The Fate of Haloacetic Acids and Trihalomethanes in an Aquifer Storage and Recovery Program, Las Vegas, Nevada     

James M. Thomas  W. Alan McKay  Erin Cole  James E. Landmeyer  Paul M. Bradley 《Ground water》2000,38(4):605-614

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Seasonal variation of Titan's atmospheric structure simulated by a general circulation model.     

T Tokano  F M Neubauer  M Laube  C P McKay 《Planetary and Space Science》1999,47(3-4):493-520

The seasonal variation of Titan's atmospheric structure with emphasis on the stratosphere is simulated by a three-dimensional general circulation model. The model includes the transport of haze particles by the circulation. The likely pattern of meridional circulation is reconstructed by a comparison of simulated and observed haze and temperature distribution. The GCM produces a weak zonal circulation with a small latitudinal temperature gradient, in conflict with observation. The direct reason is found to be the excessive meridional circulation. Under uniformly distributed opacity sources, the model predicts a pair of symmetric Hadley cells near the equinox and a single global cell with the rising branch in the summer hemisphere below about z = 230 km and a thermally indirect cell above the direct cell near the solstice. The interhemispheric circulation transports haze particles from the summer to the winter hemisphere, causing a maximum haze opacity contrast near the solstice and a smaller contrast near the equinox, contrary to observation. On the other, if the GCM is run under modified cooling rate in order to account for the enhancement in nitrites and some hydrocarbons in the northern hemisphere near the vernal equinox, the meridional cell at the equinox becomes a single cell with rising motions in the autumn hemisphere. A more realistic haze opacity distribution can be reproduced at the equinox. However, a pure transport effect (without particle growth by microphysics, etc.) would not be able to cause the observed discontinuity of the global haze opacity distribution at any location. The stratospheric temperature asymmetry can be explained by a combination of asymmetric radiative heating rates and adiabatic heating due to vertical motion within the thermally indirect cell. A seasonal variation of haze particle number density is unlikely to be responsible for this asymmetry. It is likely that a thermally indirect cell covers the upper portion of the main haze layer. An artificial damping of the meridional circulation enables the formation of high-latitude jets in the upper stratosphere and weaker equatorial superrotation. The latitudinal temperature distribution in the stratosphere is better reproduced.  相似文献   

Enhanced CO₂ trapping in water ice via atmospheric deposition with relevance to Mars     

Melissa G. Trainer  Margaret A. Tolbert  Christopher P. McKay 《Icarus》2010,206(2):707-19772

It has been suggested that inclusions of CO₂ or CO₂ clathrate hydrates may comprise a portion of the polar deposits on Mars. Here we present results from an experimental study in which CO₂ molecules were trapped in water ice deposited from CO₂/H₂O atmospheres at temperatures relevant for the polar regions of Mars. Fourier-Transform Infrared spectroscopy was used to monitor the phase of the condensed ice, and temperature programmed desorption was used to quantify the ratio of species in the generated ice films. Our results show that when H₂O ice is deposited at 140-165 K, CO₂ is trapped in large quantities, greater than expected based on lower temperature studies in amorphous ice. The trapping occurs at pressures well below the condensation point for pure CO₂ ice, and therefore this mechanism may allow for CO₂ deposition at the poles during warmer periods. The amount of trapped CO₂ varied from 3% to 16% by mass at 160 K, depending on the substrate studied. Substrates studied were a tetrahydrofuran (C₄H₈O) base clathrate and Fe-montmorillonite clay, an analog for Mars soil. Experimental evidence indicates that the ice structures are likely CO₂ clathrate hydrates. These results have implications for the CO₂ content, overall composition, and density of the polar deposits on Mars.  相似文献   

Feldspathic clasts in Yamato-86032: Remnants of the lunar crust with implications for its formation and impact history     

L. Nyquist  D. Bogard  A. Yamaguchi  C.-Y. Shih  Y. Karouji  M. Ebihara  Y. Reese  D. Garrison  G. McKay  H. Takeda 《Geochimica et cosmochimica acta》2006,70(24):5990-6015

Low concentrations of Th and Fe in the Yamato (Y)-86032 bulk meteorite support earlier suggestions that Y-86032 comes from a region of the moon far distant from the Procellarum KREEP Terrain (PKT), probably from the lunar farside. ³⁹Ar–⁴⁰Ar, Rb–Sr, Sm–Nd, and Sm-isotopic studies characterize the chronology of Y-86032 and its precursors in the mega regolith. One of the rock types present in a light gray breccia lithology is an anorthosite characterized by plagioclase with An 93, i.e., more sodic than lunar FANs, but with very low ⁸⁷Rb/⁸⁶Sr and ⁸⁷Sr/⁸⁶Sr similar to those of FANs. (FAN stands for Ferroan Anorthosite). This “An93 anorthosite” has Nd-isotopic systematics similar to those of nearside norites. A FAN-like “An97 anorthosite” is present in a second light-colored feldspathic breccia clast and has a more negative ε_Nd value consistent with residence in a LREE-enriched environment as would be provided by an early plagioclase flotation crust on the Lunar Magma Ocean (LMO). This result contrasts with generally positive values of ε_Nd for Apollo 16 FANs suggesting the possibility of assymetric development of the LMO. Other possible explanations for the dichotomy in ε_Nd values are advanced in the text. The Y-86032 protolith formed at least 4.43 ± 0.03 Ga ago as determined from a Sm–Nd isochron for mineral fragments from the breccia clast composed predominantly of An93 anorthosite and a second clast of more varied composition. We interpret the mineral fragments as being predominatly from a cogenetic rock suite. An ³⁹Ar–⁴⁰Ar age of 4.36–4.41 ± 0.035 Ga for a third clast composed predominantly of An97 anorthosite supports an old age for the protolith. Initial ¹⁴³Nd/¹⁴⁴Nd in that clast was −0.64 ± 0.13 ε-units below ¹⁴³Nd/¹⁴⁴Nd in reservoirs having chondritic Sm/Nd ratios, consistent with prior fractionation of mafic cumulates from the LMO. A maximum in the ³⁹Ar–⁴⁰Ar age spectrum of 4.23 ± 0.03 Ga for a second sample of the same feldspathic breccia clast probably reflects some diffusive ⁴⁰Ar loss. Lack of solar wind and lunar atmosphere implanted Ar in the light gray breccia clast allows determination of an ³⁹Ar/⁴⁰Ar age of 4.10 ± 0.02 Ga, which is interpreted as the time of initial brecciation of this litholgy. After correction for implanted lunar atmosphere ⁴⁰Ar, impact melt and dark regolith clasts give Ar ages of 3.8 ± 0.1 Ga implying melt formation and final breccia assembly 3.8 Ga ago. Some breccia lithologies were exposed to thermal neutron fluences of 2 × 10¹⁵ n/cm², only about 1% of the fluence experienced by some other lunar highlands meteorites. Other lithologies experienced neutron fluences of 1 × 10¹⁵ n/cm². Thus, Y-86032 spent most of the time following final brecciation deeply buried in the megaregolith. The neutron fluence data are consistent with cosmogenic ³⁸Ar_cos cosmic ray exposure ages of 10 Ma. Variations among differing lithologies in the amount of several regolith exposure indicators, including cosmogenic noble gas abundances, neutron capture induced variations in Sm isotopic abundances, and Ir contents, are consistent with a period of early (>3.8 Ga ago) lunar regolith exposure, subsequent deep burial at >5 m depth, and ejection from the moon 7–10 Ma ago.  相似文献   

Do ice caves exist on Mars?     

K.E. Williams  Christopher P. McKay  James W. Head 《Icarus》2010,209(2):358-368

We have developed a numerical model for assessing the lifetime of ice deposits in martian caves that are open to the atmosphere. Our model results and sensitivity tests indicate that cave ice would be stable over significant portions of the surface of Mars. Ice caves on Earth commonly occur in lava tubes, and Mars has been significantly resurfaced by volcanic activity during its history, including the two main volcanic provinces, the Tharsis and Elysium rises. These areas, known or suspected of having subsurface caves and related voids are among the most favorable regions for the occurrence of ice stability. The martian ice cave model predicts regions which, if caves occur, would potentially be areas of astrobiological importance as well as possible water sources for future human missions to Mars.  相似文献   

The role of organic haze in Titan's atmospheric chemistry: I. Laboratory investigation on heterogeneous reaction of atomic hydrogen with Titan tholin     

Yasuhito Sekine  Hiroshi Imanaka  Takafumi Matsui  Emma L.O. Bakes  Christopher P. McKay 《Icarus》2008,194(1):186-200

In Titan's atmosphere consisting of N₂ and CH₄, large amounts of atomic hydrogen are produced by photochemical reactions during the formation of complex organics. This atomic hydrogen may undergo heterogeneous reactions with organic aerosol in the stratosphere and mesosphere of Titan. In order to investigate both the mechanisms and kinetics of the heterogeneous reactions, atomic deuterium is irradiated onto Titan tholin formed from N₂ and CH₄ gas mixtures at various surface-temperatures of the tholin ranging from 160 to 310 K. The combined analyses of the gas species and the exposed tholin indicate that the interaction mechanisms of atomic deuterium with the tholin are composed of three reactions; (a) abstraction of hydrogen from tholin resulting in gaseous HD formation (HD recombination), (b) addition of D atom into tholin (hydrogenation), and (c) removal of carbon and/or nitrogen (chemical erosion). The reaction probabilities of HD recombination and hydrogenation are obtained as ηabst=1.9(±0.6)×¹⁰⁻³×exp(−300/T) and ηhydro=2.08(±0.64)×exp(−1000/T), respectively. The chemical erosion process is very inefficient under the conditions of temperature range of Titan's stratosphere and mesosphere. Under Titan conditions, the rates of hydrogenation > HD recombination ? chemical erosion. Our measured HD recombination rate is about 10 times (with an uncertainty of a factor of 3-5) the prediction of previous theoretical model. These results imply that organic aerosol can remove atomic hydrogen efficiently from Titan's atmosphere through the heterogeneous reactions and that the presence of aerosol may affect the subsequent organic chemistry.  相似文献   

Laboratory studies of methane and ethane adsorption and nucleation onto organic particles: Application to Titan's clouds     

Daniel B. Curtis  Courtney D. Hatch  Christa A. Hasenkopf  Owen B. Toon  Margaret A. Tolbert  Christopher P. McKay 《Icarus》2008,195(2):792-801

Titan, Saturn's largest moon, has a thick nitrogen/methane atmosphere. The temperature and pressure conditions in Titan's atmosphere are such that the methane vapor should condense near the tropopause to form clouds. Several ground-based measurements have observed sparse cloud-like features in Titan's atmosphere, while the Cassini mission to Saturn has provided large scale images of the clouds. However, Titan's cloud formation conditions remain poorly constrained. Heterogeneous nucleation (from the vapor phase onto a solid or liquid aerosol surface) greatly enhances cloud formation relative to homogeneous nucleation. In order to elucidate the cloud formation mechanism near the tropopause, we have performed laboratory measurements of the adsorption of methane and ethane onto solid organic particles (tholins) representative of Titan's photochemical haze. We find that monolayers of methane adsorb onto tholin particles at saturation ratios less than unity. We also find that solid methane nucleates onto the adsorbed methane at a saturation ratio of S=1.07±0.008. This implies that Titan's methane clouds should form easily. This is consistent with recent measurements of the column of methane ruling out excessive methane supersaturation. In addition, we find ethane adsorbs onto tholin particles in a metastable phase prior to nucleation. However, ethane nucleation onto the adsorbed ethane occurs at a relatively high saturation ratio of S=1.36±0.08. These findings are consistent with the recent report of polar ethane clouds in Titan's lower stratosphere.  相似文献   

Modelling suspended sediment discharge in a glaciated Arctic catchment–Lake Peters,Northeast Brooks Range,Alaska     

Lorna Louise Thurston  Erik Schiefer  Nicholas P. McKay  Darrell S. Kaufman 《水文研究》2020,34(19):3910-3927

Seasonal suspended sediment transfer in glaciated catchments is responsive to meteorological, geomorphological, and glacio-fluvial conditions, and thus is a useful indicator of environmental system dynamics. Knowledge of multifaceted fluvial sediment-transfer processes is limited in the Alaskan Arctic – a region sensitive to contemporary environmental change. For two glaciated sub-catchments at Lake Peters, northeast Brooks Range, Alaska, we conducted a two-year endeavour to monitor the hydrology and meteorology, and used the data to derive multiple-regression models of suspended sediment load. Statistical selection of the best models shows that incorporating meteorological or temporal explanatory variables improves performances of turbidity- and discharge-based sediment models. The resulting modelled specific suspended sediment yields to Lake Peters are: 33 (20–60) t km⁻² yr⁻¹ in 2015, and 79 (50–140) t km⁻² yr⁻¹ in 2016 (95% confidence band estimates). In contrast to previous studies in Arctic Alaska, fluvial suspended sediment transfer to Lake Peters was primarily influenced by rainfall, and secondarily influenced by temperature-driven melt processes associated with clockwise diurnal hysteresis. Despite different sub-catchment glacier coverage, specific yields were the same order of magnitude from the two primary inflows to Lake Peters, which are Carnivore Creek (128 km²; 10% glacier coverage) and Chamberlin Creek (8 km²; 23% glacier coverage). Seasonal to longer-term sediment exhaustion and/or contrasting glacier dynamics may explain the lower than expected relative specific sediment yield from the more heavily glacierized Chamberlin Creek catchment. Absolute suspended sediment yield (t yr⁻¹) from Carnivore Creek to Lake Peters was 27 times greater than from Chamberlin Creek, which we attribute to catchment size and sediment supply differences. Our results provide a foundational understanding of the current sediment transfer regime and are useful for predicting changes in fluvial sediment transport in glaciated Alaskan Arctic catchments.  相似文献   

Fluvial suspended sediment transfer and lacustrine sedimentation of recent flood turbidites in proglacial Eklutna Lake,western Chugach Mountains,Alaska     

Erik Schiefer  Jason Geck  Johnse S. Ostman  Nicholas P. McKay  Nore Praet  Michael G. Loso  Darrell S. Kaufman 《水文研究》2021,35(10):e14375

Suspended sediment delivery and deposition in proglacial lakes is generally sensitive to a wide range of hydrometeorologic and geomorphic controls. High discharge conditions are of particular importance in many glaciolacustrine records, with individual floods potentially recorded as distinctive turbidites. We used an extensive network of surface sediment cores and hydroclimatic monitoring data to analyse recent flood turbidites and associated sediment transfer controls over instrumental periods at Eklutna Lake, western Chugach Mountains, Alaska. Close to a decade of fluvial data from primary catchment tributaries show a dominating influence of discharge on sediment delivery, with various interconnections with other related hydroclimatic controls. Multivariate fluvial models highlight and help quantify some complexities in sediment transfer, including intra-annual variations, meteorological controls, and the influence of subcatchment glacierization. Sediments deposited in Eklutna Lake during the last half century are discontinuously varved and contain multiple distinctive turbidites. Over a 30-year period of stratigraphic calibration, we correlate the four thickest flood turbidites (1989, 1995, 2006, and 2012) to specific regional storms. The studied turbidites correlate with late-summer and early-autumn rainstorms with a magnitude of relatively instantaneous sedimentation 3–15 times greater than annual background accumulation. Our network of sediment core data captured the broad extent and sediment variability among the study turbidites and background sediment yield. Within-lake spatial modelling of deposition quantifies variable rates of downlake thinning and sediment focusing effects, and highlights especially large differences between the thickest flood turbidites and background sedimentation. This we primarily relate to strongly contrasting dispersion processes controlled by inflow current strength and turbidity. Sediment delivery is of interest for this catchment because of reservoir and water supply operations. Furthermore, although smaller floods may not be consistently represented, the lake likely contains a valuable proxy record of regional flooding proximal to major population centers of south-central Alaska including Anchorage.  相似文献   

Viruses and Bacteria in Karst and Fractured Rock Aquifers in East Tennessee,USA   总被引：2，自引：0，他引：2  

Trisha B. Johnson  Larry D. McKay  Alice C. Layton  Sidney W. Jones  Greg C. Johnson  Jennifer L. Cashdollar  Daniel R. Dahling  Leah F. Villegas  G. Shay Fout  Daniel E. Williams  Gary Sayler 《Ground water》2011,49(1):98-110

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