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11.
Loess-palaeosol deposits in the lower Danube area represent the southeastern edge of the loess cover in Europe. Detailed rock magnetic investigations of the loess/palaeosol sequence in Viatovo in NE Bulgaria reveal that magnetite and maghemite of very fine superparamagnetic grain size are responsible for the magnetic enhancement of palaeosol units. A detailed palaeoclimatic record is obtained through high-resolution measurements of magnetic susceptibility, frequency dependent magnetic susceptibility and CaCO3 content. Magnetic proxies indicate a more warm and humid climate during the development of the older palaeosol units (S4–S6).  相似文献   
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13.
 A need for rapid and inexpensive (proxy) methods of outlining areas exposed to increased pollution by atmospheric particulates of industrial origin caused scientists in various fields to use and validate different non-traditional (or non-chemical) techniques. Among them, soil magnetometry seems to be a suitable tool, at least in some cases. This method is based on the knowledge that ferrimagnetic particles, namely magnetite, are produced from pyrite during combustion of fossil fuel. Besides the combustion processes, magnetic particles can also originate from road traffic, for example, or can be included in various waste-water outlets. Magnetite, Fe3O4, ranks among the main ferrimagnetic minerals and its identification in various ecosystems can contribute to fast and simple outlining of areas and sites exposed to higher pollution impact. Here the method of magnetic mapping of anthropogenic pollution will be introduced using a review of our recent case studies on different ecosystems in the Czech Republic and Germany. Received: 20 June 1998 · Accepted: 9 November 1998  相似文献   
14.
The enhanced magnetic susceptibility of modern soils is assumed to have several reasons including, e.g., weathering of an iron-rich geological basement, natural fires, bacterial processes and atmospheric deposition of anthropogenic particles. We report on a case where none of the above sources of magnetic enhancement is evident: a modern soil with high magnetic susceptibility over the whole soil profile, developed on nonmagnetic limestones, in an area with no industrial activities. The surface magnetic susceptibility varies from 60 to 110×10−5 SI, while that of the rock basement is nearly zero. Moreover, significant frequency-dependent magnetic susceptibility (> 12%) suggests that superparamagnetic secondary magnetite/maghemite plays an important role. Possible mechanisms, responsible for this magnetic enhancement, are discussed.  相似文献   
15.
Jordanova  V.K.  Thorne  R.M.  Farrugia  C.J.  Dotan  Y.  Fennell  J.F.  Thomsen  M.F.  Reeves  G.D.  McComas  D.J. 《Solar physics》2001,204(1-2):361-375
We study the development of the terrestrial ring current during the time interval of 13–18 July, 2000, which consisted of two small to moderate geomagnetic storms followed by a great storm with indices Dst=−300 nT and Kp=9. This period of intense geomagnetic activity was caused by three interplanetary coronal mass ejecta (ICME) each driving interplanetary shocks, the last shock being very strong and reaching Earth at ∼ 14 UT on 15 July. We note that (a) the sheath region behind the third shock was characterized by B z fluctuations of ∼35 nT peak-to-peak amplitude, and (b) the ICME contained a negative to positive B z variation extending for about 1 day, with a ∼ 6-hour long negative phase and a minimum B z of about −55 nT. Both of these interplanetary sources caused considerable geomagnetic activity (Kp=8 to 9) despite their disparity as interplanetary triggers. We used our global ring current-atmosphere interaction model with initial and boundary conditions inferred from measurements from the hot plasma instruments on the Polar spacecraft and the geosynchronous Los Alamos satellites, and simulated the time evolution of H+, O+, and He+ ring current ion distributions. We found that the O+ content of the ring current increased after each shock and reached maximum values of ∼ 60% near minimum Dst of the great storm. We calculated the growth rate of electromagnetic ion cyclotron waves considering for the first time wave excitation at frequencies below O+ gyrofrequency. We found that the wave gain of O+ band waves is greater and is located at larger L shells than that of the He+ band waves during this storm interval. Isotropic pitch angle distributions indicating strong plasma wave scattering were observed by the imaging proton sensor (IPS) on Polar at the locations of maximum predicted wave gain, in good agreement with model simulations.  相似文献   
16.
Rock magnetic investigations of archaeological materials of burnt clay from Eneolithic ovens (4500 years BC) showed particular changes with time in the magnetic mineralogy of samples, stored under normal conditions. Our results indicate that well-burnt clay from the archaeological materials contains a significant amount of very fine magnetic grains, which could notably influence the rock magnetic properties and behavior at room temperature. The main observations after 4 years of storage under laboratory conditions are as follows: 1) decrease in the final unblocking temperature of NRM from 600–620°C to 580°C and 2) increase in the capacity of laboratory TRM acquisition. The most probable mechanism responsible for the observed changes is supposed to be fast low-temperature oxidation of the finest (superparamagnetic) grains and the development of the maghemite shell in coarser single-domain grains. The Thellier palaeointensity experiments, carried out at the beginning of the study, showed very good results, which satisfy all acceptance criteria, applied to evaluation of the results, quite well. Palaeointensity determinations repeated 4 years later on samples from the same material showed the experimental results to be of significantly inferior quality. The main difference is the presence of the significant deviation (change in the slope) on the Arai diagram after T>350–400°C. The calculated palaeointensity is either higher than the one obtained before, or similar, but evaluated with large uncertainty. Therefore, we conclude that the possibility to obtain biased palaeointensity values increases during short-time storage (i.e. several years) due to the low-temperature changes of the material.  相似文献   
17.
Former zinc and lead mines that have been operating for half a century are located in the massif of Bou Caid (Tissemsilt, Algeria). Hazardous heavy metals emitted from the mines are abundant in the surrounding soil and cause strong metal pollution in the region. This paper investigates the extent of lead and zinc mine activity derived pollution by characterizing both magnetic and geochemical properties of samples collected in the vicinity of the mines. The results of the magnetic study show the coexistence of magnetic minerals such as magnetite, hematite and goethite. Analyses on surface soils and weathered rocks suggest that hematite and goethite have ore-related lithogenic origins. Magnetic susceptibility shows a positive correlation with lead content when present in low-to-medium concentrations (< ~500 mg/kg). At higher lead concentrations, there is no correlation with magnetic susceptibility. The relationship between magnetic susceptibility and zinc content is not straightforward. These observations are explained by the higher affinity of Pb to iron oxides at lower pollution levels and their preferential bonding to carbonates when Pb and Zn contents are extremely high, as demonstrated by Iavazzo et al. (J Geochem Explor 113:56–67, 2012) in a study of former Zn–Pb mine in Morocco. Based on the general features of the spatial maps of field-measured magnetic susceptibility, mass-specific magnetic susceptibility, Pb and Zn contents, it is concluded that field magnetic measurements provide a good qualitative proxy of pollution spread out of the mining galleries, while laboratory measurements afford a more detailed investigation of the links between iron oxides and the main heavy metals in the ore.  相似文献   
18.
Magnetic signature of different vegetation species in polluted environment   总被引:2,自引:0,他引:2  
Detailed magnetic study on vegetation samples from several strongly polluted and clean sites in Bulgaria is carried out in order to evaluate suitability of different species as passive dust collectors in magnetometry. From each location, available species among lichens, mosses, poplar leaves, dandelion, needles have been sampled. Magnetic susceptibility calculated on mass-specific basis shows wide variability between diamagnetic signal up to 846 × 10−8 m3/kg. Lichens and mosses are found to be the species, showing magnetic signals with the strongest contrast between clean and polluted environment. The main magnetic phase is magnetite-like according to the results from thermomagnetic analysis of susceptibility on magnetic extracts. Scanning electron microscopy (SEM) microphotographs reveal the presence of abundant particulate matter on vegetation surface both with anthropogenic (spherules) and lithogenic origin. Magnetic grain size deduced by the ratio of saturation remanent magnetization (SIRM) and mass-specific magnetic susceptibility (χ) and coercivities (Bc and Bcr) suggest that different species accumulate preferentially small SD-like grains from pollution emissions. Contrasting relationship of the ratio of anhysteretic remanent magnetization (ARM) and χ for polluted vs clean sites deduced by needles and lichens may be related to transformation of the accumulated dust particles within lichens’ tissue. This finding indicates that the exact species used as biological dust collector is of importance when studying spatial grain size distribution of magnetic dust particles. Pilot study on polycyclic aromatic hydrocarbons (PAH) content and its relation to magnetic parameters shows good correspondence between high levels of PAHs and high SIRM values for locations affected by non-ferrous industrial production.  相似文献   
19.
A detailed record of mineral magnetic properties of a loess–palaeosol profile comprising seven loess horizons, six interbedded palaeosols and recent soil at the top in NE Bulgaria is analysed. A strong contrast between the soil and loess susceptibilities as well as other concentration-dependent hysteresis parameters is present, similar to the well-documented magnetic characteristics of the Chinese loess ( Hus & Han 1992 ; Maher & Thompson 1992 ; Heller & Evans 1995 ; Hunt et al. 1995 ). The magnetic enhancement of the palaeosol units is caused by very fine-grained pedogenic magnetite with superparamagnetic behaviour. Thermomagnetic analyses on bulk material suggest magnetite and maghemite as the main ferrimagnetic carriers in both soil and loess horizons. Their relative proportions are shown to reflect different palaeoclimatic conditions. Chernozem soils, which include recent soil S0 and first and second palaeosols S1 and S2 developed under steppe vegetation, show a high degree of low-temperature oxidation of the pedogenic magnetite to maghemite. This material is characterized by coercive force H c showing even higher values than those of the parent loess material. The older palaeosols (S4 to S6 ) were formed during more humid climatic conditions and therefore probably developed as forest types. Rock magnetic data suggest the existence here of only partly oxidized magnetite grains. The behaviour of the thermomagnetic curves, characterized by a kink at 200 °C, may be due to either a release of internal stress (built up as a result of partial low-temperature oxidation) or interactions between two phases.  相似文献   
20.
Archaeomagnetic dates derived from geomagnetic field direction records in baked materials are proposed for a mediaeval brick kiln (from inclination I and declination D) and for bricks from a brick wall (from I only) in northern Belgium. They are used to verify whether a brick chronology based on the format of bricks is feasible in Flanders. The brick kiln yielded a highly reliable average magnetization direction corresponding to an archaeomagnetic date around A.D. 1650, using the British and French geomagnetic field secular variation curves as a reference, at least half a century younger than expected from historical data. The fidelity of the geomagnetic records was controlled by measuring the magnetic anisotropy of the bricks. Anisotropy of magnetic susceptibility (AMS) measurements demonstrate that the bricks have a shape related magnetic fabric, which is induced during the molding process. A test to control whether AMS can substitute for the anisotropy of thermo‐remanent magnetization (ATRM) failed because of induced changes during laboratory heating. © 2003 Wiley Periodicals, Inc.  相似文献   
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