Hydrous olivine alteration on Mars and Earth     

Zoltn Vci  Carl B. Agee  Christopher D. K. Herd  Erin Walton  Oliver Tschauner  Karen Ziegler  Vitali B. Prakapenka  Eran Greenberg  Sylvia Monique‐Thomas 《Meteoritics & planetary science》2020,55(5):1011-1030

Hydrous alteration of olivine macrocrysts in a Martian olivine phyric basalt, NWA 10416, and a terrestrial basalt from southern Colorado are examined using SEM, EPMA, TEM, and µXRD techniques. The olivines in the meteorite contain linear nanotubes of hydrous material, amorphous areas, and fluid dissolution textures quite distinct from alteration identified in other Martian meteorites. Instead, they bear resemblance to terrestrial deuteric alteration features. The presence of the hydrous alteration phase Mg‐laihunite within the olivines has been confirmed by µXRD analysis. The cores of the olivines in both Martian and terrestrial samples are overgrown by unaltered rims whose compositions match those of a separate population of groundmass olivines, suggesting that the core olivines are xenocrysts whose alteration preceded crystallization of the groundmass. The terrestrial sample is linked to deep crustal metasomatism and the “ignimbrite flare‐up” of the Oligocene epoch. The comparison of the two samples suggests the existence of an analogous relatively water‐rich magmatic reservoir on Mars.  相似文献   

Heat flux apportionment to heterogeneous surfaces using flux footprint analysis     

彭谷亮  蔡旭晖  张宏升  李爱国  胡非 《大气科学进展》2008,25(1):107-116

Heat flux data collected from the Baiyangdian Heterogeneous Field Experiment were analyzed using the footprint method. High resolution （25 m） Landsat-5 satellite imaging was used to determine the land cover as one of four surface types： farmland, lake, wetland, or village. Data from two observation sites in September 2005 were used. One site （Wangjiazhai） was characterized by highly heterogeneous surfaces in the central area of the Baiyangdian： lake/wetland. The other site （Xiongxian） was on land with more uniform surface cover. An improved Eulerian analytical flux footprint model was used to determine “source areas” of the heat fluxes measured at towers located at each site from surrounding landscapes of mixed surface types. In relative terms results show that wetland and lake areas generally contributed most to the observed heat flux at Wangjiazhai, while farmland contributed most at Xiongxian. Given the areal distribution of surface type contributions, calculations were made to obtain the magnitudes of the heat flux from lake, wetland and farmland to the total observed flux and apportioned contributions of each surface type to the sensible and latent heat fluxes. Results show that on average the sensible heat flux from wetland and farmland were comparable over the diurnal cycle, while the latent heat flux from farmland was somewhat larger by about 30-50 W m-2 during daytime. The latent and sensible fluxes from the lake source in daytime were about 50 W m-2 and 100 W m-2 less, respectively, than from wetland and farmland. The results are judged reasonable and serve to demonstrate the potential for flux apportionment over heterogeneous surfaces.  相似文献   

Arsenic — a Review. Part II: Oxidation of Arsenic and its Removal in Water Treatment     

Monique Bissen  Fritz H. Frimmel 《洁净——土壤、空气、水》2003,31(2):97-107

In natural waters arsenic normally occurs in the oxidation states +III (arsenite) and +V (arsenate). The removal of As(III) is more difficult than the removal of As(V). Therefore, As(III) has to be oxidized to As(V) prior to its removal. The oxidation in the presence of air or pure oxygen is slow. The oxidation rate can be increased by ozone, chlorine, hypochlorite, chlorine dioxide, or H₂O₂. The oxidation of As(III) is also possible in the presence of manganese oxide coated sands or by advanced oxidation processes. Arsenic can be removed from waters by coprecipitation with Fe(OH)₃, MnO₂ or during water softening. Fixed‐bed filters have successfully been applied for the removal of arsenic.The effectiveness of arsenic removal was tested in the presence of adsorbents such as FeOOH, activated alumina, ferruginous manganese ore, granular activated carbon, or natural zeolites. Other removal technologies are anion exchange, electrocoagulation, and membrane filtration by ultrafiltration, nanofiltration or reverse osmosis.  相似文献   

Arsenic — a Review. Part I: Occurrence,Toxicity, Speciation,Mobility     

Monique Bissen  Fritz H. Frimmel 《洁净——土壤、空气、水》2003,31(1):9-18

In natural waters arsenic concentrations up to a few milligrams per litre were measured. The natural content of arsenic found in soils varies between 0.01 mg/kg and a few hundred milligrams per kilogram. Anthropogenic sources of arsenic in the environment are the smelting of ores, the burning of coal, and the use of arsenic compounds in many products and production processes in the past. A lot of arsenic compounds are toxic and cause acute and chronic poisoning. In aqueous environment the inorganic arsenic species arsenite (As(III)) and arsenate (As(V)) are the most abundant species. The mobility of these species is influenced by the pH value, the redox potential, and the presence of adsorbents such as oxides and hydroxides of Fe(III), Al(III), Mn(III/IV), humic substances, and clay minerals.  相似文献   

Speciation of Arsenic Using Chelation Solvent Extraction and High Performance Liquid Chromatography     

Shamil J. Cathum  Carl E. Brown  Alison Obenauf  Monique Punt 《洁净——土壤、空气、水》2007,35(1):71-80

Research interest in speciation of arsenic stems from its species dependent behavior in the environment and in living organisms. The complexity of the matrix to be analyzed and low concentrations of target arsenic species that may be labile or difficult to chromatogram, indicate that a suitable pre‐treatment methodology is required. This study investigated the usefulness of chelation solvent extraction – high performance liquid chromatography (CSE‐HPLC) for the speciation of arsenic in water. It involved reacting arsenic with the chelant known for its affinity towards arsenic, followed by extraction, separation, and identification of the arsenic‐chelant‐arsenic complex. Arsenic species having different physicochemical properties were investigated. Species, such as, As₂O₃, As₃O₅, KH₂AsO₄, Na₂HAsO₄, and NaAsO₂ were detected as a group of closely eluted peaks with different retention times and spectral properties, whereas, the organic arsenic species CH₃Na₂AsO₃, o‐arsanilic acid, roxarson and triphenyl arsine separated quite well on the EnviroseP‐CM HPLC column. Key method parameters, such as, type of HPLC column, composition of mobile phase and organic solvents affecting peak resolution and sensitivity were optimized. Real environmental matrices contaminated with arsenic were analyzed under varying wavelengths (λ_max = 190, 210, 220, 234, 244, and 282 nm), with good precision. Different arsenic species were detected in these samples with excellent background and signal‐to‐noise ratios demonstrating the robustness of the method. The detection limit, reproducibility, selectivity, accuracy, and dynamic range of the calibration curves were evaluated.  相似文献   

Robotic telescopes and networks: New tools for education and science     

François R. Querci  Monique Querci 《Astrophysics and Space Science》2000,273(1-4):257-272

Nowadays many telescopes around the world are automated and some networks of robotic telescopes are active or planned. Such equipment could be used for thetraining of students and for science in the Universities of DCs and of newastronomical countries, by sending them observational data via Internetor through remotely controlled telescope. It seems that it is thetime to open up for discussion with UN and ESA organizations and also withIAU, how to implement links between robotic telescopes and suchUniversities applying for collaborations. Many scientific fields couldthus be accessible to them, for example on stellar variability, near-earthobject follow-up, -ray burst counterpart tracking, and so on.  相似文献   

盐湖丰产元素与Zintl化合物(续一)          下载免费PDF全文

贾永忠  景燕  马军  岳都元  Claude Belin  Monique Tillard 《盐湖研究》2011,19(1):66-72

Zintl化合物是以Edward Zintl命名的化合物,是一类由电正性的碱金属或碱土金属与电负性的13族或14族元素形成的特殊金属间化合物。其价键模式可以是离子键、金属键和共价键共存,其中的准金属可以共价键的形式形成各种形式的离子簇,因而其结构复杂多样。这类化合物的部分阴离子簇不仅具有稳定的笼状、层状和链状结构,并且具有特殊的光、电、磁等性能,使得在半导体、催化、电极材料等方面都有应用的前景和发展潜力。介绍了几个特殊Zintl化合物体系,盐湖丰产元素在Zintl化合物中的作用,指出了含有盐湖丰产元素的Zintl化合物的应用前景和方向。  相似文献   

A geophysical transect of the Adélie Margin,East Antarctica     

Jacques Wannesson  Monique Pelras  Bernard Petitperrin  Martine Perret  Jacques Segoufin 《Marine and Petroleum Geology》1985,2(3):192-200

In 1982, a geophysical survey of the Antarctic margin, including multichannel seismic, gravity, magnetic and bathymetric surveying, was carried out off Adélie Coast-Wilkes Land and in the eastern Ross Sea. Of the 5000 km of lines recorded, 3000 km were in the Adélie Coast area. Lines ATC 101–102, approximately following meridian 138°E, show the first complete transect of the Adélie Coast margin from the Southeast Indian abyssal plain at DSDP Site 269 to the continental shelf. These lines reveal a thick sedimentary series divided into three main acoustic units by two major unconformities considered to be Upper Eocene (42 Ma) and late Oligocene (25 Ma). Oceanic or continental basement can be traced under the whole area, and the ocean-continent boundary clearly lies beneath the lower continental slope. A deep, high-amplitude, low-frequency horizon, extending under the oceanic basement for over 300 km of line, is considered to be the Moho. Our interpretation supports a recent revision be Cande and Mutter proposing an early Upper Cretaceous opening between Australia and East Antarctica.  相似文献   

Coronal and heliospheric observations of solar particle events     

Monique Pick 《Astrophysics and Space Science》1996,243(1):179-186

Observations of accelerated particle beams are used to probe the coronal and interplanetary magnetic field structures over large distances from the Sun on the order of a few AU and for various heliolatitudes. It is shown that the propagation of low energy particles is very much controled by discrete interplanetary magnetic field structures. These discrete magnetic structures are sometimes embedded within interplanetary solar wind plasma disturbances, commonly called CMEs. The connection between the corona and the interplanetary medium is discussed. These observations lead to new insights on the origin of accelerated particles detected in association with CMEs.  相似文献   

Sand transport measurements in Chioggia inlet,Venice lagoon: Theory versus observations     

Monique M. Villatoro  Carl L. Amos  Georg Umgiesser  Christian Ferrarin  Luca Zaggia  Charlotte E.L. Thompson  Daniele Are 《Continental Shelf Research》2010

This paper presents results of recent measurements of sand transport made in Chioggia inlet as part of an extensive monitoring programme in the Venetian inlets. Measurements were made in order: (1) to define a relationship between sand transport magnitude and tidal flow; (2) to derive the thresholds for sand transport; (3) to identify the dominant modes of transport; (4) to evaluate the concentration profiles of sand within the benthic boundary layer; (5) to compare bedload transport observations with model predictions using existent bedload formulae; and (6) to produce yearly estimates of bedload transport across the inlet. The vertical distribution of sand in the water column was sampled using modified Helley–Smith bedload samplers at three sites. Transport was found to vary according to the flow and bed grain size, with considerable temporal and spatial variability. A difference of up to three orders of magnitude in transport was observed through the inlet, with higher transport rates measured on the seaward part. The dominant mode of transport in the central inlet was suspension, while bedload was dominant in the mouths. The measured profiles of sand concentration varied with the tidal stage and seabed grain size according to the Rouse parameter (R). R was high at the inlet mouths (1<R<2), indicative of a well-developed bedload layer. The inverse movability number (W_s/U_*) was also higher at these sites and appeared to be grain size dependant. Formulae for bedload transport were tested against field data; stochastic methods such as Einstein–Brown, Engelund–Hansen and Van Rijn produce the best fits. The coupled model SHYFEM-Sedtrans05 appears to simulate well observed transport for most conditions of flow. Long-term bedload predictions indicate a dominant export of sand, with a yearly average of 4500 m³.  相似文献