The oxidation state of manganese in marine sediments and ferromanganese nodules     

James W Murray  Laurie S Balistrieri  Barbara Paul 《Geochimica et cosmochimica acta》1984,48(6):1237-1247

Marine sediments and ferromanganese nodules from the Pacific Ocean have been analyzed for the $\text{O}\text{Mn}$ ratio of solid manganese. We tested six chemical methods and concluded that the iodometric and oxalate methods were equivalent and were the best choice in terms of accuracy and precision on natural samples. We choose the iodometric method for most of our analyses because the oxalate procedure is a method of differences.The ferromanganese nodules that we analyzed were all from MANOP site H and had $\text{Mn}\text{Fe}$ ratios that ranged from 5.6 to 70. These nodules were invariably highly oxidized with $\text{O}\text{Mn}$ values ranging from 1.90 to 2.00. Our most precise analyses suggest that less than 1% of the total manganese is present as Mn(II).We also analyzed red clay and hemipelagic sediments from the eastern tropical Pacific (Baja borderland and MANOP site H) and carbonate ooze samples from the equatorial Pacific. These sediments are also highly oxidized ($\text{O}\text{Mn}\text{= 1.90 to 2.00}$) except when Mn(II) appears in the interstitial water. As dissolved Mn(II) increases the value of the $\text{O}\text{Mn}$ ratio in the solid phase decreases. The $\text{O}\text{Mn}$ ratio decreases to values as low as 1.40. This decrease appears to be due to a decrease in oxidized manganese by reduction, however, an increase in reduced manganese in the solid sediments by adsorption or MnCO₃ formation can not be ruled out in all cases.  相似文献   

Modelling the effect of vegetation on channel pattern in bedload rivers     

A. Brad Murray  Chris Paola 《地球表面变化过程与地形》2003,28(2):131-143

We modify a simple numerical stream‐pattern model to examine the effect of sediment stabilization by roots on the channel pattern of bedload rivers. In the model, vegetation enhances bank resistance to erosion, causing the development of a single channel instead of a rapidly changing, multiple channel (braided) pattern. Net aggradation resulting from a high sediment supply, however, causes frequent avulsions that destroy vegetation locally, leading to the development of a multiple‐channel pattern. A stability diagram representing multiple model runs predicts whether a river will exhibit single or multiple channels, based on plant‐enhanced bank strength, and on the time scale of plant development relative to a time scale for change in unvegetated channels. A second stability diagram predicts the way in which the amplitude and period of a fluctuating imposed sediment load influence whether a single or multiple‐channel pattern develops. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Assessing representation error in point-based coverage modeling   总被引：2，自引：1，他引：2  

Alan T. Murray  Morton E. O'Kelly 《Journal of Geographical Systems》2002,4(2):171-191

 Accurately representing geographic space in a digital environment continues to confound and challenge researchers. Carrying out spatial analysis in a setting where geographic representation is subject to change poses problems to be addressed. In this paper we examine spatial representation in the context of coverage-based location modeling. A geographic region can be represented in a variety of ways. We present an evaluation of spatial representation in the location of facilities that provide coverage oriented services. The analysis shows that the modeling results are sensitive to how spatial demand for service is represented in a digital environment. We develop an approach for evaluating representational appropriateness. This research contributes to spatial analysis integrated in geographic information system environment. Received: 10 January 2001 / Accepted: 8 April 2002  相似文献   

Electrons in feldspar I: on the wavefunction of electrons trapped at simple lattice defects     

N. R. J. Poolton  J. Wallinga  A. S. Murray  E. Bulur  L. Bøtter-Jensen 《Physics and Chemistry of Minerals》2002,29(3):210-216

 The purpose of this article is to make an initial consideration of the physical properties of electrons trapped at classic hydrogenic lattice defects in feldspar. We are particularly interested to determine the radial extent of the electron wavefunctions in the ground and excited states. It is shown that for NaAlSi₃O₈, the ground-state wavefunction is expected to be confined well within a single lattice unit cell, but the first excited state is far more extensive, being spread over several unit cells. This aspect is of direct relevance to understanding the nature of various luminescence processes in the materials. Under low-energy optical stimulation (hν∼ 1.4 eV), luminescence can be a competitive process between direct electron-hole tunnelling recombination (with the charge still trapped at the defect sites), and free-to-bound recombination (after the excited state electron accesses the conduction band). We show that analysis of the thermal behaviour of the luminescence can be used to separate the two processes. Received: 6 March 2001 / Accepted: 6 September 2001  相似文献   

Outback Elvis: the story of a festival,its fans,and a town called Parkes     

Warwick Murray 《The Australian geographer》2019,50(2):265-267

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Evaluation and development of sustainable urban land use plans through spatial optimization     

Jing Yao  Alan T. Murray  Jing Wang  Xiaoxiang Zhang 《Transactions in GIS》2019,23(4):705-725

Along with rapid global urbanization, cities are challenged by environmental risks and resource scarcity. Sustainable urban planning is central to address the dilemma of economic growth and ecosystem protection, where the use of land is critical. Sustainable land use patterns are spatially explicit in nature, and can be structured and addressed using spatial optimization integrating GIS and mathematical models. This research discusses prominent sustainability concerns in land use planning and suggests a generalized multi‐objective spatial optimization model to facilitate conventional planning. The model is structured to meet land use demand while satisfying the requirements of the physical environment, society and economy. Unlike existing work relying on raster data, due to its simple data structure and ease of spatial relationship evaluation, this research develops an approach for identifying land use solutions based on vector data that better reflects the actual shape and spatial layout of land parcels as well as the ways land use information is managed in practice. An evolutionary algorithm is developed to find the set of efficient (Pareto) solutions given the complexity of vector‐based representations of space. The proposed approach is applied in an empirical study of Dafeng, China in order to support local urban growth and development. The results demonstrate that spatial optimization can be a powerful tool for deriving effective and efficient land use planning strategies. A comparison to results using a raster data approach supports the superiority of land use optimization using vector data as part of planning practice.  相似文献   

Movement patterns of an endemic South African sparid,the black musselcracker Cymatoceps nasutus,determined using mark-recapture methods     

TS Murray  PD Cowley  BQ Mann  JQ Maggs  G Gouws 《African Journal of Marine Science》2019,41(1):71-81

This study made use of data from three long-term fish tagging projects along the South African coastline to investigate the movement behaviour of the endemic black musselcracker Cymatoceps nasutus (Sparidae). From 1984 to 2016, a total of 3 430 C. nasutus (178–980 mm fork length) were tagged (with small plastic dart tags) throughout the species’ distributional range, with an overall reported recapture rate of 7.2%. Recaptured individuals displayed high levels of residency, moving an average of 14.8 km, with time-at-liberty ranging from 0 to 6 809 days. The majority of recaptures (84.6%) were made within 1 km of the tagging sites; however, some large-scale movements, of up to 528 km, were recorded. Although C. nasutus individuals moving greater distances were characterised by greater mean sizes (mm fork length) at time of recapture, the distances moved by juveniles were not significantly different from those of adults (p > 0.05). Low levels of connectivity among coastal regions were therefore expected due to the high degree of residency displayed by this species. Combining traditional management approaches together with a well-designed network of no-take marine protected areas is likely to be the most effective way to protect this vulnerable species. A lack of data on the movements of adults remains a challenge, but this could be overcome by tracking large individuals tagged with long-life acoustic transmitters.  相似文献   

Using ichnological relationships to interpret heterolithic fabrics in fluvio-tidal settings     

Scott Melnyk  Murray K. Gingras 《Sedimentology》2020,67(2):1069-1083

In fluvio-tidal settings, the sediment is dominantly derived from the river systems. However, the importance of landward tidal transport of sediment in tidally influenced sedimentary environments is difficult to assess, particularly in the rock record. This problem is addressed using two intervals within the Lower Cretaceous McMurray Formation, each representing a distinct inclined heterolithic stratification motif. The ichnological variation between the heterolithic intervals is analyzed to determine which lithosomes are associated with brackish-water (tidally influenced) colonization windows. From this, the relative fluvial influence responsible for the deposition of the fine and coarse members can be determined. Both of the inclined heterolithic stratification fabrics studied record the deposition of fluvio-tidal point bars wherein the heterolithic bedding represents variations in river discharge. The first fabric comprises inclined heterolithic stratification in which bioturbation only occurs in mudstone beds. This fabric indicates that deposition occurred in more proximal positions within a fluvio-tidal system (i.e. the outermost inner to middle estuary or distributary channels). In this example sand deposition is interpreted to represent high-energy, freshwater dune migration within a fluvial-dominated setting, whereas mud beds reflect brackish-water suspension deposition during times of low river discharge. The second fabric, which is interpreted to have developed in more distal depositional positions (i.e. the middle estuary or seaward of the turbidity maximum in deltas), consists of inclined heterolithic stratification with laminated mudstone and bioturbated sandstone. In these inclined heterolithic stratification successions the mudstone beds were deposited under the influence of freshwater and heightened sedimentation rates, whereas bioturbated sandstone was colonized under brackish-water conditions and in the presence of tidally facilitated sediment transport. In both examples, the bioturbated lithosomes are related to colonization windows that indicate the predominance at that time of marine or tidally influenced processes over fluvial processes.  相似文献   

International cooperation among nation-states of the North Pacific Ocean on the problem of competition among salmon for a common pool of prey resources     

Carrie A. Holt  Murray B. Rutherford  Randall M. Peterman 《Marine Policy》2008,32(4):607-617

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Development of a regional neural network for coastal water level predictions   总被引：2，自引：0，他引：2  

Wenrui Huang  Catherine Murray  Nicholas Kraus  Julie Rosati 《Ocean Engineering》2003,30(17):2275-2295

This paper presents the development of a Regional Neural Network for Water Level (RNN_WL) predictions, with an application to the coastal inlets along the South Shore of Long Island, New York. Long-term water level data at coastal inlets are important for studying coastal hydrodynamics sediment transport. However, it is quite common that long-term water level observations may be not available, due to the high cost of field data monitoring. Fortunately, the US National Oceanographic and Atmospheric Administration (NOAA) has a national network of water level monitoring stations distributed in regional scale that has been operating for several decades. Therefore, it is valuable and cost effective for a coastal engineering study to establish the relationship between water levels at a local station and a NOAA station in the region. Due to the changes of phase and amplitude of water levels over the regional coastal line, it is often difficult to obtain good linear regression relationship between water levels from two different stations. Using neural network offers an effective approach to correlate the non-linear input and output of water levels by recognizing the historic patterns between them. In this study, the RNN_WL model was developed to enable coastal engineers to predict long-term water levels in a coastal inlet, based on the input of data in a remote NOAA station in the region. The RNN_WL model was developed using a feed-forwards, back-propagation neural network structure with an optimized training algorithm. The RNN_WL model can be trained and verified using two independent data sets of hourly water levels.The RNN_WL model was tested in an application to Long Island South Shore. Located about 60–100 km away from the inlets there are two permanent long-term water level stations, which have been operated by NOAA since the1940s. The neural network model was trained using hourly data over a one-month period and validated for another one-month period. The model was then tested over year-long periods. Results indicate that, despite significant changes in the amplitudes and phases of the water levels over the regional study area, the RNN_WL model provides very good long-term predictions of both tidal and non-tidal water levels at the regional coastal inlets. In order to examine the effects of distance on the RNN_WL model performance, the model was also tested using water levels from other remote NOAA stations located at longer distances, which range from 234 km to 591 km away from the local station at the inlets. The satisfactory results indicate that the RNN_WL model is able to supplement long-term historical water level data at the coastal inlets based on the available data at remote NOAA stations in the coastal region.  相似文献