Physicochemical characteristics and levels of microbial activity in some florida peat swamps     

P.H. Given  W. Spackman  J.R. Imbalzano  D.J. Casagrande  A.J. Lucas  W. Cooper  C. Exarchos 《International Journal of Coal Geology》1983,3(1):77-99

Although microorganisms are certainly present in swamp and marsh peats, their geochemical role has not been demonstrated, in spite of their importance in determining the input to coalification processes. In order to obtain information on the gross level of microbial activity in the natural habitats, a broad-spectrum test for a type of enzyme important in the respiration of all organisms has been applied to cores of peat from a number of different environments in the Florida Everglades. In most cases, the respiratory activity in the upper layer is comparable to that in a fertile mineral soil, and this level of activity is found also at greater depths in several cores. In addition, some properties of the peat that tend to define their character as habitats for microorganisms were determined. pH values close to neutrality were observed at all sites. Chlorinity and total ionic strength naturally were high in the coastal swamps; seasonal variations in profiles in the brackish areas somewhat away from the coast suggested that some bulk flow of water through the peat into the porous limestone bedrock occurs in the rainy season. Eh profiles, regarded as empirical characterizations of environments, did differ considerably between saline and fresh water peats, though on a graphite indicator electrode were more positive than might have been expected in systems in which sulfate reduction was active. However, in these non-equilibrium systems, the potential recorded apparently depends on the nature of the electrode material used.  相似文献   

The origin of the Basse Normandie duplex,Boulonnais, France     

M.A. Cooper  M.R. Garton  J.R. Hossack 《Journal of Structural Geology》1983,5(2):139-152

Two Hercynian duplexes are developed in Viséan limestones in the Basse Normandie quarry. The lower duplex is completely exposed in a subvertical quarry wall; the partially exposed upper duplex lies immediately above the lower duplex. The duplexes are both located in the footwall of the Hydrequent thrust which emplaced Devonian clastic sediments above the Viséan limestones. The lower duplex exposes all the internal thrusts, a reference bed of chalky limestone, the roof and floor thrusts, and the duplex tip. The duplex has been graphically restored to its pre-deformation geometry by line-length and area balancing and its resultant geometry is close to the model of Boyer & Elliott. The lower duplex shortened by two different mechanisms, an initial phase of layer-parallel shortening which produced no cleavage, followed by thrust imbrication. The average contraction of the front portion of the duplex was ?49% (natural strain) of which ?27% is layer-parallel shortening and ?22% is thrust imbrication. However, locally the bulk shortening increases from zero at the duplex tip to over ?120% in a down-dip direction. The area balancing provides the most accurate estimates of bulk shortening; line-length balance calculations give minimum estimates only. An area balance on the whole of the lower duplex gives a bulk shortening of ?84%. An area balance of the upper duplex yields an average contraction of ?75% and the total contraction produced by both duplexes is ?92%.  相似文献   

Reconstructing spatio-temporal patterns of debris-flow activity using dendrogeomorphological methods   总被引：2，自引：0，他引：2  

Michelle Bollschweiler  Markus Stoffel  Melanie Ehmisch  Michel Monbaron 《Geomorphology》2007,87(4):337-351

Debris flows are a major threat in many parts of the Alps, where they repeatedly cause severe damage to infrastructure and transportation corridors or even loss of life. Nonetheless, the spatial behavior of past debris-flow activity and the analysis of areas affected during particular events have been widely neglected in reconstructions so far. It was therefore the purpose of this study to reconstruct spatio-temporal patterns of past debris flows on a forested cone in the Swiss Alps (Bruchji torrent, Blatten, Valais). The analysis of past events was based on a detailed geomorphic map (1:1000) of all forms related to debris flows as well as on tree-ring series from 401 heavily affected trees (Larix decidua Mill. and Picea abies (L.) Karst.) growing in or next to deposits. The samples were analyzed and growth disturbances related to debris-flow activity assessed, such as tangential rows of traumatic resin ducts, the onset of reaction wood or abrupt growth suppression or release.In total, 960 growth disturbances were identified in the samples, belonging to 40 different event years between A.D. 1867 and 2005. In addition, the coupling of tree-ring data with the geomorphic map allowed reconstruction of eleven formerly active channels and spatial representation of individual events. Based on our results we believe that before 1935, debris flows preferentially used those channels located in the western part of the cone, whereas the eastern part of the cone remained widely unaffected. The spatial representation of the 40 events also allowed identification of five different spatial patterns for debris flows at the study site.  相似文献   

Micellar-Enhanced Ultrafiltration and Air Stripping for Surfactant-Contaminant Separation and Surfactant Reuse   总被引：2，自引：0，他引：2  

K. Michelle Lipe  David A. Sabatini  Mark A. Hasegawa  Jeffrey H. Harwell 《Ground Water Monitoring & Remediation》1996,16(1):85-92

Micellar-enhanced ultrafiltration (MELT) and air stripping were evaluated for surfactant-contaminant separation and surfactant recovery. Two linear alkyl diphenyloxide disulfonate (DPDS) surfactants were evaluated with the contaminants naphthalene and trichloroethylene. A separation model developed from micellar partitioning principles showed a good correlation to batch MEUF studies, whereas flux analysis highlighted concentration polarization effects in relation to hydrophobe length. MEUF effectively concentrated the surfactant-contaminant system (93 to 99 percent retention); however, this did not result in surfactant-contaminant separation. Batch and continuous flow air stripping models were developed based upon air/water ratio, surfactant concentration, and Micellar partitioning; model predictions were validated by experimental data. Sensitivity analyses illustrated the decline in contaminant-surfactant separation with increasing surfactant concentration (e.g., TCE removal efficiency declines from 83 percent to 37 percent as C-16 DPDS concentration increases from 0 to 55 mM). This effect is greater for more hydrophobic contaminants (naphthalene vs. TCE) and surfactants with greater solubilization potential (C16-DPDS vs. C-12 DPDS). The resulting design equations can account for this effect and thus properly size air strippers to achieve the desired removal efficiency in the presence of surfactant micelles. Proper selection and design of surfactant-contaminant separation and surfactant recovery systems are integral to optimizing surfactant-enhanced subsurface remediation.  相似文献   

Spatial variability of water vapor turbulent transfer within the boundary layer     

D. I. Cooper  W. E. Eichinger  D. B. Holtkamp  R. R. Karl Jr.  C. R. Quick  W. Dugas  L. Hipps 《Boundary-Layer Meteorology》1992,61(4):389-406

Although the physics of evaporation within the inner region of the boundary layer is believed to be well understood, observations of mass-energy exchange processes have been hindered by the limitations of point sensors. A combination of point sensors and active remote sensing, namely, water-Raman Lidar measurements, offers new opportunities to study relatively large areas at temporal and spatial scales previously unattainable. Results from experiments over uniform canopies both confirm some traditional theories and challenge some of the underlying assumptions concerning the homogeneity of the surface-atmosphere interface and the use of point sensors to characterize large areas.This work was performed under the auspices of the U.S. Department of Energy. The authors would like to thank F. Archuleta, J. Archuleta, F. Barnes, W. Clements, K. Muller and W. Porch of LANL, R. Whitis of USDA, R. Jackson and P. Pinter of USDA-WCL, and L. Balick of EG&G for their invaluable time and support.  相似文献   

A structured method of landscape assessment and countryside management     

Alan Cooper  Ronald Murray 《Applied geography (Sevenoaks, England)》1992,12(4)

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Monthly suspended sediment load prediction using artificial intelligence: testing of a new random subspace method     

Viet-Ha Nhu  Khabat Khosravi  James R. Cooper  Mahshid Karimi  Ozgur Kisi  Binh Thai Pham 《水文科学杂志》2020,65(12):2116-2127

ABSTRACT

The predictive capability of a new artificial intelligence method, random subspace (RS), for the prediction of suspended sediment load in rivers was compared with commonly used methods: random forest (RF) and two support vector machine (SVM) models using a radial basis function kernel (SVM-RBF) and a normalized polynomial kernel (SVM-NPK). Using river discharge, rainfall and river stage data from the Haraz River, Iran, the results revealed: (a) the RS model provided a superior predictive accuracy (NSE = 0.83) to SVM-RBF (NSE = 0.80), SVM-NPK (NSE = 0.78) and RF (NSE = 0.68), corresponding to very good, good, satisfactory and unsatisfactory accuracies in load prediction; (b) the RBF kernel outperformed the NPK kernel; (c) the predictive capability was most sensitive to gamma and epsilon in SVM models, maximum depth of a tree and the number of features in RF models, classifier type, number of trees and subspace size in RS models; and (d) suspended sediment loads were most closely correlated with river discharge (PCC = 0.76). Overall, the results show that RS models have great potential in data poor watersheds, such as that studied here, to produce strong predictions of suspended load based on monthly records of river discharge, rainfall depth and river stage alone.  相似文献   

Calibration of diatoms along a nutrient gradient in Florida Everglades Water Conservation Area-2A, USA   总被引：2，自引：0，他引：2  

Sherri R. Cooper  Jacqueline Huvane  Panchabi Vaithiyanathan  Curtis J. Richardson 《Journal of Paleolimnology》1999,22(4):413-437

The relationship between diatom taxa preserved in surface soils and environmental variables at 31 sites in Water Conservation Area 2A (WCA-2A) of the Florida Everglades was explored using multivariate analyses. Surface soils were collected along a phosphorus (P) gradient and analyzed for diatoms, total P, % nitrogen (N), %carbon (C), calcium (Ca), and biogenic silica (BSi). Phosphorus varied from 315-1781 g g^-1, and was not found to be correlated with the other geochemical variables. Canonical correspondence analysis (CCA) was used to examine which environmental variables correlated most closely with the distributions in diatom taxa. Canonical correspondence analysis with forward selection, constrained and partial CCA, and Monte Carlo permutation tests of significance show the most significant changes in diatom assemblages along the P gradient (p < 0.01), with additional species differences correlated with soil C, N, Ca, and BSi.Weighted-averaging (WA) regression and calibration models of diatom assemblages to P and BSi were developed. The diatom-based inference model for soil [P] had a high apparent r² (0.86) with RMSE_boot = 218 g g^-1. Indicator diatom species identified by assessing species WA optima and WA tolerance to [P], such as Nitzschia amphibia and N. palea for high [P] (~1300-1400 g^-1) and Achnanthes minutissima var. scotica and Mastogloia smithii for low [P] (~400-600 g g^-1), may be useful as monitoring tools for eutrophication in WCA-2A as well as other areas of the Everglades. Diatom assemblages analyzed by cluster analysis were related to location within WCA-2A, and dominant taxa within clusters are discussed in relation to the geochemical variables measured as well as hydrology and pH. Diversity of diatom assemblages and a Disturbance Index based on diatom data are discussed in relation to the historically P-limited Everglades ecosystem. Diatom assemblages should be very useful for reconstructions of [P] through time in the Florida Everglades, provided diatoms are well preserved in soil cores.  相似文献   

Surface simulation studies of the hydration of white rust Fe(OH)₂, goethite α-FeO(OH) and hematite α-Fe₂O₃     

Nora H. de Leeuw  Timothy G. Cooper 《Geochimica et cosmochimica acta》2007,71(7):1655-1673

Computer modelling techniques were used to elucidate the hydration behaviour of three iron (hydr)oxide minerals at the atomic level: white rust, goethite and hematite. A potential model was first adapted and tested against the bulk structures and properties of eight different iron oxides, oxyhydroxides and hydroxides, followed by surface simulations of Fe(OH)₂, α-FeO(OH) and α-Fe₂O₃. The major interaction between the adsorbing water molecules and the surface is through interaction of their oxygen ions with surface iron ions, followed by hydrogen-bonding to surface oxygen ions. The energies released upon the associative adsorption of water range from 1 to 17 kJ mol⁻¹ for Fe(OH)₂, 26 to 80 kJ mol⁻¹ for goethite and 40 to 85 kJ mol⁻¹ for hematite, reflecting the increasing oxidation of the iron mineral. Dissociative adsorption at goethite and hematite surfaces releases larger hydration energies, ranging from 120 to 208 kJ mol⁻¹ for goethite and 76 to 190 kJ mol⁻¹ for hematite.The thermodynamic morphologies of the minerals, based on the calculated surface energies, agree well with experimental morphologies, where these are available. When the partial pressures required for adsorption of water from the gas phase are plotted against temperature for the goethite and hematite surfaces, taking into account experimental entropies for water, it appears that these minerals may well be instrumental in the retention of water during the cyclic variations in the atmosphere of Mars.  相似文献   

Episodes of late Holocene aridity recorded by stalagmites from Devil's Icebox Cave, central Missouri, USA   总被引：1，自引：0，他引：1  

Rhawn F. Denniston  Michelle DuPree  Jeffrey A. Dorale  Victor J. Polyak 《Quaternary Research》2007,68(1):45-52

Two stalagmites from Devil's Icebox Cave, central Missouri, display similar δ¹³C and δ¹⁸O values and trends during the late Holocene. Positive δ¹³C excursions at 3.5-2.6 ka and 1.2-0.9 ka are interpreted to reflect drier conditions. These elevated stalagmite δ¹³C values could have plausibly been driven by increasing C₄ plant abundances over the cave or an increased contribution of bedrock carbon, both of which could reflect decreased effective moisture. A lack of corresponding oxygen isotopic anomalies during these intervals suggests that neither mean annual temperature nor the seasonality of precipitation changed concomitantly with dryness. Both of the δ¹³C excursions identified in our stalagmite record are roughly coincident with dry intervals from a number of sites located across the Great Plains.  相似文献