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The efficacy and feasibility of using zerovalent zinc (ZVZ) to treat 1,2,3‐trichloropropane (TCP)‐contaminated groundwater was assessed in laboratory and field experiments. In the first portion of the study, the reactivity of commercially available granular ZVZ toward TCP was measured in bench‐scale batch‐reactor and column experiments. These results were used to design columns for on‐site pilot‐scale treatment of contaminated groundwater at a site in Southern California. Two of the ZVZ materials tested were found to produce relatively high rates of TCP degradation as well as predictable behavior when scaling from bench‐scale to field testing. In addition, there was little decrease in the rates of TCP degradation over the duration of field testing. Finally, no secondary impacts to water quality were identified. The results suggest that ZVZ may be an effective and feasible material for use in engineered treatment systems, perhaps including permeable reactive barriers.  相似文献   
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C.K. Morley  R. King  R. Hillis  M. Tingay  G. Backe 《Earth》2011,104(1-3):41-91
Deepwater fold and thrust belts (DWFTBs) are classified into near-field stress-driven Type 1 systems confined to the sedimentary section, and Type 2 systems deformed by either far-field stresses alone, or mixed near- and far-field stresses. DWFTBs can occur at all stages of the Wilson cycle up to early stage continent continent collision. Type 1 systems have either weak shale or salt detachments, they occur predominantly on passive margins but can also be found in convergent-related areas such as the Mediterranean and N. Borneo. Examples include the Niger and Nile deltas, the west coast of Africa, and the Gulf of Mexico. Type 2 systems are subdivided on a tectonic setting basis into continent convergence zones and active margin DWFTBs. Continent convergence zones cover DWFTBs developed during continent–arc or continent–continent collision, and those in a deepwater intracontinental setting (e.g. W. Sulawesi, Makassar Straits). Active margins include accretionary prisms and transform margins. The greatest variability in DWFTB structural style occurs between salt and shale detachments, and not between tectonic settings. Changes in fold amplitude and wavelength appear to be more related to thickness of the sedimentary section than to DWFTB type. In comparison with shale, salt detachment DWFTBS display a lower critical wedge taper, more detachment folds, long and episodic duration of deformation and more variation in vergence. Structures unique to salt include canopies and nappes. Accretionary prisms also standout from other DWFTBs due to their relatively long, continuous duration, rapid offshore propagation of the thrust front, and large amount of shortening. In terms of petroleum systems, many similar issues affect all DWFTBs, these include: the oceanward decrease in heat flow, offshore increase in age of mature source rock, and causes of trap failure (e.g. leaky oblique and frontal thrust faults, breach of top seal by fluid pipes). One major difference between Type 1 and Type 2 systems is reservoir rock. High quality, continent-derived, quartz-rich sandstones are generally prevalent in Type 1 systems. More diagenetically reactive minerals derived from igneous and ophiolitic sources are commonly present in Type 2 systems, or many are simply poor in well-developed turbidite sandstone units. However, some Type 2 systems, particularly those adjacent to active orogenic belts are partially sourced by high quality continent-derived sandstones (e.g. NW Borneo, S. Caspian Sea, Columbus Basin). In some cases very high rates of deposition in accretionary prisms adjacent to orogenic belts, coupled with uplift due to collision, results in accretionary prism related fold belts that pass laterally from sub-aerial to deepwater conditions (e.g. S. Caspian Sea, Indo-Burma Ranges). The six major hydrocarbon producing regions of DWFTBs worldwide (Gulf of Mexico, Niger Delta, NW Borneo, Brazil, West Africa, S. Caspian Sea) stand out as differing from most other DWFTBs in certain fundamental ways, particularly the very large volume of sediment deposited in the basins, and/or the great thickness and extent of salt or overpressured shale sdetachments.  相似文献   
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Using modern pollen and radiolarian distributions in sediments from the northwest Pacific and seas adjacent to Japan to interpret floral and faunal changes in core RC14-103 (44°02′N, 152°56′E), we recognize two major responses of the biota of eastern Hokkaido and the northwest Pacific to climatic changes since the last interglaciation. Relatively stable glacial environments (~80,000–20,000 yr B.P.) were basically cold and wet (<4°C and ~1000 mm mean annual temperature and precipitation, respectively) with boreal conijers and tundra/park-tundra on Hokkaido, and cool (<16°C) summer and cold (<1.0°C) winter surface temperatures offshore. Contrasting nonglacial environments (~10,000–4000 yr B.P.) were warm and humid (>8°C and >1200 mm mean annual temperature and precipitation, respectively), supporting climax broadleaf deciduous forest with Quercus and Ulmus/Zelkova, with surface waters in the northwest Pacific characterized by warm (>1.5°C) winter and cold (10.4°–14.3°C) summer temperatures. Climatic evidence from RC14-103 shows a high degree of local and regional variation within the context of global climatic change. Correlative ocean and land records provide the detailed input necessary to assess local/regional responses to variations in other key elements (i.e., solar radiation, monsoonal variations) of the northeast Asian climate system.  相似文献   
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The vertical or lithostatic stress is an important factor in tectonic and geomechanical studies and is commonly used in the prediction of pore pressures and fracture gradients. However, the vertical stress is not always calculated in situ and the approximation of 1.0 psi/ft (22.63 MPa/km) is often used for the vertical stress gradient. Vertical stress has been determined in 24 fields in the Baram Basin, Brunei, using density log and checkshot velocity survey data. The Baram Basin shows a variation in vertical stress gradient between 18.3 and 24.3 MPa/km at 1500 m depth below the surface. This variation has a significant effect on in situ stress related issues in field development such as wellbore stability and fracture stimulation. The variation is caused by a bulk rock density change of 2.48–2.07 g/cm3 from the hinterland of the delta to its front. Differential uplift and erosion of the delta hinterland and undercompaction associated with overpressure are the interpreted causes of the density and hence vertical stress variation.  相似文献   
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