High-pressure phase transition and behavior of protons in brucite Mg(OH)2: a high-pressure–temperature study using IR synchrotron radiation     

K. Shinoda  M. Yamakata  T. Nanba  H. Kimura  T. Moriwaki  Y. Kondo  T. Kawamoto  N. Niimi  N. Miyoshi  N. Aikawa 《Physics and Chemistry of Minerals》2002,29(6):396-402

 Infrared absorption spectra of brucite Mg (OH)₂ were measured under high pressure and high temperature from 0.1 MPa 25 °C to 16 GPa 360 °C using infrared synchrotron radiation at BL43IR of Spring-8 and a high-temperature diamond-anvil cell. Brucite originally has an absorption peak at 3700 cm⁻¹, which is due to the OH dipole at ambient pressure. Over 3 GPa, brucite shows a pressure-induced absorption peak at 3650 cm⁻¹. The pressure-induced peak can be assigned to a new OH dipole under pressure. The new peak indicates that brucite has a new proton site under pressure and undergoes a high-pressure phase transition. From observations of the pressure-induced peak under various P–T condition, a stable region of the high-pressure phase was determined. The original peak shifts to lower wavenumber at −0.25 cm⁻¹ GPa⁻¹, while the pressure-induced peak shifts at −5.1 cm⁻¹ GPa⁻¹. These negative dependences of original and pressure-induced peak shifts against pressure result from enhanced hydrogen bond by shortened O–H···O distance, and the two dependences must result from the differences of hydrogen bond types of the original and pressure-induced peaks, most likely from trifurcated and bent types, respectively. Under high pressure and high temperature, the pressure-induced peak disappears, but a broad absorption band between 3300 and 3500 cm⁻¹ was observed. The broad absorption band may suggest free proton, and the possibility of proton conduction in brucite under high pressure and temperature. Received: 16 July 2001 / Accepted: 25 December 2001  相似文献   

Polarized infrared absorbance spectra of an optically anisotropic crystal: Application to the orientation of the OH- dipole in quartz     

Keiji Shinoda  Nobuvuki Aikawa 《Physics and Chemistry of Minerals》1993,20(5):308-314

The polarized infrared (IR) absorbance spectrum was formulated for an optically anisotropic crystal under the conditions of Fourier transform microspectroscopy. The adequacy of this formulation was confirmed by comparison of calculated interference fringes with those observed in polarized absorbance spectra of optically anisotropic crystal. In accordance with the formulated absorbance, an experimental constraint for the correct measurement of polarized IR absorbance spectrum of optically anisotropic crystal is proposed. Under this experimental constraint, polarized IR absorbance spectra of quartz from Arkansas were measured. They show that the orientation of OH^- dipole which compensates the charge balance coupled with Al³⁺ in quartz is highly polarized perpendicular to the c-axis.  相似文献   

Numerical studies on the influence of the variations of the Kuroshio Path on the transport of fish eggs and larvae   总被引：2，自引：0，他引：2  

Takashige Sugimoto Dr.  Masato Kobayashi Dr. 《GeoJournal》1988,16(1):113-117

Main spawning and nursery grounds of the Pacific Sardine are formed in the coastal boundary regions of the Kuroshio S of Kyushu and S of Honshu, respectively. Numerical experiments on the transport and dispersion of particles in and neighbouring areas of the Kuroshio were done to investigate the transport process of the fish eggs and larvae from the spawning ground to the downstream nursery ground. Surface currents measured with GEK in the past were averaged for both paths with and without large meanders of the Kuroshio in the S of Honshu and used as the data basis. Particles were released in the Kuroshio SE of Kyushu. The results show that the transport rate of them into the S coastal waters of Honshu during large meandered path is larger than the rate during the straight path period. However, recruitment rates of the Pacific Sardine in the S coastal waters of Honshu decreases during the large meander periods of the Kuroshio path. This inverse correlation is considered to be caused by the poorer food environment strongly influenced by the intrusion of the Kuroshio water.  相似文献   

Recursive evaluation of interaction forces of unbounded soil in the time domain     

John P. Wolf  Masato Motosaka 《地震工程与结构动力学》1989,18(3):345-363

The interaction forces representing the contribution of the linear unbounded soil to the equations of motion of a nonlinear soil-structure-interaction analysis are specified in the form of convolution integrals. They can be evaluated recursively in the time domain. In this procedure, the forces at a specific time are computed from the displacements at the same time and from the most recent forces and most recent past displacements. It is, in principle, only approximate. When the dynamic-stiffness coefficients can be expressed as the ratios of two polynomials in frequency, the appropriately chosen recursive equations are exact. Two possibilities of choosing a recursive equation are discussed.

• (i) The impulse-invariant method, where the unknown recursive coefficients are calculated by solving a system of equations which are established by equating the rigorous and recursive formulations for a discretized unit impulse displacement.
• (ii) In the segment approach, the dynamic-stiffness coefficients in the time domain are interpolated piecewise. Applying the z-transformation analytically then results in an explicit recursive equation without solving a system of equations.

The recursive evaluation of the convolution integrals in the time domain leads to a dramatic reduction in the computational effort up to two and three orders of magnitude and in the storage requirement. This makes the time-domain analysis using the substructure method computationally competitive with the corresponding direct (non-recursive) frequency-domain procedure of determining the complex response which is, however, applicable only to a linear (total) system.  相似文献   

Mongolian herders’ vulnerability to <Emphasis Type="Italic">dzud</Emphasis>: a study of record livestock mortality levels during the severe 2009/2010 winter     

Chunling Du  Masato Shinoda  Kaoru Tachiiri  Banzragch Nandintsetseg  Hiroshi Komiyama  Shusuke Matsushita 《Natural Hazards》2018,92(1):3-17

The livelihoods of people inhabiting inland Eurasia have long been jeopardized by repeated natural hazards associated with a harsh environment and a cold, arid climate. Dzud is a Mongolian word indicating harsh winter conditions. In the present study, we considered dzud damage (e.g., livestock loss) to result from a combination of climate hazard (e.g., cold surges) and herders’ socioeconomic vulnerability. For this study, we integrated crucial socioeconomic factors accounting for major spatiotemporal variations in Mongolia by applying principal component analysis (PCA) to a comprehensive province-level, multiyear dataset. We subsequently characterized the regionality of herders’ vulnerability to the dzud event that occurred during the 2009/2010 winter by conducting a cluster analysis of the provincial principal component (PC) scores for the pre-dzud year (2009). Our results revealed a distinct geographical pattern of vulnerability. Herding households in the northern and northeastern (relatively wet and plain) areas were found to be well prepared for harsh winters, with shelters against wind and availability of forage, including hay, as well as easy access to major urban markets. By contrast, herding households in the southern and southwestern (arid and mountainous) areas were poorly prepared, with inadequate circumstances that facilitate pursuing of otor (movement of nomadic herders in search of better pastures) and lack of access to markets and dzud relief support because of their remote locations. The time coefficients of PC 2, related to winter preparedness, indicated that vulnerability increased between 2003 and 2009 (the pre-dzud year). This was partly responsible for the record-level mortality observed in 2010 across the southern and southwestern rural region, in conjunction with harsh winter weathers.  相似文献   

On the importance of accurately ray-traced troposphere corrections for Interferometric SAR data     

Thomas Hobiger  Youhei Kinoshita  Shingo Shimizu  Ryuichi Ichikawa  Masato Furuya  Tetsuro Kondo  Yasuhiro Koyama 《Journal of Geodesy》2010,84(9):537-546

Numerical weather models offer the possibility to compute corrections for a variety of space geodetic applications, including remote sensing techniques like interferometric SAR. Due to the computational complexity, exact ray-tracing is avoided in many cases and mapping approaches are applied to transform vertically integrated delay corrections into slant direction. Such an approach works well as long as lateral atmospheric gradients are small enough to be neglected. But since such an approximation holds only for very rare cases it is investigated how horizontal gradients of different atmospheric constituents can evoke errors caused by the mapping strategy. Moreover, it is discussed how sudden changes of wet refractivity can easily lead to millimeter order biases when simplified methods are applied instead of ray-tracing. By an example, based on real InSAR data, the differences of the various troposphere correction schemes are evaluated and it is shown how the interpretation of the geophysical signals can be affected. In addition, it is studied to which extend troposphere noise can be reduced by applying the exact ray-tracing solution.  相似文献   

Constraints on the source mechanism of harmonic tremors based on seismological, ground deformation, and visual observations at Sakurajima volcano, Japan     

Sukir Maryanto  Masato Iguchi  Takeshi Tameguri 《Journal of Volcanology and Geothermal Research》2008,170(3-4):198-217

Vulcanian-type eruptive activity has occurred from the summit crater of Sakurajima volcano, Japan, since 1955. Over this period, harmonic tremors have commonly occurred either several hours after swarms of B-type earthquakes (herein termed HTB: Harmonic Tremor following B-type earthquake swarm) or immediately after explosive eruptions (herein termed HTE: Harmonic Tremor after an Eruption). In this study, we analyzed the spectra and particle motions of HTBs and HTEs. Both HTBs and HTEs have spectra with peaks at fundamental frequencies and higher frequencies that are integer multiples of the fundamental frequencies. The peak frequencies of HTBs remained within a certain range, whereas those of HTEs showed a gradual increase. The spectra of an HTB that occurred on 20 July 1990 had stable fundamental frequencies of 1.46–1.66 Hz and at least 9 peaks of higher modes; in contrast, the HTE that occurred 3 minutes after an explosive eruption at 11 h 15 m (JST) on 11 October 2002 showed clear frequency gliding from 0.8 to 3.7 Hz in the fundamental mode. The peak frequencies of higher modes of the HTE also showed an increase corresponding to the shift of the fundamental mode towards a higher frequency. Particle motion analysis mainly identified Rayleigh waves from the prograde elliptical motion at the deepest borehole station (HAR) and retrograde motions at the other shallower stations. Love waves were dominant at the stations north and south of the crater. The distribution patterns of Rayleigh and Love waves of HTBs are similar to those of HTEs. The nature of the dominant surface waves of both HTBs and HTEs suggest that the sources of harmonic tremors are located at a shallow depth, corresponding to a gas pocket in the uppermost part of the volcanic conduit. Differences in the temporal characteristics of the HTB and HTE spectra reflect the internal condition of the gas pocket: HTBs are associated with inflation of the conduit, whereas HTEs occur following an eruption, associated with deflationary ground deformation. HTBs are caused by resonance of the gas pocket embedded beneath the lava dome. Although HTEs occur within the open conduit, the small size of vents enables resonance within the bubbly magma conduit. The positive gliding of dominant peaks toward higher frequencies is interpreted to result from shortening of the bubbly magma conduit due to a rise in the bubble nucleation level; this rise results from the re-pressurization that accompanies the ascent of magma from deep within the reservoir.  相似文献   

Evidence of Superposed Metamorphism from the Gokavaram Area, Eastern Ghats Belt, and its Relation with the Kemp Land Coast, East Antarctica     

Somnath Dasgupta  Pulak Sengupta  Supratim Pal  Masato Fukuoka 《Gondwana Research》1999,2(2):227

In this paper, we compare the petrological histories of the Kemp Land Coast (east Antarctica), and Gokavaram area (Eastern Ghats), that were supposed to have been juxtaposed. The area around Gokavaram is dominated by different varieties of paragneisses (pelitic, quartzofeldspathic, and calcareous composition) with relatively minor amounts of orthogneisses (mafic, enderbitic, and granitic composition). The rocks were involved in three major phases of deformation, and were finally affected by localised shear movement. On the basis of reaction textures, well preserved in high Mg-Al granulites, and calc-silicate granulites, and geothermobarometric data we deduce a polymetamorphic evolution of the rocks. Following an early M₁ metamorphism culminating at 9.2–9.4 kbar, > 950°C, the rocks cooled nearly isobarically down to 850°C. During a subsequent M₂ metamorphism, near isothermal decompression to 5–6 kbar occurred. This was followed by near isobaric cooling down to 600–650°C. M₃ is a weak amphibolite facies overprint, largely restricted to late shears, which involved hydration as well. Available radiometric data from this area can be interpreted in terms of partial resetting of U-Pb systematics in older sphenes due to M₃ metamorphism at ca. 550 Ma. Despite the absence of sufficient isotopic data on the Eastern Ghats granulites, we document a remarkable similarity in the petrological history of the two supposedly erstwhile neighbours.  相似文献   

A nonlinear parametric model based on a power law relationship for predicting the coastal tsunami height     

Yoshikawa  Masashi  Igarashi  Yasuhiko  Murata  Shin  Baba  Toshitaka  Hori  Takane  Okada  Masato 《Marine Geophysical Researches》2019,40(4):467-477

When a subduction-zone earthquake occurs, the tsunami height must be predicted to cope with the damage generated by the tsunami. Therefore, tsunami height prediction methods have been studied using simulation data acquired by large-scale calculations. In this research, we consider the existence of a nonlinear power law relationship between the water pressure gauge data observed by the Dense Oceanfloor Network System for Earthquakes and Tsunamis (DONET) and the coastal tsunami height. Using this relationship, we propose a nonlinear parametric model and conduct a prediction experiment to compare the accuracy of the proposed method with those of previous methods and implement particular improvements to the extrapolation accuracy.

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Assessment of drought frequency, duration, and severity and its impact on pasture production in Mongolia   总被引：1，自引：1，他引：0  

Banzragch Nandintsetseg  Masato Shinoda 《Natural Hazards》2013,66(2):995-1008

Drought frequency, duration, and severity and its impact on pasture productivity in the four main vegetation zones of Mongolia were analyzed using meteorological, soil moisture, and vegetation data during the growing season (April–August) of 1965–2010. Meteorological and pasture drought characteristics were explored using the Standardized Precipitation Index (SPI), the soil moisture anomalies percentile index (W _p), and Palmer Drought Severity Index (PDSI) on 1-month timescale. Generally, 35–37 (15–16 %) by SPI for meteorological drought while 27–29 (12–13 %) by W _p, and 16–21 (7–9 %) by PDSI for pasture drought with different durations were identified over the four vegetation zones during the study period. Most of these droughts (80 % by SPI and 50–60 % by both W _p and PDSI) observed during the entire events occurred on a 1-month duration with moderate intensity. Drought frequencies were not significantly (p > 0.05) different within the four zones. The frequency of the short-term meteorological droughts was observed relatively greater than pasture droughts; however, pasture droughts were more persistent and severe than meteorological droughts. The three indices show that the frequency and severity of droughts have slightly increased over the 46 years with significant (p < 0.05) dry conditions during the last decade of 2001–2010 in the four zones (except in the high mountain). The results showed the W _p was more highly significantly correlated with the precipitation anomalies (r = 0.68) and pasture production (r = 0.55) than PDSI (r = 0.51, p < 0.05 and r = 0.38, p < 0.10, respectively). A statistical model, based on pasture production and the W _p, suggested that the consecutive drought months contribution during the growing season was 30 % (p < 0.05) and that pasture production was more sensitive to the occurrence of droughts during June–August (R ² = 0.32, p < 0.05) as seen in 2000–2002 and 2007. We concluded that a greater severity and frequency of growing-season droughts, during the last decade of 2001–2010, have driven a reduction in pasture production in Mongolia.  相似文献