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11.
A. Kyono M. Kimata M. Matsuhisa Y. Miyashita K. Okamoto 《Physics and Chemistry of Minerals》2002,29(4):254-260
The crystal structure of stibnite [Sb2S3, Pnma, a=11.314(2), b=3.837(2), c=11.234(3) Å, V= 487.7(3) Å3 at 293 K] was refined in situ at 230, 173, and 128 K. It is a major characteristic of the structure that the Sb–S secondary bonds enclosing Sb 5s2 inert lone-pair electrons at 293 K are significantly shorter than the corresponding sum of the Sb and S van der Waals radii. Concerning the temperature dependence, although both the polyhedral volume and the cation eccentricity of the two SbS7 polyhedra exhibit continuous contractions with decreasing temperature, the sphericity values remain constant, indicating isotropic shrinkage. Consequently, the geometries of Sb 5s2 inert lone-pair electrons and ligand atoms remain unchanged at low temperatures. This is because the crystal structure of stibnite at low temperature induces contraction with attractive interactions, which is called the orbital overlap between Sb 5s2 inert lone-pair electrons and ligand orbitals to maintain the coordination environment. In this case, Sb 5s2 lone-pair electrons are not inert, but active. Such orbital overlaps of inert lone-electron pairs can provide a reasonable explanation for shorter secondary bonds and lower band gap energy of the binary compounds containing heavy elements such as Sb, Te, Pb, and Bi, which are key factors in tracing the origins of color, luster, and semiconductivity of their minerals or compounds. 相似文献
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K. Kuroda T. Irifune T. Inoue N. Nishiyama M. Miyashita K. Funakoshi W. Utsumi 《Physics and Chemistry of Minerals》2000,27(8):523-532
Determination of the phase boundary between ilmenite and perovskite structures in MgSiO3 has been made at pressures between 18 and 24 GPa and temperatures up to 2000 °C by in situ X-ray diffraction measurements
using synchrotron radiation and quench experiments. It was difficult to precisely define the phase boundary by the present
in situ X-ray observations, because the grain growth of ilmenite hindered the estimation of relative abundances of these phases.
Moreover, the slow reaction kinetics between these two phases made it difficult to determine the phase boundary by changing
pressure and temperature conditions during in situ X-ray diffraction measurements. Nevertheless, the phase boundary was well
constrained by quench method with a pressure calibration based on the spinel-postspinel boundary of Mg2SiO4 determined by in situ X-ray experiments. This yielded the ilmenite-perovskite phase boundary of P (GPa) = 25.0 (±0.2) – 0.003
T (°C) for a temperature range of 1200–1800 °C, which is generally consistent with the results of the present in situ X-ray
diffraction measurements within the uncertainty of ∼±0.5 GPa. The phase boundary thus determined between ilmenite and perovskite
phases in MgSiO3 is slightly (∼0.5 GPa) lower than that of the spinel-postspinel transformation in Mg2SiO4.
Received: 19 May 1999 / Accepted: 21 March 2000 相似文献
13.
Jianliang Deng Hiroshi Kameya Yukika Miyashita Jiro Kuwano Reiko Kuwano Junichi Koseki 《Engineering Geology》2011,123(4):302
Among the extensive failed slopes in the 2004 Niigata-ken Chuetsu Earthquake, Japan, a dip slope at Yokowatashi, Ojiya, was investigated intensively. The sliding plane was along a weak thin tuff sandy layer which had been deeply weathered. Triaxial compression tests and plane strain compression tests were performed on undisturbed specimens obtained by block sampling and boring sampling to evaluate the strength that was mobilized on the sliding plane. Stability analysis based on the test results reveals that, at normal time, without earthquake and without an extremely high groundwater level, the slope is stable. Furthermore, the calculation of earthquake-induced displacement provides a reasonable simulation of the failure of this slope. 相似文献
14.
Spectral ratios of teleseismic P waves for 15 deep (>200 km) earthquakes recorded at 146 High-Sensitivity Seismographic Network stations in the Kanto district and its surrounding area, eastern Japan, were inverted for attenuation parameter $ t_P^{ * } $ . The dataset consisted of good-quality vertical-component seismograms, whose P phases were handpicked. The P wave spectral ratios with high signal-to-noise ratios were calculated up to 1 Hz for all the station pairs, linear regressed, and then inverted for $ t_P^{ * } $ using the technique of least squares . The result showed that the active volcanic areas were clearly characterized by high $ t_P^{ * } $ . In contrast, $ t_P^{ * } $ varied in the nonvolcanic areas. The present result on the $ t_P^{ * } $ distribution was roughly consistent with the shallow part (<30 km) of an attenuation structure, which has been previously obtained based on 3-D tomography by using records of high-frequency (around 5 Hz) P waves from local earthquakes. This suggested that the present method of $ t_P^{ * } $ estimation is valid. The advantage and possible application to other areas were also discussed. 相似文献
15.
U–Pb ages of detrital zircons and white mica K–Ar ages are obtained from two psammitic schists from the western and eastern units of the Sanbagawa Metamorphic Belt located in the Sakuma–Tenryu area. The detrital zircons in the sample from the western unit (T1) show an age cluster around 95 Ma, and the youngest age in the detrital zircons is 94.0 ± 0.6 Ma. The detrital zircons in the sample from the eastern unit (T5) show a main age cluster in the Late Cretaceous with some older ages, and the youngest age in the detrital zircons is 72.8 ± 0.9 Ma. The youngest zircon ages restrict the older limit of the depositional ages of each sample. White mica K–Ar ages of T1 and T5 are 69.8 ± 1.5 Ma and 56.1 ± 1.2 Ma, respectively, which indicate the age of exhumation and restrict the younger limit on the depositional age of each sample. The results show that the western and eastern units were different in their depositional and exhumation ages, suggesting the episodic subduction and exhumation of the Sanbagawa Belt in the Sakuma–Tenryu area. These results also suggest simultaneous existence of subduction and exhumation paths of metamorphic rocks in the high‐P/T Sanbagawa Metamorphic Belt. 相似文献
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Applying the iterative shooting/bisection technique for rapid forward modeling to the seismic explosion data, we could refine the crustal velocity structure model of the western part of the Hidaka collision zone, Hokkaido, Japan. We used only the precise P-wave first arrival data obtained by the Research Group for Explosion Seismology, which set up a 113.4-km-long profile in August 2000 along with 327 observation points and four shot points with TNT charges from 100 to 300 kg. We could estimate a two-dimensional inhomogeneous crustal velocity structure model with a velocity decrease in the eastern direction at a depth of 15.7 km, several portions of velocity reversals with depth and a low velocity anomaly proposed in previous studies. The root-mean-square of travel-time residuals was improved from 0.398 s for the previous structure model to 0.176 s for the present model with a reduction of 55.8%. 相似文献
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19.
Yoshiki Shirahama Yukari Miyashita Masao Kametaka Yuji Suzuki Yosuke Miyairi Yusuke Yokoyama 《Island Arc》2021,30(1):e12376
The NE-trending Hinagu fault zone, length 81 km, is one of the major active faults in Kyushu, Japan. From north to south, it is divided into three segments based on geomorphic features and paleoseismic behavior: the Takano-Shirahata, Hinagu, and Yatsushiro Sea segments. The 2016 Kumamoto earthquake produced a 6-km-long surface rupture with a dextral strike-slip displacement on the northern part of the Takano-Shirahata segment. Surface rupture, a faint east-side-up flexure with a vertical offset of less than 8 cm, was observed near the middle of the Takano-Shirahata segment. To examine past surface-rupturing earthquakes on the Takano-Shirahata segment, including rupture frequency and timing, we conducted a paleoseismic study with boring and trenching at Yamaide. A trench across the surface rupture exposed multiple fault strands associated with multiple surface-rupturing events that deformed several strata of fine-grained sediments. By structural and stratigraphic interpretation, high-density radiocarbon dating and tephra analysis, and Bayesian modeling, we constrained the timing of seven events, Events 1–7, to 0.84–1.25, 1.31–7.06, 9.99–11.0, 10.8–12.1, 12.0–13.0, 14.2–15.1, and before 14.8 kcal BP. Slip during Events 1–6 was obviously larger than the 2016 slip. The estimated average recurrence interval was about 2596–2860 years, but the interval between Events 2 and 3 was much longer than other intervals. Moreover, the vertical throw associated with Event 2 was larger than that of other events. This implies that the Takano-Shirahata segment has a period with rare larger earthquakes and a period with frequent smaller earthquakes. Some events might have produced ruptures on both the Takano-Shirahata and the northern part of the Hinagu segments simultaneously or in a short time. The variety of recurrence intervals suggests that the seismic activity has been affected by one or both activities of the Futagawa fault zone and the Hinagu segment. 相似文献
20.
Dietary analysis of harbour seals (Phoca vitulina) from faecal samples and overlap with fisheries in Erimo,Japan 
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下载免费PDF全文 Tabitha C. Y. Hui Yuka Morita Yumi Kobayashi Yoko Mitani Kazushi Miyashita 《Marine Ecology》2017,38(3)
The number of harbour seals in Japan has been rebounding since protection began in the mid‐1980s. With the increase in seal numbers, increased conflict with fisheries has occurred through depredation and the belief that seals compete with fisheries for prey. However, competition can only be determined if the prey species and quantities seals consume over time are known. We studied the diet of harbour seals in Erimo, site of the largest population of harbour seals in Japan, from 2011 to 2012 and assessed the degree of prey overlap with local fisheries. We used both hard parts and DNA techniques to identify prey items in seal scats, and compared these results to local fisheries data. A total of 46 prey occurrences was detected by both methods, of which 17 matched between techniques at least to the family level. Hard parts methods identified five incidences of prey undetected by DNA methods in five scats (one incidence per scat). DNA methods identified 24 additional prey occurrences in 13 scats, for which no hard part evidence for that prey had been found. This more than doubled the total number of prey occurrences across the 15 scats compared. Overall, the most frequently occurring harbour seal prey were walleye pollock (Theragra chalcogramma), sculpins and snailfishes. In contrast, the top three groups targeted by fisheries were codfishes, salmon and invertebrates. Many species common in the harbour seal's diet such as snailfishes and blennies were not targeted by fisheries. Fishes such as greenlings, sculpins, rockfishes and Japanese anchovy (Engraulis japonicus) were common in the diet of harbour seals, but made up a very small proportion of fisheries catches in Erimo. The importance of other prey species varied between seasons. Sculpins, greenlings and forage fishes were the top three prey groups for harbour seals in spring by percent modified frequency of occurrence, whereas the most important target groups by percentage mass caught by fisheries were codfishes, cephalopods and other invertebrates. Sculpins and rockfishes remained as important prey items for harbour seals in summer and autumn, in addition to codfishes, snailfishes and blennies. In contrast, the main groups caught by fisheries in summer were other fishes, particularly Japanese amberjack (Seriola quinqueradiata) and various species of sharks and eels, and invertebrates. By autumn, Erimo fisheries had focussed on catching salmon. Salmon were taken by harbour seals as well during this period, but at a relatively lower frequency compared to other prey groups. The results of our study show that although harbour seals consumed several of the prey species targeted by fisheries, the relative importance of these species to seals and fisheries and the seasons in which they were targeted were different. 相似文献