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排序方式: 共有263条查询结果,搜索用时 31 毫秒
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G. W. Harris D. Klemp T. Zenker J. P. Burrows B. Mathieu 《Journal of Atmospheric Chemistry》1992,15(3-4):315-326
Measurements of NO2, HCHO, and H2O2 were made by the highly specific method of mid infra-red absorption spectroscopy using tunable diode lasers (TDLAS) during the 1988 Polarstern expedition. The TDLAS data are compared to those obtained during the cruise using less direct methods. Southern Hemisphere NO2 levels suggest nett photochemical destruction of O3 in the boundary layer. Northern Hemisphere HCHO averaged 0.47±0.2 ppbv; the HCHO measurements are used in a simple calculation to estimate OH noontime maxima of 3–6×106 cm-3. 相似文献
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Dounia Hamoutene Anne Mathieu Paul Hofmann Jean-Pierre Salaun Marc Lafaurie 《Marine environmental research》1995,39(1-4)
The capacity of the mammalian liver microsomal P-450-dependent systems to metabolize a wide variety of endogenous and exogenous compounds is thought to reflect the presence of multiple forms of P-450 haemoproteins with broad and overlapping substrate specificity. In plants, the functions and specificity of cytochrome P-450 systems are less well known.This study was designed to prepare and characterize subcellular fractions from fresh sheaths (basal parts of leaves) of a mediterranean seagrass Posidonia oceanica (Linnaeus) Delile, the aim being the preparation of a microsomal fraction suitable for studying xenobiotic metabolism. The purity of the different fractions obtained by centrifugation, as well as the recovery of different organelles, was determined using enzyme markers (cytochrome c oxidase, alkaline phosphatase, glucose-6-phosphatase) and morphological examination by transmission electron microscopy. Some assays of enzymes involved in xenobiotic metabolism (cytochrome c reductase, laurate hydroxylase, ethoxyresorufin O-deethylase and glutathione-S-transferase) were also performed on different fractions of the preparation. The subcellular distribution for drug metabolism and marker enzymes showed a loss of endoplasmic reticulum in the pellet obtained after the first centrifugation, but the microsomal fraction was relatively free of mitochondria and fragments of the plasma membrane.Some assays are still being performed to avoid the small loss of endoplasmic reticulum experienced with the first pellet. However, the microsomes prepared in this study from sheaths of Posidonia oceanica appear suitable for further investigation of xenobiotic metabolism. 相似文献
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Mathieu Mongin David M. Nelson Philippe Pondaven Mark A. Brzezinski Paul Trguer 《Deep Sea Research Part I: Oceanographic Research Papers》2003,50(12):1445-1480
We report the first application of a biogeochemical model in which the major elemental composition of the phytoplankton is flexible, and responds to changing light and nutrient conditions. The model includes two phytoplankton groups: diatoms and non-siliceous picoplankton. Both fix C in accordance with photosynthesis-irradiance relationships used in other models and take up NO3− and NH4+ (and Si(OH)4 for diatoms) following Michaelis-Menten kinetics. The model allows for light dependence of photosynthesis and NO3− uptake, and for the observed near-total light independence of NH4+ uptake and Si(OH)4 uptake. It tracks the resulting C/N ratios of both phytoplankton groups and Si/N ratio of diatoms, and permits uptake of C, N and Si to proceed independently of one another when those ratios are close to those of nutrient-replete phytoplankton. When the C/N or Si/N ratio of either phytoplankton group indicates that its growth is limited by N, Si or light, uptake of non-limiting elements is controlled by the content of the limiting element in accordance with the cell-quota formulation of Droop (J. Mar. Biol. Ass. U.K 54 (1974) 825).We applied this model to the Bermuda Atlantic Time-series Study (BATS) site in the western Sargasso Sea. The model was tuned to produce vertical profiles and time courses of [NO3−], [NH4+] and [Si(OH)4] that are consistent with the data, by adjusting the kinetic parameters for N and Si uptake and the rate of nitrification. The model then reproduces the observed time courses of chlorophyll-a, particulate organic carbon and nitrogen, biogenic silica, primary productivity, biogenic silica production and POC export with no further tuning. Simulated C/N and Si/N ratios of the phytoplankton indicate that N is the main growth-limiting nutrient throughout the thermally stratified period and that [Si(OH)4], although always limiting to the rate of Si uptake by diatoms, seldom limits their growth rate. The model requires significant nitrification in the upper 200 m to yield realistic time courses and vertical profiles of [NH4+] and [NO3−], suggesting that NO3− is not supplied to the upper water column entirely by physical processes. A nitrification-corrected f-ratio (fNC), calculated for the upper 200 m as: (NO3− uptake—nitrification)/(NO3− uptake+NH4+ uptake) has annual values ranging from only 0.05–0.09, implying that 90–95% of the N taken up annually by phytoplankton is supplied by biological regeneration (including nitrification) in the upper 200 m. Reported discrepancies between estimates of organic C export based on seasonal chemical changes and POC export measured at the BATS site can be almost completely resolved if there is significant regeneration of NO3− via organic-matter decomposition in the upper 200 m. 相似文献
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Petrological evidence for stepwise accretion of metamorphic soles during subduction infancy (Semail ophiolite,Oman and UAE)
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Mathieu Soret Philippe Agard Benoît Dubacq Alexis Plunder Philippe Yamato 《Journal of Metamorphic Geology》2017,35(9):1051-1080
Metamorphic soles are tectonic slices welded beneath most large‐scale ophiolites. These slivers of oceanic crust metamorphosed up to granulite facies conditions are interpreted as forming during the first million years of intraoceanic subduction following heat transfer from the incipient mantle wedge towards the top of the subducting plate. This study reappraises the formation of metamorphic soles through detailed field and petrological work on three key sections from the Semail ophiolite (Oman and United Arab Emirates). Based on thermobarometry and thermodynamic modelling, it is shown that metamorphic soles do not record a continuous temperature gradient, as expected from simple heating by the upper plate or by shear heating as proposed in previous studies. The upper, high‐T metamorphic sole is subdivided in at least two units, testifying to the stepwise formation, detachment and accretion of successive slices from the down‐going slab to the mylonitic base of the ophiolite. Estimated peak pressure–temperature conditions through the metamorphic sole, from top to bottom, are 850°C and 1 GPa, 725°C and 0.8 GPa and 530°C and 0.5 GPa. These estimates appear constant within each unit but differing between units by 100–200°C and ~0.2 GPa. Despite being separated by hundreds of kilometres below the Semail ophiolite and having contrasting locations with respect to the ridge axis position, metamorphic soles show no evidence for significant petrological variations along strike. These constraints allow us to refine the tectonic–petrological model for the genesis of metamorphic soles, formed via the stepwise stacking of several homogeneous slivers of oceanic crust and its sedimentary cover. Metamorphic soles result not so much from downward heat transfer (ironing effect) as from progressive metamorphism during strain localization and cooling of the plate interface. The successive thrusts originate from rheological contrasts between the sole, initially the top of the subducting slab, and the peridotite above as the plate interface progressively cools. These findings have implications for the thickness, the scale and the coupling state at the plate interface during the early history of subduction/obduction systems. 相似文献
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The latest data on holes in the spinous processes of the vertebrae of woolly mammoths, a rare pathology, are presented. This was identified at 19 sites of northern Eurasia. Such destructive changes are recorded ca. 34–12k 14C a bp , and only two sites dated to >50k and >41k 14C a bp. The main hypotheses about hole formation are: vertebral abnormalities; bone infections; genetic traits; and unfavourable geochemical environment. The pathology occurred in mammoths of all age groups, and could have arisen at the embryonic stage. There are two types: classic holes associated with osteolytic changes; and very rarely tumour-like lesions. The most likely cause of the lesions is alimentary osteodystrophy caused by chronic mineral starvation. The aetiology of this disease is usually associated with a deficiency or excess of macro- and microelements in the geochemical landscape, and through forage and water this leads to a severe metabolic disorder. Analysis of palaeopathological data shows two waves of geochemical stress in animals, ca. 26–18k and ca. 16–12k 14C a bp. Therefore, the woolly mammoth extinction can be viewed as a non-linear function, with two peaks of high mortality corresponding to the Last Glacial Maximum and the Lateglacial. 相似文献
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