The role of bromine and chlorine chemistry for arctic ozone depletion events in Ny-Ålesund and comparison with model calculations     

M. Martinez  T. Arnold  D. Perner 《Annales Geophysicae》1999,17(7):941-956

During the Arctic Tropospheric Ozone Chemistry (ARCTOC) campaigns at Ny-Ålesund, Spitsbergen, the role of halogens in the depletion of boundary layer ozone was investigated. In spring 1995 and 1996 up to 30 ppt bromine monoxide were found whenever ozone decreased from normal levels of about 40 ppb. Those main trace gases and others were specifically followed in the UV-VIS spectral region by differential optical absorption spectroscopy (DOAS) along light paths running between 20 and 475 m a.s.l. The daily variation of peroxy radicals closely followed the ozone photolysis rate J(O₃(O¹D)) in the absence of ozone depletion most of the time. However, during low ozone events this close correlation was no longer found because the measurement of radicals by chemical amplification (CA) turned out to be sensitive to peroxy radicals and ClO_x. Large CA signals at night can sometimes definitely be assigned to ClO_x and reached up to 2 ppt. Total bromine and iodine were both stripped quantitatively from air by active charcoal traps and measured after neutron activation of the samples. Total bromine increased from background levels of about 15 ppt to a maximum of 90 ppt during an event of complete ozone depletion. For the spring season a strong source of bromine is identified in the pack ice region according to back trajectories. Though biogenic emission sources cannot be completely ruled out, a primary activation of halogenides by various oxidants seems to initiate an efficient autocatalytic process, mainly driven by ozone and light, on ice and perhaps on aerosols. Halogenides residing on pack ice surfaces are continuously oxidised by hypohalogenous acids releasing bromine and chlorine into the air. During transport and especially above open water this air mixes with upper layer pristine air. As large quantities of bromine, often in the form of BrO, have been observed at polar sunrise also around Antarctica, its release seems to be a natural phenomenon. The source strength of bromine from halogen activation on the pack ice, as based on the measured inorganic bromine levels, averages about 10¹² Br-atoms m⁻² s⁻¹ during sunlit periods in Arctic spring. The total source strength of inorganic bromine from sunlit polar regions may therefore amount to 30 kt y⁻¹.  相似文献   

The Measurement of Active Chlorine in the Atmosphere by Chemical Amplification     

D. Perner  T. Arnold  J. Crowley  T. Klüpfel  M. Martinez  R. Seuwen 《Journal of Atmospheric Chemistry》1999,34(1):9-20

Chemical amplification, CA, a method commonly used for the detection of peroxy radicals, HO₂ and RO₂, was found to be sensitive towards ClOx (Cl+ClO+OClO) as well. ClOx is reduced by NO to Cl atoms which react with carbon monoxide in the presence of O₂. The reaction sequence thus initiated oxidizes CO to CO₂ and NO to NO₂, with a chain length of 300 ± 60. This allows the atmospheric ClOx content to be measured under ambient conditions with a detection limit of better than 1 ppt. In parallel peroxy radicals are indicated with a chain length of 160 ± 15. Chemical amplification is not specific and does not indicate which radical chain it is seeing. Identification relies solely on plausibility. During the ARCtic Tropospheric Ozone Chemistry (ARCTOC) campaign in spring 1995 and 1996 the CA technique was used at Ny-Ålesund. ClOx at mixing ratios of up to 2 ppt were found in the boundary layer under certain conditions. The low concentrations of ClOx indicate that the arctic boundary ozone depletion is mainly driven by bromine.  相似文献   

Long-term fluctuations in volcanic activity: implications for future environmental impact     

Hazel Rymer  Corinne A. Locke  rea Borgia  Maria Martinez  Jorge Brenes  Rodolfo Van der Laat  Glyn Williams-Jones 《地学学报》2009,21(4):304-309

Acidic crater lakes at persistently active volcanoes act as both an index and a moderator of volcanic processes. A catastrophic drop in lake level can therefore lead to serious local environmental damage. In the early 1990s, the crater lake at Poás volcano, Costa Rica diminished, and acid aerosols erupted with devastating consequences for local health, environment and economy. The first indications of this event can be  retrospectively identified to have started from 1985, on the basis of our unique 20-year data time series, which provides evidence for the shallow intrusion of magma. New data presented in this article show similar trends and we conclude that Poás has now entered another active period with renewed intrusion. Severe environmental damage in this region is expected within the next few years if the current trend continues.  相似文献   

29 frequencies for the δ Scuti variable BI CMi: the 1997–2000 multisite campaigns     

M. Breger  R. Garrido  G. Handler  M.A. Wood  R.R. Shobbrook  K.M. Bischof  F. Rodler  R. O. Gray  A. Stankov  P. Martinez  D. O'Donoghue  R. Szabó  W. Zima  A. B. Kaye  C. Barban  U. Heiter 《Monthly notices of the Royal Astronomical Society》2002,329(3):531-542

A multisite campaign of BI CMi was carried out with excellent frequency resolution and high photometric accuracy from 1997 to 2000, including two long observing seasons. 29 pulsation frequencies could be extracted from the 1024 h (177 nights) of photometry used. The detected frequencies include 20 pulsation modes in the main pulsation frequency range from 4.8 to 13.0 cycle d⁻¹ (55 to 150 μHz), eight linear combinations of these frequencies, and a very low frequency at 1.66 cycle d⁻¹. Since the value of the low frequency at 1.66 cycle d⁻¹ cannot be identified with a linear combination of other frequencies, g-mode pulsation is suspected, but rotational modulation of abundance spots cannot be ruled out. BI CMi, which is situated near the cool edge of the classical instability strip, may be both a δ Scuti and a γ Doradus star. Another outstanding property of BI CMi is the presence of a number of close frequency pairs in the power spectrum with separations as small as 0.01 cycle d⁻¹.
A rotational velocity of     was determined from a high-dispersion spectrum. From phase differences, the dominant modes can be identified with ℓ values from 0 to 2. The spectral type and evolutionary status of BI CMi are examined.  相似文献   

Conrad deep: a new northern Red Sea deep: Origin and implications for continental rifting     

James R. Cochran  Fernando Martinez  Michael S. Steckler  Michael A. Hobart 《Earth and Planetary Science Letters》1986,78(1)

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X-ray diffraction study of magnesite at high pressure and high temperature     

J. Zhang  I. Martinez  F. Guyot  P. Gillet  S. K. Saxena 《Physics and Chemistry of Minerals》1997,24(2):122-130

 P–V–T measurements on magnesite MgCO₃ have been carried out at high pressure and high temperature up to 8.6 GPa and 1285 K, using a DIA-type, cubic-anvil apparatus (SAM-85) in conjunction with in situ synchrotron X-ray powder diffraction. Precise volumes are obtained by the use of data collected above 873 K on heating and in the entire cooling cycle to minimize non-hydrostatic stress. From these data, the equation-of-state parameters are derived from various approaches based on the Birch-Murnaghan equation of state and on the relevant thermodynamic relations. With K′₀ fixed at 4, we obtain K₀=103(1) GPa, α(K⁻¹)=3.15(17)×10⁻⁵ +2.32(28)×10⁻⁸ T, (∂K_T/∂T)_P=−0.021(2) GPaK⁻¹, (dα/∂P)_T=−1.81×10⁻⁶ GPa⁻¹K⁻¹ and (∂K_T/∂T)_V= −0.007(1) GPaK⁻¹; whereas the third-order Birch-Murnaghan equation of state with K′₀ as an adjustable parameter yields the following values: K₀=108(3) GPa, K′₀=2.33(94), α(K⁻¹)=3.08(16)×10⁻⁵+2.05(27) ×10⁻⁸ T, (∂K_T/∂T)_P=−0.017(1) GPaK⁻¹, (dα/∂P)_T= −1.41×10⁻⁶ GPa⁻¹K⁻¹ and (∂K_T/∂T)_V=−0.008(1) GPaK⁻¹. Within the investigated P–T range, thermal pressure for magnesite increases linearly with temperature and is pressure (or volume) dependent. The present measurements of room-temperature bulk modulus, of its pressure derivative, and of the extrapolated zero-pressure volumes at high temperatures, are in agreement with previous single-crystal study and ultrasonic measurements, whereas (∂K_T/∂T)_P, (∂α/∂P)_T and (∂K_T/∂T)_V are determined for the first time in this compound. Using this new equation of state, thermodynamic calculations for the reactions (1) magnesite=periclase+CO₂ and (2) magnesite+enstatite=forsterite+CO₂ are consistent with existing experimental phase equilibrium data. Received September 28, 1995/Revised, accepted May 22, 1996  相似文献   

Loss of regional population structure in Atlantic salmon, Salmo salar L., following stocking     

Ayllon  Fernando; Martinez  Jose L.; Garcia-Vazquez  Eva 《ICES Journal of Marine Science》2006,63(7):1269-1273

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Three-dimensional SeaMARC II,gravity, and magnetics study of large-offset rift propagation at the Pito Rift,Easter microplate   总被引：1，自引：0，他引：1  

Fernando Martinez  David F. Naar  Thomas B. Reed IV  Richard N. Hey 《Marine Geophysical Researches》1991,13(4):255-285

We present results from a SeaMARC II bathymetry, gravity, and magnetics survey of the northern end of the large-offset propagating East Rift of the Easter microplate. The East Rift is offset by more than 300 km from the East Pacific Rise and its northern end has rifted into approximately 3 Ma lithosphere of the Nazca Plate forming a broad (70–100 km) zone of high (up to 4 km) relief referred to as the Pito Rift. This region appears to have undergone distributed and asymmetric extension that has been primarily accommodated tectonically, by block faulting and tilting, and to a lesser degree by seafloor spreading on a more recently developed magmatic accretionary axis. The larger fault blocks have dimensions of 10–15 km and have up to several km of throw between adjacent blocks suggesting that isostatic adjustments occur on the scale of the individual blocks. Three-dimensional terrain corrected Bouguer anomalies, a three-dimensional magnetic inversion, and SeaMARC II backscatter data locate the recently developed magmatic axis in an asymmetric position in the western part of the rift. The zone of magmatic accretion is characterized by an axis of negative Bouguer gravity anomalies, a band of positive magnetizations, and a high amplitude magnetization zone locating its tip approximately 10 km south of the Pito Deep, the deepest point in the rift area. Positive Bouguer gravity anomalies and negative magnetizations characterize the faulted area to the east of the spreading axis supporting the interpretation that this area consists primarily of pre-existing Nazca plate that has been block faulted and stretched, and that no substantial new accretion has occurred there. The wide zone of deformation in the Pito Rift area and the changing trend of the fault blocks from nearly N-S in the east to NW-SE in the west may be a result of the rapidly changing kinematics of the Easter microplate and/or may result from ridge-transform like shear stresses developed at the termination of the East Rift against the Nazca plate. The broad zone of deformation developed at the Pito Rift and its apparent continuation some distance south along the East Rift has important implications for microplate mechanics and kinematic reconstructions since it suggests that initial microplate boundaries may consist in part of broad zones of deformation characterized by the formation of lithospheric scale fault blocks, and that what appear to be pseudofaults may actually be the outer boundaries of tectonized zones enclosing significant amounts of stretched pre-existing lithosphere.  相似文献   

The genetic structure of Pandalus borealis in the Northeast Atlantic determined by RAPD analysis     

Martinez  Iciar; Aschan  Michaela; Skjerdal  Taran; Aljanabi  Salah M. 《ICES Journal of Marine Science》2006,63(5):840-850

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Projection of future climate change conditions using IPCC simulations, neural networks and Bayesian statistics. Part 1: Temperature mean state and seasonal cycle in South America     

Jean-Philippe Boulanger  Fernando Martinez  Enrique C. Segura 《Climate Dynamics》2006,27(2-3):233-259

Projections for South America of future climate change conditions in mean state and seasonal cycle for temperature during the twenty-first century are discussed. Our analysis includes one simulation of seven Atmospheric-Ocean Global Circulation Models, which participated in the Intergovernmental Panel on Climate Change Project and provided at least one simulation for the twentieth century (20c3m) and one simulation for each of three Special Report on Emissions Scenarios (SRES) A2, A1B, and B1. We developed a statistical method based on neural networks and Bayesian statistics to evaluate the models’ skills in simulating late twentieth century temperature over continental areas. Some criteria [model weight indices (MWIs)] are computed allowing comparing over such large regions how each model captures the temperature large scale structures and contributes to the multi-model combination. As the study demonstrates, the use of neural networks, optimized by Bayesian statistics, leads to two major results. First, the MWIs can be interpreted as optimal weights for a linear combination of the climate models. Second, the comparison between the neural network projection of twenty-first century conditions and a linear combination of such conditions allows the identification of the regions, which will most probably change, according to model biases and model ensemble variance. Model simulations in the southern tip of South America and along the Chilean and Peruvian coasts or in the northern coasts of South America (Venezuela, Guiana) are particularly poor. Overall, our results present an upper bound of potential temperature warming for each scenario. Spatially, in SRES A2, our major findings are that Tropical South America could warm up by about 4°C, while southern South America (SSA) would also undergo a near 2–3°C average warming. Interestingly, this annual mean temperature trend is modulated by the seasonal cycle in a contrasted way according to the regions. In SSA, the amplitude of the seasonal cycle tends to increase, while in northern South America, the amplitude of the seasonal cycle would be reduced leading to much milder winters. We show that all the scenarios have similar patterns and only differ in amplitude. SRES A1B differ from SRES A2 mainly for the late twenty-first century, reaching more or less an 80–90% amplitude compared to SRES A2. SRES B1, however, diverges from the other scenarios as soon as 2025. For the late twenty-first century, SRES B1 displays amplitudes, which are about half those of SRES A2.  相似文献