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12.
Motoo Ukawa 《Earth and Planetary Science Letters》1979,43(3):434-440
Composite P-wave seismograms are constructed for intermediate earthquakes in the Kurile region using seismic stations in central and western Japan. Ray paths are approximately parallel to the intermediate seismic zone along the Kurile-Japan arc. A compressional velocity structure model is constructed from the travel time and relative amplitude data for the upper mantle involving this intermediate seismic zone. The absence of any significant low-velocity layer below the descending slab of lithosphere can be shown from the data. Instead, the model consistent with the observed data has a non-velocity gradient layer of about 30 km thickness beneath the descending slab. The result suggests that the low-velocity layer beneath the Pacific plate thins landward across the Kurile-Japan trench and does not descend along the base of the descending slab. 相似文献
13.
The oxygen isotopic micro-distributions within and among minerals in a coarse-grained Ca, Al-rich inclusion (CAI), 7R-19-1 from the Allende meteorite, were measured by in situ using secondary ion mass spectrometry (SIMS). All values of O isotopic ratios in 7R-19-1 minerals fall along the carbonaceous chondrite anhydrous mineral mixing (CCAM) line on a δ17OSMOW vs. δ18OSMOW plot. Major refractory minerals (spinel, fassaite and melilite) in 7R-19-1 showed large negative anomalies of Δ17O in the order, spinel (−21‰) > 16O-rich melilite (∼−18‰) > fassaite (−15 to +1‰) > 16O-poor melilite (−8 to +2‰). However, the lower limit values of Δ17O are similar at about −21‰, a value commonly observed in CAIs. The similarity in the extreme values of the isotope anomaly anomalies suggests that crystallization of all CAIs started from an 16O enrichment of 21‰ (Δ17O) relative to terrestrial values. The order of the O isotopic anomalies observed for 7R-19-1, except for 16O-poor melilite, is parallel to the crystallization sequence determined by experiment from CAI liquid (Stolper, 1982), indicating that the O isotopic exchange in 7R-19-1 occurred between CAI melt and surrounding gas while 7R-19-1 was crystallizing from the 16O enriched CAI liquid (∼−21‰ in Δ17O) in the 16O-poor solar nebula. However, the a single crystallization sequence during the cooling stage cannot explain the existence of 16O-poor melilite. The presence of 16O-poor melilite suggests that multiple heating events occurred during CAI formation. The sharp contact between 16O-rich and 16O-poor melilite crystals and within 16O-rich melilite indicates that these multiple heatings occurred quickly. Based on the O isotopic and chemical compositions, fassaite crystals were aggregates of relic crystals formed from CAI melt whichthat have had various O isotopic compositions from the remelting processes. The results of intra-mineral distributions of O isotopes also support multiple heating events during CAI formation. 相似文献
14.
In situ X-ray observations of the coesite-stishovite transition: reversed phase boundary and kinetics 总被引：1，自引：1，他引：1
Jianzhong Zhang Baosheng Li Wataru Utsumi Robert C. Liebermann 《Physics and Chemistry of Minerals》1996,23(1):1-10
Using a DIA-type, cubic-anvil, high-pressure apparatus (SAM-85) in conjunction with in situ X-ray diffraction, we have investigated phase relations between coesite and stishovite up to 12 GPa and 1530 °C using synthetic powders of the two phases as the starting materials. The phase transition between coesite and stishovite was identified by observing the first appearance of a phase that did not already exist or by a change in the relative intensity of the two patterns. In most experiments, the diffraction patterns on samples were collected within 10 minutes after reaching a pressure and temperature condition. On this time scale, two phase boundaries associated with the coesite-stishovite transition have been determined: (1) for the stishovite-to-coesite transition, observations were made in the temperature range of 950–1530 °C, and (2) for the coesite-to-stishovite transition from 500 to 1300 °C. These observations reveal that there exists a critical temperature of about 1000 °C to constrain the coesite-stishovite equilibrium phase boundary. Above this temperature, both boundaries are linear, have positive dP/dT slopes, and lie within a pressure interval of 0.4 GPa. Below this temperature, the dP/dT slope for the stishovite-to-coesite phase boundary becomes significantly larger and that for the coesite-tostishovite phase boundary changes from positive to negative. As a result, an equilibrium phase boundary can only be determined from the results above 1000 °C and is described by a linear equation P (GPa)=6.1 (4)+ 0.0026 (2) T (°C). This dP/dT slope is in good agreement with that of Zhang et al. (1993) but more than twice that of Yagi and Akimoto (1976). For the kinetics of the phase transition, preliminary rate data were obtained for the stishovite-to-coesite transition at 1160 and 1430 °C and are in agreement with the simple geometric transformation model of Avrami and Cahn. 相似文献
15.
S. Ono E. Ito T. Katsura A. Yoneda M. J. Walter S. Urakawa W. Utsumi K. Funakoshi 《Physics and Chemistry of Minerals》2000,27(9):618-622
In situ synchrotron X-ray experiments in the system SnO2 were made at pressures of 4–29 GPa and temperatures of 300–1400 K using sintered diamond anvils in a 6–8 type high-pressure
apparatus. Orthorhombic phase (α-PbO2 structure) underwent a transition to a cubic phase (Pa3ˉ structure) at 18 GPa. This transition was observed at significantly lower pressures in DAC experiments. We obtained the
isothermal bulk modulus of cubic phase K
0 = 252(28) GPa and its pressure derivative K
′=3.5(2.2). The thermal expansion coefficient of cubic phase at 25 GPa up to 1300 K was determined from interpolation of the
P-V-T data obtained, and is 1.7(±0.7) × 10−5 K−1 at 25 GPa.
Received: 7 December 1999 / Accepted: 27 April 2000 相似文献
16.
K. Kuroda T. Irifune T. Inoue N. Nishiyama M. Miyashita K. Funakoshi W. Utsumi 《Physics and Chemistry of Minerals》2000,27(8):523-532
Determination of the phase boundary between ilmenite and perovskite structures in MgSiO3 has been made at pressures between 18 and 24 GPa and temperatures up to 2000 °C by in situ X-ray diffraction measurements
using synchrotron radiation and quench experiments. It was difficult to precisely define the phase boundary by the present
in situ X-ray observations, because the grain growth of ilmenite hindered the estimation of relative abundances of these phases.
Moreover, the slow reaction kinetics between these two phases made it difficult to determine the phase boundary by changing
pressure and temperature conditions during in situ X-ray diffraction measurements. Nevertheless, the phase boundary was well
constrained by quench method with a pressure calibration based on the spinel-postspinel boundary of Mg2SiO4 determined by in situ X-ray experiments. This yielded the ilmenite-perovskite phase boundary of P (GPa) = 25.0 (±0.2) – 0.003
T (°C) for a temperature range of 1200–1800 °C, which is generally consistent with the results of the present in situ X-ray
diffraction measurements within the uncertainty of ∼±0.5 GPa. The phase boundary thus determined between ilmenite and perovskite
phases in MgSiO3 is slightly (∼0.5 GPa) lower than that of the spinel-postspinel transformation in Mg2SiO4.
Received: 19 May 1999 / Accepted: 21 March 2000 相似文献
17.
Masayuki Uesugi Motoo Ito Hikaru Yabuta Hiroshi Naraoka Fumio Kitajima Yoshinori Takano Hajime Mita Yoko Kebukawa Aiko Nakato Yuzuru Karouji 《Meteoritics & planetary science》2019,54(3):638-666
Carbonaceous materials in the sample catcher of the Hayabusa spacecraft were assigned as category 3 particles. We investigated the category 3 particles with a suite of in situ microanalytical methods. Possible contaminants collected from the cleanrooms of the spacecraft assembly and extraterrestrial sample curation center (ESCuC) were also analyzed in the same manner as category 3 particles for comparison. Our data were integrated with those of the preliminary examination team for category 3 particles. Possible origins for the category 3 particles include contamination before and after the operation of the Hayabusa spacecraft. 相似文献
18.
It has been often accepted that rising troposphere temperatures will lead to higher precipitation intensities. This argument is based on the Clausius?CClapeyron (C?CC) relation, which indicates an increase in atmospheric moisture storage capacity of approximately 7?% K?1. However, recent studies carried out in mid-latitude regions indicate that changes in precipitation intensity as a function of temperature do not necessarily follow the C?CC relation. This study aimed to evaluate the correlation between precipitation extremes and temperature in tropical regions, using measured data obtained at low latitude ranges over Brazil. The results indicate that, at daily timescale, the C?CC relation alone is unlikely to explain the relation between precipitation extremes and temperatures in tropical regions. Additional aspects, such as moisture availability and the duration of precipitation events, should be further analyzed to allow a comprehensive understanding of the relationship between temperature and precipitation intensity. Moreover, we show that in tropical regions, higher temperatures may reduce the magnitude of extreme precipitation events at daily timescales, independent of the season of the year. 相似文献
19.
Abstract— Among the calcium‐aluminum‐rich inclusions (CAIs), excess 41K (41K*), which was produced by the decay of the short‐lived radionuclide 41Ca (t1/2 = 0.1 Myr), has so far been detected in fassaite and in two grains of melilites. These observations could be used to provide important constraints on the thermal history and size of the planetesimals into which the CAIs were incorporated, provided the diffusion kinetic properties of K in these minerals are known. Thus, we have experimentally determined K diffusion kinetics in the melilite end‐members, åkermanite and gehlenite, as a function of temperature (900–1200 °C) and crystallographic orientation at 1 bar pressure. The closure temperature of K diffusion in melilite, Tc(K:mel), for the observed grain size of melilite in the CAIs and cooling rate of 10–100 °C/Myr, as calculated from our diffusion data, is much higher than that of Mg in anorthite. The latter was calculated from the available Mg diffusion data in anorthite. Assuming that the planetesimals were heated by the decay of 26Al and 60Fe, we have calculated the size of a planetesimal as a function of the accretion time tf such that the peak temperature at a specified radial distance rc equals Tc(K:mel). The ratio (rc/R)3 defines the planetesimal volume fraction within which 41K* in melilite grains would be at least partly disturbed, if these were randomly distributed within a planetesimal. A similar calculation was also carried out to define R versus tf relation such that 26Mg* was lost from ?50% of randomly distributed anorthite grains, as seems to be suggested by the observational data. These calculations suggest that ?60% of melilite grains should retain 41K* if ?50% of anorthite grains had retained 26Mg*. Assuming that tf was not smaller than the time of chondrule formation, our calculations yield minimum planetesimal radius of ?20–30 km, depending on the choice of planetesimal surface temperature and initial abundance of the heat producing isotope 60Fe. 相似文献
20.
T. Okada W. Utsumi H. Kaneko M. Yamakata O. Shimomura 《Physics and Chemistry of Minerals》2002,29(7):439-445
An experimental technique to make real-time observations at high pressure and temperature of the diamond-forming process
in candidate material of mantle fluids as a catalyst has been established for the first time. In situ X-ray diffraction experiments
using synchrotron radiation have been performed upon a mixture of brucite [Mg(OH)2] and graphite as starting material. Brucite decomposes into periclase (MgO) and H2O at 3.6 GPa and 1050 °C while no periclase is formed after the decomposition of brucite at 6.2 GPa and 1150 °C, indicating
that the solubility of the MgO component in H2O greatly increases with increasing pressure. The conversion of graphite to diamond in aqueous fluid has been observed at
7.7 GPa and 1835 °C. Time-dependent X-ray diffraction profiles for this transformation have been successfully obtained.
Received: 17 July 2001 / Accepted: 18 February 2002 相似文献