Quantum-thermodynamic treatment of intrinsic anharmonicity; Wallace’s theorem revisited   总被引：1，自引：0，他引：1  

Michel H.G. Jacobs  Bernard H.W.S. de Jong 《Physics and Chemistry of Minerals》2005,32(8-9):614-626

Wallace (in Thermodynamics of crystals, 1972) developed a theorem, rooted in rigid lattice dynamics, which incorporates intrinsic anharmonic effects in solids. The practical application of this theorem in mineral physics is computationally involved and this is the main reason for the theorem not getting the attention it deserves. Because intrinsic anharmonicity is an important issue at the extreme conditions in planetary mantles, we derived a method which removes the computational obstacles in applying this theorem. We extended the theorem to incorporate details of the phonon spectrum and tested our algorithm on forsterite (Mg₂SiO₄). Using a least squares inversion technique applied to all available experimental data, we show that it results in an accurate representation of thermodynamic properties and sound wave velocities of Mg₂SiO₄ in its complete pressure–temperature stability range. We also show that the accuracy of our results is not significantly affected by the use of a different equation of state.  相似文献   

Low-pressure adsorption of Ar, Kr, and Xe on carbonaceous materials (kerogen and carbon blacks), ferrihydrite, and montmorillonite: Implications for the trapping of noble gases onto meteoritic matter     

Yves Marrocchi  Angelina Razafitianamaharavo  Bernard Marty 《Geochimica et cosmochimica acta》2005,69(9):2419-2430

Noble gases trapped in meteorites are tightly bound in a carbonaceous carrier labeled “phase Q.” Mechanisms having led to their retention in this phase or in its precursors are poorly understood. To test physical adsorption as a way of retaining noble gases into precursors of meteoritic materials, we have performed adsorption experiments for Ar, Kr, and Xe at low pressures (10⁻⁴ mbar to 500 mbar) encompassing pressures proposed for the evolving solar nebula. Low-pressure adsorption isotherms were obtained for ferrihydrite and montmorillonite, both phases being present in Orgueil (CI), for terrestrial type III kerogen, the best chemical analog of phase Q studied so far, and for carbon blacks, which are present in phase Q and can be considered as possible precursors.Based on adsorption data obtained at low pressures relevant to the protosolar nebula, we propose that the amount of noble gases that can be adsorbed onto primitive materials is much higher than previously inferred from experiments carried out at higher pressures. The adsorption capacity increases from kerogen, carbon blacks, montmorillonite to ferrihydrite. Because of its low specific surface area, kerogen can hardly account for the noble gas inventory of Q. Carbon blacks in the temperature range 75 K-100 K can adsorb up to two orders of magnitude more noble gases than those found in Q. Irreversible trapping of a few percent of noble gases adsorbed on such materials could represent a viable process for incorporating noble gases in phase Q precursors. This temperature range cannot be ruled out for the zone of accretion of the meteorite precursors according to recent astrophysical models and observations, although it is near the lower end of the temperatures proposed for the evolving solar nebula.  相似文献   

Chronology and stratigraphy of the Magdalen Islands archipelago from the last glaciation to the early Holocene: new insights into the glacial and sea‐level history of eastern Canada          下载免费PDF全文

Audrey M. Rémillard  Guillaume St‐Onge  Pascal Bernatchez  Bernard Hétu  Jan‐Pieter Buylaert  Andrew S. Murray  Benoit Vigneault 《Boreas: An International Journal of Quaternary Research》2016,45(4):604-628

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Development of a soil moisture‐based distributed hydrologic model for determining hydrologically based critical source areas          下载免费PDF全文

Sisi Li  Margaret Gitau  David Bosch  Bernard A. Engel  Liang Zhang  Yun Du 《水文研究》2017,31(20):3543-3557

A simple grid cell‐based distributed hydrologic model was developed to provide spatial information on hydrologic components for determining hydrologically based critical source areas. The model represents the critical process (soil moisture variation) to run‐off generation accounting for both local and global water balance. In this way, it simulates both infiltration excess run‐off and saturation excess run‐off. The model was tested by multisite and multivariable evaluation on the 50‐km² Little River Experimental Watershed I in Georgia, U.S. and 2 smaller nested subwatersheds. Water balance, hydrograph, and soil moisture were simulated and compared to observed data. For streamflow calibration, the daily Nash‐Sutcliffe coefficient was 0.78 at the watershed outlet and 0.56 and 0.75 at the 2 nested subwatersheds. For the validation period, the Nash‐Sutcliffe coefficients were 0.79 at the watershed outlet and 0.85 and 0.83 at the 2 subwatersheds. The per cent bias was less than 15% for all sites. For soil moisture, the model also predicted the rising and declining trends at 4 of the 5 measurement sites. The spatial distribution of surface run‐off simulated by the model was mainly controlled by local characteristics (precipitation, soil properties, and land cover) on dry days and by global watershed characteristics (relative position within the watershed and hydrologic connectivity) on wet days when saturation excess run‐off was simulated. The spatial details of run‐off generation and travel time along flow paths provided by the model are helpful for watershed managers to further identify critical source areas of non‐point source pollution and develop best management practices.  相似文献   

New UV-source catalogs,UV spectral database,UV variables and science tools from the GALEX surveys     

Luciana Bianchi  Alexander de la Vega  Bernard Shiao  Ralph Bohlin 《Astrophysics and Space Science》2018,363(3):56

We present a new, expanded and improved catalog of Ultraviolet (UV) sources from the GALEX All-Sky Imaging survey: GUVcat_AIS (Bianchi et al. in Astrophys. J. Suppl. Ser. 230:24, 2017). The catalog includes 83 million unique sources (duplicate measurements and rim artifacts are removed) measured in far-UV and near-UV. With respect to previous versions (Bianchi et al. in Mon. Not. R. Astron. Soc. 411:2770 2011a, Adv. Space Res. 53:900–991, 2014), GUVcat_AIS covers a slightly larger area, 24,790 square degrees, and includes critical corrections and improvements, as well as new tags, in particular to identify sources in the footprint of extended objects, where pipeline source detection may fail and custom-photometry may be necessary. The UV unique-source catalog facilitates studies of density of sources, and matching of the UV samples with databases at other wavelengths.We also present first results from two ongoing projects, addressing respectively UV variability searches on time scales from seconds to years by mining the GALEX photon archive, and the construction of a database of ～120,000 GALEX UV spectra (range ～1300–3000 Å), including quality and calibration assessment and classification of the grism, hence serendipitous, spectral sources.  相似文献   

Segmentation and kinematics of the North America‐Caribbean plate boundary offshore Hispaniola          下载免费PDF全文

Sylvie Leroy  Nadine Ellouz‐Zimmermann  Jordane Corbeau  Frédérique Rolandone  Bernard Mercier de Lépinay  Bertrand Meyer  Roberte Momplaisir  José‐Luis Granja Bruña  Anne Battani  Céline Baurion  Evgueni Burov  Valérie Clouard  Rémy Deschamps  Christian Gorini  Youri Hamon  Manfred Lafosse  Jottin Leonel  Laetitia Le Pourhiet  Pilar Llanes Estrada  Nicolas Loget  Francis Lucazeau  Daniel Pillot  Jeffrey Poort  Kevin R. Tankoo  José‐Luis Cuevas  José‐Fernando Alcaide  Claude Jean Poix  Alfonso Muñoz‐Martin  Serge Mitton  Yamil Rodriguez  Julien Schmitz  Leonardo Seeber  Andres Carbo‐Gorosabel  Santiago Muñoz 《地学学报》2015,27(6):467-478

We explored the submarine portions of the Enriquillo–Plantain Garden Fault zone (EPGFZ) and the Septentrional–Oriente Fault zone (SOFZ) along the Northern Caribbean plate boundary using high‐resolution multibeam echo‐sounding and shallow seismic reflection. The bathymetric data shed light on poorly documented or previously unknown submarine fault zones running over 200 km between Haiti and Jamaica (EPGFZ) and 300 km between the Dominican Republic and Cuba (SOFZ). The primary plate‐boundary structures are a series of strike‐slip fault segments associated with pressure ridges, restraining bends, step overs and dogleg offsets indicating very active tectonics. Several distinct segments 50–100 km long cut across pre‐existing structures inherited from former tectonic regimes or bypass recent morphologies formed under the current strike‐slip regime. Along the most recent trace of the SOFZ, we measured a strike‐slip offset of 16.5 km, which indicates steady activity for the past ~1.8 Ma if its current GPS‐derived motion of 9.8 ± 2 mm a^?1 has remained stable during the entire Quaternary.  相似文献   

The Satah Mountain and Baldface Mountain volcanic fields: Pleistocene hot spot volcanism in the Anahim Volcanic Belt,west-central British Columbia,Canada     

Christian Kuehn  Bernard Guest  James K. Russell  Jeff A. Benowitz 《Bulletin of Volcanology》2015,77(3):1-27

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Dating megafaunal extinction on the Pleistocene Darling Downs,eastern Australia: the promise and pitfalls of dating as a test of extinction hypotheses     

Gilbert J. Price  Gregory E. Webb  Jian-xin Zhao  Yue-xing Feng  Andrew S. Murray  Bernard N. Cooke  Scott A. Hocknull  Ian H. Sobbe 《Quaternary Science Reviews》2011,30(7-8):899-914

A key to understanding Late Pleistocene megafaunal extinction dynamics is knowledge of megafaunal ecological response(s) to long-term environmental perturbations. Strategically, that requires targeting fossil deposits that accumulated during glacial and interglacial intervals both before and after human arrival, with subsequent palaeoecological models underpinned by robust and reliable chronologies. Late Pleistocene vertebrate fossil localities from the Darling Downs, eastern Australia, provide stratigraphically-intact, abundant megafaunal sequences, which allows for testing of anthropogenic versus climate change megafauna extinction hypotheses. Each stratigraphic unit at site QML796, Kings Creek Catchment, was previously shown to have had similar sampling potential, and the basal units contain both small-sized taxa (e.g., land snails, frogs, bandicoots, rodents) and megafauna. Importantly, sequential faunal horizons show stepwise decrease in taxonomic diversity with the loss of some, but not all, megafauna in the geographically-small palaeocatchment. The purpose of this paper is to present the results of our intensive, multidisciplinary dating study of the deposits (>40 dates). Dating by means of accelerator mass spectrometry (AMS) ¹⁴C (targeting bone, freshwater molluscs, and charcoal) and thermal ionisation mass spectrometry U/Th (targeting teeth and freshwater molluscs) do not agree with each other and, in the case of AMS ¹⁴C dating, lack internal consistency. Scanning electron microscopy and rare earth element analyses demonstrate that the dated molluscs are diagenetically altered and contain aragonite cements that incorporated secondary young C, suggesting that such dates should be regarded as minimum ages. AMS ¹⁴C dated charcoals provide ages that occur out of stratigraphic order, and cluster in the upper chronological limits of the technique (～40–48 ka). Again, we suggest that such results should be regarded as suspicious and only minimum ages. Subsequent OSL and U/Th (teeth) dating provide complimentary results and demonstrate that the faunal sequences actually span ～120–83 ka, thus occurring beyond the AMS ¹⁴C dating window. Importantly, the dates suggest that the local decline in biological diversity was initiated ～75,000 years before the colonisation of humans on the continent. Collectively, the data are most parsimoniously consistent with a pre-human climate change model for local habitat change and megafauna extinction, but not with a nearly simultaneous extinction of megafauna as required by the human-induced blitzkrieg extinction hypothesis. This study demonstrates the problems inherent in dating deposits that lie near the chronological limits of the radiocarbon dating technique, and highlights the need to cross-check previously-dated archaeological and megafauna deposits within the timeframe of earliest human colonisation and latest megafaunal survival.  相似文献   

Sulphate incorporation in monazite lattice and dating the cycle of sulphur in metamorphic belts     

Antonin T. Laurent  Anne-Magali Seydoux-Guillaume  Stéphanie Duchene  Bernard Bingen  Valérie Bosse  Lucien Datas 《Contributions to Mineralogy and Petrology》2016,171(11):94

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Cl-rich hydrous mafic mineral assemblages in the Highiș massif,Apuseni Mountains,Romania     

Bernard Bonin  Mihai Tatu 《Mineralogy and Petrology》2016,110(4):447-469

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