Degradation of chlorinated ethylenes by Fe0: inhibition processes and mineral precipitation   总被引：2，自引：0，他引：2  

Ralf Köber  Oliver Schlicker  Markus Ebert  Andreas Dahmke 《Environmental Geology》2002,41(6):644-652

. Granular zero-valent iron was used for the treatment of groundwater pollution caused by chlorinated ethylenes, mainly TCE, cis-DCE and VC at an industrial site. The rapidly decreasing rates of de-chlorination in the initial phase were attributed to the precipitation of carbonates and the development of hydrogen by anaerobic corrosion. After 70 pore volumes, sulphate was reduced by bacteria. From this point in time, the degradation of TCE was slightly accelerated whereas the de-chlorination rates of the other chlorinated ethylenes decreased only slowly. This relative improvement was assumed to be caused by the uptake of electron-transfer-blocking hydrogen by bacteria. Because the overall trend of the degradation rates is negative we conclude that the inhibitive effect of carbonate precipitation and hydrogen formation cannot be compensated for by the positive influence of the activity of sulphate-reducing bacteria.  相似文献   

Variations of O/O in plants from temperate peat bogs (Switzerland): implications for paleoclimatic studies     

Guillemette Ménot-Combes  Stephen J. Burns  Markus Leuenberger 《Earth and Planetary Science Letters》2002,202(2):419-434

Despite the great potential of peat bogs as climatic archives, to date only few studies have focused on the climatic controls on cellulose isotopic composition in modern bog plants. This study attempts to calibrate plant-climate relationships by sampling a set of modern plant species (both vascular plants and mosses) and bog surface waters along an altitude transect in Switzerland. Isotopic analyses of water samples show that the δ¹⁸O-values of surface bog waters follow the trend of precipitation despite significant scatter in the data set. Detailed sampling of surface waters within one bog shows that δ¹⁸O-values vary widely and are closely related to the micro-topography of the bog surface. More enriched ¹⁸O/¹⁶O ratios in water samples collected from small raised hummocks than the ones collected from hollows are documented in both horizontal and vertical profiles. A δ¹⁸O-δD plot indicates that the process leading to the isotopic enrichment of the uppermost surface waters is evaporation, greater above Sphagnum covered hummocks than above open pools. To investigate the implications of such high variability of source water for plant α-cellulose δ¹⁸O-values, a detailed study of both surface water and α-cellulose δ¹⁸O-values within one site is conducted. The large δ¹⁸O variability observed in surface waters is found to be considerably smoothed in α-cellulose (by a factor of 5-10 depending on the plant species). This indicates that the water used by plant photosynthetic processes reflects the isotopic composition of the average annual precipitation. This points to a source water level for plants of a few decimeters where the variations are smaller than at the air-water interface. The response of the α-cellulose δ¹⁸O to the environmental gradient along the altitude transect varies considerably from species to species. For most of the species studied, the δ¹⁸O-values decrease with altitude, following the trends of δ¹⁸O-values in precipitation and in surface water samples. Some species, the cotton sedge Eriophorum vaginatum and the moss Sphagnum capillifolium, show statistically significant δ¹⁸O relationships to an altitude of −1.8‰/km and −2.9‰/km respectively. However, some other plant species, Calluna vulgaris, Vaccinium uliginosum, Andromeda poliflora, Carex pauciflora, Sphagnum cuspidatum and Sphagnum magellanicum, do not, or only partially, reflect changes in climatic parameters associated with an altitude increase. Furthermore, changes in relative humidity, which are not correlated with altitude, are found to explain a large part of the variability in δ¹⁸O-values for the sedge Carex pauciflora and the moss Sphagnum cuspidatum. Therefore, this study confirms the importance of species-specific studies when interpreting ¹⁸O/¹⁶O ratios of macrofossils along a fossil peat sequence as a record of past climate changes. Our study allows to extend the mechanistic model that isotopically links source water and cellulose to the physiological specificities of sedges and mosses. A comparison of the modeled and calculated net biological fractionation factors for Eriophorum vaginatum and Sphagnum capillifolium reveals that these two species appear to have a more homogeneous leaf reservoir than trees.  相似文献   

A Mediterranean earthquake project     

Markus Bth 《Tectonophysics》1979,58(3-4)

Cumulative frequency and cumulative energy may vary from one sample of earthquakes to another either in the same or in the opposite sense. Conditions for the variations are deduced theoretically and illustrated by numerical examples.  相似文献   

Transient waves in visco-elastic media: Norman H. Ricker. Elsevier Scientific Publishing Co., Amsterdam-Oxford-New York,N.Y., 1977, 278 pp., Dfl. 120.00/US $ 48.95     

Markus Båth 《Physics of the Earth and Planetary Interiors》1978,16(2):179-180

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Seismic wave velocities in the lower mantle — Part II     

Markus Båth 《Pure and Applied Geophysics》1967,68(1):19-23

Summary In an earlier paper the author developed mathematical expressions for the longitudinal and transverse wave velocities in the lower mantle in the form of power functions of the radius. In the present paper we shall instead develop the velocities as power series or polynomials of the radius. The two procedures are compared with regard to accuracy and convenience in applications. The power series expansion can permit higher accuracy in the representation of the velocities, but often entails greater complications in applications.  相似文献   

Propagation ofSn andPn to teleseismic distances     

Markus Båth 《Pure and Applied Geophysics》1966,64(1):19-30

Summary Sn andPn waves propagated to teleseismic distances are investigated by means of short-period seismograph records of the Swedish network.Sn is found in the distance range of 2400 to 4600 km andPn in the range 3500 to 3900 km, but only provided the path is exceptionally homogeneous. Almost all paths are restricted to the Russian platform. There are probably very few areas in the world offering similar propagation paths. The velocities just under the Mohorovii discontinuity are found to be 4.72 km/sec and 8.26 km/sec for transverse and longitudinal waves respectively. In addition, other properties of the teleseismicSn andPn are investigated, such as periods, dispersion, amplitudes, particle motions, propagation mechanisms, and comparisons are made withPa, Sa, withLi, Lg1, Lg2 and withP. The fact that teleseismicPn occurs much more seldom than teleseismicSn could be explained by different velocity profiles just under the crust.  相似文献   

Surface-wave magnitude corrections for intermediate and deep earthquakes     

Markus Båth 《Physics of the Earth and Planetary Interiors》1985,37(4):228-234

The small amplitudes of surface waves for intermediate and deep-focus earthquakes lead to too low values of the surface-wave magnitudes. On the basis of available material, average magnitude corrections are deduced, which increase with focal depth and amount to 0.1–0.5 for focal depths of 50 100 km and to 0.5–0.7 for depths of 100–700 km.  相似文献   

Analogy between elastic and electric systems     

Rune Olsson  Markus Båth 《Physics of the Earth and Planetary Interiors》1975,10(1):1-11

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A method for mapping seismic intensities applied to Sweden     

Markus Båth 《Tectonophysics》1980,66(4):T11-T18

Based on a combination of instrumental and macroseismic data, a method for calculating maximum seismic intensities is developed and applied to Sweden for the period 1951–1976. The method is particularly useful for areas with a low seismicity and a sparse population. Tectonophysical and engineering aspects on the resulting map are discussed.  相似文献   

Development of instrumental seismology in Sweden in 1949–1958     

Dr. Markus Båth 《Pure and Applied Geophysics》1959,43(1):108-130

Summary A review is given of the present (1959) seismological stations in Sweden, i.e. Uppsala, Kiruna, Skalstugan, and Göteborg, as well as of older stations, which are no longer in operation, i.e. Vassijaure, Abisko, and Lund, including all pertinent information. The disturbing effect of the loose ground at Lund in distinction from the four first-mentioned stations is clearly demonstrated. The very good ground at Uppsala, Kiruna, Skalstugan, and Göteborg, together with the use of modern equipment of high magnification has made these stations, especially Uppsala and Kiruna, very sensitive. This is obvious from the number of recorded earthquakes. The method of time measurements, including direct recording of time signals, is described, and means to reach a high time accuracy are outlined, including the recommendation to use quartz clocks. Long-period (0.5–2 min) disturbances on the long-period Benioff combinations were mainly due to air currents in the seismometer room and were eliminated by providing the seismometers with special covers. The method of ground amplitude determinations is outlined, especially for the Benioff instruments, and typical magnification curves are given. Comparisons of ground amplitudes from simultaneous records of BenioffE, N and WiechertE, N and of BenioffZ and GrenetZ have been made. The amplitude comparison between Benioff and Wiechert has given a new estimate of the effect of friction (especially of the recording pen against the paper) in the Wiechert apparatus.

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Zusammenfassung Eine Übersicht sowohl von den gegenwärtigen (1959) seismologischen Stationen in Schweden, d.h. Uppsala, Kiruna, Skalstugan und Göteborg, als auch von früheren Stationen, die nicht mehr im Betrieb sind, d.h. Vassijaure, Abisko und Lund, wird gegeben. Die störende Wirkung des lockeren Bodens in Lund zum Unterschied gegen die vier erstgenannten Stationen wird deutlich hervorgehoben. Der sehr gute Untergrund in Uppsala, Kiruna, Skalstugan und Göteborg und die Verwendung moderner Apparate hoher Vergrösserung haben diese Stationen, besonders Uppsala und Kiruna, sehr empfindlich gemacht. Dieser Umstand geht aus der Anzahl registrierter Beben hervor. Die Methode der Zeitmessungen (direkte Registrierung der Zeitsignale einbegriffen) wird beschrieben, und Massnahmen eine hohe Zeitgenauigkeit zu erreichen werden erwähnt, die auch die Verwendung von Quarz-Uhren umfassen. Langperiodische Störungen (Perioden 0.5–2 Min) auf den langperiodischen Benioff-Registrierungen waren hauptsächlich durch Luftströmungen im Seismometerraum verursacht und wurden durch spezielle Kappen über den Seismometern eliminiert. Die Methode der Bestimmung von Boden-Amplituden wird beschrieben, hauptsächlich für die Benioff-Instrumente, und typische Vergrösserungskurven sind gegeben. Vergleichungen der Bodenamplituden von parallelen Registrierungen von BenioffE, N und WiechertE, N und von BenioffZ und GrenetZ sind ausgeführt worden. Die Amplitudenvergleichung zwischen Benioff und Wiechert hat eine neue Schätzung des Einflusses der Reibung (speziell vom Schreibfeder gegen das Papier) im Wiechert-Seismographen gegeben.

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