Determination of Halogens (F, Cl, Br, I), Sulfur and Water in Seventeen Geological Reference Materials   总被引：5，自引：0，他引：5  

Agnès Michel  Benoît Villemant 《Geostandards and Geoanalytical Research》2003,27(2):163-171

Fluorine, chlorine, bromine, iodine and sulfur were determined in seventeen geological reference materials after extraction by pyrohydrolysis. Fluorine, Cl and S (as sulfate ions) were determined in the extraction solution by ion chromatography with detection limits of around 0.2 mg l⁻¹. Bromine and I were measured by ICP-MS with detection limits of 1 μg l⁻¹ for Br and 0.1 μg l⁻¹ for I. For rock samples, using normal extraction conditions (500 mg of sample and 100 ml of final solution) detection limits were 40 mg kg⁻¹ for F and Cl, 15 mg kg⁻¹ for S, 0.2 mg kg⁻¹ for Br and 0.02 mg kg⁻¹ for I. These detection limits may be improved by increasing the amount of sample and hence the concentration of the final solution. Water was also determined using an extraction technique based on H₂O degassing, reduction on zinc at 1000 °C and H₂ manometry. Our results for fluorine, chlorine, sulfur and water are in good agreement with literature data. Very few reference materials have recommended values for bromine and especially for iodine. Among the analysed samples, three are new reference materials: BHVO-2, BCR-2 and AGV-2.  相似文献   

Private property—national legacy: Protecting privately owned archaeological sites in the united states     

Mark Michel 《Natural Resources Research》1997,6(2):131-136

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A model for the Am (Km) planetary geomagnetic activity index and application to prediction     

Christian Francq  Michel Menvielle 《Geophysical Journal International》1996,125(3):729-746

We studied the existence of dynamical stochastic relations in the evolution of the am index. A first analysis of the autocorrelation functions showed evidence of several seasonalities. We first used linear (ARMA) models, and it was found that these do not account for the whole internal dynamics of the data series. We then used various non-linear models to provide a better fit to reality. The forecast performances of the non-linear models are not significantly different from those of the linear model. We give a tentative explanation for the failure of the non-linear predictions. Finally, ARCH models were used in order to take into account the fact that the confidence interval for the predicted value depends on past observations.  相似文献   

Investigating the Halogen Chemistry From High-Latitude Nighttime Stratospheric Measurements of OClO and NO2     

Emmanuel Damien Rivière  Michel Pirre  Gwenaël Berthet  Jean-Baptiste Renard  Franck Lefèvre 《Journal of Atmospheric Chemistry》2004,48(3):261-282

Two cases of simultaneous nighttime measurements of NO₂ and OClO in the winter polar stratosphere are analyzed in order to test our present knowledge of halogen chemistry in the presence of high amount of NO₂ at low temperature. Comparisons with Lagrangian model calculations using several hypotheses are performed. First simulations, using the admitted constant rates of chemical reaction, strongly underestimate the measured OClO while the NO₂ profiles are correctly reproduced. If uncertainties in actinic fluxes calculations are taken into account, simulation results do not show a significant reduction of the underestimation. A better agreement can be achieved if the formation of unstable isomers of ClONO₂ and of BrONO₂ occurs in the cold conditions of the polar stratosphere. An approximate value of the branching ratios of the channels leading to ClONO₂ and ClOONO, and to BrONO₂ and BrOONO, necessary to reproduce both OClO and NO₂ is given and discussed.  相似文献   

华南石炭纪岩关-大塘界线期牙形石地层分带   总被引：4，自引：0，他引：4  

田树刚  M.科恩 《地质通报》2004,23(8):737-749

系统采集不同沉积相区和连续沉积的剖面，即浅海台地相广西柳江龙殿山剖面、台缘缓坡相云南施甸鱼硐剖面和台内盆地相广西柳州碰冲剖面，运用数理统计方法，研究了华南岩关一大塘界线过渡期牙形石的产出丰度和相分布，在恢复生物演化序列的基础上，对各剖面首先详细分带，再进一步综合成系统的5个牙形石带，即Gnathodus typicus—G．cuneiformis带、Gnathodus typicus—Protognathodus cordiformis带、Scaliognathus anchoralis—Gnathodus pseu-dosemiglaber带、Gnathodus praebilineatus带和Paragnathodus horrtopunctatus带。以生物系统发生为标准，严格限定各带的界线，并与北美、西欧同期地层进行精确对比，为建立杜内阶一维宪阶界线的全球层型(GSSP)提供可靠依据。  相似文献   

CO₂ solubility in dacitic melts equilibrated with H₂O-CO₂ fluids: Implications for modeling the solubility of CO₂ in silicic melts     

Harald Behrens  Susanne Ohlhorst  Michel Champenois 《Geochimica et cosmochimica acta》2004,68(22):4687-4703

The solubility of CO₂ in dacitic melts equilibrated with H₂O-CO₂ fluids was experimentally investigated at 1250°C and 100 to 500 MPa. CO₂ is dissolved in dacitic glasses as molecular CO₂ and carbonate. The quantification of total CO₂ in the glasses by mid-infrared (MIR) spectroscopy is difficult because the weak carbonate bands at 1430 and 1530 cm⁻¹ can not be reliably separated from background features in the spectra. Furthermore, the ratio of CO_2,mol/carbonate in the quenched glasses strongly decreases with increasing water content. Due to the difficulties in quantifying CO₂ species concentrations from the MIR spectra we have measured total CO₂ contents of dacitic glasses by secondary ion mass spectrometry (SIMS).At all pressures, the dependence of CO₂ solubility in dacitic melts on x^fluid_CO2,total shows a strong positive deviation from linearity with almost constant CO₂ solubility at x_CO2fluid > 0.8 (maximum CO₂ solubility of 795 ± 41, 1376 ± 73 and 2949 ± 166 ppm at 100, 200 and 500 MPa, respectively), indicating that dissolved water strongly enhances the solubility of CO₂. A similar nonlinear variation of CO₂ solubility with x_CO2fluid has been observed for rhyolitic melts in which carbon dioxide is incorporated exclusively as molecular CO₂ (Tamic et al., 2001). We infer that water species in the melt do not only stabilize carbonate groups as has been suggested earlier but also CO₂ molecules.A thermodynamic model describing the dependence of the CO₂ solubility in hydrous rhyolitic and dacitic melts on T, P, f_CO2 and the mol fraction of water in the melt (x_water) has been developed. An exponential variation of the equilibrium constant K₁ with x_water is proposed to account for the nonlinear dependence of x_CO2,totalmelt on x_CO2fluid. The model reproduces the CO₂ solubility data for dacitic melts within ±14% relative and the data for rhyolitic melts within 10% relative in the pressure range 100-500 MPa (except for six outliers at low x_CO2fluid). Data obtained for rhyolitic melts at 75 MPa and 850°C show a stronger deviation from the model, suggesting a change in the solubility behavior of CO₂ at low pressures (a Henrian behavior of the CO₂ solubility is observed at low pressure and low H₂O concentrations in the melt). We recommend to use our model only in the pressure range 100-500 MPa and in the x_CO2fluid range 0.1-0.95. The thermodynamic modeling indicates that the partial molar volume of total CO₂ is much lower in rhyolitic melts (31.7 cm³/mol) than in dacitic melts (46.6 cm³/mol). The dissolution enthalpy for CO₂ in hydrous rhyolitic melts was found to be negligible. This result suggests that temperature is of minor importance for CO₂ solubility in silicic melts.  相似文献   

Field and petrological evidence for a Late Palaeozoic (Upper Carboniferous–Permian) age of the Erfaulet orthogneiss (Gran Paradiso,western Alps)     

Benjamin Le Bayon  Michel Ballèvre 《Comptes Rendus Geoscience》2004,336(12):1079-1089

In the Gran Paradiso massif (western Alps), the boundary between the Erfaulet orthogneiss and the overlying metasediments (Money Complex) is interpreted as a Late Palaeozoic intrusive contact. Major arguments in favour of this hypothesis are: (i) the obliquity of the sedimentary layering with respect to the contact; (ii) the presence of aplitic dykes within the Money Complex; (iii) the lack of a mylonitic zone; and (iv) rare relics of an early generation of garnet in the Money metasediments, interpreted as evidence of the contact metamorphism of the Erfaulet granite. To cite this article: B. Le Bayon, M. Ballèvre, C. R. Geoscience 336 (2004).  相似文献   

Instability of a periodic system of faults     

Michel Campillo  Cristian Dascalu  Ioan R. Ionescu 《Geophysical Journal International》2004,159(1):212-222

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Fabric studies within the Cascade Lake shear zone, Sierra Nevada, California   总被引：1，自引：0，他引：1  

Basil Tikoff  Matthew R. Davis  Christian Teyssier  Michel de St. Blanquat  Guillaume Habert  Sven Morgan   《Tectonophysics》2005,400(1-4):209-226

The Cascade Lake shear zone occurs on the eastern margin of the Tuolumne Intrusive Suite, Sierra Nevada Batholith, California. Foliation in the zone is NNW trending and subvertical, and lineation is moderately south plunging. Deformation is syn-tectonic with emplacement of the Cathedral Peak granodiorite. A deformation gradient exists toward the NE margin of this pluton, with higher strains and lower temperatures of deformation found near the contact. We compare fabric data collected very densely in this shear zone using several techniques: field fabrics, 3D orientation of K-feldspar megacrysts, and AMS (anisotropy of magnetic susceptibility) analysis. In general, the results from the three different methods are in agreement. Deformation in this shear zone is part of a larger pattern of deformation within the Cathedral Peak granodiorite, as recorded by AMS analysis, and dextral shearing associated within the last stage of plutonism within the Sierra Nevada magmatic arc.  相似文献   

Quantum-thermodynamic treatment of intrinsic anharmonicity; Wallace’s theorem revisited   总被引：1，自引：0，他引：1  

Michel H.G. Jacobs  Bernard H.W.S. de Jong 《Physics and Chemistry of Minerals》2005,32(8-9):614-626

Wallace (in Thermodynamics of crystals, 1972) developed a theorem, rooted in rigid lattice dynamics, which incorporates intrinsic anharmonic effects in solids. The practical application of this theorem in mineral physics is computationally involved and this is the main reason for the theorem not getting the attention it deserves. Because intrinsic anharmonicity is an important issue at the extreme conditions in planetary mantles, we derived a method which removes the computational obstacles in applying this theorem. We extended the theorem to incorporate details of the phonon spectrum and tested our algorithm on forsterite (Mg₂SiO₄). Using a least squares inversion technique applied to all available experimental data, we show that it results in an accurate representation of thermodynamic properties and sound wave velocities of Mg₂SiO₄ in its complete pressure–temperature stability range. We also show that the accuracy of our results is not significantly affected by the use of a different equation of state.  相似文献