Silica depleted melting of pelites. Petrogenetic grid and application to the Susqueda Aureole, Spain   总被引：2，自引：0，他引：2  

M. Riesco  K. Stüwe  J. Reche  F. J. Martinez 《Journal of Metamorphic Geology》2004,22(5):475-494

Metapelitic rocks in the low pressure contact metamorphic aureole around the Susqueda igneous complex, Spain show a number of features that make them an ideal testing ground for the modelling of silica‐undersaturated melting. Rocks in the aureole experienced localized depletion in silica by the segregation of quartz veins during a pre‐anatectic, regional cordierite‐andalusite grade metamorphic event. These rocks were then intruded by gabbroic to dioritic rocks of the Susqueda igneous complex that formed a migmatitic contact metamorphic aureole in the country rocks. This migmatisation event caused quartz‐saturated hornfels and restite formation in rocks that had experienced no quartz vein segregation in the previous regional metamorphic event, but silica‐undersaturated melting in those rocks that were previously depleted in silica. Silica‐undersaturated melting is investigated using a new petrogenetic P–T projection and equilibrium pseudosections calculated in the KFMASH and NCKFMASH systems, respectively. The grid considers quartz absent equilibria and a range of phases that form typically in silica‐undersaturated bulk compositions, for example corundum. It is shown that the quartz‐rich precursors in the Susqueda contact aureole produced about 10% melt during contact metamorphism. However, most of this melt was extracted leaving behind rocks with restitic bulk compositions and minor leucosome segregation. It is suggested that the melt mixed with the host igneous rocks causing an apparent magmatic zoning from diorite in the centre of the complex to tonalite at the margins. In contrast, the quartz‐poor precursors (from which the quartz veins segregated) melted in the silica‐undersaturated field producing a range of assemblages including peritectic corundum and spinel. Melting of the silica‐undersaturated rocks produced only negligible melt and no subsequent melt loss.  相似文献   

An interhemispheric mechanism for glacial abrupt climate change     

Rubén Banderas  Jorge Alvarez-Solas  Alexander Robinson  Marisa Montoya 《Climate Dynamics》2015,44(9-10):2897-2908

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Snowmelt contribution to the sustainability of the irrigated Mendoza’s Oasis,Argentina: an isotope study     

Hector Massone  Daniel Martinez  Alberto Vich  Mauricio Quiroz Londoño  Darío Trombotto  Sebastián Grondona 《Environmental Earth Sciences》2016,75(6):520

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Anaerobic digestion of residual liquid effluent (brown juice) from a green biorefinery     

E. J. Martinez  F. Micolucci  X. Gomez  B. Molinuevo-Salces  H. Uellendahl 《International Journal of Environmental Science and Technology》2018,15(12):2615-2624

This work studied the anaerobic digestion of brown juice, a liquid residual stream generated from biomass fractionation in a green biorefinery. Biomethane potential batch tests and inhibition studies of brown juice were performed during continuous processing in an upflow anaerobic sludge blanket reactor. Prolongation of the lag phase in the batch tests with increasing substrate/inoculum ratio suggested initial inhibition, which was, however, overcome by adaptation. This was indicated by high final methane yields, which were close to the theoretical maximum of up to 500 L-CH₄ kg-VS^?1, achieved after 15 days for most of the set-ups. Reactor operation at the organic loading rate of 13.9 g-COD L^?1 day^?1 and hydraulic retention time of 3 days revealed methane yields of 202 L-CH₄ kg-COD^?1 (307 L-CH₄ kg-VS^?1). Particle size analysis of the granules used in the reactor showed disintegration of the larger granules.  相似文献   

New observations on high‐pressure phases in a shock melt vein in the Villalbeto de la Peña meteorite: Insights into the shock behavior of diopside     

Marina Martinez  Adrian J. Brearley  Josep M. Trigo‐Rodríguez  Jordi Llorca 《Meteoritics & planetary science》2019,54(11):2845-2863

The petrology and mineralogy of shock melt veins in the L6 ordinary chondrite host of Villalbeto de la Peña, a highly shocked, L chondrite polymict breccia, have been investigated in detail using scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, and electron probe microanalysis. Entrained olivine, enstatite, diopside, and plagioclase are transformed into ringwoodite, low‐Ca majorite, high‐Ca majorite, and an assemblage of jadeite‐lingunite, respectively, in several shock melt veins and pockets. We have focused on the shock behavior of diopside in a particularly large shock melt vein (10 mm long and up to 4 mm wide) in order to provide additional insights into its high‐pressure polymorphic phase transformation mechanisms. We report the first evidence of diopside undergoing shock‐induced melting, and the occurrence of natural Ca‐majorite formed by solid‐state transformation from diopside. Magnesiowüstite has also been found as veins injected into diopside in the form of nanocrystalline grains that crystallized from a melt and also occurs interstitially between majorite‐pyrope grains in the melt‐vein matrix. In addition, we have observed compositional zoning in majorite‐pyrope grains in the matrix of the shock‐melt vein, which has not been described previously in any shocked meteorite. Collectively, all these different lines of evidence are suggestive of a major shock event with high cooling rates. The minimum peak shock conditions are difficult to constrain, because of the uncertainties in applying experimentally determined high‐pressure phase equilibria to complex natural systems. However, our results suggest that conditions between 16 and 28 GPa and 2000–2200 °C were reached.  相似文献   

Genetic structure of Octopus vulgaris around the Iberian Peninsula and Canary Islands as indicated by microsatellite DNA variation   总被引：2，自引：0，他引：2  

Cabranes  C.; Fernandez-Rueda  P.; Martinez  J. L. 《ICES Journal of Marine Science》2008,65(1):12-16

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Distribution of the organic matter in the channel-levees systems of the Congo mud-rich deep-sea fan (West Africa). Implication for deep offshore petroleum source rocks and global carbon cycle     

François Baudin  Jean-Robert Disnar  Philippe Martinez  Bernard Dennielou 《Marine and Petroleum Geology》2010

The quantity and the source of organic matter preserved in the Recent turbiditic channel-levees systems around 4000 m-depth off the Congo River were determined using bulk geochemical approaches (Rock-Eval, elemental and isotopic analyses) as well as molecular and optical analyses on selected samples. These mud-rich sediments contain high amount of organic matter (3% Corg on average), the origin of which is a mixture of terrestrial higher-plant debris and deeply oxidized phytoplanktonic material. Although the relative contribution of continental source versus marine source of the organic matter cannot be precisely quantified, the continental fraction appears significant (at least 70–80%) especially for such depths and distances from the coast. The organic matter distribution appears very homogeneous at different scales, from the single turbiditic event to the entire levee, and changes in accumulation rates have a little impact on the quantity and quality of preserved organic matter.  相似文献   

LMWOA (low molecular weight organic acid) exudation by salt marsh plants: Natural variation and response to Cu contamination     

Ana P. Mucha  C. Marisa R. Almeida  Adriano A. Bordalo  M. Teresa S.D. Vasconcelos 《Estuarine, Coastal and Shelf Science》2010

This work aimed to evaluate, in vitro, the capability of roots of two salt marsh plants to release low molecular weight organic acids (LMWOAs) and to ascertain whether Cu contamination would stimulate or not organic acids exudation. The sea rush Juncus maritimus and the sea-club rush Scirpus maritimus, both from the lower Douro river estuary (NW Portugal), were used. Plants were collected seasonally, four times a year in 2004, during low tide. After sampling, plant roots were washed for removal of adherent particles and immersed for 2 h in a solution that matched salinity (3) and pH (7.5) of the pore water from the same location to obtain plant exudates. In one of the seasons, similar experiments were carried out but spiking the solution with different amounts of Cu in order to embrace the range between 0 and 1600 nM. In the final solutions as well as in sediment pore water LMWOAs were determined by high performance liquid chromatography. Plants were able to release, in a short period of time, relatively high amounts of LMWOAs (oxalate, citrate, malate, malonate, and succinate). In the sediment pore water oxalate, succinate and acetate were also detected. Therefore, plant roots probably contributed to the presence of some of these organic compounds in pore water. Exudation differed between the plant species and also showed some seasonally variation, particularly for S. maritimus. The release of oxalate by J. maritimus increased with Cu increase in the media. However, exudation of the other LMWOAs did not seem to be stimulated by Cu contamination in the media. This fact is compatible with the existence of alternative internal mechanisms for Cu detoxification, as denoted by the fact that in media contaminated with Cu both plant species accumulated relatively high amounts (29–83%) of the initially dissolved Cu. This study expands our knowledge on the contribution of globally dominant salt marsh plants to the release of LMWOAs into the environment.  相似文献   

Changes in the ionic composition of a saline lake,Mar Chiquita,Province of Córdoba,Argentina     

D. E. Martinez 《International Journal of Salt Lake Research》1995,4(1):25-44

Mar Chiquita is the largest water-body in Argentina according to area. This ranges from 2,000 km² in dry periods to 5,000 km² in humid ones. Its very high salinity ranged this century from 200 to 300 g/L, but an increase in the average rainfall in the basin since 1973 has led to a rise in lake level and the dilution of its waters to 78 g/L in 1978 and about 30 g/L in the late 1980s. Ionic strength decreased from 6.61 in 1970 to 0.541 in 1986. The composition of the water also changed, with increases in the proportions of sulphate, calcium and magnesium concentrations. The most important processes taking place in solution are calcite and gypsum equilibrium, formation of clay minerals, and sulphate reduction in the interstitial waters of the bottom sediments. The thermodynamic state of the solutions for different years has been obtained. Results show that the solution shifted from gypsum oversaturation in 1970 to gypsum equilibrium in 1978, and to gypsum undersaturation since 1982. A geochemical simulation of the composition of the solution from its origin from mean tributary composition, following a modified Hardie-Eugster model, has been developed using PHRQPITZ. The results agree with empirical observations.  相似文献   

Rapid formation of large coastal sand bodies after emplacement of Magdalena river jetties,northern Colombia     

J. O. Martinez  O. H. Pilkey Jr.  W. J. Neal 《Environmental Geology》1990,16(3):187-194

The Magdalena River is noted for its high discharge of river sediment and its importance as the sediment source for a large delta complex and downdrift coastal sand bodies. The emplacement of jetties, completed in 1935 to stabilize the river mouth, contributed to major changes in the downstream coastal sand bodies. The western delta front retreated an average 65 m/yr. Puerto Colombia spit detached and migrated toward Puerto Colombia at rates of 230–430 m/yr, ultimately running into the town's quay and port facility. Galerazamba spit alternately elongated and shortened over the short term, leading to the destruction or damage of coastal town sites. Isla Cascajo acted as a significant sand trap with nearly 12 km² of accretion over a 47-year period. Sand is now bypassing the tombolo, and the accretion zone continues migrating southwest. The small Punta Canaos spit also has shown significant accretion since 1974. The changes imply high rates of sediment transport; furthermore their growth is probably dependent on jetty-caused alterations of wave patterns, causing remobilization of shelf sands as well as delta-derived sand.Understanding sand body evolution and behavior is important to future development of the northern Colombia coast. Placement of port facilities, recreational beaches, tourist villages, and related support facilities on these sand bodies, as well as utilizing the sand bodies for aggregate, beach nourishment sands for other areas, or heavy mineral resources will require significant planning.  相似文献