Non-isoprenoid macrocyclic glycerol diethers associated with authigenic carbonates     

Marion Baudrand  Vincent Grossi  Richard Pancost  Giovanni Aloisi   《Organic Geochemistry》2010,41(12):1341-1344

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Scales as a challenge for vulnerability assessment   总被引：4，自引：4，他引：0  

Alexander Fekete  Marion Damm  Jörn Birkmann 《Natural Hazards》2010,55(3):729-747

The aim of this paper is to introduce scale as a basic tool for improving the conceptual structure of vulnerability assessments. The terminology useful for vulnerability assessments and the current use of scale issues in theoretical vulnerability frameworks will be discussed briefly. Two case studies working on sub-national and on local level will demonstrate problems as well as benefits resulting from scale implications. Both assessments analyse vulnerability in context to river floods in Germany. In order to develop a spatial comparison and to integrate topics like environment and society, vulnerability assessments need to be aware of scale implications. The main point is that a scale debate on a broader spectrum than just in technical spatial terms is missing in vulnerability and risk conceptualisations so far. Vulnerability assessments and scale are highly intertwined, not only in technical application but also in conceptualisation, which needs more scientific development.  相似文献   

Understanding multiple thresholds of coupled social–ecological systems exposed to natural hazards as external shocks     

Fabrice G. Renaud  Jörn Birkmann  Marion Damm  Gilberto C. Gallopín 《Natural Hazards》2010,55(3):749-763

External suffusion, as selective erosion of fine particles through the contact with a coarser layer and moving away, is an important phenomenon in dams which may lead to their failure. To study the initiation of external suffusion, caused by water level increase upstream the dam, a series of experimental investigations were conducted on laboratory-scale model, in the hydrodynamic laboratory of école polytechnique de Montreal. On the built model, clay/moraine formed the core, sand was used as a filter and gravel performed the role of the pervious layer. Several different models (in geometry and constituent materials) were built and subjected to the water level increase upstream, which resulted in changes in the hydraulic gradient. The results showed no evidence of considerable suffusion on the clay/moraine and sand interface, while the visual and quantitative data show the presence of suffusion on the sand and gravel interface. The results of the experiments show that, when focusing on the critical hydraulic gradient that initiates the movement of the clay/moraine particles, it can be concluded that despite the differences in test conditions, the critical hydraulic gradient has approximately the same value in all cases. It was also shown that increasing the length of the filter layer or applying stair-like slopes does not have great impacts on the initiation of suffusion, whereas the gravel-size distribution has a great impact on the erosion rate.  相似文献   

Long-Term Trends in Submersed Aquatic Vegetation (SAV) in Chesapeake Bay, USA, Related to Water Quality     

Robert J. Orth  Michael R. Williams  Scott R. Marion  David J. Wilcox  Tim J. B. Carruthers  Kenneth A. Moore  W. Michael Kemp  William C. Dennison  Nancy Rybicki  Peter Bergstrom  Richard A. Batiuk 《Estuaries and Coasts》2010,33(5):1144-1163

Chesapeake Bay supports a diverse assemblage of marine and freshwater species of submersed aquatic vegetation (SAV) whose broad distributions are generally constrained by salinity. An annual aerial SAV monitoring program and a bi-monthly to monthly water quality monitoring program have been conducted throughout Chesapeake Bay since 1984. We performed an analysis of SAV abundance and up to 22 environmental variables potentially influencing SAV growth and abundance (1984–2006). Historically, SAV abundance has changed dramatically in Chesapeake Bay, and since 1984, when SAV abundance was at historic low levels, SAV has exhibited complex changes including long-term (decadal) increases and decreases, as well as some large, single-year changes. Chesapeake Bay SAV was grouped into three broad-scale community-types based on salinity regime, each with their own distinct group of species, and detailed analyses were conducted on these three community-types as well as on seven distinct case-study areas spanning the three salinity regimes. Different trends in SAV abundance were evident in the different salinity regimes. SAV abundance has (a) continually increased in the low-salinity region; (b) increased initially in the medium-salinity region, followed by fluctuating abundances; and (c) increased initially in the high-salinity region, followed by a subsequent decline. In all areas, consistent negative correlations between measures of SAV abundance and nitrogen loads or concentrations suggest that meadows are responsive to changes in inputs of nitrogen. For smaller case-study areas, different trends in SAV abundance were also noted including correlations to water clarity in high-salinity case-study areas, but nitrogen was highly correlated in all areas. Current maximum SAV coverage for almost all areas remain below restoration targets, indicating that SAV abundance and associated ecosystem services are currently limited by continued poor water quality, and specifically high nutrient concentrations, within Chesapeake Bay. The nutrient reductions noted in some tributaries, which were highly correlated to increases in SAV abundance, suggest management activities have already contributed to SAV increases in some areas, but the strong negative correlation throughout the Chesapeake Bay between nitrogen and SAV abundance also suggests that further nutrient reductions will be necessary for SAV to attain or exceed restoration targets throughout the bay.  相似文献   

Determination of flow exits in the Soultz borehole GPK2 by using the brine displacement method     

Reinhard Jung  Marion Schindler  Patrick Nami  Torsten Tischner 《Comptes Rendus Geoscience》2010,342(7-8):636-643

The article presents a method to derive synthetic flow logs from low rate injection tests in wells, which are otherwise not accessible for logging. The tests were carried out in the 5 km deep geothermal well GPK2 in the Enhanced Geothermal System (EGS) project of Soultz-sous-Forêts (France) and were aimed at characterizing the status of the well before chemical treatments. The method consists of injecting water at constant flow rates into the well initially filled with brine. The wellhead pressure record of this test is transformed into log of the flow velocity versus depth by a technique described in the paper. Applying this method to borehole GPK2, three outlets could be detected and quantified within the cased and uncased section of this borehole. The outlet in the cased section at 3860 m absorbed 15% of the total flow. This depth corresponds to a known casing restriction, which makes the borehole inaccessible for logging operations. The two other outlets are at the casing shoe at 4420 m (15%) and at 4670 m (70%).  相似文献   

Locational and socio-economic variation in public perceptions of economics and the environment     

Sarah Lumley  Marion Hercock 《GeoJournal》2000,51(3):235-244

Government policies for the use of publicly owned environmental resources in Australia are often justified as being for the economic good of the nation. Yet there has been little enquiry about how Australians perceive economic good in the context of the use of environmental resources. The residents of five State government electorates of Perth and one in regional south west Western Australia were surveyed. Their perceptions of economics, the environment and resources in relation to public policy were assessed. The differences in the responses were greater between the different electorates, than between the different socio-economic strata within the same electorate. This paper examines the spatial variability of the results and raises the possibility of developing a socio-locational indicator of attitudes which could provide a tool for policy implementation.  相似文献   

Tomographic radiotracer studies of the spatial distribution of heterogeneous geochemical transport processes     

Marion Gründig  Michael Richter  Anita Seese  Osama Sabri 《Applied Geochemistry》2007

Within the scope of the further development of geochemical transport models the consideration of the influence of the heterogeneous structures of the geological layers plays an important role. For the verification and parameter estimation of such models it is necessary to measure the heterogeneous transport and sorption processes inside the samples. Tomographic radiotracer methods (positron emission tomography (PET)) enable nondestructive spatially resolved observations of the transport processes in these layers. A special quantitative evaluation system for geoscientific PET studies was developed. Investigations of the water flow distribution in a drill core of a lignite mining dump and of the migration of Cu ions in a horizontal soil column illustrate the potential of this method. Spatial distribution functions of the flow velocity, the specific mass flow and the longitudinal dispersivity were determined on the basis of PET investigations.  相似文献   

Coral skeletal delta(15)N reveals isotopic traces of an agricultural revolution     

Marion GS  Dunbar RB  Mucciarone DA  Kremer JN  Lansing JS  Arthawiguna A 《Marine pollution bulletin》2005,50(9):931-944

This study introduces a new method of tracing the history of nutrient loading in coastal oceans via delta(15)N analysis of organic nitrogen preserved in the skeleton of the massive Porites coral. Four coral cores were collected in Bali, Indonesia, from reefs exposed to high levels of fertilizers in agricultural run-off, from lagoonal corals impacted by sewage, and from a reef located 30 km offshore. Skeletal delta(15)N in the agriculturally exposed coral declined from 10.7+/-0.4 per thousand in 1970-1971, when synthetic fertilizers (-0.8 per thousand+/-0.2 per thousand) were introduced to Bali, to a depleted "anthropogenic" baseline of 3.5 per thousand+/-0.4% in the mid-1990s. delta(15)N values were negatively correlated with rainfall, suggesting that marine delta(15)N lowers during flood-bourn influxes of waste fertilizers. Reef cores exposed to untreated sewage in terrestrial discharge were enriched (7.8 and 7.3+/-0.4 per thousand), while the offshore core reflected background oceanic signals (6.2+/-0.4 per thousand). delta(15)N, N concentration, and C:N systematics indicate that the N isotopic composition of skeletal organic matter was generally well preserved over 30 years. We suggest that skeletal organic delta(15)N can serve as a recorder of past nitrogen sources. In Bali, this tracer suggests that the intensification of Western style agricultural practices since 1970 are contributing to the degradation of coastal coral reefs.  相似文献   

Modeling ferrous-ferric iron chemistry with application to martian surface geochemistry     

Giles M. Marion  Jeffrey S. Kargel 《Geochimica et cosmochimica acta》2008,72(1):242-266

The Mars Global Surveyor, Mars Exploration Rover, and Mars Express missions have stimulated considerable thinking about the surficial geochemical evolution of Mars. Among the major recent mission findings are the presence of jarosite (a ferric sulfate salt), which requires formation from an acid-sulfate brine, and the occurrence of hematite and goethite on Mars. Recent ferric iron models have largely focused on 25 °C, which is a major limitation for models exploring the geochemical history of cold bodies such as Mars. Until recently, our work on low-temperature iron-bearing brines involved ferrous but not ferric iron, also obviously a limitation. The objectives of this work were to (1) add ferric iron chemistry to an existing ferrous iron model (FREZCHEM), (2) extend this ferrous/ferric iron geochemical model to lower temperatures (<0 °C), and (3) use the reformulated model to explore ferrous/ferric iron chemistries on Mars.The FREZCHEM model is an equilibrium chemical thermodynamic model parameterized for concentrated electrolyte solutions using the Pitzer approach for the temperature range from <−70 to 25 °C and the pressure range from 1 to 1000 bars. Ferric chloride and sulfate mineral parameterizations were based, in part, on experimental data. Ferric oxide/hydroxide mineral parameterizations were based exclusively on Gibbs free energy and enthalpy data. New iron parameterizations added 23 new ferrous/ferric minerals to the model for this Na-K-Mg-Ca-Fe(II)-Fe(III)-H-Cl-SO₄-NO₃-OH-HCO₃-CO₃-CO₂-O₂-CH₄-H₂O system.The model was used to develop paragenetic sequences for Rio Tinto waters on Earth and a hypothetical Martian brine derived from acid weathering of basaltic minerals. In general, model simulations were in agreement with field evidence on Earth and Mars in predicting precipitation of stable iron minerals such as jarosites, goethite, and hematite. In addition, paragenetic simulations for Mars suggest that other iron minerals such as lepidocrocite, schwertmannite, ferricopiapite, copiapite, and bilinite may also be present on the surface of Mars. Evaporation or freezing of the Martian brine led to similar mineral precipitates. However, in freezing, compared to evaporation, the following key differences were found: (1) magnesium sulfates had higher hydration states; (2) there was greater total aqueous sulfate (SO_4T = SO₄ + HSO₄) removal; and (3) there was a significantly higher aqueous Cl/SO_4T ratio in the residual Na-Mg-Cl brine. Given the similarities of model results to observations, alternating dry/wet and freeze/thaw cycles and brine migration could have played major roles in vug formation, Cl stratification, and hematite concretion formation on Mars.  相似文献   

Bioaccumulation of PAHs in marine zooplankton: an experimental study in the copepod <Emphasis Type="Italic">Pseudodiaptomus marinus</Emphasis>     

Andrés H. Arias  Anissa Souissi  Marion Roussin  Baghdad Ouddane  Sami Souissi 《Environmental Earth Sciences》2016,75(8):691

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