Arsenic — a Review. Part I: Occurrence,Toxicity, Speciation,Mobility     

Monique Bissen  Fritz H. Frimmel 《洁净——土壤、空气、水》2003,31(1):9-18

In natural waters arsenic concentrations up to a few milligrams per litre were measured. The natural content of arsenic found in soils varies between 0.01 mg/kg and a few hundred milligrams per kilogram. Anthropogenic sources of arsenic in the environment are the smelting of ores, the burning of coal, and the use of arsenic compounds in many products and production processes in the past. A lot of arsenic compounds are toxic and cause acute and chronic poisoning. In aqueous environment the inorganic arsenic species arsenite (As(III)) and arsenate (As(V)) are the most abundant species. The mobility of these species is influenced by the pH value, the redox potential, and the presence of adsorbents such as oxides and hydroxides of Fe(III), Al(III), Mn(III/IV), humic substances, and clay minerals.  相似文献   

Speciation of Arsenic Using Chelation Solvent Extraction and High Performance Liquid Chromatography     

Shamil J. Cathum  Carl E. Brown  Alison Obenauf  Monique Punt 《洁净——土壤、空气、水》2007,35(1):71-80

Research interest in speciation of arsenic stems from its species dependent behavior in the environment and in living organisms. The complexity of the matrix to be analyzed and low concentrations of target arsenic species that may be labile or difficult to chromatogram, indicate that a suitable pre‐treatment methodology is required. This study investigated the usefulness of chelation solvent extraction – high performance liquid chromatography (CSE‐HPLC) for the speciation of arsenic in water. It involved reacting arsenic with the chelant known for its affinity towards arsenic, followed by extraction, separation, and identification of the arsenic‐chelant‐arsenic complex. Arsenic species having different physicochemical properties were investigated. Species, such as, As₂O₃, As₃O₅, KH₂AsO₄, Na₂HAsO₄, and NaAsO₂ were detected as a group of closely eluted peaks with different retention times and spectral properties, whereas, the organic arsenic species CH₃Na₂AsO₃, o‐arsanilic acid, roxarson and triphenyl arsine separated quite well on the EnviroseP‐CM HPLC column. Key method parameters, such as, type of HPLC column, composition of mobile phase and organic solvents affecting peak resolution and sensitivity were optimized. Real environmental matrices contaminated with arsenic were analyzed under varying wavelengths (λ_max = 190, 210, 220, 234, 244, and 282 nm), with good precision. Different arsenic species were detected in these samples with excellent background and signal‐to‐noise ratios demonstrating the robustness of the method. The detection limit, reproducibility, selectivity, accuracy, and dynamic range of the calibration curves were evaluated.  相似文献   

Robotic telescopes and networks: New tools for education and science     

François R. Querci  Monique Querci 《Astrophysics and Space Science》2000,273(1-4):257-272

Nowadays many telescopes around the world are automated and some networks of robotic telescopes are active or planned. Such equipment could be used for thetraining of students and for science in the Universities of DCs and of newastronomical countries, by sending them observational data via Internetor through remotely controlled telescope. It seems that it is thetime to open up for discussion with UN and ESA organizations and also withIAU, how to implement links between robotic telescopes and suchUniversities applying for collaborations. Many scientific fields couldthus be accessible to them, for example on stellar variability, near-earthobject follow-up, -ray burst counterpart tracking, and so on.  相似文献   

盐湖丰产元素与Zintl化合物(续一)          下载免费PDF全文

贾永忠  景燕  马军  岳都元  Claude Belin  Monique Tillard 《盐湖研究》2011,19(1):66-72

Zintl化合物是以Edward Zintl命名的化合物,是一类由电正性的碱金属或碱土金属与电负性的13族或14族元素形成的特殊金属间化合物。其价键模式可以是离子键、金属键和共价键共存,其中的准金属可以共价键的形式形成各种形式的离子簇,因而其结构复杂多样。这类化合物的部分阴离子簇不仅具有稳定的笼状、层状和链状结构,并且具有特殊的光、电、磁等性能,使得在半导体、催化、电极材料等方面都有应用的前景和发展潜力。介绍了几个特殊Zintl化合物体系,盐湖丰产元素在Zintl化合物中的作用,指出了含有盐湖丰产元素的Zintl化合物的应用前景和方向。  相似文献   

A geophysical transect of the Adélie Margin,East Antarctica     

Jacques Wannesson  Monique Pelras  Bernard Petitperrin  Martine Perret  Jacques Segoufin 《Marine and Petroleum Geology》1985,2(3):192-200

In 1982, a geophysical survey of the Antarctic margin, including multichannel seismic, gravity, magnetic and bathymetric surveying, was carried out off Adélie Coast-Wilkes Land and in the eastern Ross Sea. Of the 5000 km of lines recorded, 3000 km were in the Adélie Coast area. Lines ATC 101–102, approximately following meridian 138°E, show the first complete transect of the Adélie Coast margin from the Southeast Indian abyssal plain at DSDP Site 269 to the continental shelf. These lines reveal a thick sedimentary series divided into three main acoustic units by two major unconformities considered to be Upper Eocene (42 Ma) and late Oligocene (25 Ma). Oceanic or continental basement can be traced under the whole area, and the ocean-continent boundary clearly lies beneath the lower continental slope. A deep, high-amplitude, low-frequency horizon, extending under the oceanic basement for over 300 km of line, is considered to be the Moho. Our interpretation supports a recent revision be Cande and Mutter proposing an early Upper Cretaceous opening between Australia and East Antarctica.  相似文献   

Coronal and heliospheric observations of solar particle events     

Monique Pick 《Astrophysics and Space Science》1996,243(1):179-186

Observations of accelerated particle beams are used to probe the coronal and interplanetary magnetic field structures over large distances from the Sun on the order of a few AU and for various heliolatitudes. It is shown that the propagation of low energy particles is very much controled by discrete interplanetary magnetic field structures. These discrete magnetic structures are sometimes embedded within interplanetary solar wind plasma disturbances, commonly called CMEs. The connection between the corona and the interplanetary medium is discussed. These observations lead to new insights on the origin of accelerated particles detected in association with CMEs.  相似文献   

Sand transport measurements in Chioggia inlet,Venice lagoon: Theory versus observations     

Monique M. Villatoro  Carl L. Amos  Georg Umgiesser  Christian Ferrarin  Luca Zaggia  Charlotte E.L. Thompson  Daniele Are 《Continental Shelf Research》2010

This paper presents results of recent measurements of sand transport made in Chioggia inlet as part of an extensive monitoring programme in the Venetian inlets. Measurements were made in order: (1) to define a relationship between sand transport magnitude and tidal flow; (2) to derive the thresholds for sand transport; (3) to identify the dominant modes of transport; (4) to evaluate the concentration profiles of sand within the benthic boundary layer; (5) to compare bedload transport observations with model predictions using existent bedload formulae; and (6) to produce yearly estimates of bedload transport across the inlet. The vertical distribution of sand in the water column was sampled using modified Helley–Smith bedload samplers at three sites. Transport was found to vary according to the flow and bed grain size, with considerable temporal and spatial variability. A difference of up to three orders of magnitude in transport was observed through the inlet, with higher transport rates measured on the seaward part. The dominant mode of transport in the central inlet was suspension, while bedload was dominant in the mouths. The measured profiles of sand concentration varied with the tidal stage and seabed grain size according to the Rouse parameter (R). R was high at the inlet mouths (1<R<2), indicative of a well-developed bedload layer. The inverse movability number (W_s/U_*) was also higher at these sites and appeared to be grain size dependant. Formulae for bedload transport were tested against field data; stochastic methods such as Einstein–Brown, Engelund–Hansen and Van Rijn produce the best fits. The coupled model SHYFEM-Sedtrans05 appears to simulate well observed transport for most conditions of flow. Long-term bedload predictions indicate a dominant export of sand, with a yearly average of 4500 m³.  相似文献   

Toxicity of a secondary-treated sewage effluent to marine biota in Bass Strait, Australia: development of action trigger values for a toxicity monitoring program     

Adams MS  Stauber JL  Binet MT  Molloy R  Gregory D 《Marine pollution bulletin》2008,57(6-12):587-598

Melbourne Water's Eastern Treatment Plant (ETP) produces a secondary-treated sewage effluent which is chlorinated and discharged into Bass Strait at Boags Rocks, Victoria, Australia. Disappearance of the sensitive brown seaweed Hormosira banksii from rock platforms immediately adjacent to the shore-line discharge was identified in the early 1990s. Subsequently, Melbourne Water and CSIRO undertook an environmental impact assessment and review of land and marine effluent disposal options, which included ambient water quality monitoring, biological monitoring, bioaccumulation studies and toxicity testing of existing effluent to assess the nature and magnitude of the environmental effects. This paper presents data from the toxicity monitoring programs since 2001. Chronic toxicity testing using macroalgal germination and cell division (H. banksii), microalgal growth rate (Nitzschia closterium) and scallop larval development (Chlamys asperrima), confirmed that ammonia was the major cause of effluent toxicity. Results from this toxicity monitoring program were used to develop action trigger values for toxicity for each species, which were then used in a refined monitoring program in 2005-2007. An upgrade of the ETP is in progress to improve nitrification/denitrification in order to reduce ammonia concentrations and the toxicity of the effluent. Toxicity testing with a simulated upgraded effluent confirmed that ammonia concentrations and toxicity were reduced. Estimated "safe" dilutions of effluent, calculated using species sensitivity distributions, decreased from 1:140-300 for existing ETP effluent to 1:20 for nitrified effluent, further confirming that treatment improvements should reduce the impact on marine biota in the vicinity of the discharge.  相似文献   

The L_X–T relation and intracluster gas fractions of X-ray clusters     

Monique Arnaud  August E. Evrard 《Monthly notices of the Royal Astronomical Society》1999,305(3):631-640

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The interpretation of XUV rocket measurements of intensity ratios of solar spectral lines of the lithiumlike ions O vi,Ne viii,and Mg x     

L. Heroux  M. Cohen  Monique Malinovsky 《Solar physics》1972,23(2):369-393

A rocket borne spectrometer was flown to measure absolute intensities of extreme ultraviolet spectral lines from the three ions O vi, Ne viii, and Mg x present in the Sun. From these measurements, intensity ratios of lines from O vi, ratios of lines from Ne viii, and ratios of lines from Mg x were formed. These experimental ratios were compared with ratios calculated by using specific theoretical values of the ionization equilibrium in which dielectronic recombination was included in the processes establishing ionization balance. The effects of the electron density and temperature gradient on the temperature distribution of the flux of the spectral lines in the solar atmosphere have been taken into account in the calculations of the ratios. The agreement between the experimental and calculated ratios is good for the ions Ne viii and Mg x and satisfactory for the ion O vi for which the calculated ratio is subject to large uncertainties. A reliable measurement of the electron temperature in the lower corona was obtained from the experimental ratios for Mg x. This experimental temperature is in good agreement with the emission temperature of the spectral lines of Mg x predicted from the theoretical values of the ionization equilibrium. The design and photometric calibration of a new rocket spectrometer developed to measure the intensity ratios over the broad spectral region 50 to 1250 Å are also described.  相似文献