Sr and Ar isotope studies of detrital smectites from the Atlantic Ocean (D.S.D.P., Legs 43, 48 and 50)     

Norbert Clauer  Patrick Giblin  Jacques Lucas 《Chemical Geology》1984,46(2):141-151

Mineralogical, morphological and isotopic (RbSr and KAr) determinations were made on some detrital smectites of Palaeocene and Cenomanian ages from D.S.D.P. drillings in the Atlantic Ocean. These minerals are not inert in their depositional environment; authigenic laths grow on detrital sheets with sharp borders. This authigenesis could occur slightly after deposition in a closed system, for some of these smectites. It has been tentatively quantified by the RbSr and KAr isotopic methods, which seem also well suited to evaluate the chemical extent of this authigenesis. At least, no preferential loss of ⁴⁰Ar vs. ⁸⁷Sr could be detected in the minerals, even in those which are smaller than 0.2 μm.  相似文献   

Attenuation of a Mixed Chromium and Chlorinated Etjeme Ground Wate Plume in Estuarine Influenced Glaciated Sediments     

Lucas A. Hellerich  Matthew A. Poneiera  Nikolaos P. Nikolaidis  Barth F. Smets  Gregory M. Dobbs 《Ground Water Monitoring & Remediation》2003,23(3):74-84

The natural attenuation behavior of a ground water contaminant plume containing chromium and chlorinated ethenes in glaciated sediments was assessed using traditional and nontraditional methods. The mixed waste is transported through and attenuated within an estuarine influenced ground water aquifer of spatially varying redox character and organic carbon content. Contaminant fate and speciation were assessed as a function of geochemical conditions. Total, speciation-based, and sequential chemical extraction analyses were performed to determine contaminant partitioning and the redox capacity of the aquifer. Chromium speciation and partitioning were correlated with the reductive capacity and redox conditions of the aquifer sediments spatially distributed within the aquifer. Reductive dechlorination and partitioning of chlorinated ethenes were correlated with the organic carbon content and redox conditions of the aquifer sediments. The data showed that sharp redox gradients existed within the aquifer. Active reduction and retardation of both chromium and chlorinated ethenes was exhibited. The aqueous hexavalent chromium concentrations decreased to near nondetect levels in the vicinity of the receptor, whereas degradation products of higher-order chlorinated ethenes increased as a fraction of the total chlorinated ethene concentrations along the length of the plume. The potential for competition for reducing power under specific cases within the aquifer was suggested by the data, highlighting the need to include contaminant interactions in natural attenuation assessments.  相似文献   

Arsenic — a Review. Part II: Oxidation of Arsenic and its Removal in Water Treatment     

Monique Bissen  Fritz H. Frimmel 《洁净——土壤、空气、水》2003,31(2):97-107

In natural waters arsenic normally occurs in the oxidation states +III (arsenite) and +V (arsenate). The removal of As(III) is more difficult than the removal of As(V). Therefore, As(III) has to be oxidized to As(V) prior to its removal. The oxidation in the presence of air or pure oxygen is slow. The oxidation rate can be increased by ozone, chlorine, hypochlorite, chlorine dioxide, or H₂O₂. The oxidation of As(III) is also possible in the presence of manganese oxide coated sands or by advanced oxidation processes. Arsenic can be removed from waters by coprecipitation with Fe(OH)₃, MnO₂ or during water softening. Fixed‐bed filters have successfully been applied for the removal of arsenic.The effectiveness of arsenic removal was tested in the presence of adsorbents such as FeOOH, activated alumina, ferruginous manganese ore, granular activated carbon, or natural zeolites. Other removal technologies are anion exchange, electrocoagulation, and membrane filtration by ultrafiltration, nanofiltration or reverse osmosis.  相似文献   

Arsenic — a Review. Part I: Occurrence,Toxicity, Speciation,Mobility     

Monique Bissen  Fritz H. Frimmel 《洁净——土壤、空气、水》2003,31(1):9-18

In natural waters arsenic concentrations up to a few milligrams per litre were measured. The natural content of arsenic found in soils varies between 0.01 mg/kg and a few hundred milligrams per kilogram. Anthropogenic sources of arsenic in the environment are the smelting of ores, the burning of coal, and the use of arsenic compounds in many products and production processes in the past. A lot of arsenic compounds are toxic and cause acute and chronic poisoning. In aqueous environment the inorganic arsenic species arsenite (As(III)) and arsenate (As(V)) are the most abundant species. The mobility of these species is influenced by the pH value, the redox potential, and the presence of adsorbents such as oxides and hydroxides of Fe(III), Al(III), Mn(III/IV), humic substances, and clay minerals.  相似文献   

BASIC: Baltic Sea cyanobacteria. An investigation of the structure and dynamics of water blooms of cyanobacteria in the Baltic Sea—responses to a changing environment     

Lucas J. Stal  Patrizia Albertano  Birgitta Bergman  Klaus von Brckel  John R. Gallon  Paul K. Hayes  Kaarina Sivonen  Anthony E. Walsby 《Continental Shelf Research》2003,23(17-19):1695

The blooms of cyanobacteria that develop each summer in the Baltic Sea are composed of two functional groups, namely the small-sized picocyanobacteria (Synechococcus sp.) and the larger, colony-forming, filamentous N₂-fixing cyanobacteria. The former encompassed both red (phycoerythrin-rich) and blue-green (phycocyanin-rich) species. The majority of the picocyanobacteria measured less than 1 μm and this size fraction comprised as much as 80% of the total cyanobacterial biomass and contributed as much as 50% of the total primary production of a cyanobacterial bloom. The picocyanobacteria are incapable of fixing N₂, do not possess gas vesicles and are not toxic. However, a small filamentous Pseudanabaena sp. that could potentially fix N₂ was isolated from the picocyanobacteria fraction. The larger cyanobacteria may form surface scums because they possess gas vesicles that make them buoyant. Although their biomass was less than the picocyanobacteria, they therefore form the more conspicuous and nuisance-forming part of the bloom. The larger cyanobacteria were composed mainly of three different species: Nodularia spumigena, Aphanizomenon flos-aquae and Anabaena sp. These all belong to the heterocystous, N₂-fixing cyanobacteria. N. spumigena and A. flos-aquae were the dominant species; only N. spumigena was toxic. Although individual Nodularia filaments showed a range of different phenotypes, they all belong to one species as judged from 16S rDNA sequencing. Through determination of the genotypes of many individual Nodularia filaments, it was shown that this population was not clonal and that horizontal exchange of genetic information occurs. N. spumigena and A. flos-aquae were different with respect to their photosynthetic and N₂-fixing potentials. Depending on prevailing environmental conditions, these differences would promote the proliferation of one species over the other and hence would determine overall the toxicity of a bloom. Daily integrals of photon irradiance rather than temperature determined the onset of bloom formation. During a bloom, the diazotrophic cyanobacteria fixed N₂ at a rate that was 10–20% in excess of their own demand for N. Picocyanobacteria assimilated most of this excess N as shown by ¹⁵N incorporation. During bloom conditions, the diazotrophic cyanobacteria met about 50% of the N demand of the total cyanobacterial community. The picocyanobacteria were predominantly N-limited while the diazotrophic cyanobacteria were probably iron limited. These findings allow us to understand the formation of toxic cyanobacterial blooms and also to develop tools to predict bloom formation.  相似文献   

Automatic Surface Reconstruction Based on the Fusion of Fuzzy Logic and Robust Estimation Techniques     

Farhad Samadzadegan  Ali Azizi  Caro Lucas  & Michael Hahn 《The Photogrammetric Record》2002,17(100):651-674

Automatic surface reconstruction by means of digital image matching essentially involves computation in both image and object spaces. In image space, image matching is performed according to certain radiometric and geometric similarity criteria for conjugate point determination. The matching operations may therefore be regarded as decision–making processes. In practice, however, the similarity criteria for conjugate point determination demonstrate non–deterministic behaviour. Thus, the nature of these decision–making processes is more compatible with fuzzy reasoning concepts. In object space, on the other hand, surface reconstruction procedures, which operate on the basis of previously determined conjugate points, are essentially deterministic in nature and hence demand rigorous geometric modelling. In this paper, a new approach for automatic surface modelling is proposed, based on two different mathematical treatments: a fuzzy logic reasoning method for the conjugate point determination in image space; and a robust finite elements approach for the surface modelling in object space. Tests carried out on real data demonstrate the high potential of the strategy proposed.  相似文献   

The planet formation imager     

John D. Monnier  Stefan Kraus  Michael J. Ireland  Fabien Baron  Amelia Bayo  Jean-Philippe Berger  Michelle Creech-Eakman  Ruobing Dong  Gaspard Duchêne  Catherine Espaillat  Chris Haniff  Sebastian Hönig  Andrea Isella  Attila Juhasz  Lucas Labadie  Sylvestre Lacour  Stephanie Leifer  Antoine Merand  Ernest Michael  Stefano Minardi  Christoph Mordasini  David Mozurkewich  Johan Olofsson  Claudia Paladini  Romain Petrov  Jörg-Uwe Pott  Stephen Ridgway  Stephen Rinehart  Keivan Stassun  Jean Surdej  Theo ten Brummelaar  Neal Turner  Peter Tuthill  Kerry Vahala  Gerard van Belle  Gautam Vasisht  Ed Wishnow  John Young  Zhaohuan Zhu 《Experimental Astronomy》2018,46(3):517-529

The Planet Formation Imager (PFI, www.planetformationimager.org) is a next-generation infrared interferometer array with the primary goal of imaging the active phases of planet formation in nearby star forming regions. PFI will be sensitive to warm dust emission using mid-infrared capabilities made possible by precise fringe tracking in the near-infrared. An L/M band combiner will be especially sensitive to thermal emission from young exoplanets (and their disks) with a high spectral resolution mode to probe the kinematics of CO and H₂O gas. In this paper, we give an overview of the main science goals of PFI, define a baseline PFI architecture that can achieve those goals, point at remaining technical challenges, and suggest activities today that will help make the Planet Formation Imager facility a reality.  相似文献   

A regional water balance indicator inferred from satellite images of an Andean endorheic basin in central-western Argentina     

Lucas O. Bianchi  Juan Antonio Rivera  Facundo Rojas  Mauro Britos Navarro  Ricardo Villalba 《水文科学杂志》2017,62(4):533-545

In the Central Andes of Argentina (30–37°S), snowmelt is the main source of freshwater, an essential natural resource for ~2.2 million people in the adjacent arid lowlands. In this region, Laguna Llancanelo collects the water inputs from the Malargüe endorheic basin. Previous studies concerning the annual and intra-annual variations of this lagoon and its relationship with regional climate are rare. We obtained a monthly record for the Laguna Llancanelo area (LLA, 1984–2013) using the modified normalized difference water index derived from Landsat images. Monthly LLA ranges between 35 km² and 411 km² and is significantly related to variations of the Río Malargüe, the main snow-fed tributary to the lagoon. There is no long-term relationship between LLA and local rainfall, but rapid increases in LLA result from heavy rainfall around the lagoon. Conversely, rapid reductions in LLA encompass periods with both reduced discharge from the Río Malargüe and low local rainfall. The LLA integrates moisture of both Pacific (snowfall in the upper Andes) and Atlantic (lowland rainfall) origins; therefore, we propose using LLA as an indicator of regional water balance.  相似文献   

Estimating sand concentrations using ADCP-based acoustic inversion in a large fluvial system characterized by bi-modal suspended-sediment distributions     

Ricardo N. Szupiany  Cecilia Lopez Weibel  Massimo Guerrero  Francisco Latosinski  Molly Wood  Lucas Dominguez Ruben  Kevin Oberg 《地球表面变化过程与地形》2019,44(6):1295-1308

Quantifying sediment flux within rivers is a challenge for many disciplines due, mainly, to difficulties inherent to traditional sediment sampling methods. These methods are operationally complex, high cost, and high risk. Additionally, the resulting data provide a low spatial and temporal resolution estimate of the total sediment flux, which has impeded advances in the understanding of the hydro-geomorphic characteristics of rivers. Acoustic technologies have been recognized as a leading tool for increasing the resolution of sediment data by relating their echo intensity level measurements to suspended sediment. Further effort is required to robustly test and develop these techniques across a wide range of conditions found in natural river systems. This article aims to evaluate the application of acoustic inversion techniques using commercially available, down-looking acoustic Doppler current profilers (ADCPs) in quantifying suspended sediment in a large sand bed river with varying bi-modal particle size distributions, wash load and suspended-sand ratios, and water stages. To achieve this objective, suspended sediment was physically sampled along the Paraná River, Argentina, under various hydro-sedimentological regimes. Two ADCPs emitting different sound frequencies were used to simultaneously profile echo intensity level within the water column. Using the sonar equation, calibrations were determined between suspended-sand concentrations and acoustic backscatter to solve the inverse problem. The study also analyzed the roles played by each term of the sonar equation, such as ADCP frequency, power supply, instrument constants, and particle size distributions typically found in sand bed rivers, on sediment attenuation and backscatter. Calibrations were successfully developed between corrected backscatter and suspended-sand concentrations for all sites and ADCP frequencies, resulting in mean suspended-sand concentration estimates within about 40% of the mean sampled concentrations. Noise values, calculated using the sonar equation and sediment sample characteristics, were fairly constant across evaluations, suggesting that they could be applied to other sand bed rivers. © 2018 John Wiley & Sons, Ltd.  相似文献   

Basinga: A cell-by-cell GIS toolbox for computing basin average scaling factors,cosmogenic production rates and denudation rates     

Julien Charreau  Pierre-Henri Blard  Jéna Zumaque  Léo C.P. Martin  Tony Delobel  Lucas Szafran 《地球表面变化过程与地形》2019,44(12):2349-2365

The calculation of denudation rates from the measured cosmogenic nuclide concentrations in river sediments requires assumptions and approximations. Several different approaches and numerical tools are available in the literature. A widely used analytical approach represents the muogenic production with one or two exponentials, assumes the attenuation length of muons to be constant and also neglects temporal variations in the Earth's magnetic field. The denudation rates are then calculated directly and analytically from the measured concentrations. A second numerical and iterative approach was more recently proposed and considers a more rigorous muogenic production law based on pre-calculated variable attenuation length of muons and accounts for temporal changes of the magnetic field. It also assumes a specific distribution of denudation rates throughout the basin and uses an iterative approach to calculate the basin average denudation rates. We tested the two approaches across several natural basins and found that both approaches provide similar denudation results. Hence, assuming exponential muogenic production and constant attenuation length of muons in the rock has little impact on the derived denudation rates. Therefore, unless a priori known distributions of denudation rates are to be tested, there does not appear to be any particular gain from using the second iterative method which is computationally less effective. Based on these findings, we developed and describe here Basinga , a new ArcGIS® and QGIS toolbox which computes the basin average scaling factors, cosmogenic production rates and denudation rates for several tens of drainage basins together. Basinga follows either the Lal/Stone or the Lifton/Sato/Dunai scaling schemes and includes several optional tools for correcting for topographic shielding, ice cover and lithology. We have also developed an original method for correcting the cosmogenic production rates for past variations in the Earth's magnetic field. © 2019 John Wiley & Sons, Ltd.  相似文献