H-bonding scheme and cation partitioning in axinite: a single-crystal neutron diffraction and Mössbauer spectroscopic study     

G. Diego Gatta  Günther J. Redhammer  Alessandro Guastoni  Giorgio Guastella  Martin Meven  Alessandro Pavese 《Physics and Chemistry of Minerals》2016,43(5):341-352

The crystal chemistry of a ferroaxinite from Colebrook Hill, Rosebery district, Tasmania, Australia, was investigated by electron microprobe analysis in wavelength-dispersive mode, inductively coupled plasma–atomic emission spectroscopy (ICP–AES), ⁵⁷Fe Mössbauer spectroscopy and single-crystal neutron diffraction at 293 K. The chemical formula obtained on the basis of the ICP–AES data is the following: \( ^{X1,X2} {\text{Ca}}_{4.03} \,^{Y} \left( {{\text{Mn}}_{0.42} {\text{Mg}}_{0.23} {\text{Fe}}^{2 + }_{1.39} } \right)_{\varSigma 2.04} \,^{Z1,Z2} \left( {{\text{Fe}}^{3 + }_{0.15} {\text{Al}}_{3.55} {\text{Ti}}_{0.12} } \right)_{\varSigma 3.82} \,^{T1,T2,T3,T4} \left( {{\text{Ti}}_{0.03} {\text{Si}}_{7.97} } \right)_{\varSigma 8} \,^{T5} {\text{B}}_{1.96} {\text{O}}_{30} \left( {\text{OH}} \right)_{2.18} \). The ⁵⁷Fe Mössbauer spectrum shows unambiguously the occurrence of Fe²⁺ and Fe³⁺ in octahedral coordination only, with Fe²⁺/Fe³⁺ = 9:1. The neutron structure refinement provides a structure model in general agreement with the previous experimental findings: the tetrahedral T1, T2, T3 and T4 sites are fully occupied by Si, whereas the T5 site is fully occupied by B, with no evidence of Si at the T5, or Al or Fe³⁺ at the T1–T5 sites. The structural and chemical data of this study suggest that the amount of B in ferroaxinite is that expected from the ideal stoichiometry: 2 a.p.f.u. (for 32 O). The atomic distribution among the X1, X2, Y, Z1 and Z2 sites obtained by neutron structure refinement is in good agreement with that based on the ICP–AES data. For the first time, an unambiguous localization of the H site is obtained, which forms a hydroxyl group with the oxygen atom at the O16 site as donor. The H-bonding scheme in axinite structure is now fully described: the O16–H distance (corrected for riding motion effect) is 0.991(1) Å and an asymmetric bifurcated bonding configuration occurs, with O5 and O13 as acceptors [i.e. with O16···O5 = 3.096(1) Å, H···O5 = 2.450(1) Å and O16–H···O5 = 123.9(1)°; O16···O13 = 2.777(1) Å, H···O13 = 1.914(1) Å and O16–H···O13 = 146.9(1)°].  相似文献   

From river to shelf,anatomy of a high‐frequency depositional sequence: The Late Pleistocene to Holocene Tiber depositional sequence          下载免费PDF全文

Salvatore Milli  Marco Mancini  Massimiliano Moscatelli  Francesco Stigliano  Mattia Marini  Gian Paolo Cavinato 《Sedimentology》2016,63(7):1886-1928

The Late Pleistocene/Holocene Tiber delta succession represents the most recent and one of the best preserved, high‐frequency/low‐rank depositional sequences developed along the Latium continental margin of the Italian peninsula. Several previous studies have established a robust data set from which it has been possible to describe the stratigraphic architecture of the entire Tiber depositional sequence from the landward to seaward sectors and over a distance of 60 km. The Tiber depositional sequence shows many characteristics found in other Late Pleistocene to Holocene deltaic and coastal successions of the Mediterranean area. The stratigraphic architecture of the Tiber depositional sequence is controlled mainly by glacioeustasy, although factors such as tectonic uplift, volcanism and subsidence, exert an influence at a local scale. The resulting depositional model allowed discussion of some important points such as: (1) the genesis of the Tiber mixed bedrock‐alluvial valley, extending from the coastal plain to the innermost portion of the shelf, recording (i) multiple episodes of incision during relative sea‐level fall, and (ii) a downstream increase of depth and width of the valley during the base‐level fall and the subsequent base‐level rise; (2) the different physical expression of the Tiber depositional sequence boundary from landward to seaward, and its diachronous and composite character; (3) the maximum depth reached by the Tiber early lowstand delta at the end of the sea‐level fall is estimated at ca 90 m below the present sea‐level and not at 120 m as suggested by previous works; (4) the backward position of the Tiber late lowstand delta relative to the deposit of early lowstand; (5) the change of the channel pattern and of the stacking pattern of fluvial deposits within the Lowstand Systems Tract, Transgressive Systems Tract and Highstand Systems Tract. All of these features indicate that the Late Pleistocene/Holocene Tiber delta succession, even if deposited in a short period of time from a geological point of view, represents the result of the close interaction among many autogenic and allogenic factors. However, global eustatic variations and sediment supply under the control of climatic changes can be considered the main factors responsible for the stratigraphic architecture of this sedimentary succession, which has been heavily modified by human activity only in the last 3000 years.  相似文献   

An Innovative Approach to Meteorite Analysis by Laser‐Induced Breakdown Spectroscopy          下载免费PDF全文

Giorgio S. Senesi  Gioacchino Tempesta  Paola Manzari  Giovanna Agrosì 《Geostandards and Geoanalytical Research》2016,40(4):533-541

An innovative approach of double pulse laser‐induced breakdown spectroscopy (DP‐LIBS) coupled with optical microscopy was applied to the characterisation and quantitative analysis of the Agoudal iron meteorite in bulk sample and in petrographic thin section. Qualitative analysis identified the elements Ca, Co, Fe, Ga, Li and Ni in the thin section and the whole meteorite. Two different methods, calibration‐free LIBS and one‐point calibration LIBS, were used as complementary methodologies for quantitative LIBS analysis. The elemental composition data obtained by LIBS were in good agreement with the compositional analyses obtained by traditional methods generally applied for the analysis of meteorites, such as ICP‐MS and EDS‐SEM. Besides the recognised advantages of LIBS over traditional techniques, including versatility, minimal destructivity, lack of waste production, low operating costs, rapidity of analysis, availability of transportable or portable systems, etc., additional advantages of this technique in the analysis of meteorites are precision and accuracy, sensitivity to low atomic number elements such as Li and the capacity to detect and quantify Co contents that cannot be obtained by EDS‐SEM.  相似文献   

Facies and Late Triassic fossils in the Roisan zone,Austroalpine Dent Blanche and Mt Mary-Cervino nappe system,NW Alps     

Gloria Ciarapica  Leonsevero Passeri  Franco Bonetto  Giorgio Vittorio Dal Piaz 《Swiss Journal of Geoscience》2016,109(1):69-81

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Time-course evaluation of ROS-mediated toxicity in mussels, Mytilus galloprovincialis, during a field translocation experiment     

Frenzilli G  Bocchetti R  Pagliarecci M  Nigro M  Annarumma F  Scarcelli V  Fattorini D  Regoli F 《Marine environmental research》2004,58(2-5):609-613

Harbours can be considered as model environments for developing and validating field monitoring procedures and to investigate mechanistic relationships between different biological responses. In this study several biomarkers were investigated in marine mussels caged for 4 weeks (June-July 2001) into an industrialized harbour of NW Italy. Organisms were collected at different time-intervals to better characterize the sensitivity, temporal variations and interactions of analysed responses. Besides single antioxidants the total oxyradical scavenging capacity (TOSC) assay was used to analyse the capability of the whole antioxidant system to neutralize specific forms of radicals: these data were further integrated by measurement of DNA integrity, oxidized bases and the impairment of lysosomal membrane stability in haemocytes. Results showed a biphasic trend for single antioxidants and TOSC, with an increase during the first 2 weeks of exposure to the polluted site followed by a progressive decrease up to a severe depletion in the final part of the experiment.  相似文献   

A high‐altitude temporary spring in a compartmentalized carbonate aquifer: the role of low‐permeability faults and karst conduits     

Emma Petrella  Paolo Capuano  Massimiliano Carcione  Fulvio Celico 《水文研究》2009,23(23):3354-3364

The aim of this research was to refine the actual conceptual model related to the activation of high‐altitude temporary springs within the carbonate Apennines in southern Italy. The research was carried out through geophysical, hydrogeological, hydrochemical and isotopic investigations at the Acqua dei Faggi experimental site during five hydrologic years. The research demonstrated that, in carbonate aquifers where low‐permeability faults cause the aquifer system to be compartmentalized, high‐altitude temporary springs may be recharged by groundwater. In such settings, neither surface water infiltration in karst systems nor perched temporary aquifers play a role of utmost importance. The rare (once or a few time a year) activation of such springs is due to the fact that groundwater unusually reach the threshold head that allows the spring to flow. The activation of the studied high‐altitude temporary spring also depended on relationships between a low‐permeability fault core and a karst system that locally interrupts the low‐permeability barrier. In fact, when the hydraulic head did not reach the karst system, the concentrated head loss within the fault core did not allow the spring to flow, because the groundwater entirely flowed through the fault towards the downgradient compartment. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Crystal size distributions of plagioclase in lavas from the July–August 2001 Mount Etna eruption     

Alessandro Fornaciai  Cristina Perinelli  Pietro Armienti  Massimiliano Favalli 《Bulletin of Volcanology》2015,77(8):1-15

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Ensemble smoothing of land subsidence measurements for reservoir geomechanical characterization          下载免费PDF全文

Domenico Baù  Massimiliano Ferronato  Giuseppe Gambolati  Pietro Teatini  Ayman Alzraiee 《国际地质力学数值与分析法杂志》2015,39(2):207-228

Geomechanical models are often used to predict the impact on land surface of fluid withdrawal from deep reservoirs, as well as investigating measures for mitigation. The ability to accurately simulate surface displacements, however, is often impaired by limited information on the geomechanical parameters characterizing the geological formations of interest. In this study, we employ an ensemble smoother, a data assimilation algorithm, to provide improved estimates of reservoir parameters through assimilation of measurements of both horizontal and vertical surface displacement into geomechanical model results. The method leverages the demonstrated potential of remote sensing techniques developed in the last decade to provide accurate displacement data for large areas of the land surface. For evaluation purposes, the methodology is applied to the case of a disk‐shaped reservoir embedded in a homogeneous, isotropic, and linearly elastic half space, subject to a uniform change in fluid pressure. Multiple sources of uncertainty are investigated, including the radius, R, the thickness, h, and the depth, c, of the reservoir; the pore pressure change, Δp; porous medium's vertical uniaxial compressibility, c_M, and Poisson's ratio, ν, and the ratio, s, between the compressibilities of the medium during loading and unloading cycles. Results from all simulations show that the ensemble smoother has the capability to effectively reduce the uncertainty associated with those parameters to which the variability and the spatial distribution of land surface displacements are most sensitive, namely, R, c, c_M, and s. These analyses demonstrate that the estimation of these parameters values depends on the number of measurements assimilated and the error assigned to the measurement values. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Experimental models of extension of continental lithosphere weakened by percolation of asthenospheric melts     

Giacomo Corti  Marco Bonini  Fabrizio Innocenti  Piero Manetti  Giovanni B. Piccardo  Giorgio Ranalli 《Journal of Geodynamics》2007,43(4-5):465-483

Analogue models are used to investigate extension of a continental lithosphere weakened by asthenospheric melts percolating through the upper mantle, a process that has been hypothesised to control the opening of the Ligurian Tethys. Models were performed in a centrifuge apparatus and reproduced, by using materials such as sand and viscous mixtures, extension of 60-km thick, three-layer continental lithosphere floating above the asthenosphere. The percolated lithospheric mantle was assumed to be characterised by a rheological behaviour similar to that of the asthenosphere. Two sets of experiments investigated the influence on deformation of (1) the thickness of the percolated mantle and the associated strength contrast between the normal and weakened lithosphere, and (2) the lateral width of the weakened zone. Model results suggest that mantle percolation by asthenospheric melts is able to promote strong localised thinning of the continental lithosphere, provided that a significant thickness of the lithospheric mantle is weakened by migrating melts within a narrow region. Strain localisation is maximised for percolation of the whole lithospheric mantle and strong strength contrast between the normal and weakened lithosphere. Under these conditions, the thickness of the lithosphere may be reduced to less than 12 km in 3 Ma of extension. Conversely, localised thinning is strongly reduced if the thickness of the percolated zone is ≤1/3 of the thickness of the whole lithospheric mantle and/or the lithosphere is weakened over wide regions. Overall, model results support the working hypothesis that mantle percolation by asthenospheric melts is a controlling factor in the transition from distributed continental deformation to localised oceanic spreading.  相似文献   

Measure of the exponential splitting of the homoclinic tangle in four-dimensional symplectic mappings     

Elena Lega  Massimiliano Guzzo  Claude Froeschlé 《Celestial Mechanics and Dynamical Astronomy》2009,104(1-2):191-204

Using four-dimensional symplectic maps as a model problem, we numerically compute the unstable manifolds of the hyperbolic manifolds of the phase space related to the single resonances. We measure an exponential dependence of the size of the lobes of these manifolds through many orders of magnitude of the perturbing parameter. This is an indirect numerical verification of the exponential decay of the normal form, as predicted by the Nekhoroshev theorem. The variation of the size of the lobes turns out to be correlated to the diffusion coefficient.  相似文献