Crystal chemistry of volcanic allanites indicative of naturally induced oxidation-dehydrogenation     

Mihoko Hoshino  Mitsuyoshi Kimata  Craig A. Chesner  Norimasa Nishida  Masahiro Shimizu  Takeshi Akasaka 《Mineralogy and Petrology》2010,99(1-2):133-141

The crystal chemistry of volcanic allanites from both the Youngest Toba Tuff (YTT), Sumatra, Indonesia and SK100 volcanic ash beds (SK100-VAB), Niigata, Japan has been examined by electron microprobe analysis (EMPA), Fourier-transform infrared spectroscopic analysis (FTIR), and single-crystal structure analysis. In the FTIR study, based on the Diamond ATR accessory, YTT and SK100- VAB allanites were observed to have different OH contents, respectively: the former has 0.64 wt% H₂O (OH: 0.40 apfu.), while the latter has 1.65 wt% H₂O (OH: 1.00 apfu.). The crystal structures of these two allanites have been refined to individual R indices (3.64 and 4.25) based on 1350 observed reflections (|Fo| > 4sig|Fo|) measured using a single-crystal diffractometer with MoKα X-radiation. The OH-poor YTT allanite has a shorter b axis, a longer c axis, and larger β value than the relatively OH-rich SK100-VAB one. The bond valence sums of O4 (accepter oxygen for H atom) and O10 (donor oxygen for H atom) are 1.962 and 1.709 v.u. for YTT allanite (valence sum: 3.671 v.u.) and 1.754 and 1.271 v.u. for SK100-VAB one (valence sum: 3.025 v.u.). The difference from the ideal total bond valence value (4.00 v.u.) of O4 and O10 in YTT allanite (0.33 v.u.) is smaller than that in SK100-VAB (0.98 v.u.). These difference values are also broadly consistent with the corresponding differences in OH content between the YTT (OH: 0.40 apfu.) and SK100-VAB allanites (OH: 1.00 apfu.) determined by FTIR- ATR. Chemical analyses, FTIR-ATR and crystal structure refinement of YTT and SK100-VAB allanites yielded the following crystal chemical formula: YTT: (Ca_0.83Mn²⁺ _0.06Fe²⁺ _0.11)(La_0.24Ce_0.32Pr_0.04Nd_0.11Sm_0.02Th_0.04Ca_0.21)(Al_0.73Fe³⁺ _0.19Ti_0.08)(Al_0.89Fe³⁺ _0.11)(Fe²⁺ _0.22Fe³⁺ _0.62Mg_0.16)(SiO₄)Si₂O₇O_1.6(OH)_0.4, SK100-VAB: (Ca_0.81Fe²⁺ _0.13Mn²⁺ _0.06)(La_0.22Ce_0.34Pr_0.05Nd_0.13Sm_0.02Th_0.02Ca_0.22)(Al_0.76Fe³⁺ _0.19Ti_0.05)Al_1.00(Fe²⁺ _0.73Fe³⁺ _0.17Mg_0.10)(Si_0.96Al_0.04O₄)Si₂O₇O(OH). Therefore, it is concluded that welding of the Youngest Toba Tuff caused the following post-crystallization changes to occur in YTT allanite: oxidation of Fe²⁺ to Fe³⁺, release of H₂, and the concomitant replacement of OH^? by O^2?. These oxidation and dehydrogenation processes advanced during the welding to thereby produce oxyallanite. Oxyallanite had been reported only in laboratory studies where it was produced by heating natural allanite. Our report on natural oxyallanite suggests that it may be present in other welded silicic volcanic rocks as well.  相似文献   

Spatial and temporal distributions of stable isotopes in precipitation over Thailand     

Jeerapong Laonamsai  Kimpei Ichiyanagi  Kiattipong Kamdee  Aksara Putthividhya  Masahiro Tanoue 《水文研究》2021,35(1):e13995

Spatial and temporal variations of the isotopic composition of precipitation over Thailand were investigated. The local meteoric water line for Thailand deviates slightly from the global meteoric water line, with lower slopes (7.62 ± 0.07, 7.59 ± 0.08) and intercepts (6.42 ± 0.39, 6.22 ± 0.42) using ordinary and precipitation weighted methods. Differences in spatial and temporal δ¹⁸O distributions between the tropical monsoon and tropical savanna climate zones were found due to differing moisture source contributions and seasonal precipitation patterns. The temporal data reveals that the northeast monsoon rains originate from isotopically-enriched local moisture with isotope values of −9.36 to −0.09‰ (mean − 3.73 ± 0.42‰), whereas the southwest monsoon clouds had a more significant rainout effect from Rayleigh distillation, with isotope values of −9.56 to −1.78‰ (mean − 5.40 ± 0.38‰). The precipitation amount at each site was negatively correlated with δ¹⁸O (−0.24 to −3.20‰ per 100 mm, R² = 0.1–0.9). Furthermore, δ¹⁸O was negatively correlated with geography (latitude, altitude) for the southwest monsoon periods, as expected based on other observed correlations. However, an inverse correlation was seen in the northeast monsoon due to differing moisture transportation as part of the continental effect. The correlation coefficient (R) was higher in the southwest monsoon (−0.84 for latitude effect, −0.64 for altitude effect) than the northeast monsoon (0.67 for latitude effect, 0.35 for altitude effect). The spatial pattern of isotopic composition reflects the southwest monsoon more clearly than the northeast monsoon, but the two monsoons also have a cancelling impact on orographic patterns. An agreement of the δ¹⁸O and deuterium excess (d-excess) was a negative correlation and found to reflect precipitation sources and re-evaporation processes. The d-excess was slightly higher for the northeast monsoon, bringing moisture from the Pacific Ocean and travelling across the continent before reaching the observed stations. By contrast, the d-excess was relatively lower for the Indian Ocean's moisture in the southwest monsoon.  相似文献   

Application of an earthquake early warning system and a real-time strong motion monitoring system in emergency response in a high-rise building   总被引：1，自引：0，他引：1  

Tomohiro Kubo  Yoshiaki Hisada  Masahiro Murakami  Fusako Kosuge  Kohei Hamano 《Soil Dynamics and Earthquake Engineering》2011

We apply a combination of earthquake early warning system (EEWS) and real-time strong motion monitoring system (RSMS) to emergency response for a high-rise building; The Kogakuin University has a 29-story high-rise building in Shinjuku Ward, Tokyo. The proposed strategy is based on the Plan, Do, Check, Action (PDCA) Cycle to brush up the systems and the users: in the “Plan” stage, we apply EEWS and RSMS to the building, where EEWS predicts not only short-period strong ground motions but also long-period ground motions [1]. The system is built into a building announcement system, an emergency elevator control system, and an email message system, which quickly send emails to the emergency response team. Meanwhile, RSMS provides information on seismic intensities at each floor of the building via the web browser in real time using the existing network in the building. In addition, the building response and structural damage can be estimated based on this information. The network system is impervious to the earthquake damage, because the network cable has extra length, there is, however, possible that a network system does not work due to power outage. Thus, we develop the network system that has uninterruptible power-supply system (UPS) and apply it to EEWS and RSMS. The high-rise building has the emergency call units to the security control center in the building on every floor. The emergency call line, however, will be busy promptly, because it is able to use only one line. Therefore, we installed IP telephone which uses the network system on main floors. UPS will work about 30 min after a major earthquake, it is supposed to be enough time for gathering the damage information about the building during initial response. In the “Do” stage, we prepare emergency response instruction manuals and educate the faculty members and students to carry out promptly emergency response. In the “Check” stage, the validity of the proposed systems are verified by carrying out an earthquake drill in an actual high-rise building. The earthquake drill confirmed that our proposed approach is valid. In the final “Action” stage, we improve these systems and emergency response manual and educate people in the building how to use effectively these systems.  相似文献   

Simulation of two types of El Niño from different convective parameters     

Yeon-Soo Jang  Daehyun Kim  Young-Ho Kim  Dong-Hoon Kim  Masahiro Watanabe  Fei-Fei Jin  Jong-Seong Kug 《Asia-Pacific Journal of Atmospheric Sciences》2013,49(2):193-199

Many recent studies have reported the presence of two types of El Niño events in observation: Cold Tongue (CT) El Niño and Warm Pool (WP) El Niño. We investigate the sensitivity of a model simulating two types of El Niño by changing a convective triggering parameter (Tokioka parameter). When deep convections are highly suppressed with a large Tokioka parameter, the model is capable of simulating distinct two-types of El Niño. However, the model has a problem in simulating two-types of El Niño distinctively when the Tokioka parameter is small, because the location of the maximum precipitation anomaly related to the CT El Niño is significantly shifted westward, leading to an atmospheric response pattern similar to that of the WP El Niño. Our results suggest that the mean precipitation over the eastern equatorial Pacific and the resultant zonal distribution in atmospheric feedback associated with ENSO can be one of the crucial factors for simulating two-types of El Niño.  相似文献   

Tropospheric adjustment to increasing CO2: its timescale and the role of land–sea contrast     

Youichi Kamae  Masahiro Watanabe 《Climate Dynamics》2013,41(11-12):3007-3024

Physical processes responsible for tropospheric adjustment to increasing carbon dioxide concentration are investigated using abrupt CO₂ quadrupling experiments of a general circulation model (GCM) called the model for interdisciplinary research on climate version 5 with several configurations including a coupled atmosphere–ocean GCM, atmospheric GCM, and aqua-planet model. A similar experiment was performed in weather forecast mode to explore timescales of the tropospheric adjustment. We found that the shortwave component of the cloud radiative effect (SWcld) reaches its equilibrium within 2 days of the abrupt CO₂ increase. The change in SWcld is positive, associated with reduced clouds in the lower troposphere due to warming and drying by instantaneous radiative forcing. A reduction in surface turbulent heat fluxes and increase of the near-surface stability result in shoaling of the marine boundary layer, which shifts the cloud layer downward. These changes are common to all experiments regardless of model configuration, indicating that the cloud adjustment is primarily independent of air–sea coupling and land–sea thermal contrast. The role of land in cloud adjustment is further examined by a series of idealized aqua-planet experiments, with a rectangular continent of varying width. Land surface warming from quadrupled CO₂ induces anomalous upward motion, which increases high cloud and associated negative SWcld over land. The geographic distribution of continents regulates the spatial pattern of the cloud adjustment. A larger continent produces more negative SWcld, which partly compensates for a positive SWcld over the ocean. The land-induced negative adjustment is a factor but not necessary requirement for the tropospheric adjustment.  相似文献   

Reliability and importance of structural diversity of climate model ensembles     

Tokuta Yokohata  James D. Annan  Matthew Collins  Charles S. Jackson  Hideo Shiogama  Masahiro Watanabe  Seita Emori  Masakazu Yoshimori  Manabu Abe  Mark J. Webb  Julia C. Hargreaves 《Climate Dynamics》2013,41(9-10):2745-2763

We investigate the performance of the newest generation multi-model ensemble (MME) from the Coupled Model Intercomparison Project (CMIP5). We compare the ensemble to the previous generation models (CMIP3) as well as several single model ensembles (SMEs), which are constructed by varying components of single models. These SMEs range from ensembles where parameter uncertainties are sampled (perturbed physics ensembles) through to an ensemble where a number of the physical schemes are switched (multi-physics ensemble). We focus on assessing reliability against present-day climatology with rank histograms, but also investigate the effective degrees of freedom (EDoF) of the fields of variables which makes the statistical test of reliability more rigorous, and consider the distances between the observation and ensemble members. We find that the features of the CMIP5 rank histograms, of general reliability on broad scales, are consistent with those of CMIP3, suggesting a similar level of performance for present-day climatology. The spread of MMEs tends towards being “over-dispersed” rather than “under-dispersed”. In general, the SMEs examined tend towards insufficient dispersion and the rank histogram analysis identifies them as being statistically distinguishable from many of the observations. The EDoFs of the MMEs are generally greater than those of SMEs, suggesting that structural changes lead to a characteristically richer range of model behaviours than is obtained with parametric/physical-scheme-switching ensembles. For distance measures, the observations and models ensemble members are similarly spaced from each other for MMEs, whereas for the SMEs, the observations are generally well outside the ensemble. We suggest that multi-model ensembles should represent an important component of uncertainty analysis.  相似文献   

Accretion of terrestrial planets from oligarchs in a turbulent disk     

Masahiro Ogihara  Alessandro Morbidelli 《Icarus》2007,188(2):522-534

We have investigated the final accretion stage of terrestrial planets from Mars-mass protoplanets that formed through oligarchic growth in a disk comparable to the minimum mass solar nebula (MMSN), through N-body simulation including random torques exerted by disk turbulence due to Magneto-Rotational Instability. For the torques, we used the semi-analytical formula developed by Laughlin et al. [Laughlin, G., Steinacker, A., Adams, F.C., 2004. Astrophys. J. 608, 489-496]. The damping of orbital eccentricities (in all runs) and type-I migration (in some runs) due to the tidal interactions with disk gas is also included. Without any effect of disk gas, Earth-mass planets are formed in terrestrial planet regions in a disk comparable to MMSN but with too large orbital eccentricities to be consistent with the present eccentricities of Earth and Venus in our Solar System. With the eccentricity damping caused by the tidal interaction with a remnant gas disk, Earth-mass planets with eccentricities consistent with those of Earth and Venus are formed in a limited range of disk gas surface density (∼10⁻⁴ times MMSN). However, in this case, on average, too many (?6) planets remain in terrestrial planet regions, because the damping leads to isolation between the planets. We have carried out a series of N-body simulations including the random torques with different disk surface density and strength of turbulence. We found that the orbital eccentricities pumped up by the turbulent torques and associated random walks in semimajor axes tend to delay isolation of planets, resulting in more coagulation of planets. The eccentricities are still damped after planets become isolated. As a result, the number of final planets decreases with increase in strength of the turbulence, while Earth-mass planets with small eccentricities are still formed. In the case of relatively strong turbulence, the number of final planets are 4-5 at 0.5-2 AU, which is more consistent with Solar System, for relatively wide range of disk gas surface density (∼¹⁰⁻⁴-¹⁰⁻² times MMSN).  相似文献   

Searching for massive clusters in weak lensing surveys     

Takashi Hamana  Masahiro Takada  Naoki Yoshida 《Monthly notices of the Royal Astronomical Society》2004,350(3):893-913

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Contraction and Fragmentation of Magnetized Rotating Clouds and Formation of Binary Systems     

Kohji Tomisaka  Masahiro N. Machida  Tomoaki Matsumoto 《Astrophysics and Space Science》2004,292(1-4):309-316

Using three-dimensional (3D) magnetohydrodynamical (MHD) nested-grid simulations, the fragmentation of a rotating magnetized molecular cloud core is studied. An isothermal rotating magnetized cylindrical cloud in hydrostatic balance is considered. We studied non-axisymmetric evolution of the cloud. It is found that non-axisymmetry hardly evolves in the early phase, but it begins to grow after the gas contracts and forms a thin disk. The disk formation and thus growth of non-axisymmetric perturbation are strongly promoted by rotation and magnetic field strength. We found two types of fragmentations: fragmentation from a ring and that from a bar. These two types of fragmentations occur in thin adiabatic cores with the thickness being smaller than 1/4 of the radial size. For the fragments to survive, they should be formed in a heavily elongated barred core or a flat round disk. In the models showing fragmentation, outflows from respective fragments are found as well as that driven by the rotating bar or the disk.  相似文献   

Negative skewness of radial pairwise velocity in the quasi-non-linear regime: Zel'dovich approximation     

Ayako Yoshisato  Masahiro Morikawa  Hideaki Mouri 《Monthly notices of the Royal Astronomical Society》2003,343(3):1038-1044

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