Accumulation features of arsenic species in various fishes collected from coastal cities in Korea     

Sung-Deuk Choi  Hee-Sik Son  Minkyu Choi  Min-Kyu Park 《Ocean Science Journal》2015,50(4):741-750

In this study, 36 fish species were collected from three coastal cities in Korea to investigate levels and patterns of six arsenicals (arsenite: As (III), arsenate: As (V), arsenocholine: AsC, arsenobetaine: AsB, monomethylarsonic acid: MMA, and dimethylarsinic acid: DMA). The levels of ∑₆ As in the different fish species varied substantially, ranging from 0.02 μg As/g ww (Islaeli carp) to 9.65 μg As/g ww (Skate ray) with a median of 0.40 μg As/g ww. All the arsenicals in marine fishes showed higher levels than those in freshwater fishes due to fish feed living in saline water. Overall, marine carnivorous fishes seem to be more contaminated with arsenic. For all the fish samples, AsB (mean fraction: 90.6%) was dominant among the six arsenicals, indicating biomethylation of inorganic arsenic and accumulation of AsB. Fish species with high water contents showed elevated levels of As (III), but there was no further significant correlations between arsenicals and water/lipid contents. Concentrations of As (V) were significantly lower than those of As (III), which implies that As (V) is reduced during biomethylation of inorganic arsenic. Consequently, we hypothesize that the toxicity of arsenic (mainly derived from As (III)) can be increased by the reduction of As (V), especially for the fish species with higher water contents.  相似文献   

Relationships Between Interplanetary Coronal Mass Ejection Characteristics and Geoeffectiveness in the Rising Phase of Solar Cycles 23 and 24   总被引：1，自引：0，他引：1  

M. Bendict Lawrance  A. Shanmugaraju  Y.-J. Moon  M. Syed Ibrahim  S. Umapathy 《Solar physics》2016,291(5):1547-1560

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Effect of Excavation-Induced Groundwater Level Drawdown on Tunnel Inflow in a Jointed Rock Mass     

J. Moon  G. Fernandez 《Engineering Geology》2010,110(3-4):33-42

Analytical and empirical methods used in current engineering practice for estimating inflow rate into a tunnel do not adequately account for the effect of groundwater level drawdown which triggers changes of the flow pattern as well as reductions of the hydraulic head. When there is no reservoir or a large body of water near the tunnel alignment, the groundwater recharge above the tunnel might not be fast enough to avoid a significant excavation-induced water level drawdown. This paper provides analytical methods for estimating groundwater inflow rate taking into account the groundwater table drawdown. The proposed analytical solutions presented here compare well with field observations as well as with results from numerical analysis using distinct element method which can adequately simulate the hydro-mechanically coupled behavior of joints in a rock mass.  相似文献   

Estimation of soil weathering degree using electrical resistivity   总被引：1，自引：0，他引：1  

Younghwan Son  Myounghak Oh  Seunghak Lee 《Environmental Earth Sciences》2010,59(6):1319-1326

In this study, the electrical resistivity of soil having different chemical weathering index (CWI) was measured, and the correlation between CWI and the electrical resistivity was estimated. The electrical resistivity of soil varies with CWI of soil. The difference in the electrical resistivities of soils having different weathering degrees is clear at lower water contents. At the volumetric water contents estimated in this study, CWI could be described by a linear equation of electrical resistivity with the constants related to the volumetric water content. The findings in this study suggest that the electrical resistivity could be used as an effective alternative for estimating the weathering degree of soil.  相似文献   

Effects of natural and calcined oyster shells on Cd and Pb immobilization in contaminated soils   总被引：5，自引：0，他引：5  

Yong Sik Ok  Sang-Eun Oh  Mahtab Ahmad  Seunghun Hyun  Kwon-Rae Kim  Deok Hyun Moon  Sang Soo Lee  Kyoung Jae Lim  Weon-Tai Jeon  Jae E. Yang 《Environmental Earth Sciences》2010,61(6):1301-1308

In Korea, soils adjacent to abandoned mines are commonly contaminated by heavy metals present in mine tailings. Further, the disposal of oyster shell waste by oyster farm industries has been associated with serious environmental problems. In this study, we attempted to remediate cadmium (Cd)- and lead (Pb)-contaminated soils typical of those commonly found adjacent to abandoned mines using oyster shell waste as a soil stabilizer. Natural oyster shell powder (NOSP) and calcined oyster shell powder (COSP) were applied as soil amendments to immobilize Cd and Pb. The primary components of NOSP and COSP are calcium carbonate (CaCO₃) and calcium oxide (CaO), respectively. X-ray diffraction, X-ray fluorescence and scanning electron microscope analyses conducted in this study revealed that the calcination of NOSP at 770°C converted the less reactive CaCO₃ to the more reactive CaO. The calcination process also decreased the sodium content in COSP, indicating that it was advantageous to use COSP as a liming material in agricultural soil. After 30 days of incubation, we found that the 0.1 N HCl-extractable Cd and Pb contents in soil decreased significantly as a result of an increase in the soil pH and the formation of metal hydroxides. COSP was more effective in immobilizing Cd and Pb in the contaminated soil than NOSP. Overall, the results of this study suggest that oyster shell waste can be recycled into an effective soil ameliorant.  相似文献   

Winter precipitation variability over Korean Peninsula associated with ENSO     

Hye-Young Son  Jong-Yeon Park  Jong-Seong Kug  Jinho Yoo  Cheol-Hee Kim 《Climate Dynamics》2014,42(11-12):3171-3186

In this study, winter precipitation variability associated with the El Niño-Southern Oscillation (ENSO) over the Korean Peninsula was investigated using a 5-pentad running mean data because significant correlation pattern cannot be revealed using seasonal-mean data. It was found a considerably significant positive correlation between Niño3 sea-surface temperature and precipitation during early winter (from Mid-November to early-December), when the correlation coefficient is close to 0.8 in early-December; the correlation is distinctively weakened during late winter. It is demonstrated that such sudden intraseasonal change in relation to ENSO is associated with the presence of anticyclonic flow over the Kuroshio extension region (Kuroshio anticyclone). In early winter, there is strong southerly wind over the Korean Peninsula, which is induced by the Philippine Sea anticyclone and Kuroshio anticyclone. However, in January, although the Philippine Sea anticyclone develops further, the Kuroshio anticyclone suddenly disappears; as a result, the impact of ENSO is considerably weakened over the Korean Peninsula. These results indicate that the Kuroshio anticyclone during El Niño peak phase plays a critical role by strongly affecting Northeast Asia climate, including the Korean Peninsula. In addition, it is also found that there are distinctive interdecadal changes of the relationship between ENSO and precipitation over the Korean Peninsula. In particular, the strong correlation in early winter is clearer in the recent 30 years than that in the previous period of 1950–1979.  相似文献   

Discharge prediction using hydraulic characteristics of mean velocity equation     

Tai Ho Choo  Soo Kwon Chae  Hyeon Cheol Yoon  Yeon Moon Choo 《Environmental Earth Sciences》2014,71(2):675-683

Discharge is an important factor in river design for water utilization, water control and hydraulic structures; therefore, an accurate estimation of the discharge is required. At present, a rating curve depicting the relationship between a stage and discharge is used to calculate the discharge from river systems. Although the rating curve has an advantage in that it can predict and use the discharge during the flood season in which the measurement is difficult, there is room for improvement as it does not reflect the hydraulic characteristics of rivers. Therefore, in this study, discharge was predicted using the convenient calculation method with empirical mediating variables of the Manning and Chezy equations which were proposed by the author’s previous research as a new methodology for estimating discharge in an open channel. This was proven, based on the data measured in a meandering open channel system in a lab at the Mississippi River in the US and at the Columbia Del Dique Canal, and an accuracy level at a coefficient of 0.8 was demonstrated. Thus, this method, which reflects the hydraulic characteristics and predicts the discharge in a simple manner, is expected to be convenient in practice.  相似文献   

Effects of biochar, cow bone, and eggshell on Pb availability to maize in contaminated soil irrigated with saline water   总被引：2，自引：0，他引：2  

Yaser A. Almaroai  Adel R. A. Usman  Mahtab Ahmad  Deok Hyun Moon  Ju-Sik Cho  Young Kyoo Joo  Choong Jeon  Sang Soo Lee  Yong Sik Ok 《Environmental Earth Sciences》2014,71(3):1289-1296

Toxicity of heavy metals adversely affects environment and human health. Organic materials derived from natural matters or wastes have been applied to soils to reduce the mobility of contaminants such as heavy metals. However, the application of cow bone powder (CB), biochar (BC), and eggshell powder (ES) is rarely investigated for the reduction of Pb bioavailability in soils irrigated with saline water. The objective of this study was to assess the effectiveness of CB, BC, and ES additions as immobilizing substances on Pb bioavailability in shooting range soil irrigated with deionized and saline water. Each additive of CB, BC, and ES at 5 % (w/w) was mixed with soils and then the deionized and saline water were irrigated for 21 days. With deionized water irrigation, the soils treated with CB, BC, and ES exhibited higher pH when compared with saline water irrigation. With saline water irrigation, the electrical conductivity, water-soluble anions, and cations were significantly increased in soils treated with CB, BC, and ES. The water-soluble Pb in soils treated with CB, BC, and ES was significantly decreased with saline water irrigation. On the other hand, the water-soluble Pb in soil treated with CB was increased with deionized water irrigation. Only BC with saline water irrigation decreased the Pb concentration in maize shoots.  相似文献   

Double injection events of mafic magma into supersolidus Yucheon granites to produce two types of mafic enclaves in the Cretaceous Gyeongsang Basin,SE Korea     

Jong-Sun Kim  Moon Son  Byoung-Hoon Hwang  Ki-Cheol Shin  Hyeongseong Cho  Young Kwan Sohn 《Mineralogy and Petrology》2014,108(2):207-229

Petrographic and geochemical features of the Cretaceous Yucheon granites and their mafic microgranular/magmatic enclaves (MMEs), SE Korea, reveal that the MMEs originated from magma mixing. Mesoscopic and microscopic features indicate that mechanical mixing operated heterogeneously to produce the MMEs with a wide range of sizes and textures. Chemical compositions of amphibole, biotite, and plagioclase rims of both the MMEs and host granites are almost identical, indicating that chemical homogenization took place to some extent after the mechanical mixing. Plagioclase cores, however, have various compositions depending on the host rocks and/or sampling locations, suggesting their sluggish re-equilibration. The MMEs are divided into Type A (low TiO₂, very fine-grained, chilled margins) and Type B (high TiO₂, fine- to medium-grained, no chilled margins). The lower TiO₂ MMEs cooled more rapidly and interacted with granitic magma for a shorter period of time than the higher TiO₂ MMEs. Additionally, the former are less enriched in HREEs than the latter. Zoned plagioclase has two zones of increased An content. These features are indicative of double injection events of mafic magma. A previous model explains the magma mixing as resulting from the generation of a slab window due to Kula-Pacific ridge subduction. The model cannot, however, explain the eastward younging of the granites in Korea, necessitating a new, more elaborate model of Cretaceous geodynamics and magmatism in East Asia.  相似文献   

Characterization of spatial and temporal variation of suspended sediments in the Yellow and East China Seas using satellite ocean color data     

SeungHyun Son  Yong Hoon Kim  Hae-Cheol Kim  Kwang-Soon Park 《地理信息系统科学与遥感》2014,51(2):212-226

Total suspended sediment (TSS) data concentrations are retrieved from two sets of satellite ocean color data (the Moderate Resolution Imaging Spectroradiometer (MODIS) onboard Aqua and the Korean Geostationary Ocean Color Imager (GOCI)) using an existing regional model to characterize spatial and temporal variation of TSS in the Yellow and East China Seas. MODIS-derived TSS maps show that TSS concentrations are, in general, high along the Korean and Chinese coasts including the Bohai Sea and the Yangtz River estuary, and lower in the middle of the Yellow Sea and the southeastern area of the East China Sea. The monthly average of 10-year MODIS data reveals that TSS values are highest during winter (January to February) and lowest in summer (July to August). Short-term TSS concentrations retrieved from GOCI data showed the dominant influence of semi-diurnal tidal changes on sediment dynamics through temporal (hourly) and spatial distribution in coastal zones of the Yellow sea. The results presented here demonstrate that the satellite-derived TSS products can be utilized as an application tool for future studies on long- and short-term sediment dynamics of turbid coastal waters. In particular, GOCI observations provide unique important capabilities to characterize and quantify the water properties at high temporal (hourly) and spatial (0.5 km) resolutions in the turbid coastal waters of the Yellow Sea and its vicinities.  相似文献