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91.
Synthetic seismograms (P-SV and SH waves) have been calculated along six profiles in Santiago de Cuba basin, with a cutoff frequency of 5 Hz, by using a hybrid approach (modal summation for a regional 1D structure plus finite differences for a local 2D structure embedded in the first). They correspond to a scenario earthquake of MS=7 that may occur in Oriente fault zone, directly south of the city. As initial data for a seismic microzoning, the characterisation of earthquake effects has been made considering several relative (2D/1D) quantities (PGDR, PGVR, PGAR, DGAR, IAR—ratios of peak ground values of displacement, velocity and acceleration, and of design ground acceleration and Arias intensity-, etc.) and functions representative of the ground motion characteristics in soil (2D) with respect to bedrock (1D). The functions are the response spectra ratio RSR(f), already routinely used in this kind of work, and the elastic energy input ratio EIR(f), defined, for the first time, in this paper. These data, sampled at 115 sites within all the profiles have been classified in two steps, using logical combinatory algorithms: connected components and compact sets. In the first step, from the original ground motion parameters or functions extracted from the synthetic seismograms, nine sets have been classified and the partial results show the spatial distribution of the soil behaviour as a function of the component of motion. In the second step, the results of the classification of the nine sets have been used as input for a further classification that shows a spatial distribution of sites with a quasi-homogeneous integral ground motion behaviour. By adding the available geological surface data, a microzoning scheme of Santiago de Cuba basin has been obtained.  相似文献   
92.
A water reservoir constructed for production of hydraulic energy and drinking water in the Riaño valley (León, northern Spain) receives leachates from polluted soils and spoil heaps from a site where small-scale As mining and smelting operations have been developed in the first half of the twentieth century. Water of the upper catchments of the Esla, Yuso and Orza Rivers is stored in this reservoir. The location of these abandoned mine works within the reservoir drainage basin suggested that the stored water could contain high As concentrations. In order to evaluate possible environmental risks, a preliminary soil and surface water geochemical survey has been carried out downstream of the Santa Águeda Mine. Total As concentrations in soils reach 23,800 mg kg?1 in soils and increase with depth, at least up to a depth of 80 cm. Total As concentrations in surface waters reach 890 μg l?1. Despite the fact that there is an important As input to the water reservoir, the water flow from the mine catchment is a negligible contribution when compared with the total volume of water inside the dam (0.07%). This fact considerably decreases the environmental risk associated with the presence of untreated spoil heaps containing As-rich minerals at Santa Águeda mine site.  相似文献   
93.
Several goethites were obtained through the hydrolysis at 60 °C of Fe(III) solutions containing variable amounts of Mn(II) ions. The obtained samples were thermally treated at temperatures ranging from 180 to 310 °C until the complete phase transformation to hematite was achieved. The effect of Mn in the dehydroxylation process was investigated using X-ray diffraction (XRD) and the Rietveld refinement of XRD data together with scanning electron microscopy (SEM), differential thermogravimetric analysis (DTA) and Fourier transform infrared spectroscopy (FTIR). In all cases, the formed hematites retained the acicular shape of the precursor goethite. The dehydroxylation temperature increased with the increase of the Mn content in the parent goethite. The cell parameters of both phases decreased with the thermal treatment, however the decrease in the goethite b-parameter was more pronounced. This fact could be attributed to the distortion in the goethite structure by the presence of manganese. The band shifts in the FT-IR spectra of the goethites with different Mn substitution were analysed. The intensities of the hydroxyl vibrations were indicative of the degree of dehydroxylation.The chemical reactivity of all the samples, before and after the thermal treatment, was also studied. The kinetic experiments were carried out at 40 °C in 4 mol dm− 3 HCl. The acid dissolution of all Mn-goethites showed a congruent behavior indicative of a homogeneous distribution of Mn in the goethite crystals, this trend was not observed in the formed hematites presenting a high Mn content. The dissolution rate in goethites increased with the increase of Mn content, the opposite effect was observed in the corresponding hematites. The activation energy in both phases was also obtained and indicated that the Mn substitution produces an opposite effect on goethite- and hematite-phases. Different kinetic laws were applied in order to explain the dissolution behavior, but the modified first-order Kabai equation described the dissolution data best.  相似文献   
94.
In this paper we propose a continuous spatio-temporal model that describes population change in a region in terms of population growth, migration drift towards regions with better economic or climate conditions, and population diffusion from more populated to less populated areas. Finite-differences are used to approximate the space and time derivatives. The model is estimated by using population data from the US census corresponding to the period 1790–1910. People tend to migrate from east to west, and to relocate towards regions with lower precipitation levels and more abundant coal and iron resources. Also population growth tends to be larger in zones with higher precipitation levels and higher temperatures.  相似文献   
95.
Type III bursts were observed between 3.5 MHz and 50 kHz by the University of Michigan radio astronomy experiment aboard the OGO-5 satellite.Decay times were measured and then combined with published data ranging up to about 200 MHz. The observed decay times increase with decreasing frequency but at a rate considerably slower than that expected from electron-proton Coulomb collisions. At 50 kHz values differ by about a factor of 100. Using Hartle and Sturrock's solar wind model, Coulomb collisional frequencies were computed and compared with the apparent collisional frequencies deduced from the observations. It was found that the ratio of observed to computed values varies with heliocentric distance according to an inverse 0.71 power. This is similar to an ad hoc function used by Wolff, Brandt, and Southwick to increase the electron-proton collisional energy exchange and make the solar wind theory agree with the measurements of electron and proton temperature near the Earth. These results may provide a clue about the nature of the non-collisional plasma wave damping process responsible for the short duration of type III bursts.  相似文献   
96.
97.
We develop a Riemann solver for transport problems including geochemistry related to oil recovery. The example considered here concerns one-dimensional incompressible flow in porous media and the transport for several chemical components, namely H2O, H+, OH?, CO2, \(\text {CO}_{3}^{2-}\), \(\text {HCO}_{3}^{-}\), and decane; they are in chemical equilibrium in the aqueous and oleic phases, leading to mass transfer of CO2 between the oleic and aqueous phases. In our ionic model, we employ equations with zero diffusion coefficients. We do so because it is well known that for upscaled equations, the convection terms dominate the diffusion terms. The Riemann solution for this model can therefore be applied for upscaled transport processes in enhanced oil recovery involving geochemical aspects. In our example, we formulate the conservation equations of hydrogen, oxygen, hydrogen, and decane, in which we substitute regression expressions that are obtained by geochemical software. This can be readily done because Gibbs phase rule together with charge balance shows that all compositions can be rewritten in terms of a single composition, which we choose to be the hydrogen ion concentration (p H). In our example, we use the initial and boundary conditions for the carbonated aqueous phase injection in an oil reservoir containing connate water with some carbon dioxide. We compare the Riemann solution with a numerical solution, which includes capillary and diffusion effects. The significant new contribution is the effective Riemann solver we developed to obtain solutions for oil recovery problems including geochemistry and a variable total Darcy velocity, a situation in which fractional flow theory does not readily apply. We thus obtain an accurate solution for a carbonated waterflood, which elucidates some mechanisms of low salinity carbonated waterflooding.  相似文献   
98.
According to various historical sources an earthquake and an associated tsunami wiped out the Greek city of Helike on the Gulf of Corinth in 373 B.C. This study combines stratigraphical data from a new series of sediment cores with archaeological findings of the Helike Project to better assess the fate of Helike. Abrupt lithological changes, for example, from coarse‐grained littoral facies at the base to fine‐grained lagoonal deposits, in three of the new cores suggest sudden formation of lagoonal or lacustrine conditions in the central delta during tectonic events of subsidence due to fault‐slip. These events date before c. 2550 B.C., before 348 cal. B.C.–64 cal. A.D. (probably 373 B.C.), and before 1437–1634 cal. A.D. (probably A.D. 1402). Vertically displaced isochronic surfaces between two neighboring cores may be related to active faulting of the fan‐delta north of the Western Helike Fault Zone in 373 B.C. and A.D. 1402. Although the Helike Project reported possible tsunami evidence in earlier cores and trenches, no unequivocal sedimentary traces of a tsunami were identified in the Classical horizons of the new cores.  相似文献   
99.
100.
Egg identification in plankton samples is usually needed for purposes of stock assessment. Until recently, only morphological characters were used for identifying the eggs of different fish species. Late developmental stages are easily distinguishable due to pigmentation as well as egg and oil globule size range. However, for early stages, these characteristics are difficult to be discriminated and may overlap with other species. European horse mackerel species (Trachurus trachurus, T. mediterraneus, T. picturatus) overlap significantly in their spawning areas in some European waters. Because of the fact that their eggs are morphologically similar, genetic methodologies are needed to identify eggs and larvae to species correctly. In the present study, formalin‐ and ethanol‐preserved eggs were tested to estimate the efficacy of genetic methodologies for species identification of eggs when different preservatives are used. A 370‐bp fragment of cytochrome b was successfully amplified followed by restriction fragment analysis with two restriction enzymes aiming to identify the eggs to species. Horse mackerel egg identification was accomplished with the maximum success in ethanol‐preserved eggs. However, it seems that various preservatives had different effects on the DNA quality of eggs as genetic identification was less successful in formalin‐preserved eggs. Preserving in ethanol a part of the eggs obtained in plankton surveys is suggested for purposes of accurate genetic identification, even if their morphological features are distorted in time.  相似文献   
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