Matrix methods in synthetic seismograms     

R. C. Y. Chin  G. W. Hedstrom  L. Thigpen 《Geophysical Journal International》1984,77(2):483-502

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The Geochemistry of Lake Joyce, McMurdo Dry Valleys, Antarctica     

Joseph A. Shacat  William J. Green  Eric H. Decarlo  Silvia Newell 《Aquatic Geochemistry》2004,10(3-4):325-352

Lake Joyce is one of the least studied lakes of the McMurdo Dry Valleys. Similar to other lakes in this region, Lake Joyce is a closed-basin, permanently ice-covered, meromictic lake. We present here a detailed investigation of major ions, nutrients, and dissolved trace elements for Lake Joyce. Specifically, we investigate the role of iron and manganese oxides and hydrous oxides in trace metal cycling.Lake Joyce is characterized by fresh, oxic waters overlying an anoxic brine, primarily Na–Cl. Surface waters have a maximum nitrate concentration of 26M with a molar dissolved inorganic nitrogen to phosphorus ratio of 477. The supply of nitrogen is attributed to atmospheric deposition, possibly from polar stratospheric clouds. Dissolved phosphorus is scavenged by hydrous iron oxides. The pH is highest (10.15) just beneath the 7-m thick ice cover and decreases to a minimum of 7.29 in the redox transition zone. Dissolved Al exceeds 8M in surface waters, and appears to be controlled by equilibrium with gibbsite. In contrast, concentrations of other trace elements in surface waters are quite low (e.g., 5.4nM Cu, 0.19nM Co, <20pM La). Dissolved Fe, Mn, Ni and Cd were below our detection limits of 13 nM, 1. 8 nM, 4.7 nM and 15pM (respectively) in surface waters. There was a 6-m vertical separation in the onset of Mn and Fe reduction, with dissolved Mn appearing higher in the water column than Fe. Based on thermodynamic calculations, dissolved Mn appears to be controlled by equilibrium with hausmannite (Mn3O4). Co tracks the Mn profile closely, suggesting Co(III) is bound in the lattice of Mn oxides, whereas the Ce profile is similar, yet the Ce anomaly suggests oxidative scavenging of Ce. Release of Cu, Ni, Cd and trivalent REE appears to be controlled by pH-induced desorption from Fe and Mn oxides, although Cu (and perhaps Ni) may be scavenged by organic matter in surface waters.  相似文献   

Nickel, Copper, Zinc and Cadmium Cycling with Manganese in Lake Vanda (Wright Valley, Antarctica)     

William J. Green  Brian R. Stage  Bonnie Jo Bratina  Shannon Wagers  Adam Preston  Kevin O’bryan  Joseph Shacat  Silvia Newell 《Aquatic Geochemistry》2004,10(3-4):303-323

Lake Vanda is a closed-basin, permanently ice-covered lake located in the Wright Valley of Antarctica. The lakes more important geochemical features include the fact that it is fed by a single glacial melt water stream for only 6–8weeks out of the year; that it has remained stratified for more than a millennium; and that, like other lakes in the region, it is remote from anthropogenic influence. These, together with the fact that it is among the least biologically productive lakes in the world, make it an ideal system for examining the transport, cycling and fate of trace metals in the aquatic environment. Like others before us, we view this lake as a natural geochemical laboratory, a flask in the desert. This paper presents the first set of closely spaced, vertical, profiles for dissolved and particulate Mn, Fe, Ni, Cu, Zn and Cd in the water column. Despite the absence of an outflow, metals in the fresh upper waters of the lake have extremely low concentrations, in the pico-molar to nano-molar range, and are partitioned largely into dissolved rather than particulate phases. Efficient metal scavenging by particles from these oxygen-rich waters is indicated. Significant increases in metal concentrations begin to appear at depth, between 57 and 60m, and these increases coincide with the onset of manganese oxide dissolution in oxic, but lower pH waters. Vertical profiles suggest that the entire suite of trace metals (Ni, Cu, Zn, and Cd) is being released from manganese oxide carrier phases. Thermodynamic analysis indicates that Mn3O4 (i.e., the mineral hausmannite) may be important in metal sequestration and recycling in the deeper waters of Lake Vanda. Manganese-reducing organisms reported by Bratina etal. (1998) are active in the zone of metal release and these could also contribute to the observed cycling.  相似文献   

Dayside isotropic precipitation of energetic protons     

Sergeev  V. A.  Bikkuzina  G. R.  Newell  P. T. 《Annales Geophysicae》1997,15(10):1233-1245

Recently it has been shown that isotropic precipitation of energetic protons on the nightside is caused by a non-adiabatic effect, namely pitch-angle scattering of protons in curved magnetic field lines of the tail current sheet. Here we address the origin of isotropic proton precipitation on the dayside. Computations of proton scattering regions in the magnetopheric models T87, T89 and T95 reveal two regions which contribute to the isotropic precipitation. The first is the region of weak magnetic field in the outer cusp which provides the 1–2° wide isotropic precipitation on closed field lines in a 2–3 hour wide MLT sector centered on noon. A second zone is formed by the scattering on the closed field lines which cross the nightside equatorial region near the magnetopause which provides isotropic precipitation starting 1.5–2 h MLT from noon and which joins smoothly the precipitation coming from the tail current sheet. We also analyzed the isotropic proton precipitation using observations of NOAA low altitude polar spacecraft. We find that isotropic precipitation of >30 to > 80 keV protons continues around noon forming the continuous oval-shaped region of isotropic precipitation. Part of this region lies on open field lines in the region of cusp-like or mantle precipitation, its equatorward part is observed on closed field lines. Near noon it extends 1–2° below the sharp boundary of solar electron fluxes (proxy of the open/closed field line boundary) and equatorward of the cusp-like auroral precipitation. The observed energy dispersion of its equatorward boundary (isotropic boundary) agrees with model predictions of expected particle scattering in the regions of weak and highly curved magnetic field. We also found some disagreement with model computations. We did not observe the predicted split of the isotropic precipitation region into separate nightside and dayside isotropic zones. Also, the oval-like shape of the isotropic boundary has a symmetry line in 10–12 MLT sector, which with increasing activity rotates toward dawn while the latitude of isotropic boundary is decreasing. Our conclusion is that for both dayside and nightside the isotropic boundary location is basically controlled by the magnetospheric magnetic field, and therefore the isotropic boundaries can be used as a tool to probe the magnetospheric configuration in different external conditions and at different activity levels.  相似文献   

Analysis of the relationship between sediment composition and benthic community structure in coastal deposits: Implications for marine aggregate dredging   总被引：6，自引：1，他引：5  

Seiderer  L. J.; Newell  R. C. 《ICES Journal of Marine Science》1999,56(5):757-765

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The New Potential for Understanding Groundwater Contaminant Transport     

Paul W. Hadley  Charles Newell 《Ground water》2014,52(2):174-186

The groundwater remediation field has been changing constantly since it first emerged in the 1970s. The remediation field has evolved from a dissolved‐phase centric conceptual model to a DNAPL‐dominated one, which is now being questioned due to a renewed appreciation of matrix diffusion effects on remediation. Detailed observations about contaminant transport have emerged from the remediation field, and challenge the validity of one of the mainstays of the groundwater solute transport modeling world: the concept of mechanical dispersion (Payne et al. 2008). We review and discuss how a new conceptual model of contaminant transport based on diffusion (the usurper) may topple the well‐established position of mechanical dispersion (the status quo) that is commonly used in almost every groundwater contaminant transport model, and evaluate the status of existing models and modeling studies that were conducted using advection‐dispersion models.  相似文献   

On‐Site Vapor‐Phase Analysis as a Novel Approach for Monitoring Groundwater Wells     

David T. Adamson  Thomas E. McHugh  Michal W. Rysz  Roberto Landazuri  Mir Ahmad Seyedabbasi  Patrick E. Haas  Charles J. Newell 《Ground Water Monitoring & Remediation》2014,34(2):42-59

The results of comprehensive field testing of on‐site vapor‐phase‐based groundwater monitoring methods are presented to demonstrate their utility as a robust and cost‐effective approach for rapidly obtaining volatile organic compounds (VOCs) concentration data from a monitoring well. These methods—which rely on sensitive, commercially available field equipment to analyze vapor in equilibrium with groundwater—proved easy to implement and can be tailored to site‐specific needs, including multilevel sampling. During field testing, low‐flow groundwater concentrations could be reasonably estimated using submerged passive vapor diffusion samplers or field equilibration of collected groundwater (R² = 0.85 to 0.96). These two methods are not as reliant on in‐well mixing to overcome vertical stratification within wells as simpler headspace methods. The importance of well and aquifer‐specific factors on concentration data (and therefore method selection) is highlighted, including the effect of changing in‐well patterns due to seasonal temperature gradients. Results indicated that vertical stratification was relatively limited within the set of wells included in these studies, resulting in similar performance for short depth‐discrete passive vapor diffusion samplers (constructed from 40‐mL vials) and longer samplers (2.5 to 5 feet in length) designed to cover a larger portion of the screened interval. A year‐long, multi‐event evaluation demonstrated that vapor‐phase‐based monitoring methods are no more variable than conventional groundwater monitoring methods, with both types subject to similar spatial and temporal variability that can be difficult to reduce. Vapor sampling methods represent a promising approach for estimation of groundwater concentrations by reducing the cost liabilities associated with monitoring while providing a more sustainable approach.  相似文献   

Modeling the Effects of Oyster Reefs and Breakwaters on Seagrass Growth     

Katharine A. Smith  Elizabeth W. North  Fengyan Shi  Shih-Nan Chen  Raleigh R. Hood  Evamaria W. Koch  Roger I. E. Newell 《Estuaries and Coasts》2009,32(4):748-757

Seagrass beds have declined in Chesapeake Bay, USA as well as worldwide over the past century. Increased seston concentrations, which decrease light penetration, are likely one of the main causes of the decline in Chesapeake Bay. It has been hypothesized that dense populations of suspension-feeding bivalves, such as eastern oysters (Crassostrea virginica), may filter sufficient seston from the water to reduce light attenuation and enhance seagrass growth. Furthermore, eastern oyster populations can form large three-dimensional reef-like structures that may act like breakwaters by attenuating waves, thus decreasing sediment resuspension. We developed a quasi-three-dimensional Seagrass-Waves-Oysters-Light-Seston (SWOLS) model to investigate whether oyster reefs and breakwaters could improve seagrass growth by reducing seston concentrations. Seagrass growth potential (SGP), a parameter controlled by resuspension-induced turbidity, was calculated in simulations in which wave height, oyster abundance, and reef/breakwater configuration were varied. Wave height was the dominant factor influencing SGP, with higher waves increasing sediment resuspension and decreasing SGP. Submerged breakwaters parallel with the shoreline improved SGP in the presence of 0.2 and 0.4 m waves when sediment resuspension was dominated by wave action, while submerged groins perpendicular to the shoreline improved SGP under lower wave heights (0.05 and 0.1 m) when resuspension was dominated by along-shore tidal currents. Oyster-feeding activity did not affect SGP, due to the oysters’ distance from the seagrass bed and reduced oyster filtration rates under either low or high sediment concentrations. Although the current implementation of the SWOLS model has simplified geometry, the model does demonstrate that the interaction between oyster filtration and along-shore circulation, and between man-made structures and wave heights, should be considered when managing seagrass habitats, planning seagrass restoration projects, and choosing the most suitable methods to protect shorelines from erosion.  相似文献   

Biocalcification in the Eastern Oyster (<Emphasis Type="Italic">Crassostrea virginica)</Emphasis> in Relation to Long-term Trends in Chesapeake Bay pH     

George G. Waldbusser  Erin P. Voigt  Heather Bergschneider  Mark A. Green  Roger I. E. Newell 《Estuaries and Coasts》2011,34(2):221-231

Anthropogenic carbon dioxide (CO₂) emissions reduce pH of marine waters due to the absorption of atmospheric CO₂ and formation of carbonic acid. Estuarine waters are more susceptible to acidification because they are subject to multiple acid sources and are less buffered than marine waters. Consequently, estuarine shell forming species may experience acidification sooner than marine species although the tolerance of estuarine calcifiers to pH changes is poorly understood. We analyzed 23 years of Chesapeake Bay water quality monitoring data and found that daytime average pH significantly decreased across polyhaline waters although pH has not significantly changed across mesohaline waters. In some tributaries that once supported large oyster populations, pH is increasing. Current average conditions within some tributaries however correspond to values that we found in laboratory studies to reduce oyster biocalcification rates or resulted in net shell dissolution. Calcification rates of juvenile eastern oysters, Crassostrea virginica, were measured in laboratory studies in a three-way factorial design with 3 pH levels, two salinities, and two temperatures. Biocalcification declined significantly with a reduction of ∼0.5 pH units and higher temperature and salinity mitigated the decrease in biocalcification.  相似文献   

A Hydrogeologic Database for Ground-Water Modeling     

Charles J. Newell  Loren P. Hopkins  Philip B. Bedient 《Ground water》1990,28(5):703-714

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