A geochemical model for evaluating theories on the genesis of Florida's sedimentary phosphate deposits     

Martha W. Gilliland 《Mathematical Geosciences》1976,8(3):219-242

Present ionic concentrations of Ca ⁺⁺,HCO ₃ ^- ,and HPO ₄ ⁼ in surface and groundwater runoff in Florida indicate that phosphorus is being concentrated in rock through dissolution and reprecipitation, with calcium phosphate increasing at the expense of calcium carbonate. Analog computer simulation of a systems model of this process suggests that significant enrichment can occur in 20 million years. The degree of enrichment depends on the supply of new phosphorus to Florida through rain and oceanic exchange processes. If the calcium phosphate content of original rock is 0.5 to 1.0 percent (0.52 to 1.05 percent P ₂ O ₅),a formation with 10 to 20 percent calcium phosphate (CaPO ₄ or 10.5 to 21.0 percent P ₂ O ₅)as in the Hawthorn Formation (Miocene)may result. Nutrient upwelling along the continental slope coupled with transport to the estuaries by lateral eddy diffusion can supply an additional 400 mg P|m ² |yr which, if deposited, would result in a sediment with a 4.3 percent CaPO ₄ (4.5 percent P ₂ O ₅)content. If this is enriched later by resolution, 40 percent CaPO ₄ (42 percent P ₂ O ₅)results. Through geologic time, the ocean may be considered as a source of phosphorus to the land through rain or estuarine sediment.  相似文献   

Nereid: Light curve for 1999-2006 and a scenario for its variations     

Bradley E. Schaefer  Suzanne W. Tourtellotte  Martha W. Schaefer 《Icarus》2008,196(1):225-240

Nereid is a small irregular moon of Neptune that displays large-, moderate-, and small-amplitude photometric variations on both fast and slow time scales. The central mystery of Nereid is now to explain the physical mechanism of these unique brightness changes and why they change with time. To characterize Nereid's variability, we have been using the SMARTS telescopes on Cerro Tololo for synoptic monitoring from 1999 to 2006. We present a well-sampled photometric time series of 493 magnitudes on 246 nights mostly in the V-band. In combination with our earlier data (for 774 magnitudes over 362 nights), our 20-year data set is the most comprehensive for any small icy body in our Solar System. Our yearly light curves show that Nereid displays various types of behaviors: large amplitude brightenings and fadings (1987 to 1990); moderate-amplitude variation about the average phase curve (1993-1997, 2003, 2005), moderate-amplitude variation and systematically brighter by roughly one-quarter magnitude throughout the entire season (2004); and nearly constant light curves superimposed on a surprisingly large-amplitude opposition surge (1998, 1999, 2000, 2006). Other than in 2004, Nereid's variations were closely centered around a constant phase curve that is well fit with a Hapke model for the coherent backscattering opposition surge mechanism with angular scale of 0.7°±0.1°. In our entire data set from 1987-2006, we find no significant periodicity. We propose that the year-to-year changes in the variability of Nereid are caused by forced precession (caused by tidal forces from Neptune) on the spin axis of a nonspherical Nereid, such that cross-sectional areas and average albedos change as viewed from Earth.  相似文献   

Bemerkungen zu Hirvonens Taylortafeln     

Martha N?bauer 《Journal of Geodesy》1956,30(1):69-73

Ohne Zusammenfassung  相似文献   

Thresholds of Adverse Effects of Macroalgal Abundance and Sediment Organic Matter on Benthic Habitat Quality in Estuarine Intertidal Flats     

Martha Sutula  Lauri Green  Giancarlo Cicchetti  Naomi Detenbeck  Peggy Fong 《Estuaries and Coasts》2014,37(6):1532-1548

Confidence in the use of macroalgae as an indicator of estuarine eutrophication is limited by the lack of quantitative data on the thresholds of its adverse effects on benthic habitat quality. In the present study, we utilized sediment profile imagery (SPI) to identify thresholds of adverse effects of macroalgal biomass, sediment organic carbon (% OC) and sediment nitrogen (% N) concentrations on the apparent Redox Potential Discontinuity (aRPD), the depth that marks the boundary between oxic near-surface sediment and the underlying suboxic or anoxic sediment. At 16 sites in eight California estuaries, SPI, macroalgal biomass, sediment percent fines, % OC, and % N were analyzed at 20 locations along an intertidal transect. Classification and Regression Tree (CART) analysis was used to identify step thresholds associated with a transition from "reference" or natural background levels of macroalgae, defined as that range in which no effect on aRPD was detected. Ranges of 3–15 g dw macroalgae m^?2, 0.4–0.7 % OC and 0.05–0.07 % N were identified as transition zones from reference conditions across these estuaries. Piecewise regression analysis was used to identify exhaustion thresholds, defined as a region along the stress–response curve where severe adverse effects occur; levels of 175 g dw macroalgae m^?2, 1.1 % OC and 0.1 % N were identified as thresholds associated with a shallowing of aRPD to near zero depths. As an indicator of ecosystem condition, shallow aRPD has been related to reduced volume and quality for benthic infauna and alteration in community structure. These effects have been linked to reduced availability of forage for fish, birds and other invertebrates, as well as to undesirable changes in biogeochemical cycling.  相似文献   

Sequential deformation of plains at the margins of Alpha Regio,Venus: Implications for tessera formation     

Martha S. GILMORE  James W. HEAD 《Meteoritics & planetary science》2000,35(4):667-687

Abstract— The boundaries between the highly deformed tessera terrain and adjacent volcanic plains are primarily those of embayment, where the tessera are stratigraphically older than the plains. Previous studies show that <3% of these boundaries display evidence of tectonic tilting after the emplacement of the plains. One of these unusual boundaries is the western margin of Alpha Regio tessera, a zone ～ 100 km in width that separates the plains from the interior structures of Alpha. This zone is characterized by margin parallel, fine‐scale (1–5 km) fractures, graben, and ridges that truncate and postdate the broad‐scale (10–30 km) ridges and troughs of the interior of Alpha. The western margin is embayed by several volcanic plains units that are progressively tilted and deformed by graben with closer proximity to Alpha Regio. The earliest deformation of the plains consists of northeast‐trending graben ～1 km in width that are similar in morphology and spacing to graben that deform intratessera plains and plains at the eastern boundary of Alpha. Northwest‐trending graben then formed over an interval marked by the emplacement of two additional plains units; their similarity to northwest‐trending structures emanating from Eve corona and the Lada Terra rift suggests a possible genetic relationship. The tilting of the plains adjacent to western Alpha implies relative vertical movement of the margin, either uplift of tessera or downwarping of plains subsequent to the formation and relaxation of the interior of Alpha Regio. Subsidence of plains at this locale is supported by the presence of a basin to the west of Alpha surrounded by a fracture belt contiguous with western Alpha. Thus, the fractures and deformation at the western boundary of Alpha may be related to the formation of a basin to the west of Alpha with some influence from the northernmost extension of the Lada Terra rift. Such a basin is not present at a section along the eastern boundary of Alpha Regio, where the origin of tilted plains remains equivocal. We conclude that the deformation along the western margin of Alpha Regio is not directly related to the process of tessera formation but is an example of tessera modification and is consistent with the stratigraphic position of tessera as the oldest unit observed on Venus.  相似文献   

An empirical test of helium diffusion in apatite: borehole data from the Otway basin, Australia   总被引：5，自引：0，他引：5  

Martha A House  Kenneth A Farley  Barry P Kohn 《Earth and Planetary Science Letters》1999,170(4):543-474

We have analyzed helium ages of apatites from several boreholes in the Otway basin, Australia, to evaluate whether laboratory helium diffusivity can be accurately extrapolated to conditions relevant in nature. Downhole apatite helium ages define a broad swath of values from 78–71 Ma at the surface (15°C) to nearly zero at depths corresponding to ambient temperatures of 80°C. The width of the swath results from uncertainties in corrected borehole temperatures, differences in the thermal history experienced by the various boreholes, and possibly from slightly different helium diffusivities among the detrital apatite grains studied. In the eastern Otway basin, the shape and position of the helium age profile is in good agreement with predictions based on the extrapolation of laboratory diffusivity data for Durango apatite coupled with published thermal histories for this part of the basin. In contrast, helium ages are much younger than predicted in the western Otway basin. Based on measured ages from Otway sediments, which have been essentially isothermal over the last few million years, an empirical diffusivity (D/a²) of 2×10⁻¹⁵ s⁻¹ can be assigned to apatites residing at downhole temperatures of 67–97°C. This empirical diffusivity is consistent with laboratory diffusion measurements, demonstrating that such measurements are reasonably accurate and can be applied with confidence to natural geologic settings. Given this confirmation of the laboratory diffusivity data, the discrepancy between the observed and modeled helium age profiles in the western Otway basin suggests that these sediments recently experienced higher temperatures than presently supposed.  相似文献   

Seasonality of stable isotope composition of atmospheric water input at the southern slopes of Mt. Kilimanjaro,Tanzania          下载免费PDF全文

Insa Otte  Florian Detsch  Adrian Gütlein  Martha Scholl  Ralf Kiese  Tim Appelhans  Thomas Nauss 《水文研究》2017,31(22):3932-3947

To understand the moisture regime at the southern slopes of Mt. Kilimanjaro, we analysed the isotopic variability of oxygen (δ¹⁸O) and hydrogen (δD) of rainfall, throughfall, and fog from a total of 2,140 samples collected weekly over 2 years at 9 study sites along an elevation transect ranging from 950 to 3,880 m above sea level. Precipitation in the Kilimanjaro tropical rainforests consists of a combination of rainfall, throughfall, and fog. We defined local meteoric water lines for all 3 precipitation types individually and the overall precipitation, δD_prec = 7.45 (±0.05) × δ¹⁸O_prec + 13.61 (±0.20), n  = 2,140, R ² = .91, p  < .001. We investigated the precipitation‐type‐specific stable isotope composition and analysed the effects of amount, altitude, and temperature. Aggregated annual mean values revealed isotope composition of rainfall as most depleted and fog water as most enriched in heavy isotopes at the highest elevation research site. We found an altitude effect of δ¹⁸O_rain = ?0.11‰ × 100 m^?1, which varied according to precipitation type and season. The relatively weak isotope or altitude gradient may reveal 2 different moisture sources in the research area: (a) local moisture recycling and (b) regional moisture sources. Generally, the seasonality of δ¹⁸O_rain values follows the bimodal rainfall distribution under the influences of south‐ and north‐easterly trade winds. These seasonal patterns of isotopic composition were linked to different regional moisture sources by analysing Hybrid Single Particle Lagrangian Integrated Trajectory backward trajectories. Seasonality of d excess values revealed evidence of enhanced moisture recycling after the onset of the rainy seasons. This comprehensive dataset is essential for further research using stable isotopes as a hydrological tracer of sources of precipitation that contribute to water resources of the Kilimanjaro region.  相似文献