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91.
Partly flooded loose sand deposits are left back from lignite mining, particularly in east Germany. After flooding, gas inclusions in macropores enhance the pore pressure increase by total stress cycles without drainage, and this can cause the transition into a kind of suspension. Thus, natural and technical changes of surface loads triggered flow slides in chain reactions of sometimes catastrophic extent. Such collapsible deposits were and are stabilized by blast-induced liquefaction and densification. Successive collapse fronts in flooded grain skeletons are seismogeneous, and this appears as wavering in the near-field and leads to power-law spectra in the far-field. Apart from this evidence of mild fractality, the wild fractality of chain reactions eludes mathematical treatment. Therefore, uncommon methods of geotechnical design, operations and monitoring are required.  相似文献   
92.
We investigated the relationships between mineral content and the physical and mechanical properties of landscape rock using a non-destructive remote sensing method applied in the laboratory. Using this technique, the spectral properties of the landscape rock could be collected at different wavelengths without harming the samples. Differences in spectral reflectance were compared with the physical and mechanical properties of the stone. Significant correlations were observed between reflectance values and the rocks’ mechanical and physical properties, with correlation coefficients of 95 to 99 %. However, establishing a correlation between two variables is not a sufficient condition to establish a causal relationship. Mineral densities and mineral content are characteristics used for the classification of landscape rock. We have concluded that although spectral signatures from landscape rock can be used for predicting which stones might have similar features when comparing two batches of stone, the high correlations we discovered cannot confirm a cause and effect relationship that would allow for the prediction of a rock’s physical and mechanical properties. Although this conclusion is disappointing, the mineral content and the significant correlations discovered by hyperspectral reflectance scanning can be used as supplementary information when comparing two samples of landscape rock.  相似文献   
93.
Groundwater vulnerability has been subject of much research due to the valuable information it provides concerning groundwater protection and exploitation potential. Up to now, most groundwater vulnerability studies adopt subjective systems of rating the various factors and subsequently, their results are often ambiguous and contradicting. Within the present study a methodology for the estimation of intrinsic groundwater vulnerability at the aquifer scale is presented. The methodology is based on travel time estimation from specified sources of pollution to the aquifer. Besides the deterministic calculation of travel times, the methodology provides a rating system for each pollution source, based on its relative severity and the estimated threat that it poses to the aquifer. Therefore, it can be regarded as a hybrid method that couples the advantages provided by the physically based methods with those of the subjective rating systems. The methodology is applied to the Neon Sidirochorion aquifer, Northeastern Greece, an overexploited aquifer where river waters, sea waters and lake waters interact, causing groundwater quality deterioration to the aquifer. The results indicated that the proposed groundwater vulnerability assessment methodology is well capturing pollution related to saltwater intrusion and agricultural activities, while it is concluded that the conceptual model is significantly affecting the vulnerability assessment results and therefore has to be previously developed.  相似文献   
94.
Blasting operations usually produce significant environmental problems which may cause severe damage to the nearby areas. Air-overpressure (AOp) is one of the most important environmental impacts of blasting operations which needs to be predicted and subsequently controlled to minimize the potential risk of damage. In order to solve AOp problem in Hulu Langat granite quarry site, Malaysia, three non-linear methods namely empirical, artificial neural network (ANN) and a hybrid model of genetic algorithm (GA)–ANN were developed in this study. To do this, 76 blasting operations were investigated and relevant blasting parameters were measured in the site. The most influential parameters on AOp namely maximum charge per delay and the distance from the blast-face were considered as model inputs or predictors. Using the five randomly selected datasets and considering the modeling procedure of each method, 15 models were constructed for all predictive techniques. Several performance indices including coefficient of determination (R 2), root mean square error and variance account for were utilized to check the performance capacity of the predictive methods. Considering these performance indices and using simple ranking method, the best models for AOp prediction were selected. It was found that the GA–ANN technique can provide higher performance capacity in predicting AOp compared to other predictive methods. This is due to the fact that the GA–ANN model can optimize the weights and biases of the network connection for training by ANN. In this study, GA–ANN is introduced as superior model for solving AOp problem in Hulu Langat site.  相似文献   
95.
96.
In this study, we investigated the structural properties of Urfa stone (US) doped with erbium oxide (Er2O3). Solid US was powdered by using an agate mortar, and its elemental composition was determined using inductive coupling plasma (ICP) methods. Varying amounts of Er2O3 (5, 10, 20, 30, and 40%) were added as a dopant to the US powder using mechanical alloying methods. The resultant samples were sintered at 1000 °C for 1 h. The structural properties of the Er2O3-doped US samples were subsequently investigated using X-ray diffraction (XRD), Fourier-transform infrared spectrometry (FTIR), and photoluminescence methods. Results from the XRD analysis of the Er2O3-doped US powder indicated two crystalline phases: (1) calcium oxide (CaO) or lime and (2) Er2O3. After the samples were sintered at 1000 °C, CaO, Er2O3, calcium carbonate (CaCO3), and mixed crystalline phases were observed. Results from the FTIR analysis of the Er2O3-doped US samples indicated absorption bands at 711.91, 872.08, and 1396.87 cm?1 in the spectra. Finally, photoluminescence analysis results indicated a shift in the emission and excitation bands to longer and shorter wavelengths, respectively, in the solid state (non-aqueous media) US-Er complex.  相似文献   
97.
Aplite dikes intruding the Proterozoic 1.42(±?3) Ga Longs Peak-St. Vrain Silver Plume-type peraluminous granite near Jamestown, Colorado, contain F, P, and rare earth element (REE)-rich globular segregations, with 40–46% REE, 3.7–4.8 wt% P2O5, and 5–8 wt% F. A combination of textural features and geochemical data suggest that the aplite and REE-rich globular segregations co-existed as two co-genetic liquids prior to their crystallization, and we propose that they are formed by silicate–fluoride?+?phosphate (+?S?+?CO2) melt immiscibility following ascent, cooling, and decompression of what was initially a single homogeneous magma that intruded the granite. The REE distribution coefficients between the silica-rich aplites and REE-rich segregations are in good agreement with experimentally determined distribution coefficients for immiscible silicate–fluoride?+?phosphate melts. Although monazite-(Ce) and uraninite U–Th–Pb microprobe ages for the segregations yield 1.420(±?25) and 1.442(±?8) Ga, respectively, thus suggesting a co-genetic relationship with their host granite, εNd1.42Ga values for the granites and related granitic pegmatites range from ??3.3 to ??4.7 (average ??3.9), and differ from the values for both the aplites and REE-rich segregations, which range from ??1.0 to ??2.2 (average ??1.6). Furthermore, the granites and pegmatites have (La/Yb)N <50 with significant negative Eu anomalies, which contrast with higher (La/Yb)N >100 and absence of an Eu anomaly in both the aplites and segregations. These data are consistent with the aplite dikes and the REE-rich segregations they contain being co-genetic, but derived from a source different from that of the granite. The higher εNd1.42Ga values for the aplites and REE-rich segregations suggest that the magma from which they separated had a more mafic and deeper, dryer and hotter source in the lower crust or upper mantle compared to the quartzo-feldspathic upper crustal source proposed for the Longs Peak-St. Vrain granite.  相似文献   
98.
The Pozanti–Karsanti ophiolite (PKO) is one of the largest oceanic remnants in the Tauride belt, Turkey. Micro-diamonds were recovered from the podiform chromitites, and these diamonds were investigated based on morphology, color, cathodoluminescence, nitrogen content, carbon and nitrogen isotopes, internal structure and inclusions. The diamonds recovered from the PKO are mainly mixed-habit diamonds with sectors of different brightness under the cathodoluminescence images. The total δ13C range of the PKO diamonds varies between ??18.8 and ??28.4‰, with a principle δ13C mode at ??25‰. Nitrogen contents of the diamonds range from 7 to 541 ppm with a mean value of 171 ppm, and the δ15N values range from ??19.1 to 16.6‰, with a δ15N mode of ??9‰. Stacking faults and partial dislocations are commonly observed in the Transmission Electron Microscopy foils whereas inclusions are rather rare. Combinations of (Ca0.81Mn0.19)SiO3, NiMnCo-alloy and nano-sized, quenched fluid phases were observed as inclusions in the PKO diamonds. We believe that the 13C-depleted carbon signature of the PKO diamonds derived from previously subducted crustal matter. These diamonds may have crystallized from C-saturated fluids in the asthenospheric mantle at depth below 250 km which were subsequently carried rapidly upward by asthenospheric melts.  相似文献   
99.
Garnet crystals with quartz inclusions were hydrothermally crystallized from oxide starting materials in piston–cylinder apparatuses at pressures from 0.5 to 3 GPa and temperatures ranging from 700 to 800 °C to study how entrapment conditions affect remnant pressures of quartz inclusions used for quartz-in-garnet (QuiG) elastic thermobarometry. Systematic changes of the 128, 206 and 464 cm?1 Raman band frequencies of quartz were used to determine pressures of quartz inclusions in garnet using Raman spectroscopy calibrations that describe the P–T dependencies of Raman band shifts for quartz under hydrostatic pressure. Within analytical uncertainties, inclusion pressures calculated for each of the three Raman band frequencies are equivalent, which suggests that non-hydrostatic stress effects caused by elastic anisotropy in quartz are smaller than measurement errors. The experimental quartz inclusions have pressures ranging from ??0.351 to 1.247 GPa that span the range of values observed for quartz inclusions in garnets from natural rocks. Quartz inclusion pressures were used to model P–T conditions at which the inclusions could have been trapped. The accuracy of QuiG thermobarometry was evaluated by considering the differences between pressures measured during experiments and pressures calculated using published equation of state parameters for quartz and garnet. Our experimental results demonstrate that Raman measurements performed at room temperature can be used without corrections to estimate garnet crystallization pressures. Calculated entrapment pressures for quartz inclusions in garnet are less than ~?10% different from pressures measured during the experiments. Because the method is simple to apply with reasonable accuracy, we expect widespread usage of QuiG thermobarometry to estimate crystallization conditions for garnet-bearing silicic rocks.  相似文献   
100.
In order to investigate the origin of the high conductivity anomalies geophysically observed in the mid-lower crust of Tibet Plateau, the electrical conductivity of plagioclase–NaCl–water system was measured at 1.2 GPa and 400–900 K. The relationship between electrical conductivity and temperature follows the Arrhenius law. The bulk conductivity increases with the fluid fraction and salinity, but is almost independent of temperature (activation enthalpy less than 0.1 eV). The conductivity of plagioclase–NaCl–water system is much lower than that of albite–NaCl–water system with similar fluid fraction and salinity, indicating a strong effect of the major mineral phase on the bulk conductivity of the brine-bearing system. The high conductivity anomalies of 10?1 and 100 S/m observed in the mid-lower crust of Tibet Plateau can be explained by the aqueous fluid with a volume fraction of 1 and 9%, respectively, if the fluid salinity is 25%. The anomaly value of 10?1 S/m can be explained by the aqueous fluid with a volume fraction of 6% if the salinity is 10%. In case of Southern Tibet where the heat flow is high, the model of a thin layer of brine-bearing aqueous fluid with a high salinity overlying a thick layer of partial melt is most likely to prevail.  相似文献   
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