The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt   总被引：4，自引：0，他引：4  

J. Sánchez España  E. López Pamo  E. Santofimia Pastor  J. Reyes Andrés  J. A. Martín Rubí 《Aquatic Geochemistry》2006,12(3):269-298

This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO₄⁼) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO₄⁼ anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb²⁺, Zn²⁺, Cu²⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10⁻¹) of the SO ₄⁼ ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.  相似文献   

Avalanche Risk During Backcountry Skiing – An Analysis of Risk Factors     

Harpa Grímsdóttir  David Mcclung 《Natural Hazards》2006,39(1):127-153

Skier-triggered avalanches are the main cause of avalanche accidents in backcountry skiing. The risk of accidents during backcountry skiing was analysed statistically and related to factors such as elevation level, aspect, stability rating and the time of the year. The analysis is based on a database about terrain usage and avalanche accidents from a large heli-skiing operator in Canada, which makes it possible to study the conditional probability of accidents given the recorded pattern of terrain usage. This study shows that the historical risk of accidentally triggering an avalanche greater than size 1 depends highly on the stability rating, with the highest risk occurring during “poor” stability. The risk is greater at high elevations, and it is lower during the late season than earlier on. Skier risk does not depend as much on aspect as may be indicated from avalanche data alone. However, it is relatively high in the N–NE–E sector. These factors are not independent of each other and therefore analyses of combined factors were also performed. Questionnaires and interviews were used to gain knowledge about the terrain selection of professional mountain guides. These results indicate that when selecting terrain, guides first look at the overall shape and size of the terrain, but avalanche history of terrain and inclination are also important factors. Finally, remarks in avalanche reports were analysed, and common human factors identified.  相似文献   

Effect of sampling and linkage on fault length and length–displacement relationship     

S-S. Xu  A. F. Nieto-Samaniego  S. A. Alaniz-Álvarez  L. G. Velasquillo-Martínez 《International Journal of Earth Sciences》2006,95(5):841-853

The power-law exponent (n) in the equation: D=cL ⁿ , with D = maximum displacement and L = fault length, would be affected by deviations of fault trace length. (1) Assuming n=1, numerical simulations on the effect of sampling and linkage on fault length and length–displacement relationship are done in this paper. The results show that: (a) uniform relative deviations, which means all faults within a dataset have the same relative deviation, do not affect the value of n; (b) deviations of the fault length due to unresolved fault tip decrease the values of n and the deviations of n increase with the increasing length deviations; (c) fault linkage and observed dimensions either increase or decrease the value of n depending on the distribution of deviations within a dataset; (d) mixed deviations of the fault lengths are either negative or positive and cause the values of n to either decrease or increase; (e) a dataset combined from two or more datasets with different values of c and orders of magnitude also cause the values of n to deviate. (2) Data including 19 datasets and spanning more than eight orders of fault length magnitudes (10⁻²–10⁵ m) collected from the published literature indicate that the values of n range from 0.55 to 1.5, the average value being 1.0813, and the peak value of n _d (double regression) is 1.0–1.1. Based on above results from the simulations and published data, we propose that the relationship between the maximum displacement and fault length in a single tectonic environment with uniform mechanical properties is linear, and the value of n deviated from 1 is mainly caused by the sampling and linkage effects.  相似文献   

Geometry and accuracy of reflecting points in bistatic satellite altimetry     

J. Kostelecký  J. Klokočník  C.A. Wagner 《Journal of Geodesy》2005,79(8):421-430

The analysis of the time and space distribution of specular (reflecting) points in bistatic altimetry between GPS and CHAMP satellites or SAC-C (taken as examples) is extended from Wagner and Klokočník (2003 J. Geod 77: 128–138). We demonstrate a significantly higher number and density of reflecting points in bistatic altimetry in comparison with traditional monostatic altimetry. After an outline of our older accuracy assessment for the vertical position of the reflecting point, we add a new independent derivation and compare both approaches. We account for orbit errors of both the transmitters (GPS) and receiver (CHAMP) satellites, and the measurement (delay) error. We found that the accuracy of the vertical position of the reflecting point decreases only slowly with increasing off-nadir angle and that the orbit errors must be accounted for if decimeter and better accuracy is required. In this paper, we do not study errors such as state of the ocean, technical parameters of the receiving system, and atmospheric corrections.  相似文献   

Daily Meteorological Observations in Cádiz – San Fernando. Analysis of the Documentary Sources and the Instrumental Data Content (1786–1996)     

Mariano Barriendos  Javier Martín-Vide  Juan Carlos Peña  Roberto Rodríguez 《Climatic change》2002,53(1-3):151-170

Meteorological observations in the city of Cádiz are acknowledged as having been made from the middle of the 18th century onwards although they were only recorded and preserved in documentary form from 1789 onwards. Data readings were taken at the new Naval Observatory in San Fernando, ten kilometres from Cádiz, from 1797 onwards. Continuous series for temperature and atmospheric pressure at a daily resolution have been compiled and constructed from 1817 until 1996. The data series is composed of thrice daily observations made at Cádiz (1821–1880) by local observers and hourly data from Naval Observatory at San Fernando (1870–1996).  相似文献   

Structural damage detection using the optimal weights of the approximating artificial neural networks     

Shih‐Lin Hung  C. Y. Kao 《地震工程与结构动力学》2002,31(2):217-234

This work presents a novel neural network‐based approach to detect structural damage. The proposed approach comprises two steps. The first step, system identification, involves using neural system identification networks (NSINs) to identify the undamaged and damaged states of a structural system. The partial derivatives of the outputs with respect to the inputs of the NSIN, which identifies the system in a certain undamaged or damaged state, have a negligible variation with different system errors. This loosely defined unique property enables these partial derivatives to quantitatively indicate system damage from the model parameters. The second step, structural damage detection, involves using the neural damage detection network (NDDN) to detect the location and extent of the structural damage. The input to the NDDN is taken as the aforementioned partial derivatives of NSIN, and the output of the NDDN identifies the damage level for each member in the structure. Moreover, SDOF and MDOF examples are presented to demonstrate the feasibility of using the proposed method for damage detection of linear structures. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

A mathematical hysteretic model for elastomeric isolation bearings     

J. S. Hwang  J. D. Wu  T.‐C. Pan  G. Yang 《地震工程与结构动力学》2002,31(4):771-789

An analytical model for high damping elastomeric isolation bearings is presented in this paper. The model is used to describe mathematically the damping force and restoring force of the rubber material and bearing. Ten parameters to be identified from cyclic loading tests are included in the model. The sensitivity of the ten parameters in affecting the model is examined. These ten parameters are functions of a number of influence factors on the elastomer such as the rubber compound, Mullins effect, scragging effect, frequency, temperature and axial load. In this study, however, only the Mullins effect, scragging effect, frequency and temperature are investigated. Both material tests and shaking table tests were performed to validate the proposed model. Based on the comparison between the experimental and the analytical results, it is found that the proposed analytical model is capable of predicting the shear force–displacement hysteresis very accurately for both rubber material and bearing under cyclic loading reversals. The seismic response time histories of the bearing can also be captured, using the proposed analytical model, with a practically acceptable precision. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

Tests on low‐ductility RC frames under high‐ and low‐frequency excitations     

Ser‐Tong Quek  Chengmei Bian  Xilin Lu  Wensheng Lu  Haibei Xiong 《地震工程与结构动力学》2002,31(2):459-474

The response of low‐ductility reinforced concrete (RC) frames, designed typically for a non‐seismic region, subjected to two frequencies of base excitations is studied. Five half‐scaled, two‐bay, two‐storey, RC frames, each approximately 5 m wide by 3.3 m high, were subjected to both horizontal and/or vertical base excitations with a frequency of 40 Hz as well as a lower frequency of about 4 Hz (close to the fundamental frequency) using a shake table. The imposed acceleration amplitude ranged from 0.2 to 1.2g. The test results showed that the response characteristics of the structures differed under high‐ and low‐frequency excitations. The frames were able to sustain high‐frequency excitations without damage but were inadequate for low‐frequency excitations, even though the frames exhibited some ductility. Linear‐elastic time‐history analysis can predict reasonably well the structural response under high‐frequency excitations. As the frames were not designed for seismic loads, the reinforcement detailing may not have been adequate, based on the crack pattern observed. The effect of vertical excitation can cause significant additional forces in the columns and moment reversals in the beams. The ‘strong‐column, weak‐beam’ approach for lateral load RC frame design is supported by experimental observations. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

Optimal design of passive energy dissipation systems based on H∞ and H2 performances     

J. N. Yang  S. Lin  J‐H. Kim  A. K. Agrawal 《地震工程与结构动力学》2002,31(4):921-936

Passive energy dissipation devices (EDDs), such as viscous dampers, viscoelastic dampers, etc., have been used to effectively reduce the dynamic response of civil infrastructures, such as buildings and bridges, subject to earthquakes and strong winds. The design of these passive energy dissipation devices (EDDs) involves the determination of the optimal locations and the corresponding capacities. In this paper, we present two optimal design methodologies for passive EDDs based on active control theories, including H_∞ and H₂ performances, respectively. The optimal design methodologies presented are capable of determining the optimal locations and the corresponding capacities of EDDs. Emphasis is placed on the application of linear matrix inequality (LMI) for the effective design of passive EDDs using the popular MATLAB toolboxes. One important advantage of the proposed approaches is that the computation of the structural response is not needed in the design process. The proposed optimal design methodologies have been applied to: (i) a 10‐storey building and a 24‐storey building both subject to earthquake excitations, and (ii) a 76‐storey wind‐excited benchmark building, to demonstrate the advantages of the proposed design methodologies over the conventional equal capacity design. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

Study on effects of damping in laminated rubber bearings on seismic responses for a ⅛ scale isolated test structure     

Bong Yoo  Yang‐Hann Kim 《地震工程与结构动力学》2002,31(10):1777-1792

The effects of damping in various laminated rubber bearings (LRB) on the seismic response of a ?‐scale isolated test structure are investigated by shaking table tests and seismic response analyses. A series of shaking table tests of the structure were performed for a fixed base design and for a base isolation design. Two different types of LRB were used: natural rubber bearings (NRB) and lead rubber bearings (LLRB). Three different designs for the LLRB were tested; each design had a different diameter of lead plug, and thus, different damping values. Artificial time histories of peak ground acceleration 0.4g were used in both the tests and the analyses. In both shaking table tests and analyses, as expected, the acceleration responses of the seismically isolated test structure were considerably reduced. However, the shear displacement at the isolators was increased. To reduce the shear displacement in the isolators, the diameter of the lead plug in the LLRB had to be enlarged to increase isolator damping by more than 24%. This caused the isolator stiffness to increase, and resulted in amplifying the floor acceleration response spectra of the isolated test structure in the higher frequency ranges with a monotonic reduction of isolator shear displacement. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献