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41.
How and how fast do hillslope soils form as the landscape’s morphology changes over time? Here results are shown from an ongoing study that simultaneously examines the morphologic and geochemical evolution of soil mantled hillslopes that have been exposed to distinctively different denudation history. In Northern Sierra Nevada, California, the authors are investigating a tributary basin to the Middle Fork Feather River. A major incision signal from the river is well marked in a knickpoint within the tributary basin which stretches from its mouth to the Feather River at an elevation of ~700 m to the plateau at an elevation of ~1500 m. Hillslopes are significantly steeper below the knickpoint. The area’s total denudation rates are currently being constrained using cosmogenic radio nuclides, but a previous study suggested an order of magnitude difference in total denudation rates below and above the knickpoint. When compared with topographic attributes calculated from LIDAR data, physical erosion rates can be modeled as a linear function of ridge top curvature. Surprisingly, over the wide range of total denudation rates, soil thicknesses do not vary significantly until a threshold point where soil mantled landscapes abruptly shift to bedrock dominated landscapes. Bioturbation by tree falls appear to buffer soil thickness over the wide range of physical soil erosion rates. From three hillslopes with different physical erosion rates, the concentrations of Zr, which were considered conserved during dissolution and leaching, were determined and used as a proxy for the degree of mass losses via chemical denudation. There is a general trend that colluvial soils along the hillslopes with lower physical erosion rates are enriched in fine size fractions, Zr, and pedogenic crystalline Fe oxides. Likewise, the saprolites show greater degrees of chemical denudation at the sites above the knickpoint, presumably because of the saprolites’ longer turnover time in the slowly eroding landscapes. In the two steep hillslopes below the knickpoint, no significant or systematic topgraphic trends were found for soil geochemistry. However, soils show increasing Zr enrichment in the downslope direction in the hillslope above the knickpoint, which suggests a critical denudation rate beyond which soils’ turnover time is too short to develop a geochemical catena. As detailed CRN-based soil production rates and catchment scale denudation rates are acquired, the data will be combined with a mass balance model to calculate the rates of chemical denudation and weathering in soils and saprolites along the denudation gradient.  相似文献   
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Both water level drops and erosion have previously been suggested as causes of fluid overpressures in the subsurface. Quantification of the relevance of these processes to supra-lithostatic fluid pressure formation with a wide selection of input parameters is lacking, and thus desired. The magnitudes and drop times that are required for water level drops to result in supra-lithostatic pore pressures in a variety of situations are calculated. Situations with pore fluids consisting of water, water with dissolved methane, water with a gas hydrate layer and dissolved methane in the underlying sediments, and water with dissolved methane, a gas hydrate layer, and free gas accumulation below the hydrate layer are separately addressed. The overpressure formation from reservoir gas expansion is also simulated. The simulation results demonstrate that high fluid overpressures can develop in a rock as a response to a water level drop without the presence of gas, provided that the rock has a sufficiently low compressibility. The contribution to fluid overpressuring is however dramatically increased if the pore water is saturated with methane prior to the water level drop, and is further amplified by the presence of gas hydrates and free gas accumulations beneath such hydrates. Gas expansion in reservoirs should be expected to significantly increase the fluid overpressures in shallow, sealed pressure compartments that experience erosion or water level drops, even if the water level drop duration exceeds one million years. Enough relationships between the calculated overpressure formation and the main controlling factors are provided in order to enable readers to make inferences about a variety of geological settings. Analyses of simulation results prompt us to suggest that pockmarks are likely to be triggered by gas expansion in vertical fluid migration pathways, that the giant craters at the seabed west of Albatross South in the Barents Sea result from hydrate dissociation, and that overpressure build-up due to gas expansion has contributed to reservoir overpressuring in many eroded basins, including the Hammerfest Basin in the Barents Sea.  相似文献   
44.
A two-fluid, small scale numerical ocean model was developed to simulate plume dynamics and increases in water acidity due to leakages of CO2 from potential sub-seabed reservoirs erupting, or pipeline breaching into the North Sea. The location of a leak of such magnitude is unpredictable; therefore, multiple scenarios are modelled with the physiochemical impact measured in terms of the movement and dissolution of the leaked CO2. A correlation for the drag coefficient of bubbles/droplets free rising in seawater is presented and a sub-model to predict the initial bubble/droplet size forming on the seafloor is proposed. With the case studies investigated, the leaked bubbles/droplets fully dissolve before reaching the water surface, where the solution will be dispersed into the larger scale ocean waters. The tools developed can be extended to various locations to model the sudden eruption, which is vital in determining the fate of the CO2 within the local waters.  相似文献   
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We discuss a model for the formation of the chromospheric Ca ii K line which does not make the usual assumption of complete redistribution. Using a physically reasonable scattering model, we find significant departures due to the frequency dependence of the line source function, particularly in the relative intensity and centre-to-limb behaviour of the K1 parts of the line and in the asymmetry produced by differential velocity fields. We conclude that the frequency dependence of the K line source function must be considered in quantitative models for the formation of the K line.  相似文献   
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Episodes of air pollution over Cape Town are identified using multi-year time series of SO2 and NOx concentrations. The associated meteorological conditions are studied both from synoptic and meso-scale perspectives using detailed observations, statistical analyses and numerical model simulations. Atmospheric conditions are most conducive to poor dispersion in the winter months, April to August. Episodes are initiated by the eastward passage of an intense, synoptic anticyclone over the Cape Town area. The 850 hPa geopotential height typically rises to 1600 gpm a day before the episode. Northeasterly berg winds are common and act to dry out the boundary layer. A nocturnal radiation inversion forms with a mean strength of 11 °C and extends from the surface to 953 hPa (500m). Gradient and thermal winds tend to cancel out providing for low net transport rates for near-surface emissions. Acoustic sounder profiles for two episodes illustrate a reduction of winds and turbulence within the boundary layer. The episode surface circulation is simulated using a two-layer model. Hills which lie upstream of Cape Town obstruct the northeasterly flow during the morning.  相似文献   
49.
Fluid mud in estuarine turbidity maximum zones (TMZ) can pose considerable navigation risks due to potentially substantial reductions in nautical depth, coupled with an inherent difficulty of detection by conventional echo-sounders. Despite intensive research efforts, however, our knowledge about the spatial and temporal dynamics of fluid mud is still not sufficient. In this study, the combined use of a side-scan sonar (Sportscan®, Imagenex) and a parametric sub-bottom profiler (SES-2000®, Innomar Technology GmbH) has proved successful for high-resolution fluid mud detection and volumetric quantification in an estuarine environment. In 2004 and 2005, repeated surveys were conducted in the navigation channel of the upper meso- to lower macrotidal Weser estuary TMZ (German North Sea coast) at different tidal stages and river discharges. Current velocity data were simultaneously collected by 1,200-kHz broadband ADCP (RDInstruments) measurements. Ground-truthing was carried out by means of grab sampling and gravity coring, adapted to fluid mud conditions. It was found that fluid mud occurrence in the Weser estuary is highly variable on time scales of a few hours and spatial scales of several metres. The riverbed is characterised by sand and mud deposits, and a complex morphology including subaqueous dunes and smooth bed deposits intermittently overlain by fluid mud. Thus, a continuous, coherent fluid mud body covering the entire TMZ riverbed was not observed. Rather, spatial distribution was patchy and highly dependent on suspended particulate matter (SPM) concentrations in the water column, as a result of which local fluid mud deposits varied in thickness from centimetres to metres. The formation of fluid mud was largely restricted to slack water, although slack-water conditions were not necessarily associated with large-scale fluid mud appearance. Advective SPM transport of resuspended fluid mud seems to be the most plausible explanation for the high spatial variability observed, even between two successive tides. The amount of fluid mud deposited and resuspended in the course of a tidal cycle can reach several 10s of tons even in small riverbed depressions.  相似文献   
50.
The blue crab, Callinectes sapidus, is distributed along the east coast of the United States from Cape Cod, Mass., through the Gulf of Mexico, including both relatively unpolluted coastal areas and estuaries contaminated with trace metals. Cadmium is of particular concern because it is concentrated in the digestive glands of blue crabs and can be passed on to consumer organisms. Tissue concentrations and partitioning of trace metals from crabs exposed in the laboratory to 10 ppb dissolved cadmium for 40 days were compared with blue crabs collected from two locations on the Hudson River, NY, Foundry Cove and Haverstraw Bay, Foundry Cove and Haverstraw Bay, both of which have elevated trace metal levels relative to estuarine areas near Beaufort, NC. Crab digestive glands, gills and muscle were removed and analyzed for total cadmium, copper, zinc and nickel concentrations using acid digestion and atomic absorption spectrophotometry, and metal-binding (metallothionein-like) proteins were determined by gel-filtration chromatography. In crabs exposed to cadmium in the laboratory, the cytosolic partitioning was similar to previous investigations at our laboratory where higher levels of cadmium (100 ppb) and shorter exposure times (14 days) were used. The similarity in cadmium partitioning from these two separate experiments indicates dose independence. In crabs from polluted environments the digestive glands contained the highest concentrations of trace metals. Chromatograms of the cytosol from the digestive glands and gills from both field and laboratory exposed crabs showed similar distributions of cadmium, copper and zinc. The gills of both field and laboratory-exposed crabs had metal-binding proteins that contained mostly cadmium, and the digestive glands had metallothionein-like proteins that contained cadmium, copper and zinc. Estimated molecular weights for these proteins were similar to the metallothioneins found in other crustaceans and mammals.  相似文献   
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