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51.
Joint estimation of transmissivity (T) and storativity (S) in a confined aquifer is done via maximum likelihood (ML). The differential equation of groundwater flow is discretized by the finite-element method, leading to equation t+x t=u t. Elements of matrices and , as well as estimated covariance matrix of noise termu t, are functions of T and S. By minimizing the negative loglikelihood function corresponding to discretized groundwater flow equation with respect to T and S, ML estimators are obtained. The ML approach is found to yield accurate estimates of T and S (within 9 and 10% of their actual values, respectively) and showed quadratic convergence in Newton's search technique. Prediction of aquifer response, using ML estimators, results in estimated piezometric heads accurate to ±0.5 m from their actual, exact values. Statistical properties of ML estimators are derived and some basic results for statistical inference are given.  相似文献   
52.
Adakite-like features are recognized in the Late Miocene (~10 Ma) porphyritic intrusions of the Los Pelambres giant porphyry copper deposit, central Chile (32°S). Located within the southern portion of the flat-slab segment (28–33°S) of the Chilean Andes, the Al- and Na-rich porphyries of Los Pelambres display distinctly higher Sr/Y (~100–300) and LaN/YbN (~25–60) ratios than contemporaneous and barren magmatic units (e.g., La Gloria pluton, Cerro Aconcagua volcanic rocks) of the same Andean magmatic belt. Strong fractionation of heavy rare earth elements (HREE), absence of Eu anomalies, high Sr/Y and Zr/Sm and low Nb/Ta ratios suggest melt extraction from a garnet-amphibolite source. The Late-Miocene adakite-like porphyritic intrusions at Los Pelambres formed closely related in time and space to the subduction of the Juan Fernández Ridge (JFR) hotspot chain along the Chilean margin. Current tectonic reconstructions reveal that, at the time of formation of the Los Pelambres rocks, a W-E segment of the JFR started to subduct beneath them, producing a slow-down of a previously rapid southward migration of a NE-ridge—trench collision. These particular tectonic conditions are favorable for the origin of the Los Pelambres porphyry suite by melting of subducting young hotspot rocks under flat-slab conditions. The incorporation of crustal components into the oceanic lithopheric magma source by subduction erosion is evidenced by the Sr-Nd isotope composition of the Los Pelambres rocks different from the MORB signatures of true adakites. A close relationship apparently exists between the origin of this adakite-like magmatism and the source of the mineralization in the Los Pelambres porphyry copper deposit.Editorial handling: R.J. Goldfarb  相似文献   
53.
We use a coarse resolution ocean general circulation model to study the relation between meridional pressure and density gradients in the Southern Ocean and North Atlantic and the Atlantic meridional overturning circulation. In several experiments, we artificially modify the meridional density gradients by applying different magnitudes of the Gent–McWilliams isopycnal eddy diffusion coefficients in the Southern Ocean and in the North Atlantic and investigate the response of the simulated Atlantic meridional overturning to such changes. The simulations are carried out close to the limit of no diapycnal mixing, with a very small explicit vertical diffusivity and a tracer advection scheme with very low implicit diffusivities. Our results reveal that changes in eddy diffusivities in the North Atlantic affect the maximum of the Atlantic meridional overturning, but not the outflow of North Atlantic Deep Water into the Southern Ocean. In contrast, changes in eddy diffusivities in the Southern Ocean affect both the South Atlantic outflow of North Atlantic Deep Water and the maximum of the Atlantic meridional overturning. Results from these experiments are used to investigate the relation between meridional pressure gradients and the components of the Atlantic meridional overturning. Pressure gradients and overturning are found to be linearly related. We show that, in our simulations, zonally averaged deep pressure gradients are very weak between 20°S and about 30°N and that between 30°N and 60°N the zonally averaged pressure grows approximately linearly with latitude. This pressure difference balances a westward geostrophic flow at 30–40°N that feeds the southbound deep Atlantic western boundary current. We extend our analysis to a large variety of experiments in which surface freshwater forcing, vertical mixing and winds are modified. In all experiments, the pycnocline depth, assumed to be the relevant vertical scale for the northward volume transport in the Atlantic, is found to be approximately constant, at least within the coarse vertical resolution of the model. The model behaviour hence cannot directly be related to conceptual models in which changes in the pycnocline depth determine the strength of Atlantic meridional flow, and seems conceptually closer to Stommel’s box model. In all our simulations, the Atlantic overturning seems to be mainly driven by Southern Ocean westerlies. However, the actual strength of the Atlantic meridional overturning is not determined solely by the Southern Ocean wind stress but as well by the density/pressure gradients created between the deep water formation regions in the North Atlantic and the inflow/outflow region in the South Atlantic.  相似文献   
54.
Seasonal (Spring and Summer 2002) concentrations of dissolved (<0.22 μm) trace metals (Ag, Al, Co, Cu, Mn, Ni, Pb), inorganic nutrients (NO3, PO4, Si), and DOC were determined in groundwater samples from 5 wells aligned along a 30 m shore-normal transect in West Neck Bay, Long Island, NY. Results show that significant, systematic changes in groundwater trace metal and nutrient composition occur along the flowpath from land to sea. While conservative mixing between West Neck Bay water and the groundwaters explains the behavior of Si and DOC, non-conservative inputs for Co and Ni were observed (concentration increases of 10- and 2-fold, respectively) and removal of PO4 and NO3 (decreases to about half) along the transport pathway. Groundwater-associated chemical fluxes from the aquifer to the embayment calculated for constituents not exhibiting conservative behavior can vary by orders of magnitude depending on sampling location and season (e.g. Co, 3.4 × 102– 8.2 × 103 μmol d−1). Using measured values from different wells as being representative of the true groundwater endmember chemical composition also results in calculation of very different fluxes (e.g., Cu, 6.3 × 103 μmol d−1 (inland, freshwater well) vs. 2.1 × 105 μmol d−1(seaward well, S = 17 ppt)). This study suggests that seasonal variability and chemical changes occurring within the subterranean estuary must be taken into account when determining the groundwater flux of dissolved trace metals and nutrients to the coastal ocean.  相似文献   
55.
We present a new method for the obtention of the nuclear component of active galatic nuclei, that relies on the convolution of a two-dimensional model of the host galaxy, based on seeing-free morphological parameters, with the seeing PSF. The procedure overcomes some limitations of the methods currently in use and does not assume that the nucleus is unresolved. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
56.
57.
The contents of the moderately volatile elements Ga, Ge, Cu and Sb in ordinary chondrites give us some clues with regard to the metal-silicate fractionation process. Their concentration in coexisting magnetic and non-magnetic portions of members of each ordinary chondrite group will be discussed. Germanium and Sb are mostly siderophilic, but Ga is strongly lithophilic in unequilibrated chondrites; its partition coefficient between magnetic and non-magnetic portions is positively correlated with petrologic type in L and LL chondrites, but not in H4–6 chondrites. From 25 to 50% of the total Cu is found in the non-magnetic fraction of chondrites, but there is no correlation between Cu content and petrologic type. The abundances of Ga, Cu and Sb (relative to Si) are constant in ordinary chondrites, independent of the amount of metal present, indicating that these elements were not in solid solution in the metal phase of chondrites when the metal-silicate fractionation process occurred. Germanium, which is the most volatile among the four elements analyzed, is more abundant in H than in L and LL chondrites, indicating that it was fractionated by this process. Nebular oxidation processes can be responsible for the behavior of Ga if this element was in oxidized form when loss of metal occurred, but cannot explain the results for Cu and Sb which are predicted to condense as metals and accrete mostly in metallic form. It is possible that Cu and Sb, upon condensation, did not form solid solutions with metallic Ni-Fe until after the separation of metal from silicates took place.  相似文献   
58.
Folds and folding mechanism in a chert sequence and related rocks of the Maláguide Complex (the uppermost tectonic unit of the Betic Zone) have been investigated. The geometric study shows that folds that developed in the chert sequence are usually angular in shape and asymmetric. Chevron and conjugate folds are common.Folding in bedded chert is explained in terms of a suggested model:
1. (1) Development of folds by kink and conjugate kinking.
2. (2) As the shortening increases, the interlimb angles decrease; in the kink folds this is caused by a reduction of the angle between the layers within the kink and the kink boundaries. There seems to be a relationship between this angle and the asymmetrical thinning-out in the limbs of many folds: the smaller is the angle between the kink boundary and the layers within the kink band, the larger is the reduction of the thickness in these layers.
Single limestone layers embedded in slate deform very probably by a buckling mechanism, implying tangential longitudinal strain and an additional flattening.  相似文献   
59.
This paper deals with the incidence and geometry of lattice bending in calcite of naturally strained marble and possible relations in time to associated {01¯12} twinning, as revealed by microscopic examination with a universal stage. Microscopic technique and graphic treatment of data with a view to identifying the relation in time of bending to twinning, and possible glide mechanisms involved in the bending process are reviewed as a basis for present and subsequent investigation of this general topic.In most instances development of surviving thin e twins postdates bending of the host crystal (such twins everywhere are rationally oriented). Rarely (in contrast with experimental experience) some thin twins are slightly irrational (Le lamellae) and apparently developed in the final stages of bending. Thick twins (a few tens of microns wide) on the other hand rather commonly predate or are synchronous with bending.The geometry of bending (external rotation) — especially for rotation less than 25° —commonly is compatible with models (based on experimental experience) of simple translation in the strained domains. The commonest translation system so identified is on {10¯11}, with sense of shear, where recognizable, either negative or positive. Translation on {02¯21} is relatively rare. Unexpectedly there is rather strong but not conclusive evidence of translation on {0001} parallel to an a axis. This mechanism, hitherto never identified with certainty, is now here documented unequivocally in a crystal of calcite experimentally strained at 300° C, 5 kb.  相似文献   
60.
Rb/Sr whole rock as well as K/Ar whole rock and mineral age determinations have been carried out on drill core samples obtained from the crystalline basement underlying the Amazonas and Maranhão Basins in Brazil. The data confirm the existence of an ancient basement under the Upper and Middle Amazonas Basin. The primary age of the granitic rocks is estimated at about 1560 Ma which correlates with recent age data obtained on granitic rocks on both sides of the Amazonas syneclise. In some areas the K/Ar ages show a decrease probably due to the effect of the Nickerie thermal episode described previously in the Guayana Shield.In the basement of the interconnected Lower Amazonas and Maranhão Basins Late Precambrian (Caririan) metamorphism and igneous activity seems to have been pervasive. The data allow the continuation of the Brazilian age province known in northeastern Brazil under the Maranhão Basin, linking this province to the Brasilia-Paraguay orogenic belt of similar age.  相似文献   
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