益阳市矿泉水的基本特征及形成机理探讨     

卜鸿鹄 《湖南地质》1997,16(3):175-181

益阳市矿泉水是一种弱酸、弱碱性、低矿化、富含偏硅酸的ＨＣＯ３－Ｃａ天然优质饮料矿泉水。它赋存于武陵期海底裂隙式喷溢形成的基性火山岩－细碧玄武岩的构造断裂和半风化层的风化裂隙之中。矿泉水水量起源于多途，化学成分形成于多因，是多因复成的产物。  相似文献   

Investigating the Halogen Chemistry From High-Latitude Nighttime Stratospheric Measurements of OClO and NO2     

Emmanuel Damien Rivière  Michel Pirre  Gwenaël Berthet  Jean-Baptiste Renard  Franck Lefèvre 《Journal of Atmospheric Chemistry》2004,48(3):261-282

Two cases of simultaneous nighttime measurements of NO₂ and OClO in the winter polar stratosphere are analyzed in order to test our present knowledge of halogen chemistry in the presence of high amount of NO₂ at low temperature. Comparisons with Lagrangian model calculations using several hypotheses are performed. First simulations, using the admitted constant rates of chemical reaction, strongly underestimate the measured OClO while the NO₂ profiles are correctly reproduced. If uncertainties in actinic fluxes calculations are taken into account, simulation results do not show a significant reduction of the underestimation. A better agreement can be achieved if the formation of unstable isomers of ClONO₂ and of BrONO₂ occurs in the cold conditions of the polar stratosphere. An approximate value of the branching ratios of the channels leading to ClONO₂ and ClOONO, and to BrONO₂ and BrOONO, necessary to reproduce both OClO and NO₂ is given and discussed.  相似文献   

华南石炭纪岩关-大塘界线期牙形石地层分带   总被引：4，自引：0，他引：4  

田树刚  M.科恩 《地质通报》2004,23(8):737-749

系统采集不同沉积相区和连续沉积的剖面，即浅海台地相广西柳江龙殿山剖面、台缘缓坡相云南施甸鱼硐剖面和台内盆地相广西柳州碰冲剖面，运用数理统计方法，研究了华南岩关一大塘界线过渡期牙形石的产出丰度和相分布，在恢复生物演化序列的基础上，对各剖面首先详细分带，再进一步综合成系统的5个牙形石带，即Gnathodus typicus—G．cuneiformis带、Gnathodus typicus—Protognathodus cordiformis带、Scaliognathus anchoralis—Gnathodus pseu-dosemiglaber带、Gnathodus praebilineatus带和Paragnathodus horrtopunctatus带。以生物系统发生为标准，严格限定各带的界线，并与北美、西欧同期地层进行精确对比，为建立杜内阶一维宪阶界线的全球层型(GSSP)提供可靠依据。  相似文献   

CO₂ solubility in dacitic melts equilibrated with H₂O-CO₂ fluids: Implications for modeling the solubility of CO₂ in silicic melts     

Harald Behrens  Susanne Ohlhorst  Michel Champenois 《Geochimica et cosmochimica acta》2004,68(22):4687-4703

The solubility of CO₂ in dacitic melts equilibrated with H₂O-CO₂ fluids was experimentally investigated at 1250°C and 100 to 500 MPa. CO₂ is dissolved in dacitic glasses as molecular CO₂ and carbonate. The quantification of total CO₂ in the glasses by mid-infrared (MIR) spectroscopy is difficult because the weak carbonate bands at 1430 and 1530 cm⁻¹ can not be reliably separated from background features in the spectra. Furthermore, the ratio of CO_2,mol/carbonate in the quenched glasses strongly decreases with increasing water content. Due to the difficulties in quantifying CO₂ species concentrations from the MIR spectra we have measured total CO₂ contents of dacitic glasses by secondary ion mass spectrometry (SIMS).At all pressures, the dependence of CO₂ solubility in dacitic melts on x^fluid_CO2,total shows a strong positive deviation from linearity with almost constant CO₂ solubility at x_CO2fluid > 0.8 (maximum CO₂ solubility of 795 ± 41, 1376 ± 73 and 2949 ± 166 ppm at 100, 200 and 500 MPa, respectively), indicating that dissolved water strongly enhances the solubility of CO₂. A similar nonlinear variation of CO₂ solubility with x_CO2fluid has been observed for rhyolitic melts in which carbon dioxide is incorporated exclusively as molecular CO₂ (Tamic et al., 2001). We infer that water species in the melt do not only stabilize carbonate groups as has been suggested earlier but also CO₂ molecules.A thermodynamic model describing the dependence of the CO₂ solubility in hydrous rhyolitic and dacitic melts on T, P, f_CO2 and the mol fraction of water in the melt (x_water) has been developed. An exponential variation of the equilibrium constant K₁ with x_water is proposed to account for the nonlinear dependence of x_CO2,totalmelt on x_CO2fluid. The model reproduces the CO₂ solubility data for dacitic melts within ±14% relative and the data for rhyolitic melts within 10% relative in the pressure range 100-500 MPa (except for six outliers at low x_CO2fluid). Data obtained for rhyolitic melts at 75 MPa and 850°C show a stronger deviation from the model, suggesting a change in the solubility behavior of CO₂ at low pressures (a Henrian behavior of the CO₂ solubility is observed at low pressure and low H₂O concentrations in the melt). We recommend to use our model only in the pressure range 100-500 MPa and in the x_CO2fluid range 0.1-0.95. The thermodynamic modeling indicates that the partial molar volume of total CO₂ is much lower in rhyolitic melts (31.7 cm³/mol) than in dacitic melts (46.6 cm³/mol). The dissolution enthalpy for CO₂ in hydrous rhyolitic melts was found to be negligible. This result suggests that temperature is of minor importance for CO₂ solubility in silicic melts.  相似文献   

Effet du vieillissement des céramiques poreuses sur leur capacité à évaluer la concentration de pesticide en solution     

Nicolas Domange  Caroline Grégoire  Véronique Gouy  Michèle Tremolières 《Comptes Rendus Geoscience》2004,336(1):49-58

The soil solution sampling by ceramic cups allows pesticide transfer monitoring in the soil during long times. The ageing of material involves a bias in the sampling results. In laboratory, the comparison of two types of ceramic suction cups, new and installed in situ during four years, shows a modification of the hydrodynamic properties and a possible evolution of the adsorption capacity of the matrix. The passage rate, as well qualitative as quantitative, is better for the old material. Recommendations about site management are finally exposed. To cite this article: N. Domange et al., C. R. Geoscience 336 (2004).  相似文献   

Field and petrological evidence for a Late Palaeozoic (Upper Carboniferous–Permian) age of the Erfaulet orthogneiss (Gran Paradiso,western Alps)     

Benjamin Le Bayon  Michel Ballèvre 《Comptes Rendus Geoscience》2004,336(12):1079-1089

In the Gran Paradiso massif (western Alps), the boundary between the Erfaulet orthogneiss and the overlying metasediments (Money Complex) is interpreted as a Late Palaeozoic intrusive contact. Major arguments in favour of this hypothesis are: (i) the obliquity of the sedimentary layering with respect to the contact; (ii) the presence of aplitic dykes within the Money Complex; (iii) the lack of a mylonitic zone; and (iv) rare relics of an early generation of garnet in the Money metasediments, interpreted as evidence of the contact metamorphism of the Erfaulet granite. To cite this article: B. Le Bayon, M. Ballèvre, C. R. Geoscience 336 (2004).  相似文献   

Particularités de la contamination crustale des phonolites : exemple du Velay oriental (Massif central)     

Jean-Marie Dautria  Jean-Michel Liotard  Danièle Briot 《Comptes Rendus Geoscience》2004,336(11):971-981

Sr and Nd isotopic compositions of one trachyte, eight phonolites and five basalts have been measured. The isotopic characteristics of the trachyte can be explained by a combined assimilation–fractional crystallization process within an upper crustal magmatic chamber. Some phonolites display isotopic signatures identical to basalts, suggesting that they have been protected against any crustal assimilation during their formation. Some others have low Sr contents, whereas they are enriched in radiogenic Sr (0.70451<⁸⁷Sr/⁸⁶Sr_i<0.71192), and display basaltic ¹⁴³Nd/¹⁴⁴Nd ratios. Both observations could be explained by very strong alkali feldspar fractionation and by subsequent very low assimilation of surrounding rocks (between 0.3 and 4%) during intrusion. To cite this article: J.-M. Dautria et al., C. R. Geoscience 336 (2004).  相似文献   

Seismic studies of the Brasília fold belt at the western border of the São Francisco Craton, Central Brazil, using receiver function, surface-wave dispersion and teleseismic tomography     

Marcelo Assumpo  Meijian An  Marcelo Bianchi  George S.L. Frana  Marcelo Rocha  Jos Roberto Barbosa  Jesús Berrocal 《Tectonophysics》2004,388(1-4):173

The Tocantins Province in Central Brazil is composed of a series of SSW–NNE trending terranes of mainly Proterozoic ages, which stabilized in the Neoproterozoic in the final collision between the Amazon and São Francisco cratons. No previous information on crustal seismic properties was available for this region. Several broadband stations were used to study the regional patterns of crustal and upper mantle structure, extending the results of a recent E–W seismic refraction profile. Receiver functions and surface wave dispersion showed a thin crust (33–37 km) in the Neoproterozoic Magmatic Arc terrane. High average crustal Vp/Vs ratios (1.74–1.76) were consistently observed in this unit. The foreland domain of the Brasília foldbelt, on the other hand, is characterized by thicker crust (42–43 km). Low Vp/Vs ratios (1.70–1.72) were observed in the low-grade foreland fold and thrust zone of the Brasília belt adjacent to the São Francisco craton. Teleseismic P-wave tomography shows that the lithospheric upper mantle has lower velocities beneath the Magmatic Arc and Goiás Massif compared with the foreland zone of the belt and São Francisco craton. The variations in crustal thickness and upper mantle velocities observed with the broadband stations correlate well with the measurements along the seismic refraction profile. The integration of all seismic observations and gravity data indicates a strong lithospheric contrast between the Goiás Massif and the foreland domain of the Brasília belt, whereas little variation was found across the foldbelt/craton surface boundary. These results support the hypothesis that the Brasília foreland domain and the São Francisco craton were part of a larger São Francisco-Congo continental plate in the final collision with the Amazon plate.  相似文献   

Low-frequency 3-D seismic survey of upper crustal magmatic intrusions in the northeastern Pannonian basin of Hungary     

Zoltn Hajnal  Endre Heged&#x;s  G. Randy Keller  Tams Fancsik  Attila Cs. Kovcs  Rbert Csabafi 《Tectonophysics》2004,388(1-4):239

A specially designed 700-km² grid survey, deploying 1000 regularly distributed low-frequency seismic recording systems, successfully investigated one of the most complex geologic environments of the Pannonian basin. The wide-angle signals penetrated through over 1000 m of multi-phase igneous lithology and recognized, for the first time, the underlying enigmatic Permian to Early Triassic basement rocks. Tomographic inversion of the first arrival grid data resulted in determination of an accurate three-dimensional (3-D) velocity field, to a depth of 4 km. The anomalous changes of the spatial velocity data outline the regional extent of the Late Miocene magmatic intrusions, which are covered by over 2000 m of Mid-Miocene to Pleistocene clastics. Complex relationship was found between the surface potential data and the intrusive bodies. This multi-faceted geophysical data analysis established a functional technique for mapping a subsurface with intricate acoustic and structural complexity.  相似文献   

Processing and interpretation of the gravity field of the East African Rift: implication for crustal extension     

A. Tessema  L.A.G. Antoine 《Tectonophysics》2004,394(1-2):87-110

Compilation of new and existing gravity data were undertaken to assess the nature of the crust beneath the East African Rift System. Using 3D gravity modeling code crustal model of gravity profiles across two sectors of the rift were computed. The results are discussed in light of the structure of the rift system.The results of the 3D modeling of gravity profiles across the two rift zones revealed northward thinning of the crust. The maximum crustal attenuation occurs beneath the Afar depression, indicating the Afar rift undergoes an intense fragmentation of the crust resulting from faulting and magmatic activity. However, our computed crustal thickness below the Afar depression falls within an upper bound compared to elsewhere below tectonically active rift zones. This can be explained in terms of crustal accretion resulting from an impact of the Afar mantle plume since 30 Ma ago.The residual gravity obtained using high-cut filtering techniques reveals significant density contrast between the northern and southern sectors of the rift. The northern part of the rift is characterized by regular patterns of positive gravity anomalies, which can be interpreted in terms of a zone of crustal thinning through which relatively dense materials have intruded the overlying crust. In contrast, south of the Main Ethiopian Rift, the anomalies are characterized by random patterns and low amplitudes. The along-rift-axis variation in gravity anomalies implies that the style of crustal deformation changed progressively, beginning with regionally distributed crustal deformation, such as the one we observe within the more juvenile and wider southern segment of the rift, to localized deformation within the active and narrow rift zones of the northern sector of the Ethiopian Rift. We suggest that the key parameters controlling along-rift-axis variation in gravity anomalies are the rate of crustal extension, faulting and magmatic activities.  相似文献