ^?, K⁺, Na⁺, As. The correlations and ratios among parameters that define the chemical composition were determined aiming to identify main processes that control the formation of the chemical composition of the analyzed waters. Groundwater from 11 analyzed sources is Na–HCO₃ type. Intense color and elevated organic matter content of these waters originate from humic substances. The importance of organic matter decay is assumed by positive correlation between organic matter content and TDS, HCO₃ content. There is no evidence that groundwater chemistry is determined by the depth of captured aquifer interval. The main processes that control the chemistry of all analyzed water are cation exchange and feldspar weathering.  相似文献   

Monitoring of heat transmission from buildings into geological environment and evaluation of soil deformation consequences in foundation engineering     

Işık Yilmaz  Marian Marschalko  David Lamich  Marián Drusa  Jiří Machačík  Silvie Heviánková  Miroslav Kyncl  Eva Lacková  Iva Bestová  David Krčmář  Egon Stutz  Martin Bednárik 《Environmental Earth Sciences》2014,72(8):2947-2955

In engineering geology a number of factors affecting foundation conditions are taken into consideration during engineering-geological investigations. This article deals with the factor of heat sourced from a structure (brick kiln) as a restrictive factor in foundation engineering in clay soils and introduces a documentation of soil deformation observations as an impact of the heat transmission into the geological environment. It was carried out in Southern Moravia in the Czech Republic, where the dominant foundation soils are Neogeneous clays where differential settlements of a tunnel kiln structure occurred as a result of ignoring the boundary conditions of temperature changes in the soil environment. The brick kilns caused heterogeneous spatial changes in the subsoil temperatures. This consequently resulted in differential settlements due to temperature changes originating from the kilns. The differential settlements reached as much as 150 mm. The major objective of the article is to highlight the importance of the heat transmission from buildings into the geological environment as a factor which should be considered in engineering geology and its application in planning. A new procedure for reducing or elimination of ground movements sourced from underlying clayey soils depending on the heat changes was also suggested in this context.  相似文献   

Controls on surface water chemistry in two lake‐watersheds in the Adirondack region of New York: differences in nitrogen solute sources and sinks     

Mari Ito  Myron J. Mitchell  Charles T. Driscoll  Robert M. Newton  Chris E. Johnson  Karen M. Roy 《水文研究》2007,21(10):1249-1264

The southwestern Adirondack region of New York receives among the highest rates of atmospheric nitrogen (N) deposition in the USA. Atmospheric N deposition to sensitive ecosystems, like the Adirondacks, may increase the acidification of soils through losses of exchangeable nutrient cations, and the acidification of surface waters associated with enhanced mobility of nitrate (NO₃^?). However, watershed attributes, including surficial terrestrial characteristics, in‐lake processing, and geological settings, have been found to complicate the relationships between atmospheric N deposition and N drainage losses. We studied two lake‐watersheds in the southwestern Adirondacks, Grass Pond and Constable Pond, which are located in close proximity (～26 km) and receive similarly high N deposition, but have contrasting watershed attributes (e.g. wetland area, geological settings). Since the difference in the influence of N deposition was minimal, we were able to examine both within‐ and between‐watershed influences of land cover, the contribution of glacial till groundwater inputs, and in‐lake processes on surface water chemistry with particular emphasis on N solutes and dissolved organic carbon (DOC). Monthly samples at seven inlets and one outlet of each lake were collected from May to October in 1999 and 2000. The concentrations of NO₃^? were high at the Grass Pond inlets, especially at two inlets, and NO₃^? was the major N solute at the Grass Pond inlets. The concentrations of likely weathering products (i.e. dissolved Si, Ca²⁺, Mg²⁺, Na⁺) as well as acid neutralizing capacity and pH values, were also particularly high at those two Grass Pond inlets, suggesting a large contribution of groundwater inputs. Dissolved organic N (DON) was the major N solute at the Constable Pond inlets. The higher concentrations of DON and DOC at the Constable Pond inlets were attributed to a large wetland area in the watershed. The DOC/DON ratios were also higher at the Constable Pond inlets, possibly due to a larger proportion of coniferous forest area. Although DON and DOC were strongly related, the stronger relationship of the proportion of wetland area with DOC suggests that additional factors regulate DON. The aggregated representation of watershed physical features (i.e. elevation, watershed area, mean topographic index, hypsometric‐analysis index) was not clearly related to the lake N and DOC chemistry. Despite distinctive differences in inlet N chemistry, NO₃^? and DON concentrations at the outlets of the two lakes were similar. The lower DOC/DON ratios at the lake outlets and at the inlets having upstream ponds suggest the importance of N processing and organic N sources within the lakes. Although an inverse relationship between NO₃^? and DOC/DON has been suggested to be indicative of a N deposition gradient, the existence of this relationship for sites that receive similar atmospheric N deposition suggest that the relationship between NO₃^? and the DOC/DON ratio is derived from environmental and physical factors. Our results suggest that, despite similar wet N deposition at the two watershed sites, N solutes entering lakes were strongly affected by hydrology associated with groundwater contribution and the presence of wetlands, whereas N solutes leaving lakes were strongly influenced by in‐lake processing. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Observations of the Ushant tidal front in September 2007     

A. Le Boyer  G. Cambon  N. Daniault  S. Herbette  B. Le Cann  L. Marié  P. Morin 《Continental Shelf Research》2009,29(8):1026-1037

The Ushant tidal front is the dominant feature of the summer season hydrological structure of the Iroise Sea. It separates tidally mixed coastal waters from thermally stratified open Celtic Sea waters. This article reports on observations made in September 2007 during two short cruises that took place aboard R/V “Côtes de la Manche”, and gives a general account of the physical structure of the front along one cross-frontal transect. The data set comprises data from a 4 month ADCP mooring, short CTD/fluorescence/nutrients transects, Lagrangian drifter trajectories, and HF radar surface current measurements. One finding is that the surface and bottom fronts, being affected by different dynamical influences, are not necessarily coincident in the vertical. This entails that the opposite density gradients located above and below the thermocline depth do not necessarily compensate, and can each be associated with a significant surface geostrophic expression. A second finding is that mixing effects bear a very strong influence on the thermal structure of the warm-water intrusions associated with frontal cyclonic eddies of the kind described by Pingree [1978. Cyclonic eddies and cross-frontal mixing. Journal of the Marine Biological Association of the United Kingdom 58 (4), 955–963].  相似文献   

Northern Adriatic phytoplankton response to short Po River discharge pulses during summer stratified conditions     

Damir Vilicic  Milivoj Kuzmic  Igor Tomažić  Zrinka Ljubešić  Sunčica Bosak  Robert Precali  Tamara Djakovac  Danijela Marić  Jelena Godrijan 《Marine Ecology》2013,34(4):451-466

A 275‐km‐long transversel Northern Adriatic profile from the mouth of the Po River (Italian Adriatic coast) to the Kvarner region (Croatian coastal island area) was investigated in three successive case studies in August 2008, 2009 and 2010. The short Po River pulses in August result in the surface advection of riverine water, nutrients and phytoplankton from the western to the eastern side of the Adriatic. This surface spreading exhibits inter‐annual variability depending on the riverine discharge in the preceding period. The Po River discharge pulse in August 2010 in particular resulted in an extraordinary tongue‐like advection of riverine water, nutrients, and phytoplankton towards the Eastern Adriatic coast. The phenomenon was detected using both satellite imagery and classical oceanographic measurements. In the advective water, toxic dinoflagellates were most abundant in August 2010, when the influence of the Po was greatest.  相似文献   

Possible climate change/variability and human impacts,vulnerability of drought-prone regions,water resources and capacity building for Africa     

T.Y. Gan  Mari Ito  S. Hülsmann  X Qin  X.X. Lu  S.Y. Liong 《水文科学杂志》2013,58(7):1209-1226

ABSTRACT

This review article discusses the climate, water resources and historical droughts of Africa, drought indices, vulnerability, impact of global warming and land use for drought-prone regions in West, southern and the Greater Horn of Africa, which have suffered recurrent severe droughts in the past. Recent studies detected warming and drying trends in Africa since the mid 20th century. Based on the Fourth Assessment Report of the Intergovernmental Panel on Climate Change and the Coupled Model Intercomparison Project Phase 5 (CMIP5), both northern and southern Africa are projected to experience drying, such as decreasing precipitation, runoff and soil moisture in the 21st century and could become more vulnerable to the impact of droughts. The daily maximum temperature is projected to increase by up to 8°C (RCP8.5 of CMIP5), precipitation indices such as total wet day precipitation (PRCPTOT) and heavy precipitation days (R10 mm) could decrease, while warm spell duration (WSDI) and consecutive dry days (CDD) could increase. Uncertainties of the above long-term projections, teleconnections to climate anomalies such as ENSO and the Madden-Julian Oscillation, which could also affect the water resources of Africa, and capacity building in terms of physical infrastructure and non-structural solutions are also discussed. Given that traditional climate and hydrological data observed in Africa are generally limited, satellite data should also be exploited to fill the data gap for Africa in the future.