An experimental study of the effect of boron on a water saturated haplogranite at 1 Kbar vapour pressure     

Michel Pichavant 《Contributions to Mineralogy and Petrology》1981,76(4):430-439

An experimental study of the effect of boron in the water saturated Q-Or-Ab-B₂O₃-H₂O system has been performed at P=1 Kbar to provide experimental data and explain the role of boron in some late magmatic and early hydrothermal events. Experiments were conducted between 500° C and 800° starting from a gel, or a previously crystallized gel, and variable amounts of boron (0 to 18% B₂O₃) added to water. The phases obtained were: quartz, sanidine, albite, silicate liquid quenched to glass, and aqueous vapour phase. Boric acids, borates and isotropic low index materials were found in the quenched vapour phase. An aluminium silicate-like mineral, not yet fully identified, is also present.The solidus temperature of the Q-Or-Ab composition is lowered by 60° C when 5 wt. % B₂O₃ is added and by more than 130° C when 17wt. % B₂O₃ is added. Compositions of equilibrated silicate melts and vapours were obtained between 780° C and 750° C for various B₂O₃ concentrations. The vapour phase is B and Si rich. It is also enriched in Na with respect to K, and in alkalis with respect to Al. Its silicate solute content is higher than in experiments with pure water. The solubility of water is increased by the addition of boron in Q-Or-Ab melts. Microprobe data show that the melts equilibrated with vapour phases become hyperaluminous and more potassic than sodic. The partition coefficient of boron is in favour of the vapour (k _D=B₂O₃% in melt/B₂O₃% in vapour=0.33±0.02). The effect of the interaction between the silicate phases and the vapour is discussed. Comparison is made between the behaviour of boron and that of chlorine and fluorine. Geological applications are also provided, which concern the influence of boron on minimum melting, on muscovite stability and on the hypersolvus-subsolvus transition.  相似文献   

Fluxes of uranium and thorium series isotopes in the Santa Barbara Basin     

Willard S. Moore  Kenneth W. Bruland  Jacqueline Michel 《Earth and Planetary Science Letters》1981,53(3):391-399

Samples from the MANOP Santa Barbara Basin sediment trap intercomparison were analyzed for the isotopes of uranium, thorium, radium, lead, and polonium. All of the traps showed approximately the same compositions and isotopic ratios, indicating that they trapped similar materials. The²³⁴Th flux via falling particles was very close to the flux predicted from the production and scavenging rates of²³⁴Th from the water column. The²¹⁰Pb content of the trapped particles and the surface sediments were the same, however, the measured flux of²¹⁰Pb was seven times greater than the predicted flux. Predicted and measured fluxes of²²⁸Th and²¹⁰Po were similarly out of balance. To explain this apparent inconsistency, we suggest (as others have done) that the Santa Barbara Basin is an area where scavenging from the water column is intensified and where sediments deposited initially on the margins may be physically remobilized on a short time scale. These two effects increase the apparent area from which the basin derives the longer-lived isotopes but does not increase significantly the supply of the short-lived²³⁴Th.  相似文献   

A fast method for the solution of a system of simultaneous linear equations—A method adapted to a particular problem     

Davis  Michael W. D.  David  Michel  Belisle  Jean-Marc 《Mathematical Geosciences》1978,10(4):369-374

Mathematical Geosciences - In mineral deposit evaluation, the estimation of block values can involve the solution of as many as 100,000 systems of linear equations. To minimize computing costs it...  相似文献   

Biotites and associated minerals as markers of magmatic fractionation and deuteric equilibration in granites     

Michel Barrière  Joseph Cotten 《Contributions to Mineralogy and Petrology》1979,70(2):183-192

Analyses of 80 biotite, alkali feldspar, oligoclase, hornblende, Fe-Ti oxide separates from the coarse-grained granites of a late-hercynian epizonal diapir, the Ploumanac'h complex, Brittany, show that these minerals display a regular concentric cryptic layering related to fractional crystallization. The Ca, Mg, Ba, Sr, Cr, V content of minerals decreases as the Na, Fe, and Rb content increases. Biotites become more dioctahedral towards the outer residual syenogranite, with a correlative K deficiency. Trioctahedral biotites from the inner accumulative monzogranite are secondarily oxidized with a gain of Fe³⁺ and a loss of OH. This alteration id due to the percolation of exsolved fluids rich in H₂O and containing a small amount of CO₂, F, S, Cl. During this autometamorphic stage, trace elements like Rb, Sr are completely redistributed on the scale of hand specimens, with a restricted range of partition coefficients between biotite, perthite and oligoclase. This equilibration occurred at a temperature about 550 ° C and a fluid pressure about 1,000 bars, with f _H2_O probably less than 500 bars. A later stage of fluid circulation along fractures brings up a slight Li metasomatism. Biotites are a sensitive marker of both magmatic and postmagmatic stages of subsolvus or ‘wet’ plutonites.  相似文献   

Review     

Michel David 《Mathematical Geosciences》1979,11(6):721-722

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Infrared study of the pyrolysis products of sporopollenin and lignite     

Paul G. Rouxhet  Michel Villey  Agnès Oberlin 《Geochimica et cosmochimica acta》1979,43(11):1705-1713

The effect of pyrolysis at increasing temperature on sporopollenin, lignite and sporopollenin oxidized at 200°C has been investigated using measured infrared band absorption coefficients.Oxidation of sporopollenin in air at 200°C is marked by a decrease in the content of saturated hydrocarbon chains and a strong increase in the concentration of carboxylic acid groups.Pyrolysis of a thick bed of sporopollenin at increasing temperatures leads to the removal of a large proportion of oxygenated functions, before the removal of hydrocarbons. For lignite and oxidized sporopollenin, the loss of both types of functional groups extends over a broader temperature range. Reorganization of the carbonaceous residue at high temperature is hindered if a sufficiently low content of oxygenated functions, carbonyl and carboxyl as well as hydroxyl and ether groups, is not reached before the elimination of hydrocarbons.  相似文献   

Depositional history of artificial radionuclides in the Ross Ice Shelf,Antarctica     

Minoru Koide  Robert Michel  Edward D. Goldberg  Michael M. Herron  Chester C. Langway 《Earth and Planetary Science Letters》1979,44(2):205-223

The annual fluxes of artificial radionuclides (²³⁸Pu,^239+240Pu,²⁴¹Am,¹³⁷Cs,⁹⁰Sr and³H) from the atmosphere to the Ross Ice Shelf in Antarctica were determined from measurements in strata dated by²¹⁰Pb. Recognizable sources include the U.S. tests (Mike-Ivy and Castle Hill) in the early 1950s, the U.S.S.R. tests of the early 1960s, the SNAP-9A burnup of 1964 and the French and Chinese tests in the late 1960s and 1970s. There are several problems still awaiting resolution: the differences in atmospheric chemistries of fission products and of transuranics produced in weapons tests and the anomalous fluxes of²³⁸Pu to the ice shelf which do not appear to reflect a one-year stratospheric residence. There is no evidence for a smearing of the fallout record as a consequence of diffusion of these radionuclides in the glacial column.  相似文献   

Essai sur la structure des domaines émergés autour de la Méditerranée occidentale     

Prof. Dr. Michel Durand Delga 《International Journal of Earth Sciences》1964,53(2):534-535

Résumé De travaux menés dans les zones littorales de l'Afrique du Nord et dans tout le S de l'Espagne, l'auteur tire une nouvelle définition des grands ensembles structuraux péri-méditerranéens. Ces ensembles sont, dans les Cordillères bétiques, du N au S: zones externes (Prébétique, Subbétiques, Pénibétiques), zones internes (Flyschs gaditans, Malaguides, Alpujarrides, Nevadides 1). Dans le Rif marocain, symétriquement, on rencontre du S au N: zones externes (Autochtone de l'Atlas, nappes prérifaines et intrarifaines), zones internes (Flyschs nord-rifains, Tétouanides 2), Ghomarides 3), Sebtides 4); la plupart de ces zones se poursuivent vers l'E, jusqu'en Tunisie et en Sicile.Le fait majeur, à souligner au départ, est la parfaite symétrie de la chaîne alpine de la Méditerranée occidentale: les nappes rifaines ne le cèdent pas en importance aux nappes bétiques. Les diverses unités des deux systèmes se raccordent de manière évidente par la courbure de Gibraltar. L'âge du paroxysme tectonique paraît entièrement compris entre Oligocène supérieur et Miocène supérieur, aucune preuve objective n'existant de nappes plus anciennes.La remise en place des divers ensembles structuraux dépend de l'hypothèse générale définie au départ. Il est d'abord fait allusion à l'interprétation classique, par charriages modérés, ne faisant pas appel à des modifications importantes dans l'emplacement des bassins sédimentaires, actuellement visibles en plan. Les objections à ce premier schéma paraissent déterminantes.Une deuxième interprétation, que l'auteur a déjà partiellement esquissée auparavant, sera envisagée: les unités externes (s'empilant sur elles-mêmes) et leurs socles s'enfonceraient sous les zones internes qui, par réaction, seraient poussées vers l'extérieur de la chaîne: chacune des nappes dépasserait la nappe plus basse, au cours de ce mouvement. Dans le cas de l'Espagne, avant les charriages, les domaines sédimentaires des zones internes se placeraient à l'inverse de la disposition actuelle, soit du N au S: Nevadides, Alpujarrides, Malaguides, Pénibétique et Flyschs gaditans (ultras). Du côté marocain, nous aurions de même du S au N: Sebtides, Ghomarides, Tétouanides, Flyschs nord-rifains (ultras). Cela obligerait, au total, à faire rapprocher l'un de l'autre, en profondeur, les bâtis de la Meseta ibérique et de l'Atlas marocain, d'environ 300 à 500 km, l'actuelle largeur de la mer d'Alboran (150 km) ne permettant pas de reloger les domaines de toutes les nappes. Un axe d'enfouissement serait à rechercher sous l'actuelle Méditerranée.Une troisième interprétation, proposée aujourd'hui par l'auteur, considère que la chaîne péri-méditerranéenne montre une cicatrice structurale fondamentale, qui séparerait domaines internes bétiques et rifains, d'une part, domaines bétiques et rifains plus externes, de l'autre. Cette cicatrice se couderait au niveau de Gibraltar. Les nappes internes seraient comme aspirées vers la cicatrice ainsi que, en sens inverse, les nappes externes. La reconstitution paléogéographique finale est fort satisfaisante et l'ampleur des rétrécissements sensiblement diminuée.La position du domaine des Flyschs kabyles, nord-rifains et gaditans, fait enfin l'objet d'un examen nouveau: sans rejeter l'origine ultra, déjà proposée, l'auteur envisage d'autres solutions, qui auraient l'avantage de mieux s'intégrer dans l'image proposée aujourd'hui.  相似文献   

Uncertainty assessment and analysis of the calibrated parameter values of an urban storm water quality model   总被引：1，自引：0，他引：1  

Eric Gaume  Jean-Pierre Villeneuve  Michel Desbordes 《Journal of Hydrology》1998,210(1-4):38-50

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Flowage differentiation: Limitation of the “Bagnold effect” to the narrow intrusions     

Michel Barrière 《Contributions to Mineralogy and Petrology》1976,55(2):139-145

The Bagnold effect, the most important in the flowage differentiation, is practically inoperative in porphyritic rocks in the case of large dykes and pipes with a width or a diameter over 100 meters. For these large channels, the magmatic differentiation between the core and the walls is not related to the forced magmatic flow, but should be ascribed to other mechanisms: crystal settling, natural convection, synchronous injection of already differentiated materials.  相似文献