Solubilities of nitrogen and noble gases in silicate melts under various oxygen fugacities: implications for the origin and degassing history of nitrogen and noble gases in the earth     

Akiko Miyazaki  Hajime Hiyagon  Kei Hirose 《Geochimica et cosmochimica acta》2004,68(2):387-401

Solubility experiments for nitrogen and noble gases (Ar and Ne) in silicate melts were conducted using two experimental configurations: one was conducted at 1 atmospheric pressure, T =1300°C and oxygen fugacity (fO₂) of IW + 0.9 (i.e., 0.9 log units higher than the iron-wüstite buffer) and the other at high pressures (P_total ∼ 2 × 10⁸ Pa), 1500°C and fO₂ ∼ IW + 6. For the former experiment, isotopically labeled-nitrogen (¹⁵N¹⁵N-enriched) was used to distinguish dissolved nitrogen from contaminating atmospheric or organic nitrogen and to examine dissolution mechanisms of nitrogen in silicate melts. The results obtained for the two series of experiments are consistent with each other, suggesting that Henry's law is satisfied for fN₂ of up to ∼250 atm (2.5 × 10⁷ Pa). The results are also consistent with our earlier results (Miyazaki et al., 1995) obtained at highly oxidizing conditions (fO₂ ∼ IW + 10). All these results support physical dissolution of nitrogen as N₂ molecules in silicate melts for fO₂ from ∼IW + 10 down to ∼IW. The observed solubility (Henry's constant) of nitrogen (3-5 × 10⁻⁹ mol/g/atm) is comparable to that of Ar (2-4 × 10⁻⁹ mol/g/atm), and much lower than that of Ne (11-14 × 10⁻⁹ mol/g/atm) at 1300°C. A preliminary experiment was also performed for partitioning of nitrogen and noble gases between clinopyroxene (cpx) and basaltic melt using a piston cylinder-type apparatus at 1.5 GPa and at 1270 to 1350°C. The obtained cpx/melt partition coefficient of nitrogen is 0.06, slightly lower than those of noble gases (∼0.1 for Ne to Xe), suggesting that nitrogen is as incompatible as or even slightly more incompatible than noble gases. The present results imply that a large nitrogen/Ar fractionation would not be produced by magmatic processes. Therefore, the two orders of magnitude difference between the N₂/³⁶Ar ratios in the Earth's atmosphere (∼10⁴) and that in the mantle (∼10⁶) must be explained by some other processes, such as incomplete segregation of metal blobs into the core and their later oxidation.  相似文献   

Wet deposition of radionuclides derived from the Chernobyl accident     

Katsumi Hirose  Sukeyoshi Takatani  Michio Aoyama 《Journal of Atmospheric Chemistry》1993,17(1):61-71

Chernobyl radioactivity in precipitation was measured at Tsukuba, Japan, as were both surface-air concentrations and particle-size distributions of Chernobyl-released radionuclides. To understand the wet removal processes of the Chernobyl radionuclides, i.e.¹³⁷Cs,¹⁰³Ru, and⁹⁰Sr, wet deposition velocities were calculated. The wet deposition velocities of the Chernobyl radioactivity for individual rainfall events varied largely. The wet deposition velocity is given as the product of washout ratio and rainfall rate. Typically, it was found that the washout ratios of⁹⁰Sr are systematically larger than those of¹³⁷Cs. In order to explain this fact, we examined the relationship between the washout ratios and particle sizes of radionuclide-bearing aerosols. A positive correlation between corrected washout ratios and particle size was found with a particle diameter range from 0.35 to 1.2 µm. The result strongly suggests that the factors controlling the wet removal of the Chernobyl radioactivity for individual rainfall events are surface air concentration, particle size, and rainfall rate, rather than precipitation amount, which is in agreement with previous understandings. This suggests that high contamination areas of radioactivity are formed during heavy rainfall events with high rainfall rates in the case of tropospheric injection such as the Chernobyl accident.  相似文献   

1992 compilation of analytical data for rare-earth elements, scandium, yttrium, zirconium and hafnium in twenty-six GSJ reference samples     

Shiro ITOH  Shigeru TERASHIMA  Noboru IMAI  Hikari KAMIOKA  Naoki MITA  Atsushi ANDO 《Geostandards and Geoanalytical Research》1993,17(1):5-79

Abstract: Analytical data for fourteen rare-earth elements, scandium, yttrium, zirconium and hafnium, received by May 1992, have been compiled on twenty-six GSJ (Geological Survey of Japan) reference samples. Seventeen of them are 'Igneous rock series' and nine are "Sedimentary rock series". The reported data including personal communication were evaluated under the consideration on analytical methods and geochemical evidences. No significant difference has been observed between the values obtained by the different analytical methods. Based on the selected available data, 1992 compilation values were tabulated.  相似文献   

Miocene fossil pinnipeds of the genera Prototaria and Neotherium (Carnivora; Otariidae; Imagotariinae) in the North Pacific Ocean: Evolution, relationships and distribution     

Naoki  Kohno Lawrence G.  Barnes Kiyoharu  Hirota 《Island Arc》1994,3(4):285-308

Abstract Fossil otariid pinnipeds of the extinct genera Prototaria Takeyama and Ozawa, 1984, and Neotherium Kellogg, 1931, known from Middle Miocene deposits bordering the North Pacific Ocean, are small, primitive pinnipeds in the subfamily Imagotariinae. They have a small supraorbital process of the frontal or have lost it entirely, a three-rooted first molar, small paroccipital process, and ear morphology indicating that they belong in the subfamily Imagotariinae. Their unique derived characters include extreme intertemporal constriction and highly modified cheek teeth, the premolars having become molarized by the addition of protocones and lingual cingula. Prototaria Takeyama and Ozawa, 1984, the most primitive known imagotariine genus, contains two species, P. primigena Takeyama and Ozawa, 1984, and P. planicephala Kohno, 1994, both of early Middle Miocene age from Japan. Prototaria has a few derived characters, including a large antorbital process, narrow intertemporal region, and large orbit, but its primitive characters apparently were inherited from enaliarctine ancestors. The long enigmatic Neotherium mirum Kellogg, 1931, of Middle Miocene age from California, USA, is related to Prototaria, but differs by having an elongate skull, very slender zygomatic arch, ventrally exposed median lacerate foramen, and smaller but more molarized premolars. A more primitive new genus and species, Proneotherium repenningi Barnes, related to N. mirum, is from the early Middle Miocene Astoria Formation, coastal Oregon, USA. It shares some derived characters with Prototaria, and shares many other important derived characters with N. mirum. Imagotariines probably arose from some species of Early Miocene enaliarctines, became diverse in Middle and Late Miocene time, and are only known from the North Pacific realm. Although they might include the ancestors of true walruses of the subfamily Odobeninae, no known imagotariines appear to have been adapted for mollusk feeding as are the highly evolved modern walruses. Instead, imagotariines appear to have retained a primitive piscivorous diet, as did the fur seals and sea lions of the subfamily Otariinae.  相似文献   

Oxygen isotopic composition of minerals in the Kenna ureilite     

Robert N. Clayton  Toshiko K. Mayeda  Naoki Onuma  John Shearer   《Geochimica et cosmochimica acta》1976,40(12):1475-1476

The δ¹⁸O and δ¹⁷O values of olivine from Kenna are 7.6 and 3.0%, respectively, relative to SMOW. These values are typical of ureilites which form a unique group on a δ¹⁷O -δ¹⁸O graph. The ureilites are related to, but not directly derived from, the anhydrous phases of C2 and C3 meteorites. The ¹⁸O/¹⁶O fractionation between pyroxene and olivine is 0.60, indicating a temperature of last equilibration of 1000 ± 100°C.  相似文献   

Mechanism of two rapid and long-runout landslides in the 16 April 2016 Kumamoto earthquake using a ring-shear apparatus and computer simulation (LS-RAPID)   总被引：3，自引：3，他引：0  

Khang Dang  Kyoji Sassa  Hiroshi Fukuoka  Naoki Sakai  Yuji Sato  Kaoru Takara  Lam Huu Quang  Doan Huy Loi  Pham Van Tien  Nguyen Duc Ha 《Landslides》2016,13(6):1525-1534

Around hundred landslides were triggered by the Kumamoto earthquakes in April 2016, causing fatalities and serious damage to properties in Minamiaso village, Kumamoto Prefecture, Japan. The landslides included many rapid and long-runout landslides which were responsible for much of the damage. To understand the mechanism of these earthquake-triggered landslides, we carried out field investigations with an unmanned aerial vehicle to obtain DSM and took samples from two major landslides (Takanodai landslide and Aso-ohashi landslide) to measure parameters of the initiation and the motion of landslides. A series of ring-shear tests and computer simulations were conducted using a measured Kumamoto earthquake acceleration record from KNet station KMM005, 10 km west of Aso-ohashi landslide. The research results supported our assumed mechanism of sliding-surface liquefaction for the rapid and long-runout motion of these landslides.  相似文献   

Observations of Flares and Active Regions from Yohkoh, and Magnetodynamic Models Explaining Them     

Y. Uchida  S. Hirose  S. Morita  M. Torii  T. Tanaka  T. Yabiku  T. Miyagoshi  S. Uemura  T. Yamaguchi 《Astrophysics and Space Science》1998,264(1-4):145-169

We discuss here some of the new aspects about solar flares and active regions found by the Solar X-ray Satellite Yohkoh, by taking advantage of the wider dynamic range and higher cadence observations with higher spatial resolution compared with the previous satellites. Those new aspects have lead us to new ways of understandings, with contradictions to the previous views about flares and active regions that are widely conceived for a long time. We give some models that explain those newly revealed observational results. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Vertical Nutrient Distributions in the Western North Pacific Ocean: Simple Model for Estimating Nutrient Upwelling, Export Flux and Consumption Rates     

Katsumi Hirose  Hitomi Kamiya 《Journal of Oceanography》2003,59(2):149-161

A one-dimensional, steady-state model has been developed to understand the factors controlling vertical distributions of nutrients such as nitrate and phosphate in the western North Pacific water columns. The model includes simple physics and some biogeochemical processes. Nutrients are supplied by upwelling of nutrient-rich deep waters with a constant upwelling velocity and nutrient regeneration due to decomposition of sinking particulate matter; the latter is expressed by an exponential-type export flux. Nutrients are consumed in the water column due to uptake by marine organisms, represented by a first-order substrate kinetics. The consumption rate constant is given as an exponential function of depth. The model has been applied to a data set of WOCE (World Ocean Circulation Experiment) P9 one-time measurements observed in the western North Pacific. The calculated curves fit well to observed vertical nutrient profiles from 100 m depth to over 2,500 m depth at 35 stations from 19°N to 33°30′ N along 137°E with correlation factors of greater than 0.998. A modified model, including a correction term representing a depth-dependent upwelling velocity, can reproduce observed vertical nutrient profiles at 32 stations from 5°N to 18°30′ N along 137°E with correlation factors greater than 0.993. The results support the hypothesis that most of the vertical nutrient profiles in the western North Pacific are controlled by particle export flux, consumption rate, remineralization rate and upwelling velocity. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Geographical and seasonal variations in abundance,biomass and estimated production rates of microzooplankton in the Inland Sea of Japan   总被引：3，自引：1，他引：3  

Shin-ichi Uye  Naoki Nagano  Hidenori Tamaki 《Journal of Oceanography》1996,52(6):689-703

We measured abundance and biomass of 3 major groups of microzooplankton, i.e. tintinnids, naked ciliates and copepod nauplii, at 21 stations in the Inland Sea of Japan in October 1993, January, April and June 1994. The average abundance of the microzooplankton over the entire Inland Sea of Japan ranged from 2.39×10⁵ indiv. m^–3 in January to 4.00×10⁵ indiv. m^–3 in April. Ciliated protozoans, i.e. tintinnids plus naked ciliates, numerically dominated the microzooplankton. The average biomass of the microzooplankton was exceedingly high in October (8.62 mg C m^–3) compared to that in the other months (2.06, 2.79 and 2.68 mg C m^–3 in January, April and June, respectively). The ciliated protozoans also dominated in terms of biomass except in October, when copepod nauplii were more important. Estimated production rate of the microzooplankton was highest in October (average: 6.02 mg C m^–3d^–1) and followed in order by June, April and January (1.94, 1.14 and 0.54 mg C m^–3d^–1, respectively). Due to higher specific growth rate, the production rate by the ciliated protozoans far exceeded that by the copepod nauplii. The trophic importance of the microzooplankton in the pelagic ecosystem of the Inland Sea of Japan was assessed by estimating carbon flow through the microzooplankton community.  相似文献   

I-2 Hydraulic model test on a wave energy conversion system with semi-circular air-chambers     

Manabu Hirose  Masanobu Kato 《Ocean Engineering》1985,12(6):556

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