Noble gas elemental and isotopic abundances in deep-sea trenches in the western Pacific     

George Igarashi  Masako Kodera  Minoru Ozima  Yuji Sano  Hiroshi Wakita  Jacques Boulgue 《Earth and Planetary Science Letters》1987,86(1)

Noble gas elemental and isotopic abundances were measured in seven deep-sea water samples from five different sampling sites in the Nankai Trough, the Japan Trench and the Kuril Trench. The samples were obtained by the manned submersible “Nautile”. Most of the sampling sites are associated with clam colonies and/or fluid venting. Excesses both in³He/⁴He ratio and He concentration are observed in a seawater sample collected a few kilometers off the clam colonies which were found at a depth of 3830 m at the mouth of the Tenryu Canyon. Concentrations of noble gases (Ne, Ar, Kr and Xe) in this sample show progressive depletion from Ne to Xe relative to those in 1°C air-saturated seawater, which can be attributed to mixing of hot water ( 15°C) with cold ambient water ( 1°C). Isotopic compositions of Ne, Ar, Kr and Xe in this sample are atmospheric. These observations may reflect venting of hot pore water around the Tenryu Canyon. All the other samples show a significant excess in concentration of all noble gases relative to 1°C air-saturated seawater and the isotopic compositions are atmospheric. This excess of noble gas concentrations may appear to be air contamination in the samples. However, results of hydrocarbon analyses of the Kaiko samples imply that such large amount of air contamination is improbable. Decomposition of gas hydrate in deep-sea sediments is a more likely explanation for the observed excess of noble gas concentration.  相似文献   

Theory of electronic structures of chemisorption on oxide surfaces     

Masaru Tsukada  Nobuyuki Shima 《Physics and Chemistry of Minerals》1987,15(1):35-40

Surface electronic structures of metal oxides such as MgO, TiO₂, SrTiO₃, ReO₃ and transition-metal monoxides are discussed based on the first-principles DV-Xα cluster and slab methods. Particular attention is paid to the origin and properties of intrinsic and extrinsic surface states. A close correlation between the surface structure and electronic states is confirmed. Some exotic properties of polar oxide surfaces, for example the formation of a two-dimensional metallic band, are predicted.  相似文献   

Two modes of climatic control in the Holocene stalagmite record from the Japan Sea side of the Japanese islands          下载免费PDF全文

Tomomi Sone  Akihiro Kano  Kenji Kashiwagi  Taiki Mori  Tomoyo Okumura  Chuan‐Chou Shen  Masako Hori 《Island Arc》2015,24(3):342-358

The Holocene stalagmite FG01 collected at the Fukugaguchi Cave in Itoigawa, central Japan provides a unique high‐resolution record of the East Asian winter monsoon. Because of the climate conditions on the Japan Sea side of the Japanese islands, the volume of precipitation during the winter is strongly reflected in the stalagmite δ¹⁸O signal. Examination of the carbon isotopes and the Mg/Ca ratio of FG01 provided additional information on the Holocene climate in Itoigawa, which is characterized by two different modes separated at 6.4 ka. Dripwater composition and the correlation between the δ¹³C and Mg/Ca data of FG01 indicate the importance of prior calcite precipitation (PCP), a process that selectively eliminated ¹²C and calcium ions from infiltrating water from CO₂ degassing and calcite precipitation. In an earlier period (10.0–6.4 ka), an increase in soil pCO₂ associated with warming and wetting climate trends was a critical factor that enhanced PCP, and resulted in an increasing trend in the Mg/Ca and δ¹³C data and a negative correlation between the δ¹³C and δ¹⁸O profiles. A distinct peak in the δ¹³C age profile at 6.8 ka could be a response to an increase of approximately 10% in C4 plants in the recharge area. At 6.4 ka, the climate mode changed to another, and correlation between δ¹⁸O and δ¹³C became positive. In addition, a millennial‐scale variation in δ¹⁸O and pulsed changes in δ¹³C and Mg/Ca became distinct. Assuming that δ¹⁸O and PCP were controlled by moisture in the later period, the volume of precipitation was high during 6.0–5.2, 4.4–4.0, and 3.0–2.0 ka. In contrast, the driest interval in Itoigawa was during 0.2–0.4 ka, and broadly corresponds to the Little Ice Age.  相似文献   

Holocene Refreshening and Reoxygenation of a Bothnian Sea Estuary Led to Enhanced Phosphorus Burial     

Nikki Dijkstra  Nadine B. Quintana Krupinski  Masako Yamane  Stephen P. Obrochta  Yosuke Miyairi  Yusuke Yokoyama  Caroline P. Slomp 《Estuaries and Coasts》2018,41(1):139-157

Salinity variations in restricted basins like the Baltic Sea can alter their vulnerability to hypoxia (i.e., bottom water oxygen concentrations <2 mg/l) and can affect the burial of phosphorus (P), a key nutrient for marine organisms. We combine porewater and solid-phase geochemistry, micro-analysis of sieved sediments (including XRD and synchrotron-based XAS), and foraminiferal δ¹⁸O and δ¹³C analyses to reconstruct the bottom water salinity, redox conditions, and P burial in the Ångermanälven estuary, Bothnian Sea. Our sediment records were retrieved during the Integrated Ocean Drilling Program (IODP) Baltic Sea Paleoenvironment Expedition 347 in 2013. We demonstrate that bottom waters in the Ångermanälven estuary became anoxic upon the intrusion of seawater in the early Holocene, like in the central Bothnian Sea. The subsequent refreshening and reoxygenation, which was caused by gradual isostatic uplift, promoted P burial in the sediment in the form of Mn-rich vivianite. Vivianite authigenesis in the surface sediments of the more isolated part of the estuary ultimately ceased, likely due to continued refreshening and an associated decline in productivity and P supply to the sediment. The observed shifts in environmental conditions also created conditions for post-depositional formation of authigenic vivianite, and possibly apatite formation, at ～8 m composite depth. These salinity-related changes in redox conditions and P burial are highly relevant in light of current climate change. The results specifically highlight that increased freshwater input linked to global warming may enhance coastal P retention, thereby contributing to oligotrophication in both coastal and adjacent open waters.  相似文献   

Geographic and sex‐specific variation in growth of yellow‐eyed mullet,Aldrichetta forsteri,from estuaries around New Zealand     

Thomas D. Curtis  Jeffrey S. Shima 《新西兰海洋与淡水研究杂志》2013,47(6):1277-1285

Survival and reproductive rates in fish are often a function of body size. Consequently, spatial‐ and sex‐specific variation in somatic growth rates can have important consequences for population growth and resilience. We used otolith‐based approaches to estimate geographic‐ and sex‐specific growth rates of yellow‐eyed mullet (Aldrichetta forsteri) collected from 14 estuaries and harbours around New Zealand. Aldrichetta forsteri is an abundant and dominant component of New Zealand's estuarine fish fauna. We extracted otoliths from 511 fish, validated daily and annual increments, and prepared transverse thin sections of otoliths to determine age. “Size‐at‐age” relationships were estimated using both linear‐ and non‐linear (von Bertalanffy) growth models, and model performance was evaluated using Akaike's Information Criterion. Because growth rates of sampled fish were best approximated by linear functions, we used ANCOVA to test the null hypothesis that growth rates of A. forsteri were homogeneous between sexes and among geographic locations around New Zealand. Our analyses suggest heterogeneous growth rates between sexes and among locations. Interestingly, relative growth rates between sexes appeared to vary across separate latitudinal gradients for North Island and South Island. Within each island (but not across islands), female A. forsteri generally grew faster than males at the lowest latitudes; relative growth rates of females declined progressively below males with increasing latitude.  相似文献