Health risk of heavy metals from vegetables irrigated with sewage water in peri-urban of Dera Ismail Khan,Pakistan     

H. Ullah  N. U. Khan  F. Ali  Z. A. Shah  Q. Ullah 《International Journal of Environmental Science and Technology》2018,15(2):309-322

Health risks of heavy metals in vegetables irrigated with sewage water were investigated in the present study. The findings indicated a massive accumulation of heavy metals in soil and vegetables collected from Dera Ismail khan, Pakistan. The concentration levels of heavy metal in vegetables grown on soil irrigated with untreated sewage water were significantly higher at (P ≤ 0.001) than in vegetables grown on fresh-water-irrigated soil and proceeded the recommended limits of World health organization. Moreover, the findings also indicated that the adults and children consuming such vegetables ingested a large proportion of the selected toxic metals. Health risk index was greater than one for Pb and Cd in all the selected vegetables and was greater than one for Ni in three vegetables like Spinacia oleracea, Benincasa fistulosa and Lactuca sativa. Health risk assessment would be a useful tool for information regarding any threats of heavy metals contamination in vegetables.  相似文献   

Green synthesis of magnetic mesoporous silica nanocomposite and its adsorptive performance against organochlorine pesticides     

W. A. El-Said  D. M. Fouad  M. H. Ali  M. A. El-Gahami 《International Journal of Environmental Science and Technology》2018,15(8):1731-1744

Green synthesis of nanomaterials has received increasing attention as an eco-friendly technology in materials science. Here, we have used two types of extractions from green tea leaf (i.e., total extraction and tannin extraction) as reducing agents for a rapid, simple and one-step synthesis method of mesoporous silica nanoparticles/iron oxide nanocomposite based on deposition of iron oxide onto mesoporous silica nanoparticles. Mesoporous silica nanoparticles/iron oxide nanocomposite were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray, vibrating sample magnetometer, N₂ adsorption and high-resolution transmission electron microscopy. Mesoporous silica nanoparticles/iron oxide nanocomposite was used as a solid adsorbent for removal of lindane pesticide from aqueous solutions. The developed system possesses the advantages of silica as core that include large surface area and advantages of iron oxide (shell) that include the capability to interact with chlorinated compounds and ability to release by using external magnetic field. UV-Vis technique was used as a simple and easy method for monitoring the removal of lindane. Effects of pH and temperature on the removal efficiency of the developed mesoporous silica nanoparticles/iron oxide nanocomposite toward lindane pesticide were also investigated. Fourier transform infrared spectroscopy, high-performance liquid chromatography and gas chromatography techniques were used to confirm the high ability of mesoporous silica nanoparticles/iron oxide nanocomposite for sensing and the capture of lindane molecules with high sorption capacity (about 99%) that could develop a new eco-friendly strategy for detection and removal of pesticide and as a promising material for water treatment.  相似文献   

Impact of drilling mud on chemistry and microbiology of an Upper Triassic groundwater after drilling and testing an exploration well for aquifer thermal energy storage in Berlin (Germany)     

Simona Regenspurg  Mashal Alawi  Guido Blöcher  Maria Börger  Stefan Kranz  Ben Norden  Ali Saadat  Traugott Scheytt  Lioba Virchow  Andrea Vieth-Hillebrand 《Environmental Earth Sciences》2018,77(13):516

After completion of an exploration well, sandstones of the Exter Formation were hydraulically tested to determine the hydraulic properties and to evaluate chemical and microbial processes caused by drilling and water production. The aim was to determine the suitability of the formation as a reservoir for aquifer thermal energy storage. The tests revealed a hydraulic conductivity of 1–2 E-5 m/s of the reservoir, resulting in a productivity index of 0.6–1 m³/h/bar. A hydraulic connection of the Exter Formation to the overlaying, artesian “Rupelbasissand” cannot be excluded. Water samples were collected for chemical and microbiological analyses. The water was similarly composed as sea water with a maximum salinity of 24.9 g/L, dominated by NaCl (15.6 g/L Cl and 7.8 g/L Na). Until the end of the tests, the water was affected by drilling mud as indicated by the high pH (8.9) and high bicarbonate concentration (359 mg/L) that both resulted from the impact of sodium carbonate (Na₂CO₃) additives. The high amount of dissolved organic matter (>?58 mg/L) and its molecular-weight distribution pattern indicated that residues of cellulose, an ingredient of the drilling mud, were still present at the end of the tests. Clear evidence of this contamination gave the measured uranine that was added as a tracer into the drilling mud. During fluid production, the microbial community structure and abundance changed and correlated with the content of drilling mud. Eight taxa of sulfate-reducing bacteria, key organisms in processes like bio-corrosion and bio-clogging, were identified. It can be assumed that their activity will be affected during usage of the reservoir.  相似文献   

Geospatial assessment of soil erosion intensity and sediment yield: a case study of Potohar Region,Pakistan   总被引：2，自引：0，他引：2  

Saleem Ullah  Amjad Ali  Muhammad Iqbal  Muhammad Javid  Muhammad Imran 《Environmental Earth Sciences》2018,77(19):705

Estimation of spatial extent of soil erosion, one of the most serious forms of land degradation, is critical because soil erosion has serious implications on soil fertility, water ecosystem, crop productivity and landscape beauty. The primary objective of the current study was to assess and map the soil erosion intensity and sedimentation yield of Potohar region of Pakistan. Potohar is the rainfed region with truncated and complex topography lying at the top of the Indus Basin, the world’s largest irrigation networks of canals and barrages. Spatially explicit Revised Universal Soil Loss Equation (RUSLE) Model integrated with Remote Sensing-GIS techniques was used for detecting/mapping of erosion prone areas and quantification of soil losses. The results show that the Potohar region is highly susceptible to soil erosion with an average annual soil loss of 19 tons ha^?1 year^?1 of which the maximum erosion (70–208 tons ha^?1 year^?1) was near the river channels and hilly areas. The sediment yield due to the erosion is as high as 148 tons ha^?1 year^?1 with an average of 4.3 tons ha^?1 year^?1. It was found that 2.06% of the total area falls under severe soil erosion, 13.34% under high erosion, 15.35% under moderate soil erosion while 69.25% of the area lies in the low (tolerable) soil erosion. Chakwal and Jhelum districts of the region are seriously affected by erosion owing to their topography and soil properties. The information generated in this study is a step forward towards proper planning and implementation of strategies to control the erosion and for protection of natural resources. It is, hence, necessary that suitable water harvesting structures be made to control water to prevent soil erosion and provision of water in the lean season in this region. Tree plantation and other erosion control practices such as strip cropping can also minimize soil erosion in this region.  相似文献   

Air pollution forecasting from sky images with shallow and deep classifiers     

Mohammad Saleh Vahdatpour  Hedieh Sajedi  Farzad Ramezani 《Earth Science Informatics》2018,11(3):413-422

Air pollution is one of the most important problems in the new era. Detecting the level of air pollution from an image taken by a camera can be informative for the people who are not aware of exact air pollution level be declared daily by some organizations like municipalities. In this paper, we propose a method to predict the level of the air pollution of a location by taking an image by a camera of a smart phone then processing it. We collected an image dataset from city of Tehran. Afterward, we proposed two methods for estimation of level of air pollution. In the first method, the images are preprocessed and then Gabor transform is used to extract features from the images. At the end, two shallow classification methods are employed to model and predict the level of air pollution. In the second proposed method, a Convolutional Neural Network(CNN) is designed to receive a sky image as an input and result a level of air pollution. Some experiments have been done to evaluate the proposed method. The results show that the proposed 9 method has an acceptable accuracy in detection of the air pollution level. Our deep classifier achieved accuracy about 59.38% which is 10 about 6% higher than traditional combination of feature extraction and classification methods.  相似文献   

Development of an efficient surrogate model based on aquifer dimensions to prevent seawater intrusion in anisotropic coastal aquifers,case study: the Qom aquifer in Iran     

Ali Ranjbar  Najmeh Mahjouri 《Environmental Earth Sciences》2018,77(11):418

Coastal aquifers are usually exposed to saltwater intrusion. Therefore, groundwater extracted from these aquifers should be regulated considering their dimensions and effective parameters. In this paper, optimum discharge from a large number of exploitation wells is evaluated according to variations of width, length, and anisotropy coefficient in the Qom aquifer near the salt lake in central Iran. First, the wells are divided into clusters to decrease the number of decision variables. Then, the location and discharge from each cluster is obtained using SEAWAT and charged system search (CSS) simulation–optimization model with the assumption of three-dimensional variable density flow. The maximum discharge considering various anisotropy rates is computed based on different values of lengths and widths of the aquifer. Finally, an M5-tree model is trained using the obtained samples to derive a linear relationship between input and output data. Based on the results, for various ranges of width and length of an aquifer with impermeable boundaries, different linear equations for optimum discharge are obtained. Also, it was found that for an aquifer with a small width, the critical discharge is a function of the length while the effect of the boundaries is negligible. Sensitivity analysis of the anisotropy coefficient reveals that with increasing the anisotropy rate, thickness and slope of the transition zone decrease and as the maximum discharge increases consequently. However, the sensitivity of the discharge to anisotropy rate is not remarkable. A comparison between the results of this study with those of the analytical method based on sharp interface assumption is carried out. For the critical condition, the best agreement between analytical equation (\(\overline {L} =0.87\overline {W} +0.62\)) and proposed method (\(\overline {L} =0.83\overline {W} - 1.41\)) is achieved for the anisotropic aquifer when the 50% isochlor is assumed as the measure of salt water intrusion.  相似文献   

Ghaleh-khargushi rhyodacite and Gorid andesite from Iran: characterization,uses, and durability     

Ahmad Zalooli  David Martín Freire-Lista  Mashalah Khamehchiyan  Mohammad Reza Nikudel  Rafael Fort  Shahram Ghasemi 《Environmental Earth Sciences》2018,77(8):315

Durability of building stones is an important issue in sustainable development. Crystallization of soluble salts is recognized as one of the most destructive weathering agents of building stones. For this reason, durability of Ghaleh-khargushi rhyodacite and Gorid andesite from Iran was investigated against sodium sulfate crystallization aging test. Petrographic and physico-mechanical properties and pore size distribution of these stones were examined before and after the aging test. The characteristics of the microcracks were quantified with fluorescence-impregnated thin sections. Durability and physico-mechanical characteristics of Ghaleh-khargushi rhyodacite are mainly influenced by preferentially oriented preexisting microcracks. Stress induced by salt crystallization led to the widening of preexisting microcracks in Ghaleh-khargushi rhyodacite, as confirmed by the pore size distributions before and after the aging test. The preexisting microcracks of Gorid andesite were attributed to the mechanical stress induced by contraction of lava during cooling. The number of transcrystalline microcracks was significantly increased after the aging test. The degree of plagioclase microcracking was proportional to its size. Durability of the studied stones depends on initial physico-mechanical properties, pore size distribution, and orientation of microcracks. Initial effective porosity is found to be a good indicator of the stones’ durability. Salt crystallization resulted in an increase in the effective porosity with a parallel decrease in the wave velocities. Surface microroughness parameters increased with the development of salt crystallization-induced microcracking. Gorid andesite showed higher quality and durability than Ghaleh-khargushi rhyodacite.  相似文献   

Hydrothermal alteration and evolution of Zr-Th-U-REE mineralization in the microgranite of Wadi Ras Abda,North Eastern Desert,Egypt     

Amr Abdel Aty Abdel Hamid  Hassan Ismail El Sundoly  Ahmed Ali Abu Steet 《Arabian Journal of Geosciences》2018,11(11):273

Ras Abda plutonic suite, North Eastern Desert of Egypt, consists predominantly of Neoproterozoic calc-alkaline older granites. Minor exposures of pink microgranite are occurring along Wadi Ras Abda within the older granites. Previous studies on this area demonstrated that the microgranite is altered in some parts and contains anomalous concentrations of rare metal elements (Zr, Th, and U). These altered and mineralized zones are re-assessed using field observations, chemical analysis, and by the application of various transmitted light and electron microscopic techniques. The rare metals exist as mineral segregation grew freely into open cavities of the microgranite and concordant with the NNE strike-slip fault movement. The mineralized zones contain an assemblage of secondary magnetite, zircon, uranothorite, columbite-(Mn), fergusonite-(Y), and allanite-(Ce). The extreme abundance of zircon in the mineralized zone, along with other evidence, indicates a hydrothermal origin of this zircon together with associated rare metals. The geochemical investigation and mass balance calculations revealed extreme enrichment of Zr, Th, U, Y, Nb, Ta, and REE. Post-magmatic hydrothermal alterations resulted in such pronounced chemical and mineralogical heterogeneity. The hydrothermal fluids are thought to be oxidizing, alkaline and of medium temperature (>?250 °C). The average contents of the elements Zr (1606 ppm), Th (1639 ppm), U (306 ppm), Nb (955 ppm), and REE (1710 ppm) in the mineralized microgranite reach sub-economic levels and could be a potential source of these elements.  相似文献   

Diagenetic evolution vis-a-vis reservoir characteristics of Dhosa sandstones,Ler dome,Kachchh, western India     

Asma A. Ghaznavi  Mohammad Masroor Alam  Zuhi Khan  A. H. M. Ahmad 《Arabian Journal of Geosciences》2018,11(14):387

The detrital mineralogy as well as diagenetic characters of the Dhosa Sandstone Member of Chari Formation exposed at the Lerdome, south of Bhuj was studied. In order to assess the potential of the Dhosa Sandstone as a reservoir, it is substantial to understand the diagenetic processes that are controlled largely by post-depositional cementation and compaction in addition to framework composition and original depositional textures. The petrologic analysis of 33 thin sections was carried out to discern primary composition and diagenetic features including primary and secondary porosity patterns. Monocrystalline quartz dominates the detrital mineralogy followed by polycrystalline quartz. Among the polycrystalline variety recrystallized metamorphic quartz surpasses stretched metamorphic quartz in terms of abundance. Feldspars comprise microcline and plagioclase where the former is dominant over the latter. Orthoclase too comprises a very small percentage. Mica, chert, rock fragments, and heavies form the remaining detrital constituent in descending order of their constituent percentage. The diagenetic precipitates are mainly carbonate (8.30%) and iron (7.80%) followed by clay (0.66%) and silica (0.88%) that are minor constituent of the total cementing material. The main paragenetic events identified are early cementation, mechanical compaction, late cementation, dissolution, and authigenesis of clays. The overall reservoir quality seems to be controlled by compaction and authigenic carbonate cementation. The minus cement porosity average 29.4%. The porosity loss due to compaction is 21.92% and by cementation is 29.71%. The loss of original porosity was due to early cementation followed by moderate mechanical compaction during shallow burial. Preservation of available miniscule primary porosity was ascribed to dissolution of carbonates and quartz overgrowth which resisted chemical compaction during deep burial. The studied sandstones may have low reservoir quality owing to existing porosity of less than 9%. More carbonate dissolution and its transformation in dolomite in sub-surface condition and macro-fracture porosity may result in enhanced secondary porosity and good diagenetic traps.  相似文献   

Analysis of pervasive precipitation in similar gradient areas of Iran     

Hossein Asakereh  Mohammad Darand  Mehdi Doostkamian 《Arabian Journal of Geosciences》2018,11(17):511

Precipitation is a major climatic element with high spatial variations. Temporal and spatial variations may differ in large and small scales. It is, therefore, of utmost importance to study areas with similar gradients in terms of precipitation patterns in order to shed light on the complexities of precipitation variations. In the present study, attempts were made to identify areas with similar gradients experiencing the same precipitation pattern over a 50-year period (1964–2013). To this end, data were collected from synoptic stations in Iran in two phases (i.e., 1434 stations in the first phase and 673 stations in the second one). Alexanderson’s technique was adopted to examine sudden changes in precipitation patterns. The results showed that five regions with similar gradients could be identified in terms of precipitation patterns: negative and high variations, negative and moderate variations, positive and high variations, positive and moderate variations, and little or no variations. The distribution of such regions indicated that the regions with positive trends experienced more annual variations and had further spatial distribution. Furthermore, the findings revealed that the regions with negative precipitation patterns experienced more sudden changes in comparison with those with positive precipitation patterns. Additionally, more variations were observed in the precipitation patterns in recent years.  相似文献