On the cumulant expansion up scaling of ground water contaminant transport equation with nonequilibrium sorption     

Hakan Sirin  Miguel A. Mariño 《Stochastic Environmental Research and Risk Assessment (SERRA)》2008,22(4):551-565

The laboratory-scale ground water transport equation with nonequilibrium sorption reaction subjected to unsteady, nondivergence-free, and nonstationary velocity fields is up-scaled to the field-scale by using the ensemble-averaged equations obtained from the cumulant expansion ensemble-averaging method. It is found that existing ensemble-averaged equations obtained with the help of the cumulant expansion method for the system of linear partial differential equations are not second-order exact. Although the cumulant expansion methodology is designed for noncommuting operators, it is found that there are still commudativity requirements that need to be satisfied by the functions and constants exist in the coefficient matrix of the system of ordinary/partial differential equations. A reversibility requirement, which covers the commudativity requirements, is also proposed when applying the cumulant expansion method to a system of partial differential equations/a partial differential equation. The significance of the new velocity correction obtained in this study due to the applied second-order exact cumulant expansion is investigated on a numerical example with a linear trend in the distribution coefficient. It is found that the effect of the new velocity correction can be significant enough to affect the maximum concentration values and the plume center of mass in the case of a trending distribution coefficient in a physically heterogeneous environment.  相似文献   

Biodegradation of Crude Oil by Individual Bacterial Strains and a Mixed Bacterial Consortium Isolated from Hydrocarbon Contaminated Areas     

Muthuswamy Sathishkumar  Arthur Raj Binupriya  Sang‐Ho Baik  Sei‐Eok Yun 《洁净——土壤、空气、水》2008,36(1):92-96

A preliminary study was undertaken to determine the optimal conditions for the biodegradation of a crude oil. Among 57 oil‐degrading bacterial cultures isolated from oil‐contaminated soil samples, Bacillus sp. IOS1‐7, Corynebacterium sp. BPS2‐6, Pseudomonas sp. HPS2‐5, and Pseudomonas sp. BPS1‐8 were selected for the study based on the efficiency of crude oil utilization. Along with the selected individual strains, a mixed bacterial consortium prepared using the above strains was also used for degradation studies. The mixed bacterial consortium showed more growth and degradation than did individual strains. At 1% crude oil concentration, the mixed bacterial consortium degraded a maximum of 77% of the crude oil. This was followed by 69% by Pseudomonas sp. BPS1‐8, 64% by Bacillus sp. IOS1‐7, 45% by Pseudomonas sp. HPS2‐5, and 41% by Corynebacterium sp. BPS2‐6. The percentage of degradation by the mixed bacterial consortium decreased from 77 to 45% as the concentration of crude oil was increased from 1 to 12%. Temperature of 35°C and pH 7 were found to be optimum for maximum degradation.  相似文献   

Movement of Heavy Metals in Soil through Preferential Flow Paths under Different Rainfall Intensities   总被引：1，自引：0，他引：1  

Young‐Jin Kim  Tammo S. Steenhuis  Kyoungphile Nam 《洁净——土壤、空气、水》2008,36(12):984-989

Preferential flow in soils deserves attention due to its potential role in accelerating the movement of contaminants to groundwater. This study investigates the movement of Cd, Cu, and Pb through preferential flow paths under different applied rainfall intensities. Artificial acid rain (pH of 4.1) containing CdCl₂, CuCl₂, and Pb(NO₃)₂ was applied to undisturbed soil and repacked sand columns at low and high intensities, and leachate metals and chloride concentrations were measured. Cd was found in the leachate at both low and high rates in all columns, while the increase in Cu concentrations in the leachate was detected only at the high rate of the undisturbed columns. Pb was retained in both columns. For undisturbed columns, the breakthrough curves of Cd and Cu were similar to those of Cl, showing early initial breakthrough by preferential flow and dependency on rainfall intensities. The Cd concentrations were detected in the leachate from repacked columns for high rate rainfall, implying that even homogeneous soil may not be perfectly able to retain metals and the initially wet condition is more harmful for subsurface contaminant transport. In conclusion, the study demonstrated that, despite its highly sorptive nature, the transport of some metals may be as fast as that of a tracer under preferential flow conditions, and the rainfall intensity is a significant factor for the degree of transport.  相似文献   

Insights into syndepositional fault movement in a foreland basin; trends in seismites of the Upper Cretaceous,Wahweap Formation,Kaiparowits Basin,Utah, USA     

Hannah L. Hilbert‐Wolf  Edward L. Simpson  Wendy S. Simpson  Sarah E. Tindall  Michael C. Wizevich 《Basin Research》2009,21(6):856-871

The Upper Cretaceous Wahweap Formation accumulated in the active Cordilleran foreland basin of Utah. Soft‐sediment deformation structures are abundant in the capping sandstone member of the Wahweap Formation. By comparing with well‐established criteria, a seismogenic origin was determined for the majority of structures, which places these soft‐sediment deformation features in a class of sedimentary features referred to as seismites. A systematic study of the seismite trends included their vertical and horizontal distribution and a semi‐quantitative intensity analysis using a scale from 1 to 5 that is based on magnitude, sedimentary structure type, and the predominance of inferred process of hydroplastic deformation, liquefaction or fluidization. In addition, orientations of soft‐sediment fold axes were recorded. Construction of a northwest‐to‐southeast stratigraphic and seismite intensity cross‐section demonstrates: (1) reduction in stratigraphic thickness and percentage of conglomerates to the southeast, (2) the presence of lower seismite, middle nonseismite, and upper seismite zones within the capping sandstone (permitting subdivision of the capping sandstone member), and (3) elimination of the nonseismite zone and amalgamation of the lower and upper seismite zones to the southeast. Regional isoseismal contour maps generated from the semi‐quantitative analysis indicate a decrease in overall intensity from northwest to southeast in the upper and lower seismic zones and in sandstone within 5 m stratigraphically of the contact between the upper and capping sandstone members. In addition, cumulative seismite fold orientations support a west–northwest direction towards regional epicentres. Isoseismal maps are used to distinguish the effects of intrabasinal normal faulting from those of regional orogenic thrusting. Thus, this study demonstrates the utility of mapping seismites to separate the importance of regional vs. local tectonic activity influencing foreland basin sedimentation by identifying patterns that delineate palaeoepicentres associated with specific local intrabasinal normal faults vs. regional trends in soft‐sediment deformation related to Sevier belt earthquakes.  相似文献   

Rare earth elements in sediments of the Vigo Ria,NW Iberian Peninsula     

Ricardo Prego  Miguel Caetano  Carlos Vale  Judith Marmolejo-Rodríguez 《Continental Shelf Research》2009

The abundance and distribution of rare earth elements (REE) and their signatures in the Vigo Ria were studied from 50 samples of surface sediments and related to the geological formation in its watershed. The total amount of REE in the Ria is heterogeneous. It ranges from 220 mg kg⁻¹ in the southern middle Ria margin in the vicinity of the Galiñeiro geological shore complex, which contains REE-enriched minerals, to 2 mg kg⁻¹ near the Ria mouth due to dilution with high levels of carbonated biogenic particles (31% of Ca). Rare earth elements of the Ria sediments are considerably enriched in light-REE relative to heavy-REE (a LREE/HREE ratio of 9.7±1.6) and also show a slightly negative Eu-anomaly. Low European shale normalised REE patterns were distinguished in the innermost sediments of Vigo Ria, but were not correlated with Al. This suggests a minor contribution of REE from upstream freshwater inputs to the sediments in the middle Vigo Ria zone. Normalised REE ratios in the middle Ria imply that fine particles enriched in REE may be exported from the Ria to shelf mud patches and REE can be useful as sediment tracers of Ria input on the shelf.  相似文献   

Seismic response of an urban bridge-support system in soft clay     

Juan M. Mayoral  Yolanda AlbertoManuel J. Mendoza  Miguel P. Romo 《Soil Dynamics and Earthquake Engineering》2009

The numerical simulation of an instrumented urban bridge support and its foundation system was conducted. The bridge works as a deck in a surface subway station and was built 12 yr ago in the so-called Lake Zone in Mexico City, where very soft clays, exhibiting low shear strength and high compressibility prevail. Since the beginning of its construction, pile loads, soil–raft contact pressures and the overall response of the foundation system have been monitored. Within this period, several earthquakes have occurred. Thus, an extensive database of accelerations, pore pressures and load histories have been recorded. In particular, this paper focuses on the bridge response observed during two moderated intensity events, the 2004, 6.3 M_w, Guerrero Coast and the 1999, 7.0 M_w, Tehuacan earthquakes. Finite element models were developed to reproduce the measured responses and to assess the soil–foundation-support performance for long-term conditions, including the effects of potential changes in the dynamic soil properties due to regional subsidence. The computed dynamic responses obtained with the simulation for the free field and structure compares fairly well with the recordings.  相似文献   

Elimination of Carbamazepine,Diclofenac and Naproxen from Treated Wastewater by Nanofiltration     

Markus Röhricht  Jürgen Krisam  Ulrich Weise  Uta R. Kraus  Rolf‐A. Düring 《洁净——土壤、空气、水》2009,37(8):638-641

Most conventional wastewater treatment plants remove very small amounts of micropollutants, such as pharmaceuticals. Here, the ability of two different types of submerged nanofiltration flat sheet modules to remove pharmaceuticals from wastewater is analyzed. The two nanofiltration membranes were used at relatively low pressures of only 0.3 and 0.7 bar. At such low pressures, the membranes did not retain salts to a great extent. This is advantageous in wastewater treatment because no salt concentrate is produced. Carbamazepine was retained only slightly by the nanofiltration membranes, whereas approximately 60% of diclofenac and naproxen were retained by both membranes. This level of effectiveness might not be enough to justify the use of such a system as an additional treatment step in wastewater treatment plants.  相似文献   

The price of spice: Ethnic minority livelihoods and cardamom commodity chains in upland northern Vietnam     

Claire Tugault‐Lafleur  Sarah Turner 《Singapore journal of tropical geography》2009,30(3):388-403

The northern uplands of Vietnam are witness to rapidly developing commodity markets for a range of forest and agricultural products. Since the early 1990s the cultivation of black cardamom (Amomum aromaticum) has become a source of cash income for a growing number of ethnic minority households in these uplands. Drawing on ethnographic fieldwork, and utilizing a commodity chain and livelihoods approach, this article investigates the contemporary dynamics surrounding the cultivation, harvesting and trade of dried cardamom fruit from Hmong cultivators in Lao Cai province to consumers elsewhere in Vietnam and beyond to China and the global market. We analyse the spatial and social structures of these commodity chains, drawing attention to a range of mechanisms of access. We find that these mechanisms are reliant upon specific ethnic relations as well as different forms of capital that together sustain economic advantages for particular actors. While focusing on the ethnic minority cultivators active in these commodity chains, we also call for more nuanced understandings of how the trade in forest products fits within local agricultural systems and household livelihood decision making processes in the Vietnam uplands.  相似文献   

Contribution to the study of composite spectra: XI. Orbital elements of some faint systems     

J.‐M. Carquillat  J.‐L. Prieur 《Astronomische Nachrichten》2007,328(1):46-54

We present the results of a radial‐velocity study of nine new faint SB1 spectroscopic binaries with composite spectra: HD 137975‐6, 177984, HDE 226489, 231613‐4, 255387‐8, 256138‐9, 264997‐8, 276787 and 293041‐2. The observations were made at Haute‐Provence and Cambridge observatories with CORAVEL instruments between 1982 and 2006. From the radial‐velocity measurements of the cool components, we derive the orbital elements of those spectroscopic binaries for the first time. Using all the available data, we propose a model for each system that describes the nature of the individual components, with an estimation of the angular separation and orbital inclination. Finally we discuss the rotation–revolution synchronism of the cool components. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

Optical flares from the faint mid‐dM star 2MASS J00453912+4140395     

Zs. K&#x;vri  F. Vilardell  I. Ribas  K. Vida  L. van Driel‐Gesztelyi  C. Jordi  K. Olh 《Astronomische Nachrichten》2007,328(9):904-908

We present B and V light curves of a large stellar flare obtained with the Wide Field Camera at the Isaac Newton 2.5‐m telescope (La Palma). The source object is a faint (m_V = 21.38) foreground star in the field of the Andromeda galaxy, with its most probable spectral type being dM4. We provide an estimate of the total flare energy in the optical range and find it to be of the order of 1035 erg. The cooling phase of the large flare shows three additional weak flare‐like events, which we interpret as results of a triggering mechanism also observed on the Sun during large coronal mass ejections. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献